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1.
A comparative study
of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd / O. S. Ivanova [et al.]> // J. Sib. Fed. Univ. Math. Phys. - 2016. -
Vol. 9
,
Is. 4
. - P. 459–462 ; Журн. СФУ. Сер. "Математика и физика",
DOI
10.17516/1997-1397-2016-9-4-459-462. - Cited References: 6. - The work was supported partly by the RFBR, 14-02-01211-a, and by the President of Russia Grant NSh-7559.2016.2. . - ISSN 1997-1397
Перевод заглавия:
Сравнительное изучение γ-Fe2O3 и ϵ-Fe2O3 наночастиц, формирующихся в стекле, допированном железом и гадолинием
Кл.слова (ненормированные):
magnetic nanoparticles
--
magnetic circular
dichroism
--
magnetic measurements
--
магнитные наночастицы
--
магнитный круговой дихроизм
--
магнитные измерения
Аннотация:
Formation and properties of the iron oxides γ -Fe2O3 and ϵ-Fe2O3 nanoparticles arising in glasses of basic compositions Ge2O-K2O-Al2O3-B2O3 and K2O-Al2O3-B2O3 doped with different concentrations of Fe2O3 and Gd2O3 and subjected to the additional thermal treatment are studied. The X-ray diffraction, TEM microscopy, magnetooptical effects, and electron spin resonance study allow elucidating the matrix and Gd role in determining the nanoparticle properties.
Изучены свойства наночастиц γ-Fe2O3 и ϵ-Fe2O3, формирующихся в стеклах основного состава Ge2O-K2O-Al2O3-B2O3 и K2O-Al2O3-B2O3, допированных Fe2O3 и Gd2O3 и подвергнутых дополни- тельной термической обработке. Результаты исследования рентгеновской дифракции, электрон- ной микроскопии, магнитооптических эффектов и электронного спинового резонанса позволили объяснить роль матрицы и гадолиния в определении свойств наночастиц.
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Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна
}
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2.
A comparative study
of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd / O. S. Ivanova [et al.]> //
VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P9.11. - P. 397. - References: 1. - The work was supported partly by the RFBR grant No. 14-02-01211 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
magnetic nanoparticles
--
magnetic circular
dichroism
--
magnetic measurements
Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН
Нет сведений об экземплярах
}
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3.
Analysis of the
structure and magnetic properties of an interface in multilayered (Fe/Si) N nanostructures with the surface-sensitive XMCD method / M. S. Platunov [et al.]> // JETP Letters. - 2014. -
Vol. 99
,
Is. 12
. - P. 706-711,
DOI
10.1134/S002136401412011X. - Cited References: 26. - We are grateful to S.V. Komogortsev for stimulating discussions and to the management of BESSY II, Helmholtz-Zentrum Berlin, for the opportunity of performing experiments at the UE46-PGM1 beamline. This work was supported by the Russian Foundation for Basic Research (project nos. 13-02-01265a and 14-02-31051mol-a), by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. NSh- 2886.2014.2), by the Presidium of the Russian Academy of Sciences (program no. 24.34), and by the Ministry of Education and Science of the Russian Federation (state contract no. 02.G25.31.0043 and state task for research at Siberian Federal University in 2014). . - ISSN 0021-3640. - ISSN 1090-6487
РУБ
Physics, Multidisciplinary
Рубрики:
RAY CIRCULAR-
DICHROISM
YIELD
SPECTRA
Fe
Аннотация:
The structural and magnetic properties of (Fe/Si) N nanostructures obtained by successive deposition on the SiO2/Si(100) surface at a temperature of the substrate of 300 K have been studied. The thicknesses of all Fe and Si layers have been determined by transmission electron microscopy measurements. The magnetic properties have been studied by the X-ray magnetic circular
dichroism
(XMCD) method near the Fe L 3, 2 absorption edges. The orbital (m l ) and spin (m S ) contributions to the total magnetic moment of iron have been separated. The thicknesses of magnetic and nonmagnetic iron silicide on the Si/Fe and Fe/Si interfaces have been determined with the surface sensitivity of the XMCD method and the model of the interface between the nonmagnetic and weakened magnetic phases.
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Публикация на русском языке
Анализ структуры и магнитных свойств интерфейса в многослойных наноструктурах (Fe/Si)N с применением поверхностно-чувствительного метода XMCD [Текст] / М. С. Платунов [и др.] // Письма в Журн. эксперим. и теор. физ. - 2014. - Т. 99 Вып. 11-12. - С. 817-823
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Helmholtz Zentrum Berlin, BESSY II, D-12489 Berlin, Germany
Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Varnakov, S. N.; Варнаков, Сергей Николаевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Weschke, E.; Schierle, E.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research [13-02-01265a, 14-02-31051mol-a]; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh- 2886.2014.2]; Presidium of the Russian Academy of Sciences [24.34]; Ministry of Education and Science of the Russian Federation [02.G25.31.0043]
}
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4.
