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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Mikhaleva E. A., Gorev M. V., Kartashev A. V.
Заглавие : Caloric and multicaloric effects in oxygen ferroics and multiferroics
Коллективы : Всероссийская конференция по физике сегнетоэлектриков
Место публикации : Phys. Solid State/ Всероссийская конференция по физике сегнетоэлектриков (20 ; 2014 ; 18-22 авг. ; Красноярск): MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 3. - P.429-441. - ISSN 1063, DOI 10.1134/S1063783415030075. - ISSN 10906460(eISSN)
Примечания : Cited References:53. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-924.2014.2).
Предметные рубрики: PHASE-TRANSITIONS
MAGNETOCALORIC MATERIALS
ELECTROCALORIC MATERIALS
REFRIGERATION
CERAMICS
OXYFLUORIDES
Аннотация: The main problems of the current state-of-the-art research into the caloric effects observed in oxygen ferroics, multiferroics, and composites, as well as the influence of different factors (anisotropy, dimensional parameters, direct and indirect interferroic interactions) on these effects, have been considered. Possible ways to increase the caloric efficiency of materials have been analyzed.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Bondarev V. S., Gorev M. V., Mikhaleva E. A., Flerov I. N.
Заглавие : Cooling method based on electrocaloric effect realized in periodically switching electric filed in triglycinesulphate
Коллективы : Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, International Conference Functional Materials and Nanotechnologies
Место публикации : Joint 12th Russia/CIS/Baltic/Japan Symp. Ferroelectricity. 9th Int. Conf. Funct. Mater. Nanotechnologies : book of abstracts/ mem. of progr. comm.: I. N. Flerov, V. I. Zinenko. - 2014. - P.126. - ISBN 978-9984-45-875-5
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev V. S., Mikhaleva E. A., Gorev M. V., Flerov I. N.
Заглавие : Direct and indirect studies of the electrocaloric effect in single crystalline ferrielectric (NH4)2SO4
Место публикации : J. Alloys Compd. - 2022. - Vol. 892. - Ст.162130. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2021.162130
Примечания : Cited References: 38. - The reported study was supported by the Russian Science Foundation (project no. 19-72-00023)
Аннотация: The influence of an electric field on the phase transition parameters and the electrocaloric response in ferrielectric (NH4)2SO4 was studied using a universal multifunctional adiabatic calorimeter. The very low sensitivity of the phase transition temperature to the electric field, dT0/dE ≈ 5·10-3 K/(kV/cm), was shown to be the reason for the low maximum value of the intensive electrocaloric effect, ΔTAD, at E = 11 kV/cm: direct and indirect measurements gave the values of 0.01 K and 0.05 K, respectively. However, the extensive electrocaloric response revealed by an analysis of the entropy–temperature–electric field phase diagram was relatively large, with a value of ΔSECE ≈ − 19 J/kg K, due to the significant contribution of a jump in the excess entropy to the total value, δS0/ΔS0 ~ 0.37. An additional irreversible increase in temperature under the electric field was associated with the Joule effect and indicated a significant electrical conductivity of ammonium sulphate.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mikhaleva E.A., Flerov I.N., Bondarev V.S., Gorev M.V., Vasiliev A.D., Davydova T.N.
Заглавие : Electrocaloric and barocaloric effects in some ferroelectric hydrosulfates and triglycinesul- phate
Коллективы : European Meeting on Ferroelectricity
Место публикации : 12th European Meeting on Ferroelectricity: Abstracts. - 2011. - Ст.9-6
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Bondarev V. S., Gorev M. V., Vasiliev A. D., Davydova T. N.
Заглавие : Electrocaloric and barocaloric effects in some ferroelectric hydrosulfates and triglycinesulfate
Коллективы : European Meeting on Ferroelectricity
Место публикации : European Meeting on Ferroelectricity (12 ; 2011 ; 26 June - 1 July ; Bordeaux, France). Ferroelectrics: Taylor & Francis LTD, 2012. - Vol. 430. - P.78-83. - ISSN 0015-0193, DOI 10.1080/00150193.2012.677717
Примечания : Cited References: 14. - This work was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools (project no, Nsh - 4645.2010.2).
