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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Peng J. L., Bulcock S., Belobrov P. I., Bursill L. A.
Заглавие : Surface bonding states of nano-crystalline diamond balls
Место публикации : Int. J. Mod. Phys. B: WORLD SCIENTIFIC PUBL CO PTE LTD, 2001. - Vol. 15, Is. 31. - P4071-4085. - ISSN 0217-9792, DOI 10.1142/S0217979201007865
Примечания : Cited References: 20
Предметные рубрики: PLASMON RESPONSE
POWDER
SPECTROSCOPY
MICROSCOPY
SILICON
SI(111)
Ключевые слова (''Своб.индексиров.''): diamond--article--crystal structure--electron--energy transfer--nanoparticle--particulate matter--structure analysis--surface property--transmission electron microscopy
Аннотация: The rough surface of nano-crystalline diamond spheres induces surface electronic states which appear as a broadened pre-peak over approx. 15 eV at the C K-edge energy threshold for carbon in the parallel electron energy loss spectrum (PEELS). This appears to be at least partially due to 1s-pi* transitions, although typically the latter occupy a range of only 4 eV for the sp(2) edge of highly-oriented pyrollytic graphite (HOPG). No pi* electrons appear in the conduction band inside the diamond particles, where all electrons are sp(3) hybridized. PEELS data were also obtained from a chemical vapour deposited diamond film (CVDF) and gem-quality diamond for comparison with the spectra of nano-diamonds. The density of sp(2) and sp(3) states on the surface of diamond nano-crystals is calculated for simple structural models of the diamond balls, including some conjecture about surface structures. The results are used to interpret the sp(2)/sp(3) ratios measured from the PEELS spectra recorded as scans across the particles. Surface roughness at the atomic scale was also examined using high-resolution transmission electron microscopy (HRTEM) and electron nano-diffraction patterns were used to confirm the crystal structures.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavriliuk A. G., Trojan I. A., Lyubutin I. S., Ovchinnikov S. G., Sarkissian V. A.
Заглавие : High-pressure magnetic properties and P-T phase diagram of iron borate
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 2005. - Vol. 100, Is. 4. - P688-696. - ISSN 1063-7761, DOI 10.1134/1.1926429
Примечания : Cited References: 24
Предметные рубрики: FEBO3 SINGLE-CRYSTALS
NUCLEAR-RESONANCE
BAND-STRUCTURE
TRANSITION
TEMPERATURE
SCATTERING
Ключевые слова (''Своб.индексиров.''): antiferromagnetic materials--diamonds--ferromagnetic materials--high pressure effects--low temperature effects--magnetic moments--magnetic properties--magnetization--phase diagrams--powders--single crystals--synchrotron radiation--diamond anvil cells--electronic transition--iron borate--nuclear forward scattering (nfs)--iron compounds
Аннотация: The high-pressure magnetic states of iron borate (FeBO3)-Fe-57 single-crystal and powder samples have been investigated in diamond anvil cells by nuclear forward scattering (NFS) of synchrotron radiation at different temperatures. In the low-pressure (0 < P < 46 GPa) antiferromagnetic phase, an increase of the Neel temperature from 350 to 595 K induced by pressure was found. At pressures 46-49 GPa, a transition from the antiferromagnetic to a new magnetic state with a weak magnetic moment (magnetic collapse) was discovered. It is attributed to the electronic transition in Fe3+ ions from the high-spin 3d(5) (S = 5/2, (6)A(1g)) to the low-spin (S = 1/2, T-2(2g)) state (spin crossover) due to the insulator-semiconductor-type transition with extensive suppression of strong d-d electron correlations. At low temperatures, NFS spectra of the high-pressure phase indicate magnetic correlations in the low-spin system with a magnetic ordering temperature of about 50 K. A tentative magnetic P-T phase diagram of FeBO3 is proposed. An important feature of this diagram is the presence of two triple points where magnetic and paramagnetic phases of the high-spin and low-spin states coexist. © 2005 Pleiades Publishing, Inc.
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Вид документа : Однотомное издание
Шифр издания :
Автор(ы) : Isakova V. G., Petrakovskaya E. A., Isakov V. P., Bayukov O. A., Velikanov D. A.