Antiferromagnetic
dichroism
in
a complex multisublattice magnetoelectric CuB2O4 / K. N. Boldyrev [et al.]> // Phys. Rev. Lett. - 2015. -
Vol. 114
,
Is. 24
. - Ст. 247210,
DOI
10.1103/PhysRevLett.114.247210. - Cited References:40. - This study was supported by the Russian Academy of Sciences under the Programs for Basic Research, by the President of the Russian Federation (Grant No. MK-3521.2015.2, K. N. B.), by the Russian Foundation for Basic Research (Grants No. 15-32-20613, K. N. B., and No. 15-02-04222, R. V. P.), and by the Ministry of Education and Science of the Russian Federation (Grant No. 14.B25.0031.25, R. V. P.). . - ISSN 0031. - ISSN 1079-7114
Перевод заглавия:
Антиферромагнитный дихроизм в сложном многоподрешеточном магнетоэлектрике CuB2O4
РУБ
Physics, Multidisciplinary
Рубрики:
MAGNETIC SOLITON LATTICE
COPPER METABORATE
GYROTROPIC BIREFRINGENCE
SPECTROSCOPY
EXCITATIONS
TRANSITIONS
CRYSTALS
Cr2O3
FIELD
Аннотация:
Magnetic control of the crystal chirality was announced by Saito et al. [Phys. Rev. Lett. 101, (2008)] on the ground of experiments in CuB2O4. This claim has raised a sharp dispute in the literature because it seemed to contradict the fundamental symmetry principles. We settle this dispute on the basis of a high-resolution optical spectroscopy study of excitonic transitions in CuB2O4. We find that a large sublattice-sensitive antiferromagnetic linear
dichroism
(LD) emerges at the Néel temperature TN=21 K and show how it could simulate a “magnetic-field control of the crystal chirality.” We prove that the discovered LD is related microscopically to the magnetic Davydov splitting. This LD is highly sensitive to subtle changes in the spin subsystems, which allowed us to observe a splitting of the phase transition into an incommensurate magnetic phase into two transitions (T∗1=8.5 and T∗2=7.9 K) and to suggest elliptical spiral structures below T∗1, instead of a simple circular helix proposed earlier.
О магнитном контроле кристаллической хиральности сообщил Сайто и др. [Phys. Rev. Lett. 101, 117402 (2008)] на основании экспериментов в CuB2O4. Это требование вызвало резкий спор в литературе, потому что это казалось, противоречат основным принципам симметрии. Мы урегулировать этот спор на основе исследования с помощью оптической спектроскопии высокого разрешения экситонных переходов в CuB2O4. Мы считаем, что большой подрешетко-чувствительный антиферромагнитный линейный дихроизм (LD) возникает при температуре Нееля TN= 21 Kи показываем, как это может имитировать "контроль магнитным полем кристаллической хиральности." Мы докажем, что обнаруженный LD связанс микроскопическим магнитным Давыдовским расщеплением. Этот Л.Д. весьма чувствителен к тонким изменениям в спиновых подсистем, которые позволили нам наблюдать расщепление фазового перехода в несоизмеримы магнитная фаза в двух переходов (T*1= 8,5 и Т*2 = 7,9 К) и предположить эллиптическую спиральную структуру ниже T*1, вместо простой круговой спирали предложенный ранее.
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Держатели документа:
RAS, Inst Spect, Moscow 142190, Russia.
RAS, Ioffe Phys Tech Inst, St Petersburg 194021, Russia.
RAS, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Boldyrev, K. N.; Pisarev, R. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.; Russian Academy of Sciences under the Programs for Basic Research; Russian Federation [MK-3521.2015.2]; Russian Foundation for Basic Research [15-32-20613, 15-02-04222]; Ministry of Education and Science of the Russian Federation [14.B25.0031.25]
}
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5.
Ovchinnikov, S. G.
Application of synchrotron radiation to the study of magnetic materials / S. G. Ovchinnikov> // Uspekhi Fiz. Nauk. - 1999. -
Vol. 169
,
Is. 8
. - P. 869-887. - Cited References: 93 . - ISSN 0042-1294
РУБ
Physics, Multidisciplinary
Рубрики:
X-RAY-SCATTERING
RESONANCE EXCHANGE SCATTERING
RARE-EARTH-METALS
CIRCULAR-
DICHROISM
VALENCE STATES
CO/PD(111) MULTILAYERS
ABSORPTION-SPECTRA
PHASE-TRANSITIONS
SPIN POLARIZATION
EDGE STRUCTURE
Аннотация:
The recent results of the studies of magnetic materials using synchrotron irradiation are reviewed. The influence of magnetic effects on X-ray scattering is studied for linearly and circularly polarized photons, and effects of magnetic circular
dichroism
on the spectra of X-ray absorption and photoelectron emission are discussed. It is shown that X-ray magnetooptics techniques provide fine details of crystal and magnetic structures and also make it possible to separate the spin and orbital contributions to the total moment; to obtain element- and position-sensitive information on the magnetic properties of the material; to visualize domains and domain walls; and to probe magnetization reversal dynamics. A comparison of magnetic neutron and X-ray methods is given.
WOS
,
Scopus
Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
L.V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, 660036 Krasnoyarsk, Russian Federation
Доп.точки доступа:
Овчинников, Сергей Геннадьевич
}
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6.
Sokolov, V. V.
Comparative study of magnetic circular
dichroism
of f-f transitions in ErAl3(BO3)4 and ErFe3(BO3)4 / V. V. Sokolov, A. V. Malakhovskii, I. A. Gudim> //
XVII International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions (IFS'XVII) : book of abstracts. - 2018. - P. 207-208
Материалы конференции
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Соколов, Валерий Владимирович; International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions(17 ; 2018 ; Sept. ; 23-28 ; Ekaterinburg, Russia)
}
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7.