Предметные рубрики: PHASE-TRANSITIONS
AMMONIUM
RbHSO4
Ключевые слова (''Своб.индексиров.''): ferroelectrics--phase transitions--electrocaloric and barocaloric effects
Аннотация: A comparative analysis of electrocaloric and barocaloric efficiency of order-disorder ferroelectrics Rbx(NH4)1-xHSO4 and TGS is performed. A good agreement was found between intensive electrocaloric effects measured experimentally and calculated using electric equation of state. Barocaloric effects were evaluated analyzing the experimental data on heat capacity and T-p phase diagrams. In some crystals under study the same adiabatic temperature change can be produced by low pressure and rather high electric field.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Mikhaleva E. A.
Заглавие : Electrocaloric effect and anomalous conductivity of the ferroelectric NH4HSO4
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 3. - P478-484. - ISSN 1063-7834, DOI 10.1134/S1063783408030141
Примечания : Cited References: 10
Предметные рубрики: PHASE-TRANSITIONS
Аннотация: An intensive electrocaloric effect in the uniaxial ferroelectric NH4HSO4 near the second-order phase transition (T-1 approximate to 271 K) is studied. A high electrical conductivity of the NH4HSO4 crystal is revealed, and its temperature dependence is investigated. The results obtained are analyzed together with the data available for the ferroelectrics, which hold promise for the use as solid-state cooling agents.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev V. S., Mikhaleva E. A., Flerov I. N., Gorev M. V.
Заглавие : Electrocaloric effect in triglycine sulfate under equilibrium and nonequilibrium thermodynamic conditions
Коллективы : Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [16-42-240428r_a]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2017. - Vol. 59, Is. 6. - P.1118-1126. - ISSN 1063-7834, DOI 10.1134/S1063783417060051. - ISSN 1090-6460(eISSN)
Примечания : Cited References:25. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research, project no. 16-42-240428r_a.
Предметные рубрики: PERIODIC ELECTRIC-FIELD
Аннотация: The direct and indirect measurements of intensive electrocaloric effect in a triglycine sulfate ferroelectric crystal are performed under equilibrium and nonequilibrium thermodynamic conditions implemented in the adiabatic calorimeter. The effect of the electric field parameters (frequency, profile, and strength) on the value of the effect and degree of its reversibility are studied. The difference between the temperature variation values in a switched-on and switched-off dc field under quasi-isothermal conditions is established. The low-frequency periodic electric field induces the temperature gradient along the electrocaloric element and heat flux from its free end to the thermostated base. A significant excess of the field switching-off rate over the switching-on rate leads to a noticeable intensification of the cooling effect.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev V. S., Flerov I. N., Gorev M. V., Pogoreltsev E. I., Molokeev M. S., Mikhaleva E. A., Shabanov A. V., Es'kov A. V.
Заглавие : Influence of thermal conditions on the electrocaloric effect in a multilayer capacitor based on doped BaTiO3
Место публикации : J. Adv. Dielectr. - 2017. - Vol. 7, Is. 6. - Ст.1750041. - ISSN 2010-135X, DOI 10.1142/S2010135X17500412. - ISSN 2010-1368
Примечания : Cited References: 32. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research, project no. 16-42-240428 r_a, and partially financially supported by Government of Russian Federation, Grant 074-U01.