Заглавие : The research of powder fullerene and ultra-despersed diamond composites with metal and oxide nanoparicles
Место публикации : The Physics of Metals and Metallography. - 2006. - Vol. 102, Suppl.1. - С. S57-S60. - DOI 10.1134/S0031918X06140146
Примечания : Библиогр.: 7
Аннотация: Magnetic properties of new nanophase materials based on oxide and metal particles of dtransition metals included in the powder fullerite C60 and detonative ultradispersed diamonds (UDD) are investigated. The materials are obtained by an original method of catalytic combustion reaction.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korets A. Y., Krylov A. S., Mironov E. V.
Заглавие : Molecular structural nonuniformity of ultradispersed diamond-containing material and the reasons why it arises
Место публикации : Russ. J. Phys. Chem. B: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 1, Is. 5. - P485-492. - ISSN 1990-7931, DOI 10.1134/S1990793107050077
Примечания : Cited References: 25. - В описании WOS - Vol. 2 (ошибочно), Is. 5. - P 485-492
Предметные рубрики: DETONATION
Аннотация: An analysis of IR spectra, Raman spectra, and X-ray diffraction intensity curves for diamond-containing materials obtained by the detonation method under different conditions and purified by different methods was used to examine the structural nonuniformity of diamond-containing particles and the reasons why it arises.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ding Y., Haskel D., Ovchinnikov S. G., Tseng Y. C., Orlov Y. S., Lang J. C., Mao H. K.
Заглавие : Novel pressure-induced magnetic transition in magnetite (Fe(3)O(4))
Разночтения заглавия :авие SCOPUS: Novel pressure-induced magnetic transition in magnetite (Fe3O4)
Место публикации : Phys. Rev. Lett.: AMER PHYSICAL SOC, 2008. - Vol. 100, Is. 4. - Ст.45508. - ISSN 0031-9007, DOI 10.1103/PhysRevLett.100.045508
Примечания : Cited References: 39
Предметные рубрики: MULTIPLE-SCATTERING THEORY
X-RAY DICHROISM
LOWER MANTLE
VERWEY TRANSITION
K-EDGE
CIRCULAR-DICHROISM
SPIN TRANSITION
BAND-STRUCTURE
IRON
FE
Ключевые слова (''Своб.индексиров.''): emission spectroscopy--magnetoelectronics--pressure effects--synchrotron radiation--diamond anvil cell--magnetic transition--x-ray magnetic circular dichroism--magnetite
Аннотация: Fe K-edge x-ray magnetic circular dichroism of magnetite (Fe(3)O(4)) powders was measured with synchrotron radiation under variable pressure and temperature conditions in diamond anvil cell. The magnetic dichroism was observed to decrease discontinuously by similar to 50% between 12 and 16 GPa, independent of temperature. The magnetic transition is attributed to a high-spin to intermediate-spin transition of Fe(2+) ions in the octahedral sites and could account for previously observed structural and electrical anomalies in magnetite at this pressure range. The interpretation of x-ray magnetic circular dichroism data is supported by x-ray emission spectroscopy and theoretical cluster calculations.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisov I.A., Belobrov P. I., Tsegelnik S.S., Shaikhutdinov K. A., Znak D.A., Balaev D. A., Bayukov O. A., Korchagina S.B., Petrakovskaya E. A., Velikanov D. A., Volkov N. V., Gordeev S.K.
Заглавие : Magnetization of diamond-graphene flakes composites
Коллективы : Trends in NanoTechnology
Место публикации : Trends in NanoTechnology (TNT 2009). - 2009
Примечания : This research was supported by RFBR Grants 07-04-01340-а and 08-02-00259-a, ME&S of RF Grant No. 2.2.2.2/5309 and U.S. CRDF Grant RUX0-002-KR-06/BP4M02.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korets A. Y., Krylov A. S., Mironov E. V.