Competing magnetic states
in silicene and germanene 2D ferromagnets / D. V. Averyanov, I. S. Sokolov, M. S. Platunov [et al.]> // Nano Res. - 2020. -
Vol. 13
,
Is. 12
. - P. 3396-3402,
DOI
10.1007/s12274-020-3027-y. - Cited References: 58. - This work was supported by National Research Center (NRC) "Kurchatov Institute" (No. 1359, characterization) and the Russian Science Foundation (No. 19-19-00009 (synthesis) and No. 20-79-10028 (magnetization measurements)). D. V. A. also acknowledges support from the President's scholarship (SP 1398.2019.5). The measurements have been carried out using equipment of the resource centers of electrophysical and electron microscopy techniques in NRC "Kurchatov Institute" . - ISSN 1998-0124. - ISSN 1998-0000
РУБ
Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science,
Рубрики:
RAY CIRCULAR-
DICHROISM
ABSORPTION
Кл.слова (ненормированные):
silicene
--
germanene
--
2D ferromagnetism
--
X-ray magnetic circular
dichroism
(XMCD)
--
monolayer
Аннотация:
Two-dimension (2D) magnets have recently developed into a class of stoichiometric materials with prospective applications in ultra-compact spintronics and quantum computing. Their functionality is particularly rich when different magnetic orders are competing in the same material. Metalloxenes REX2 (RE = Eu, Gd; X = Si, Ge), silicene or germanene — heavy counterparts of graphene — coupled with a layer of rare-earth metals, evolve from three-dimension (3D) antiferromagnets in multilayer structures to 2D ferromagnets in a few monolayers. This evolution, however, does not lead to fully saturated 2D ferromagnetism, pointing at a possibility of coexisting/competing magnetic states. Here, REX2 magnetism is explored with element-selective X-ray magnetic circular
dichroism
(XMCD). The measurements are carried out for GdSi2, EuSi2, GdGe2, and EuGe2 of different thicknesses down to 1 monolayer employing K absorption edges of Si and Ge as well as M and L edges of the rare-earths. They access the magnetic state in REX2 and determine the seat of magnetism, orbital, and spin contributions to the magnetic moment. High-field measurements probe remnants of the bulk antiferromagnetism in 2D REX2. The results provide a new platform for studies of complex magnetic structures in 2D materials.
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Держатели документа:
Natl Res Ctr Kurchatov Inst, Kurchatov Sq 1, Moscow 123182, Russia.
ESRF European Synchrotron, CS 40220, F-38043 Grenoble 9, France.
ALBA Synchrotron Light Source, Barcelona 08290, Spain.
LOrme Merisiers, Synchrotron SOLEIL, F-91192 Gyf Sur Yvette, France.
RAS, Kirensky Inst Phys, Fed Res Ctr KSC SB, Akad Gorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Averyanov, D. V.; Sokolov, Ivan S.; Platunov, M. S.; Платунов, Михаил Сергеевич; Wilhelm, Fabrice; Rogalev, Andrei; Gargiani, Pierluigi; Valvidares, Manuel; Jaouen, Nicolas; Parfenov, Oleg E.; Taldenkov, Alexander N.; Karateev, Igor A.; Tokmachev, Andrey M.; Storchak, V. G.
}
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8.
Correlation between magneto-optical
and transport properties of Sr doped manganite films / Y. E. Samoshkina [et al.]> // J. Alloys Compd. - 2019. -
Vol. 782
. - P. 334-342,
DOI
10.1016/j.jallcom.2018.12.158. - Cited References: 51. - The authors are grateful to A.V. Malakhovskii (Kirensky Institute of Physics, Federal Research Center KSC SB RAS) for fruitful discussions of the magneto-optics data and V.I. Chichkov and N.V. Andreev (National University of Science and Technology MISiS) for the preparation of the manganite films. The work was supported partly by Russian Academy of Sciences , [grant number 0356-2017-0030 ], and the Russian Foundation for Basic Research , [grant number 16-32-00209 ]. . - ISSN 0925-8388
Кл.слова (ненормированные):
Thin films
--
Manganites
--
Crystal structure
--
Electrical transport
--
Electronic properties
--
Magnetic circular
dichroism
Аннотация:
The features of electronic structure of La0.7Sr0.3MnO3 Pr0.8Sr0.2MnO3, and Pr0.6Sr0.4MnO3 polycrystalline films of different thickness have been investigated using magnetic circular
dichroism
(MCD) in the range of 1.1–4.2 eV. The temperature behavior of the samples electrical resistance were also has been studied. It was found that films with high Sr content (0.3 and 0.4) act as high-temperature semiconductors, while the maximum in the temperature dependences of resistivity these films indicates the transition of the samples to the metallic state at some temperature TM-S, which is different for different sample thickness. The films with the lower Sr content (0.2) act as insulators in the used temperature range. The MCD spectra have been decomposed to the Gaussian-shaped lines, and the temperature dependence of intensity of each line has been analyzed in comparison with temperature dependence of the films magnetization and with their electric conductivity type. Different temperature behavior of the intensity of four specified Gaussian-lines was revealed for semiconductor films. In the case of insulating Pr0.8Sr0.2MnO3 samples, the intensity of three specified Gaussian lines changes with the temperature in the same way as the magnetization changed. It was established that the lanthanide (La, Pr) type does not affect the MCD spectra shape for the films with the same electrical conductivity type. Besides, the correlation between the MCD data of the films and their conductivity type was revealed. Due to the detailed analysis of the specified Gaussian lines with taking into account the well-known in the literature absorption bands, lying outside the studied spectral region, the MCD bands for the studied manganite films have been identified with electronic transitions of a different nature.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Samoshkina, Yu. E.; Самошкина, Юлия Эрнестовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич
}
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9.