Ключевые слова (''Своб.индексиров.''): electrocaloric effect--ferroelectrics--layered structures--nonequilibrium conditions--phase transitions
Аннотация: We present the results of studies of thermal expansion, heat capacity, permittivity, polarization and the influence of different thermal conditions on the intensive electrocaloric effect (ECE), ΔTAD, in a commercial multilayer capacitor based on doped BaTiO3. Investigations in a wide temperature range revealed one anomaly in the behavior of the physical properties at about 290K characteristic for the relaxors. Direct measurements showed a high reversibility of ECE under equilibrium thermal conditions. Good agreement was found between the values of ΔTAD determined by direct and indirect measurements at the electric field up to 15.4 kV/cm. Quasi-isothermal conditions lead, firstly, to decrease of large ΔTAD ≈0.94K obtained in adiabatic conditions under E = 308 kV/cm to 0.87 K, and, secondly, the appearance of a difference between the values of ΔTON and ΔTOFF determined when the electric field is applied and removed. Using this phenomenon and changing the frequency of the periodic electric field, E = 15.4 kV/cm, the effect of cooling was obtained equal to [(ΔTON + ΔT OFF)/2]max = -0,032 K. The results obtained are useful for further development of the electrocaloric refrigeration technique without thermal switches.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev V. S., Flerov I. N., Gorev M. V., Pogoreltsev E. I., Molokeev M. S., Mikhaleva E. A., Shabanov A. V., Es'kov A. V.
Заглавие : Intensive electrocaloric effect in the multilayer capacitor under equilibrium and nonequilibrium thermal conditions
Место публикации : Scripta Mater. - 2018. - Vol. 146. - P.51-54. - ISSN 13596462 (ISSN), DOI 10.1016/j.scriptamat.2017.11.017
Примечания : Cited References: 27. - The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research, project no. 16-42-240428 r_a. A. V. Es'kov acknowledges the support from the Government of Russian Federation under grant 074-U01.
Ключевые слова (''Своб.индексиров.''): electrocaloric effect--phase transition--ferroelectrics
Аннотация: Precise direct measurements of the intensive electrocaloric effect (ECE) in commercial multilayer capacitor based on doped BaTiO3 were performed using an adiabatic calorimeter. High reversibility of ECE studied under equilibrium thermal conditions was observed. The nonequilibrium thermal conditions caused by fixing the temperature of one of the ends of the linear EC element lead to the predominance of ECE when the electric field is turned off. The heat flow through the EC element appearing under the influence of a periodic electric field and depending on its frequency makes it possible to create a cooling cycle without thermal keys.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev V. S., Mikhaleva E. A., Gorev M. V., Flerov I. N.
Заглавие : Intensive electrocaloric effect in triglycine sulfate under nonequilibrium thermal conditions and periodic electric field
Коллективы : RFBR; Government of Krasnoyarsk Territory [16-42-240428 p_a]
Место публикации : Phys. Status Solidi B. - 2016. - Vol. 253, Is. 10. - P.2073-2078. - ISSN 0370-1972, DOI 10.1002/pssb.201600339. - ISSN 1521-3951(eISSN)
Примечания : Cited References:29. - The reported study was funded by RFBR and Government of Krasnoyarsk Territory according to the research project no. 16-42-240428 p_a.
Ключевые слова (''Своб.индексиров.''): electrocaloric effect--ferroelectrics--nonequilibrium processes--phase--transitions
Аннотация: We present the results of both direct measurements and modeling of the intensive electrocaloric effect ΔTAD in ferroelectric triglycine sulfate under nonequilibrium thermal conditions and periodically varying electric field. In the narrow region around the phase transition temperature TC, a visible difference was observed between the electrocaloric responses at applying ΔTON and removal ΔTOFF of the constant electric field: |ΔTON| |ΔTOFF| and |ΔTON| |ΔTOFF| at T TC and T TC, respectively. The variation of the frequency and profile of the periodic electric field at T TC allowed one to obtain the gradual decrease in the average temperature of the top of the sample compared to the bottom kept at the constant temperature. At low frequency electric field, qualitative agreement was found between the time dependences of the measured experimentally and calculated ΔT values. Experimental and modeling studies of electrocaloric effect ΔTAD in triglycine sulfate showed that the applying/removal of a periodic electric field to/from the bulk sample decreases the average value of the waiving temperature of the top Ttop compared to T ≃ const of the bottom. Both frequency and duty cycle of the electric field impulses strongly affect Ttop.
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