Заглавие : Structural Nonuniformity of Detonation-Produced Diamond-Containing Material
Место публикации : Russ. J. Phys. Chem. B: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 4, Is. 5. - P793-796. - ISSN 1990-7931, DOI 10.1134/S1990793110050155
Примечания : Cited References: 10
Ключевые слова (''Своб.индексиров.''): diamond-like material--structural nonuniformity--raman scattering spectroscopy
Аннотация: Raman backscattering spectra (RBS), infrared spectra, and X-ray diffraction intensity curves for various fractions of ultradispersed diamond-containing material (UDDCM) were recorded. The RBS and XRD curves obtained suggest that UDDCM is characterized by sharp variations in the ratio between the diamond and nondiamond components, a factor that makes it possible to consider this phase as an individual product and determines the scale of variations in the main characteristics. Fine UDDCM fractions contain only small amounts diamond-like (sp(3) carbon) grains, if any. One possible reason for changes in the ratio between the phases is density fluctuations under nonequilibrium conditions of synthesis.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Korets A.Ya., Krylov A.S., Mironov E.V.
Заглавие : Structural heterogeneity detonation diamond containing mate rial
Коллективы : International Shock Interaction Symposium
Место публикации : 19th International Shock Interaction Symposium/ International Shock Interaction Symposium (19 ; 2010 ; Moscow, Russia). - 2010. - С. 19
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Korets A.Ya., Krylov A.S., Mironov E.V.
Заглавие : Structural heterogeneity detonation diamond-containing mate rial
Коллективы : Chaotic modeling and Simulation International Conference
Место публикации : 3rd Chaotic modeling and Simulation International Conference: CHAOS 2010. - 2010. - С. 34
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Korets A.Ya., Krylov A. S., Mironov E. V.
Заглавие : Structural Inhomogeneity of Detonation Diamond Containing Materials
Коллективы : International Conference on Equations of State for Matter, Physics of Ex treme States of Matter
Место публикации : Physics of extreme states of matter - 2010/ International Conference on Equations of State for Matter, Physics of Ex treme States of Matter (25 ; 2010 ; MAR ; 1-6 ; Elbrus, Russia). - 2010. - С. 33-34. - ISBN 978-5-901675-96-0
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korets A., Krylov A. S., Mironov E.
Заглавие : Structural heterogeneity of diamond-containing detonation material
Место публикации : Eur. Phys. J. - Appl. Phys. - 2010. - Vol. 52, Is. 1. - P.10901-10905. - ISSN 1286-0042, DOI 10.1051/epjap/2010126
Примечания : Cited References: 17
Предметные рубрики: NANODIAMONDS
Ключевые слова (''Своб.индексиров.''): influence of density--raman and infrared spectra--structural heterogeneity--variable ratio--detonation--diamonds--diffraction--holographic interferometry--spectroscopy--x ray diffraction--synthetic diamonds
Аннотация: Diamond-containing material (DCM) synthesized by detonation was separated into fractions. Raman and infrared spectra and X-ray diffraction patterns of the individual fractions were measured. The particles of this material were characterized by the variable ratio of the diamond (sp(3)) and non-diamond components. The distribution of sp(3)-grains in the particles was of complicated character. The fine DCM particles contained an insignificant amount of diamond. The influence of density fluctuations on the DCM formation is discussed.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chernozatonskii L.A., Sorokin P.B., Kuzubov A.A., Kvashnin A.G., Kvashnin D.G., Avramov P.V., Yakobson B.I., Sorokin B.P.