Effect of gadolinium
on magnetic circular
dichroism
and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses / I. Edelman [et al.]> // J. Non-Cryst. Solids. - 2019. -
Vol. 506
. - P. 68-79,
DOI
10.1016/j.jnoncrysol.2018.12.006. - Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030. . - ISSN 0022-3093
Кл.слова (ненормированные):
Iron oxides
--
ε-Fe2O3
--
Borate glasses
--
Nanoparticles
--
Magnetic circular
dichroism
--
Electron magnetic resonance
Аннотация:
A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular
dichroism
(MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by gadolinium. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
LOMA, UMR 5798 Universite de Bordeaux-CNRS, Talence cedex, 33405, France
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, 630090, Russian Federation
NRC “Kurchatov Institute”, Moscow, 123182, Russian Federation
Vavilov State Optical Institute, St.-Petersburg, 199053, Russian Federation
Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Kliava, J.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zaikovskii, V.; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zubavichus, Y.; Stepanov, S.
}
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10.
Effects of processing
parameters on the morphology, structure, and magnetic properties of Cu1-xFexCr2Se4 nanoparticles synthesized with chemical methods / R. D. Ivantsov [et al.]> // J. Alloys Compd. - 2015. -
Vol. 650
. - P. 887-895,
DOI
10.1016/j.jallcom.2015.08.017. - Cited References: 36. - The paper was partially supported by the Russian Foundation for Basic Research (grant #14-02-01211), by the President of Russia (grant #NSh-2886.2014.2), and by the Ministry of Education and Science of the Russian Federation (grant #2014/71/1763 in the framework of the state assignment for the Siberian Federal University for 2014-2016). We also thank the Ministry of Science and Technology of Taiwan and the Siberian Branch of RAS (MOST 102-2112-M-153 -002 -MY3) for financial support. . - ISSN 0925-8388
Перевод заглавия:
Влияние параметров получения на морфологию, структуру и магнитные свойства наночастиц Cu1-xFexCr2Se4, синтезированных химическими методами
РУБ
Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
CuCr2Se4 SINGLE-CRYSTALS
TRANSPORT-PROPERTIES
CHROMIUM SPINELS
NANOSTRUCTURES
DIFFRACTION
Li
Кл.слова (ненормированные):
Copper selenide
--
Magnetic nanoparticles
--
Visible magnetic circular
dichroism
Аннотация:
Cu1-xFexCr2Se4 nanoparticles with x = 0, 0.2, and 0.4 were synthesized via thermal decomposition of metal nitrate or chloride salts and selenium powder using different precursor compositions and processing details. Single crystalline nano-belts or nano-rods coexist in the synthesized powder samples with hexagon-shaped plates in dependence on the precursor composition. The belts gathered into conglomerates forming "hierarchical" particles. Visible magnetic circular
dichroism
(MCD) of Cu1-xFexCr2Se4 nanoparticles embedded into a transparent matrix was investigated for the first time. The similarity of the MCD spectra of all samples showed the similarity of the nanoparticles electronic structure independent of their morphology. Basing on the MCD spectral maxima characteristics, electron transitions from the ground to the excited states were identified with the help of the conventional band theory and the multi-electron approach. © 2015 Elsevier B.V.
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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
National Pingtung University, Pingtung City, Pingtung County, Taiwan
Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Zharkov, S. M.; Жарков, Сергей Михайлович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Petrov, D. A.; Петров, Дмитрий Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Lin, C.-R.; Li, O.; Tseng, Y.-T.
}
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11.
Samoshkina, Yu. E.
Electronic and magnetic states of Pr and Mn in the Pr1–xSrxMnO3 films studied by XANES and XMCD spectroscopy / Y. E. Samoshkina, A. Rogalev> // J. Exp. Theor. Phys. - 2018. -
Vol. 126
,
Is. 5
. - P. 660-665,
DOI
10.1134/S1063776118040131. - Cited References: 35. - We thank V.I. Chichkov and N.V. Andreev (National University of Science and Technology MISiS) for the preparation of the manganite films. - This work was supported by the Russian Foundation for Basic Research (project no. 16-32-00209 mol_a) and a grant of the President of the Russian Federation (NSh-7559.2016.2). . - ISSN 1063-7761
Кл.слова (ненормированные):
Circular
dichroism
spectroscopy
--
Dichroism
--
Film growth
--
Magnetic moments
--
Manganese
--
Praseodymium
--
Strontium compounds
--
X ray absorption
Аннотация:
The spectral dependences of X-ray absorption near-edge spectroscopy (XANES) and X-ray magnetic circular
dichroism
(XMCD) and the field dependences of XMCD near the K edge of Mn and the L2,3 edges of Pr in the Pr0.8Sr0.2MnO3 and Pr0.6Sr0.4MnO3 films at T = 90 K are studied. The spectral dependences point to a mixed valence state of Mn and Pr in the films. It is found that, as compared to XANES, XMCD is more sensitive to the valence state of Pr4+. The field dependences of XMCD point to ferromagnetic behavior of Mn ions and the Van Vleck paramagnetism of Pr ions, which makes a significant contribution to the total magnetization of the films. It is shown that as the Sr concentration increases, the XMCD intensity at the K edge of Mn increases, which indicates a growth of the total magnetic moment of the film due to an increase in the 4p–3d hybridization.
