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Общее количество найденных документов : 270
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1.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Abramova G. A., Boehm M., Roessli B., Raseh J., Petrakovskiy G. A., Velikanov D. A., Vorotynov A. M., Bovina A. F., Sokolov V. V.
Заглавие : Neutron diffraction measurements of the FexMn1-xS solid solutions
Коллективы : European conference on neutron scattering
Место публикации : 4th European conference on neutron scattering: Lund, Sweden, 25-29 June 2007 : [сб. тезисов]. - p.128
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2.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Shakhura I. E., Vyunishev A. M., Zaitsev A. I., Zamkov A. V.
Заглавие : Nonlinear diffraction and random QPM in strontium tetraborate
Место публикации : 4th International Conference on Advanced Optoelectronics and Lasers (CAOL 2008), Sept. 29 2008-Oct. 4, 2008,Alushta, Crimea, Ukraine, p.398
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volkova E. A., Platunov M. S., Antipin A. M., Alpanova R. R., Dubrovskiy A. A., Pyastolova Yu. V., Podobraznyh A. D., Kosorukov V. L., Koporulina E. V., Maltsev V. V.
Заглавие : Synthesis, structure and magnetic properties of monoclinic lanthanum-chromium borate LaCr3(BO3)4
Колич.характеристики :9 с
Место публикации : J. Alloys Compd. - 2024. - Vol. 994. - Ст.174683. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2024.174683. - ISSN 1873-4669
Примечания : Cited References: 38. - Single crystal X-ray analysis was carried out within the State assignment NRC "Kurchatov institute" (research contribution of A.M.A.). The research contribution of M.S.P. was partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for Synchrotron radiation facility "SKIF", Boreskov Institute of Catalysis (project FWUR-2024–0040)
Аннотация: Single crystals of LaCr3(BO3)4 were synthesized through spontaneous nucleation from a K2Mo3O10 flux melt. The crystal structure was determined using single-crystal X-ray diffraction (XRD) at temperatures of 293 K and 85 K. LaCr-borate crystallizes in the monoclinic C2/c space group with unit cell parameters a = 7.47980(5) Å, b = 9.55180(7) Å, c = 11.48330(8) Å, β= 104.0060(6)°, V = 796.04(1) Å3 (for C1, T = 293 K), and a = 7.47380(5) Å, b = 9.55520(7) Å, c = 11.47100(8) Å, β = 103.9330(6)°, V = 795.08(1) Å3 (for C2, T = 85 K), each with Z = 4. The temperature dependence of the unit cell parameters, including the monoclinic angle (β) and the unit cell volume (V), was investigated over the range of 85–293 K. No structural phase transitions were observed in the low-temperature region down to 85 K. Differential scanning calorimetry (DSC) measurements revealed no high-temperature phase transitions between 50 and 1350°C. Infrared (IR) spectroscopy confirmed the monoclinic structure of LaCr3(BO3)4 crystals, revealing characteristic absorption bands, including the lowest frequency mode associated with the translational vibrations of the La3+ ion.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Soldatenko A. S., Molokeev M. S., Lazareva N. F.
Заглавие : N-silylmethyl-2-(1-naphthyl)acetamides: Synthesis, structure and computational screening
Колич.характеристики :8 с
Место публикации : Curr. Org. Chem. - 2024. - Vol. 28, Is. 12. - P.959-966. - ISSN 13852728 (ISSN), DOI 10.2174/0113852728296495240409062733. - ISSN 18755348 (eISSN)
Примечания : Cited References: 75. - This work was supported by the Russian Science Foundation using the analytical equipment of the Baikal Center for Collective Use of the SB RAS and the analytical equipment of the Krasnoyarsk Center for Collective Use of SB RAS. M.S. Molokeev’s work was carried out within the framework of the Strategic Academic Leadership Program "Priority-2030" for the Siberian Federal University
Аннотация: Synthesis of new hybrid organosilicon compounds based on the amides 1- naphthylacetic acid was described. N-Organyl-2-(1-naphthyl)-N-[(triethoxysilyl)methyl]- acetamides were obtained by the reaction of 1-naphthylacetyl chloride with α-silylamines RNHCH2Si(OEt)3 (R = Me, i-Pr and Ph). Their subsequent interaction with N(CH2CH2OH)3 led to the formation of N-organyl-2-(1-naphthyl)-N-(silatranylmethyl)acetamides. The structure of these hybrid compounds was characterized by 1H, 13C, and 29Si NMR spectroscopy. The structure of N-methyl- and N-isopropyl-2-(1-naphthyl)-N-(silatranylmethy)acetamides was confirmed by X-ray diffraction analysis. Results of computational screening showed that these silatranes are bioavailable and have drug-likeness.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Oreshonkov A. S., Aleksandrovsky A. S., Chimitova O.D., Pankin D.V., Popov Z.I., Sukhanova E.V., Molokeev M. S., Adichtchev S.V., Pugachev A.M., Nemtsev I. V.