Заглавие : Influence of Size Effect on the Electronic and Elastic Properties of Diamond Films with Nanometer Thickness
Место публикации : J. Phys. Chem. C. - 2011. - Vol. 115, Is. 1. - P.132-136. - JAN 13. - ISSN 1932-7447, DOI 10.1021/jp1080687
Примечания : Cited Reference Count: 37. - Гранты: L.A.C. was supported by the Russian Academy of Sciences, program No. 21 and by the Russian Foundation for Basic Research (project no. 08-02-01096). P.B.S. and B.I.Y. acknowledge support by the Office of Naval Research (MURI project). P.V.A. and P.B.S. also acknowledge the collaborative RFBR-JSPS grant no. 09-02-92107-R Phi. We are grateful to the Joint Supercomputer Center of the Russian Academy of Sciences for the possibility of using a cluster computer for quantum chemical calculations. The geometry of all presented structures was visualized by commercial Chem-Craft software.Финансирующая организация: Russian Academy of Sciences [21]; Russian Foundation for Basic Research [08-02-01096]; Office of Naval Research (MURI); RFBR-JSPS [09-02-92107-RPhi]
Предметные рубрики: REVERSIBLE HYDROGENATION
GRAPHENE
GRAPHANE
Atomic structure
Band gaps
Diamond nanocrystals
Elastic properties
Electronic band structure calculation
Energy stability
Experimental data
Hydrogen atoms
Nanometer thickness
Size effects
Theoretical result
Diamond films
Elasticity
Carbon films
Ключевые слова (''Своб.индексиров.''): atomic structure--band gaps--diamond nanocrystals--elastic properties--electronic band structure calculation--energy stability--experimental data--hydrogen atoms--nanometer thickness--size effects--theoretical result--diamond films--elasticity--carbon films
Аннотация: The atomic structure and physical properties of few-layered 111 oriented diamond nanocrystals (diamanes), covered by hydrogen atoms from both sides, are studied using electronic band structure calculations. It was shown that energy stability linearly increases upon increasing of the thickness of proposed structures. All 2D carbon films display direct dielectric band gaps with nonlinear quantum confinement response upon the thickness. Elastic properties of diamanes reveal complex dependence upon increasing of the number of 111 layers. All theoretical results were compared with available experimental data.The atomic structure and physical properties of few-layered 〈111〉 oriented diamond nanocrystals (diamanes), covered by hydrogen atoms from both sides, are studied using electronic band structure calculations. It was shown that energy stability linearly increases upon increasing of the thickness of proposed structures. All 2D carbon films display direct dielectric band gaps with nonlinear quantum confinement response upon the thickness. Elastic properties of diamanes reveal complex dependence upon increasing of the number of 〈111〉 layers. All theoretical results were compared with available experimental data. © 2010 American Chemical Society.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korets A., Krylov A. S., Mironov E., Rabchevskii E.
Заглавие : Experimental study of the structure of milled diamond-containing particles obtained by the detonation method
Место публикации : EPJ Appl. Phys. - 2012. - Vol. 57, Is. 3. - Ст.30701. - ISSN 1286-0042, DOI 10.1051/epjap/2012110208
Примечания : Cited References: 15
Предметные рубрики: PURIFICATION
NANODIAMOND
Ключевые слова (''Своб.индексиров.''): chemical change--diamond grains--experimental spectra--experimental studies--ir spectrum--mechanical force--detonation--diamonds--x ray diffraction--agglomeration
Аннотация: A diamond-containing material (DCM) produced by detonation was mechanically milled using KM-1 and AGO-2S mills. Experimental spectra for infrared (IR) absorption, Raman scattering and X-ray diffraction patterns (XRD) were obtained for the treated DCM samples. We compared the Raman and IR spectra for the KM-1 milled samples and concluded that the surface of the DCM particles was not uniform. The mechanical force that resulted from milling with the AGO-2S destroyed the non-diamond part of the particles and initiated irreversible physical and chemical changes in them. The destruction of the diamond grains was the consequence of these irreversible changes. It follows from the experiments that the dipole momentum of the DCM particle was caused by the presence of polar fragments of molecules. The constant dipole momentum of the particles facilitated the aggregation. Based on this, we proposed a model of a structurally inhomogeneous DCM particle. В© 2012 EDP Sciences.
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rashchenko S. V., Likhacheva A. Y., Krylov A. S., Mikhno A. O.
Заглавие : Diamond anvil cell in high-pressure petrology: studying the metamorphic reactions in situ
Коллективы : International Eclogite Conference (10; 2013 ; Sept. ; 2-10; Courmayeur, Italy)
Место публикации : Int. Ecologite Conf.: Abstract Vol. - 2013. - P.104
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Корец, Анатолий Яковлевич, Королькова И. В., Крылов, Александр Сергеевич, Миронов Е. В., Рабчевский Е. В.