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Публикация на русском языке
Самошкина, Юлия Эрнестовна. Электронные и магнитные состояния Pr и Mn в пленках Pr1-xSrxMnO3 по данным спектроскопии XANES и XMCD [Текст] / Ю. Э. Самошкина, А. Л. Рогалев // Журн. эксперим. и теор. физ. - 2018. - Т. 153 Вып. 5. - С. 794-799
Держатели документа:
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center,” Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
European Synchrotron Radiation Facility, Grenoble, CS, France
Доп.точки доступа:
Rogalev, A.; Самошкина, Юлия Эрнестовна
}
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12.
Element selective magnetism
in Ho0.5Nd0.5Fe3(BO3)4 single crystal probed with hard X-ray magnetic circular
dichroism
/ M. Platunov [et al.]> // J. Magn. Magn. Mater. - 2019. -
Vol. 479
. - P. 312-316,
DOI
10.1016/j.jmmm.2019.02.040. - Cited References: 40. - The study was supported in part by the grants of the Russian Foundation for Basic Research (project Nos. 16-32-60049, 17-02-00826, 18-42-243007) and the Foundation for Assistance to Small Innovative Enterprises (FASIE, UMNIK program). The magnetic measurements were carried out in the Shared Facility Centre of P.N. Lebedev Physical Institute of RAS. We are grateful to Dr. Alexey Bosak for providing assistance of the structural experiments on the ID28 beamline. We are also grateful to Dr. Evgeniy Eremin from Kirensky Institute of Physics for providing the results of magnetic measurements and for useful discussions. The authors thank the ID12 beamline staffs for help during the XMCD experiment and also gratefully acknowledge the beamtime provision (proposal HC-1804) by the ESRF. . - ISSN 0304-8853. - ISSN 1873-4766
РУБ
Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
MICROSTRUCTURE
TRANSITIONS
ND
Кл.слова (ненормированные):
X-ray magnetic circular
dichroism
--
X-ray absorption
--
Magnetic properties
Аннотация:
We present a study of a Ho0.5Nd0.5Fe3(BO3)4 single crystal aiming at understanding the roles of each magnetic sublattices in magnetic transitions at low temperatures. The crystal structure is determined to have the R32 symmetry in whole studied temperature range but the crystal appears to be racemic. Element selective magnetic properties studied with X-ray magnetic circular
dichroism
at the L2,3-edges of Ho and Nd, and at the Fe K-edge at T = 3 K under magnetic fields of ±17 T are compared with the results of macroscopic magnetization measurements in pure and substituted crystals. All three magnetic sublattices are shown to be strongly coupled and to undergo a spin-reorientation transition when magnetic field is applied along the trigonal c-axis. On the contrary, when magnetic field is applied in the ab-plane only the holmium atoms exhibit a sizeable magnetization jump. This result allows us to conclude that the spin-flop transitions observed in macroscopic magnetization curves and associated anomalies of electric polarization are due to the Ho3+ magnetic moment reorientation.
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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
European Synchrotron, ESRF, 71 Ave Martyrs CS40220, F-38043 Grenoble 9, France.
Swiss Norwegian Beamlines ESRF, 71 Ave Martyrs CS40220, F-38043 Grenoble 9, France.
RAS, PN Lebedev Phys Inst, Moscow 119991, Russia.
Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Kazak, N. V.; Казак, Наталья Валерьевна; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Gavrilkin, S. Yu.; Dyadkin, Vadim; Dovgaliuk, Iurii; Chernyshov, Dmitry; Hen, Amir; Wilhelm, Fabrice; Rogalev, Andrei; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research [16-32-60049, 17-02-00826, 18-42-243007]; Foundation for Assistance to Small Innovative Enterprises (FASIE, UMNIK program)
}
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13.
Evolution of morphology
and magnetic properties of α-Fe2−xCrxO3 nanoparticles in dependence on Cr concentration / I. S. Edelman, R. D. Ivantsov, C.-R. Lin [et al.]> // J. Magn. Magn. Mater. - 2022. -
Vol. 564
. - Ст. 170101,
DOI
10.1016/j.jmmm.2022.170101. - Cited References: 69. - The work was supported financially by the Russian Foundation for Basic Research, Grant № 19-52-52002 and Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3, № 110-2811-M-153-001 and № 110-2112-M-153-005. The support was obtained also from the Joint Scientific Center of the Siberian Federal University supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the electron microscopy studies were carried out . - ISSN 0304-8853
Перевод заглавия:
Эволюция морфологии и магнитных свойств наночастиц α-Fe2−xCrxO3 в зависимости от концентрации Cr
Кл.слова (ненормированные):
Hematite
--
α-Fe2−xCrxO3
--
Morin transition
--
Nanorods
--
Magnetization
--
Magnetic circular
dichroism
Аннотация:
Hematite, α-Fe2O3, one of the most widely studied magnetic compounds known to mankind since ancient times, has amazing properties and continues to puzzle researchers to this day. In this work, we found exceptionally strong changes in the morphology and magnetic properties of hematite nanoparticles upon doping with rather low concentrations of chromium. Nanoparticles α-Fe2−xCrxO3 with x varied from zero to 0.15 were prepared by solvothermal method using FeCl3·6H2O, CrCl3·6H2O, and 1,2-diaminopropane, (CH2)3(NH2)2, as precursors and temperature 180 °C for 6 h. The X-ray diffraction data showed the presence of only one crystal phase α-Fe2O3 for all x meanings with growing average crystalline size as the x increases. For the parent α-Fe2O3 powdered samples, the transmission electron microscopy revealed very long narrow nanorods with rounded ends that transform into spindles of increasing volume and cross section diameter as the Cr concentration increases. Vibrating sample magnetometry (VSM) and magnetic circular
dichroism
(MCD) study of the nanoparticles behavior in dependences on temperature and magnetic field revealed many unusual peculiarities. Among them there are strong increase of NPs magnetization with x increase (usually opposite picture is observed), the Morin transition temperature TM dependence on magnetic field, VSM sees the Morin transition in samples with small x only while MCD – in all samples, magnetization field dependences also are different when measured with VSM and MCD, and so on. Qualitative considerations were proposed to explain the observed phenomena.