Заглавие : Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4
Колич.характеристики :10 с
Место публикации : Mater. Chem. Phys. - 2024. - Vol. 320. - Ст.129400. - ISSN 02540584 (ISSN), DOI 10.1016/j.matchemphys.2024.129400. - ISSN 18793312 (eISSN)
Примечания : Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Matveeva A. N., Zobkalo I. A., Meven M., Freidman A. L., Semenov S. V., Terentjev K. Yu., Pavlovskiy N. S., Kolkov M. I., Shaykhutdinov K. A., Hutanu V.
Заглавие : Complex interplay between 3d and 4f magnetic systems in multiferroic DyMnO3
Место публикации : J. Magn. Magn. Mater. - 2023. - Vol. 569. - Ст.170415. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2023.170415
Примечания : Cited References: 28. - The authors are grateful to S.V. Gavrilov for the technical assistance. This work was supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA 3688/1-1, also by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects number 18-42-243024 and 20-42-243008. The neutron data were obtained at the instrument HEiDi operated jointly by RWTH Aachen University and Jülich Centre for Neutron Science within JARA cooperation
Аннотация: Structural and magnetic properties of single crystals of DyMnO3 were investigated by neutron diffraction in order to study the peculiarities of 3d-4f interactions in this compound. Precise magnetic order and its detailed temperature evolution were determined using single crystal neutron diffraction. Elliptical cycloid on manganese subsystem below TCh = 19 K was confirmed, with temperature decrease the elipticity of the Mn magnetic structure reduces significantly, creating almost circular cycloid. Temperature evolution of the magnetic structure demonstrate specific hysteretic behavior. The results show a complex interplay between transition metal and rare earth magnetic sublattices leading to so-called “Mn- controlled” and “Dy- controlled” magnetic states. The strong and complicate 3d-4f interaction leads to the unusual very slow magnetic structure relaxation.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vyunishev A. M., Arkhipkin V. G., Chirkin A. S.
Заглавие : Frequency doubling of femtosecond laser pulses in three dimensional nonlinear photonic crystals
Колич.характеристики :6 с
Место публикации : Laser Phys. Lett. - 2023. - Vol. 20, Is. 3. - Ст.035402. - ISSN 16122011 (ISSN), DOI 10.1088/1612-202X/acb7f5. - ISSN 1612202X (eISSN)
Примечания : Cited References: 20. - This work was supported by the Russian Science Foundation (Grant # 19-12-00203). The authors thank N Davletshin for graphical illustration of NPC
Аннотация: Quasi-phase matched nonlinear frequency conversion in three dimensional nonlinear photonic crystals (NPCs) has been considered for implementation of the second harmonic generation of transform-limited and chirped femtosecond laser pulses. Spatial distribution of the second harmonic intensity is shown to be caused by Cherenkov- and Raman–Nath-type nonlinear diffraction. These types of nonlinear diffraction may occur simultaneously resulting in an efficient multi-order nonlinear diffraction in the Bragg regime, which can be realized by a proper choice of the modulation period of NPC structure in longitudinal direction for considered transverse diffraction order. Three dimensional NPCs open up new possibilities for ultrafast nonlinear photonics and parametric interactions in optics.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev, Nicolay N., Gerasimova, Marina A., Ostapenko, Ivan A., Zolotov, Andrey O., Molokeev M. S.