Заглавие : Исследование влияния длительной термообработки на детонационный алмазосодержащий материал
Место публикации : Изв. Кабардино-балкарского гос. ун-та. - 2014. - Т. 4, Вып. 3. - С. 74-78
Ключевые слова (''Своб.индексиров.''): детонационный синтез материалов--структурная неоднородность--детонационный алмазосодержащий материал
Аннотация: С целью исследования изменений, происходящих в структуре частиц, полученных в высокоэнергетических условиях взрыва, была произведена термообработка образцов детонационного алмазосодержащего материала в интервале так называемого «кислородного окна» 430 °С. Продолжительность термообработки изменялась от 0,5 часа до 48 часов. Были проведены эксперименты и проанализированы результаты ИК-поглощения, комбинационного рассеяния света, рентгеновской дифракции и динамического рассеяния света термообработанных образцов.Thermal treatment of detonation diamond-containing material in the interval of so-called «oxygen window» 430 C to investigate changes in the structure of the particles obtained under explosion conditions was performed. The duration of the thermal treatment varied from 0.5 to 48 hours. Infrared and Raman experiments and data of X-Ray diffraction and dynamic light scattering of the treatment samples were carried out.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva, Yu. V., Palyanov, Yu. N., Sokol A. G., Borzdov, Yu. M., Bayukov O. A.
Заглавие : The role of rocks saturated with metallic iron in the formation of ferric carbonate-silicate melts: experimental modeling under PT-conditions of lithospheric mantle
Коллективы : Siberian Branch of the Russian Academy of Sciences [31], Russian Foundation for Basic Research [12-05-00740]
Место публикации : Russ. Geol. Geophys.: Elsevier Science, 2015. - Vol. 56, Is. 1-2. - P.143-154. - ISSN 1068, DOI 10.1016/j.rgg.2015.01.008. - ISSN 1878030X(eISSN)
Примечания : Cited References:68. - This work was supported by Integration project 31 from the Siberian Branch of the Russian Academy of Sciences and by grant 12-05-00740 from the Russian Foundation for Basic Research.
Предметные рубрики: OXYGEN FUGACITY
DIAMOND FORMATION
OXIDATION-STATE
EARTHS MANTLE
Ключевые слова (''Своб.индексиров.''): carbonate-silicate melt--graphite--co2 fluid--iron carbide--garnet--redox gradient--high-pressure experiment
Аннотация: Experimental modeling of the processes of formation of ferric carbonate-silicate melts through the carbonate-oxide-metal interaction is performed in the (Mg,Ca)CO3-SiO2-Al2O3-Fe0 system at 6.3 and 7.5 GPa and within 1150-1650 °C, using a multianvil high-pressure apparatus of “split-sphere” type (BARS). Two parallel reactions run in the subsolidus region (1150-1450 °C): decarbonation, producing pyrope-almandine (Fe# = 0.40-0.75) and CO2 fluid, and redox interaction between carbonate and Fe0, resulting in the crystallization of iron carbide in assemblage with magnesiowustite (Fe# = 0.75-0.85). It is shown that the reduction of carbonate or CO2 fluid by iron carbide and parallel redox interaction of magnesiowustite with CO2 produce graphite in assemblage with Fe3 + -containing magnesiowustite. In the temperature range of 1450-1650 °C, generation of carbonate-silicate melts coexisting with pyrope-almandine, magnesiowustite, magnetite, ferrospinel, and graphite takes place. The composition of the produced melts is as follows: SiO2 - 10-15 wt.%, X(FeO + Fe2O3) = 36-43 wt.%, and Fe3+/XFe - 0.18-0.23. These Fe3 + -enriched carbonate-silicate melts/fluids are saturated with carbon and are the medium of graphite crystallization. Oxide and silicate phases (almandine, ferrospinel, and magnetite) coexisting with graphite are also characterized by high Fe3+/XFe values. It has been established that Fe3 + -enriched carbonate-silicate melts can result from the interaction of Fe0-containing rocks with carbonated rocks. In the reduced mantle (with the presence of iron carbides or oxides), melts of this composition can be the source of carbon and the medium of graphite crystallization at once. After separation and ascent, these ferric carbonate-silicate melts can favor oxidizing metasomatism in the lithospheric mantle.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva, Yu. V., Palyanov, Yu. N., Borzdov, Yu. M., Bayukov O. A., Sobolev N. V.
Заглавие : Interaction of iron carbide and sulfur under P–T conditions of the lithospheric mantle
Коллективы : Russian Foundation for Basic Research [14-05-31061], Council for Grants and Support of the Leading Scientific Schools of the President of the Russian Federation [NSh 2024.2014.5]
Место публикации : Dokl. Earth Sci.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 463, Is. 1. - P.707-711. - ISSN 1028-334X, DOI 10.1134/S1028334X15070077
Примечания : This study was supported by the Russian Foundation for Basic Research (project no. 14-05-31061) and by the Council for Grants and Support of the Leading Scientific Schools of the President of the Russian Federation (NSh 2024.2014.5).