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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Applied Physics, National Pingtung University, Pingtung City, 90003, Taiwan
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Lin, C. -R.; Zharkov, S. M.; Жарков, Сергей Михайлович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zeer, G. M.; Chen, Y. -Z.; Spivakov, A. A.
}
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14.
Exchange bias in
graphitic C/Co composites / H. -S. Hsu [et al.]> // Carbon. - 2017. -
Vol. 114
. - P. 642-648,
DOI
10.1016/j.carbon.2016.12.060. - Cited References: 54. - The authors would like to thank the Ministry of Science and Technology of the Republic of China, Taiwan, for financially supporting this research under Contract No. MOST 104-2112-M-153 -002 -MY3 (Hua-Shu Hsu), MOST 103-2112-M-213-004-MY3 (Hong-Ji Lin), and MOST 104-2112-M-390-001 (Shih-Jye Sun). We are thankful also to the President of Russia Program of support the leading scientific schools, grant NSh-7559,2016.2 (SGO). . - ISSN 0008-6223
Перевод заглавия:
Обменное смещение в графитовом композитном материале C/Co
Кл.слова (ненормированные):
Carbides
--
Carbon
--
Dichroism
--
High resolution transmission electron microscopy
--
Magnetoelectronics
--
Transmission electron microscopy
--
X ray absorption
--
Electronics production
--
Exchange bias effects
--
Experimental evidence
--
Magnetic interactions
--
Potential materials
--
Spintronics application
--
Theoretical modeling
--
X-ray magnetic circular
dichroism
--
Magnetic materials
Аннотация:
The exchange bias (EB) effect, which is the shift of the hysteresis loop of a ferromagnet in direct contact with an antiferromagnet, is highly advantageous for the development of spintronics applications. Carbon (C) has been considered as a potential material in next generation electronics production as well as spintronics devices beyond silicon. Here we show experimental evidence for an EB in C/Co composites. The significant EB needs thermal annealing to occur. X-ray absorption spectra and transmission electron microscopy data of these samples reveal that Co carbides in as grown samples decompose and form graphitic C/Co interfaces after annealing. Using x-ray magnetic circular
dichroism
we have detected the C spins that are responsible for the EB. These results inspire a theoretical model to investigate the magnetic interactions in graphitic C/Co interfaces and interpret the observed results. © 2016 Elsevier Ltd
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Держатели документа:
Department of Applied Physics, National Pingtung University, 4-18, Minsheng Road, Pingtung, Taiwan
National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu, Taiwan
Department of Applied Physics, National University of Kaohsiung, 700, Kaohsiung University Road, Kaohsiung, Taiwan
Kirensky Institute of Physics SB RAS, Akademgorodok 50, Bld. 38, Krasnoyarsk, Russian Federation
Siberian Federal University, 79 Svobodny pr., Krasnoyarsk, Russian Federation
Доп.точки доступа:
Hsu, Hua-Shu; Chang, Y.-Y.; Chin, Y.-Y.; Lin, H.-J.; Chen, C.-T.; Sun, S.-J.; Zharkov, S. M.; Жарков, Сергей Михайлович; Lin, C.-R.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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15.
Exotic spin structures
and phase transitions in a complex magnetoelectric CuB2O4 as evidenced by optical linear
dichroism
studies / K. N. Boldyrev [et al.]> //
20th Int. Сonf. on Magnetism (ICM-2015) : book of abstracts. - 2015. - Ст. TH.C-P107
Материалы конференции
Доп.точки доступа:
Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Popova, M. N.; Попова, Марина Николаевна; Pisarev, R. V.; Писарев, Роман Васильевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; International Conference on Magnetism(20 ; 2015 ; Jul ; 5-10 ; Barselona, Spain)
}
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16.
Fe3S4 and Fe3O4
magnetic nanocrystals: magnetooptical and Mössbauer spectroscopy study / C-R Lin [et al.]> // Mater. Research Express. - 2014. -
Vol. 1
,
Is. 2
. - P. 025033
DOI
10.1088/2053-1591/1/2/025033. - We thank the National Science Council of Taiwan (NSC 100-2923-M-153-001-MY3 and NSC 102-2112-M-153-002-MY3) for financial support. Support by the Russian Foundation for Basic Research (Grants #14-12-00848 and 14-02-0121) is acknowledged. This work was also supported by the Russian Federation President Grant NSh-2886.2014.2.