Заглавие : Two organic-inorganic manganese(II) halide hybrids containing protonated N,N’-dialkylthioureas with efficient green-emission
Место публикации : J. Mol. Struct. - 2023. - Vol. 1277. - Ст.134851. - ISSN 0022-2860 (ISSN), DOI 10.1016/j.molstruc.2022.134851
Примечания : Cited References: 42. - The reported study was funded by RFBR according to the research project № 19-52-80003. X-ray data from single crystals and powders were obtained with the analytical equipment of Krasnoyarsk Center of collective use of SB RAS
Аннотация: Luminescent (C5H13N2S)2[MnBr4] (1) and (C7H17N2S)2[MnBr4] (2) (C5H12N2S = N,N′-diethylthiourea, C7H16N2S = N,N′-diisopropylthiourea) were prepared via solvothermal method, and the structures of these compounds have been resolved using X-ray single crystal diffraction. The structures consist of electrostatically bound MnBr42− anions and organic C5H13N2S+ and C7H17N2S+ cations. The intermolecular N−H···Br and N−H···S hydrogen bonds additionally stabilize crystal structures of 1-2. Upon excitation over broadband covering the range 265 to 515 nm, these compounds show green emission peaking at 526 nm for 1 and 522 nm for 2, which is assigned to the 4T1→ 6A1 electronic transition of Mn2+ from isolated within the crystal structures MnBr42− tetrahedra. The photoluminescence quantum yield (PLQY) of powder 1 is 97 ± 7% for excitation at 440 nm and that of powder 2 is 83 ± 7% for excitation at 365 nm. The high PLQY indicates the absence of noticeable concentration quenching at shortest Mn···Mn distance of 8.11 and 8.73 Å between Mn2+ ions within the structures of 1 and 2. The high-performance photoluminescence of 0D (C5H13N2S)2[MnBr4] and (C7H17N2S)2[MnBr4] compounds demonstrated promising applications in photonics.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ikonnikov D. A., Myslivets S. A., Davletshin N. N., Baron F. A., Arkhipkin V. G., Vyunishev A. M.
Заглавие : Unveiling Talbot effect under Fresnel diffraction at a fork-shaped grating
Место публикации : Ann. Phys. (Berlin). - 2023. - Vol. 535, Is. 3. - Ст.2200480. - ISSN 00033804 (ISSN), DOI 10.1002/andp.202200480. - ISSN 15213889 (eISSN)
Примечания : Cited References: 31. - The work was supported by the Russian Science Foundation (Grant No. 19-12-00203)
Аннотация: The near-field effect of diffraction image self-reproduction or self-imaging of a periodic grating illuminated by quasi-monochromatic wave is well-known as the Talbot effect. Introducing a dislocation to a periodic structure provides a fork-shaped modulation of the phase/amplitude, which produces discrete diffraction pattern in a far-field consisting of optical vortices. In this paper, Fresnel diffraction at amplitude fork-shaped grating is theoretically and experimentally studied. The coexistence of spatial ordering and local violation of translational symmetry of the structure manifests itself in a strict diffraction pattern consisting of optical vortices in the far-field, which is shown to be accompanied by formation of a spatially ordered intensity distribution in the near-field, reminiscent the Talbot carpets for periodic structures. These results demonstrate the first evidence of Talbot effect occurred under light diffraction at fork-shaped gratings, being promising for deep understanding of near-field singular optics phenomena.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ikonnikov, Denis A., Myslivets S. A., Arkhipkin V. G., Vyunishev A. M.
Заглавие : Near-field evolution of optical vortices and their spatial ordering behind a fork-shaped grating
Место публикации : Photonics. - 2023. - Vol. 10, Is. 4. - Ст.469. - ISSN 23046732 (eISSN), DOI 10.3390/photonics10040469
Примечания : Cited References: 32. - The work is supported by the Russian Science Foundation (grant No. 19-12-00203)
Аннотация: Fork-shaped gratings are periodic structures containing a spatial dislocation known to be used for the production of optical vortices in a far field. Spatial overlapping of diffraction orders in a near field results in complex spatial evolution of optical vortices. In this paper, we report the results of near-field diffraction on fork-shaped gratings with different topological charges and analyze the evolution of specific optical vortices during propagation. Optical vortices have been shown to form two-dimensional well-ordered spatial configurations in specific transverse planes. The locus of points of optical singularities has been shown to form two helical lines twisted around the ±1 diffraction order directions. Our results demonstrate that the spatial behaviour of optical vortices is in close connection with the spatial ordering arising from the Talbot effect. The quantity of optical vortices demonstrates complex spatial dynamics, which includes spatial oscillations and decreasing along the propagation direction. These results provide a foundation towards a deeper understanding of near-field singular optics phenomena.
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