Предметные рубрики: MINERAL INCLUSIONS
DIAMOND
CARBON
EVOLUTION
CORES
Аннотация: Experimental studies were performed in the Fe3C–S system at P = 6.3 GPa, T = 900–1600°C, and t = 18–20 h. The study aimed to characterize the conditions of iron carbide stability in a reduced lithospheric mantle and to reveal the possibility of the formation of elemental carbon by the interaction of iron carbide and sulfur. It was found that the reaction at T 1200°C proceeds with the formation of a pyrrhotite–graphite assemblage by the following scheme: 2Fe3C + 3S2 → 6FeS + 2C0. The crystallization of graphite at T 1200°C is accompanied by the generation of sulfide and metal–sulfide melts and via 2Fe3C + 3S2 → 6[Fe–S(melt) + Fe–S–C(melt)] + 2C(graphite)0 reaction. Resulting from the carbon-generating reactions, not only graphite crystallized in sulfide or metal–sulfide melts, but the growth of diamond also takes place. The obtained data allow one to consider cohenite as a potential source of carbon in the processes of diamond and graphite crystallization under the conditions of a reduced lithospheric mantle. The interaction of iron carbide and sulfur under which carbon extraction proceeds may be one of possible processes of the global carbon cycle. © 2015, Pleiades Publishing, Ltd
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov S. V., Krylov A. S., Vtyurin A. N., Pan Y.
Заглавие : Raman study of datolite CaBSiO4(OH) at simultaneously high pressure and high temperature
Коллективы : Russian Foundation for Basic Research [N 14-05-00616, 13-05-00185], Ministry of Education and Science of the Russian Federation
Место публикации : J. Raman Spectrosc.: Wiley-Blackwell, 2015. - Vol. 46, Is. 1. - P.177-181. - ISSN 0377, DOI 10.1002/jrs.4614. - ISSN 10974555(eISSN)
Примечания : Cited References:30. - This work was partly supported by the Russian Foundation for BasicResearch (grants N 14-05-00616 and 13-05-00185) and the Ministry ofEducation and Science of the Russian Federation.
Предметные рубрики: X-RAY-DIFFRACTION
CRYSTAL-STRUCTURE
HYDROGEN-BOND
SPECTROSCOPY
Ключевые слова (''Своб.индексиров.''): raman spectra--datolite--high pressure--high temperature--diamond anvil--cell
Аннотация: Using an in situ method of Raman spectroscopy and resistance-heated diamond anvil cell, the system datolite CaBSiO4(OH) – water has been investigated at simultaneously high pressure and temperature (up to Р ~5 GPa and Т ~250 °С). Two polymorphic transitions have been observed: (1) pressure-induced phase transition or the feature in pressure dependence of Raman band wavenumbers at P = 2 GPа and constant T = 22 °С and (2) heating-induced phase transition at T ~90 °С and P ~5 GPа. The number of Raman bands is retained at the first transition but changed at the second transition. The first transition is mainly distinguished by the changes in the slopes of pressure dependence of Raman peaks at 2 GPa. The second transition is characterized by several strong changes: the wavenumber jumps of major bands, the merging of strong doublets at 378 and 391 cm−1 (values for ambient conditions), the splitting of the intermediate-intensity band at 292 cm−1, and the transformation of some low-wavenumber bands at 160–190 cm−1. No spectral and visual signs of overhydration and amorphization have been observed. No noticeable dissolution of datolite in the water medium occurred at 5 GPa and 250 °С after 3 h, which corresponds to typical conditions of the ‘cold’ zones of slab subduction. Copyright © 2014 John Wiley & Sons, Ltd.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva Yu. V., Palyanov Y. N., Borzdov Y. M., Bayukov O. A., Sobolev N. V.
Заглавие : The formation of graphite upon the interaction of subducted carbonates and sulfur with metal-bearing rocks of the lithospheric mantle
Место публикации : Dokl. Earth Sci.: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 466, Is. 1. - P.88-91. - ISSN 1028334X (ISSN), DOI 10.1134/S1028334X16010190
Примечания : Cited References: 15. - This study was supported by the Russian Science Foundation (project no. 14-27-00054).