Кл.слова (ненормированные):
iron sulfide Fe3S4
--
iron oxide Fe3O4
--
magnetic nanoparticles
--
Mössbauer spectroscopy
--
magnetic circular
dichroism
--
ab-initio band structure
--
calculations
Аннотация:
Iron oxide magnetite (Fe3O4) should be a reasonable analog for conception and understanding of the magnetic properties of iron sulfide greigite (Fe3S4)—one of the most required magnetic materials having numerous applications but being far from the complete understanding now. We present here a comparative study of the Mössbauer effect (ME) and the magnetic circular
dichroism
(MCD) spectroscopy of Fe3O4 and Fe3S4 nanoparticles. The ME spectrum parameters of Fe3S4 are shown to distinguish strongly from that of Fe3O4, and the MCD spectrum shapes are shown to be absolutely different for two compounds. To clarify the origin of the Fe3S4 MCD spectrum we have performed ab initio band structure calculations and identified the MCD spectrum features with the transitions between calculated energy states.
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Держатели документа:
Department of Applied Physics, National Pintung University of Education, Pintung 90003, Taiwan
L.V. Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Krasnoyarsk, 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia
University of Nevada, Reno, NV 89557, USA
Shubnikov Institute of Crystallography, Russian Academy of Sciences, Moscow 119333, Russia
Доп.точки доступа:
Lin, C.-R.; Tseng, Y.-T.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Fedorov, D. A.; Федоров, Дмитрий Александрович; Starchikov, S. S.; Lyubutin, I. S.
}
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17.
Giant hydrogen effect
on the structure and physical properties of ZnO and Co-doped ZnO films fabricated by the RF magnetron sputtering in Ar + H2 atmosphere / I. S. Edelman [et al.]> // J. Magn. Magn. Mater. - 2019. -
Vol. 489
. - Ст. 165461,
DOI
10.1016/j.jmmm.2019.165461. - Cited References: 39. - The work is supported by the Russian Academy of Sciences in the frames of Project No 0356-2017-0030 and by the Ministry of Science and Technology of Taiwan MOST 106-2112-M-110-001. . - ISSN 0304-8853. - ISSN 1873-4766
Перевод заглавия:
Колоссальное влияние водорода на структуру и физические свойства пленок ZnO и ZnO допированных кобальтом, полученных методом высокочастотного магнетронного распыления в атмосфере аргона и водорода
РУБ
Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
MAGNETOOPTICAL PROPERTIES
OPTICAL-PROPERTIES
FERROMAGNETISM
Кл.слова (ненормированные):
ZnO films
--
Co-doped ZnO films
--
Films hydrogenation
--
Magnetic circular
--
dichroism
--
Room temperature ferromagnetism
Аннотация:
ZnO and Co-doped ZnO films were synthesized by the radio frequency magnetron sputtering in mixed atmosphere of Ar + 20% O2 and Ar + 20–50% H2. The morphology, chemical composition, crystal structure, optical transmission, electrical resistance, and magnetic circular
dichroism
of the films were investigated. It was established that the films thickness decreased several times when Ar was partly replaced by hydrogen in the sputtering chamber. At the same time, for the Co-doped ZnO films, the increase in the relative Co content with the increasing hydrogen concentration was observed. These phenomena are explained by the formation of gaseous ZnH2 because of the hydrogen reaction with the growing films under the conditions of the high substrate temperature (450 °C) and, respectively, the decrease in the Zn component in the films. The hydrogenated Co-doped ZnO films exhibit an increase in electric conductivity and ferromagnetic behavior at room temperature. The magnetic nature of the films is explained by a combination of the intrinsic ferromagnetism (due to the formation of the Co-H-Co complex) with the inclusion of metallic Co clusters.
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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 80424, Taiwan.
Natl Univ Kaohsiung, Dept Appl Phys, Kaohsiung 81148, Taiwan.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
ESRF, CS 40220, F-38043 Grenoble, France.
Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Chou, Hsiung; Samoshkina, Yu. E.; Самошкина, Юлия Эрнестовна; Petrov, D. A.; Петров, Дмитрий Анатольевич; Lin, Hsien C.; Chan, Wen L.; Sun, Shih-Jye; Zharkov, S. M.; Жарков, Сергей Михайлович; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Platunov, M. S.; Платунов, Михаил Сергеевич; Rogalev, A.; Russian Academy of Sciences [0356-2017-0030]; Ministry of Science and Technology of Taiwan [MOST 106-2112-M-110-001]
}
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18.
Giant natural circular
dichroism
of vibronic transitions in HoAl3(BO3)4 / A. V. Malakhovskii [et al.]> // JETP Letters. - 2015. -
Vol. 102
,
Is. 8
. - P. 493-495,
DOI
10.1134/S0021364015200084. - Cited References: 15. - This work was supported by the Council of the President of the Russian Federation for the Support of Leading Scientific Schools (project no. NSh-2886.2014.2). . - ISSN 0021-3640
РУБ
Physics, Multidisciplinary
Рубрики:
SINGLE-CRYSTAL
OPTICAL-ABSORPTION
SPECTRA
Ho3+
IONS
PR3+
Аннотация:
The giant natural optical activity of vibronic replicas of the f–f5/8 → 5F2 transition in HoAl3(BO3)4 is observed. It exceeds the optical activity related to purely electronic transitions by two orders of magnitude and corresponds to the almost complete circular polarization of the transitions. This effect is explained by the local distortions of the crystal in the excited electronic state, which lead to the mixing of electron and vibrational wavefunctions and, as a consequence, to the delocalization of the vibronic wavefunction and the enhancement of spatial dispersion, which is responsible for the optical activity.
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Публикация на русском языке
Гигантский естественный круговой дихроизм вибронных переходов в HoAl3(BO3)4 [Текст] / А. В. Малаховский [и др.] // Письма в ЖЭТФ : Наука, 2015. - Т. 102 Вып. 8. - С. 555-557
Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Sokolov, V. V.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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19.
Hard X-ray magnetochiral
dichroism
in a paramagnetic molecular 4f complex / D. Mitcov, M. Platunov, C. D. Buch [et al.]> // Chem. Sci. - 2020. -
Vol. 11
,
Is. 31
. - P. 8306-8311,
DOI
10.1039/d0sc02709j. - Cited References: 74. - SP thanks the VILLUM FONDEN for research grant 13376. SP and DM thank the Danish Ministry of Higher Education and Science for travel support through the Instrument Center DANSCATT. AR thanks the Carlsberg Foundation (grant CF18-0613) and the Independent Research Fund Denmark (grant 9036-00015B) for funding. MP thanks the Russian Science Foundation (grant 19-72-00002) for funding . - ISSN 2041-6520. - ISSN 2041-6539
РУБ
Chemistry, Multidisciplinary
Рубрики:
CHIRAL
DICHROISM
SINGLE-CRYSTAL
SPIN QUBITS
READ-OUT
L3-EDGE
Аннотация:
Magnetochiral
dichroism
(MΧD) originates in the coupling of local electric fields and magnetic moments in systems where a simultaneous break of space parity and time-reversal symmetries occurs. This magnetoelectric coupling, displayed by chiral magnetic materials, can be exploited to manipulate the magnetic moment of molecular materials at the single molecule level. We demonstrate herein the first experimental observation of X-ray magnetochiral
dichroism
in enantiopure chiral trigonal single crystals of a chiral mononuclear paramagnetic lanthanide coordination complex, namely, holmium oxydiacetate, at the Ho L3-edge. The observed magnetochiral effect is opposite for the two enantiomers and is rationalised on the basis of a multipolar expansion of the matter–radiation interaction. These results demonstrate that 4f–5d hybridization in chiral lanthanoid coordination complexes is at the origin of magnetochiral
dichroism
, an effect that could be exploited for addressing of their magnetic moment at the single molecule level.
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Держатели документа:
Univ Copenhagen, Dept Chem, Univ Pk 5, DK-2100 Copenhagen, Denmark.
ESRF European Synchrotron, CS 40220, F-38043 Grenoble 9, France.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Univ Penn, Dept Chem, 231 South 34th St, Philadelphia, PA 19014 USA.
Доп.точки доступа:
Mitcov, D.; Platunov, M. S.; Платунов, Михаил Сергеевич; Buch, C. D.; Reinholdt, A.; Dossing, A. R.; Wilhelm, F.; Rogalev, A.; Piligkos, S.; VILLUM FONDEN [13376]; Carlsberg FoundationCarlsberg Foundation [CF18-0613]; Independent Research Fund Denmark [9036-00015B]; Russian Science FoundationRussian Science Foundation (RSF) [19-72-00002]
}
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20.
Identification of ε-Fe2O3
nano-phase in borate glasses doped with Fe and Gd / O. S. Ivanova [et al.]> // J. Magn. Magn. Mater. - 2016. -
Vol. 401
. - P. 880-889,
DOI
10.1016/j.jmmm.2015.10.126. - Cited References: 40. - This work was supported partly by the Russian Foundation for Basic Research, Grants No 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. Authors are grateful to G.A. Bukhtiyarova and U.N. Martyanov for the assistance in the ε-Fe2O3 nanoparticles prepared by a wet chemical pore filling impregnation method and for the discussion of the obtained results . - ISSN 0304-8853
РУБ
Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
IRON-OXIDE
NANOPARTICLES
CERAMICS
CRYSTAL
PARTICLES
SURFACE
Кл.слова (ненормированные):
Magnetic nanoparticles
--
ε-Fe2O3
--
Magnetic circular
dichroism
--
Electron magnetic resonance
Аннотация:
A new type of magnetic nanoparticles was revealed in borate glasses co-doped with low contents of iron and gadolinium. Structure and magnetic properties of the particles differ essentially from that of the α-Fe2O3, γ-Fe2O3, or Fe3O4 nanoparticles which were detected earlier in similar glass matrices. Transmission electron microscopy including STEM-HAADF and EDX, synchrotron radiation-based XRD, static magnetic measurements, magnetic circular
dichroism
, and electron magnetic resonance studies allow referring the nanoparticles to the iron oxide phase-ε-Fe2O3. Analysis of the data set has shown that it is Gd atoms that govern the process of nanoparticles' nucleation and its incorporation into the particles in different proportions can be used to adjust their magnetic and magneto-optical characteristics. © 2015 Elsevier B.V.
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Держатели документа:
L.V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
NRC Kurchatov Institute, Moscow, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, Russian Federation
Novosibirsk State University, Novosibirsk, Russian Federation
Vavilov State Optical Institute, All-Russia Research Center, Petersburg, Russian Federation
Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zubavichus, Y. V.; Zaikovskii, V .I.; Stepanov, S. A.
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