Предметные рубрики: Diamond formation
Silicon
Iron
Аннотация: Experimental studies of the Fe0–(Mg, Ca)CO3–S system were carried out during 18–20 h at 6.3 GPa, 900–1400°C. It is shown that the major processes resulting in the formation of free carbon include reduction of carbonates upon redox interaction with Fe0 (or Fe3C), extraction of carbon from iron carbide upon interaction with a sulfur melt/fluid, and reduction of the carbonate melt by Fe–S and Fe⎯S–C melts. Reconstruction of the processes of graphite formation indicates that carbonates and iron carbide may be potential sources of carbon under the conditions of subduction, and participation of the sulfur melt/fluid may result in the formation of mantle sulfides. © 2016, Pleiades Publishing, Ltd.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva, Yu. V., Palyanov, Yu. N., Borzdov, Yu. M., Bayukov O. A., Sobolev N. V.
Заглавие : Conditions for diamond and graphite formation from iron carbide at the P-T parameters of lithospheric mantle
Коллективы : Russian Science Foundation [14-27-00054]
Место публикации : Russ. Geol. Geophys.: Elsevier Science, 2016. - Vol. 57, Is. 1: Tectonics, geodynamics, and petrology of earth’s lithosphere and mantle (to the 80th birthday of Academician Nikolai Leontievich Dobretsov). - P.176-189. - ISSN 1068-7971, DOI 10.1016/j.rgg.2016.01.012. - ISSN 1878-030X(eISSN)
Примечания : Cited References:55. - This work was supported by the Russian Science Foundation under Grant No. 14-27-00054.
Предметные рубрики: DEEP CARBON-CYCLE
EARTHS MANTLE
MINERAL INCLUSIONS
HIGH-PRESSURE
KOKCHETAV MASSI
SUBDUCTION ZONES
REDOX BUDGET
FERRIC IRON
MOSSBAUER
METAL
Ключевые слова (''Своб.индексиров.''): iron carbide--wusite--graphite--diamond--oxides--olivine--subduction--redox interaction--lithospheric mantle--high-pressure experiment
Аннотация: To estimate conditions for the stability of iron carbide under oxidation conditions and to assess the possibility of formation of elemental carbon by interaction between iron carbide and oxides, experimental modeling of redox interaction in the systems Fe3C-Fe2O3 and Fe3C-Fe2O3-MgO-SiO2 was carried out on a split-sphere high-pressure multianvil apparatus at 6.3 GPa and 900-1600 degrees C for 18-20 h. During carbide-oxide interaction in the system Fe3C-Fe2O3, graphite crystallizes in assemblage with Fe3+-containing wusite. Graphite forms from carbide carbon mainly by cohenite oxidation: Fe3C + 3Fe(2)O(3) - 9FeO + C-0 and FeO + Fe3C - (Fe2+, Fe3+)O + C-0. At above-solidus temperatures (= 1400 degrees C), when metal-carbon melt is oxidized by wusite, graphite and diamond crystallize by the redox mechanism and form the Fe3+-containing wstite + graphite/diamond assemblage. Interaction in the system Fe3C-Fe2O3-MgO-SiO2 results in the formation of Fe3+-containing mannesiowusite-olivine-graphite assemblage. At = 1500 degrees C, two melts with contrasting f(O2) values are generated: metal-carbon and silicate-oxide; their redox interaction leads to graphite crystallization and diamond growth. Under oxidation conditions, iron carbide is unstable in the presence of iron, silicon, and magnesium oxides, even at low temperatures. Iron carbide-oxide interaction at the mantle temperatures and pressures leads to the formation of elemental carbon; graphite is produced from carbide carbon mainly by redox reactions of cohenite (or metal-carbon melt) with Fe2O3 and FeO as well as by interaction between metal-carbon and silicate-oxide melts. The results obtained suggest that cohenite can be a potential source of carbon during graphite (diamond) formation in the lithospheric mantle and the interaction of iron carbide with iron, silicon, and magnesium oxides, during which carbon is extracted can be regarded as a process of the global carbon cycle. (C) 2016, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.
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