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    Музалевский, Константин Викторович.
    Дистанционное измерение профилей влажности в пахотном слое почвы на основе поляриметрических наблюдений коэффициента отражения в P- и C-диапазонах частот. Эксперимент / К. В. Музалевский // Соврем. проблемы дистанц. зондир. Земли из космоса. - 2020. - Т. 17, № 3. - С. 145-148, DOI 10.21046/2070-7401-2020-17-3-145-148. - Библиогр.: 5. - Работа выполнена в рамках проекта Российского фонда фундаментальных исследований № 18-05-00405, методика измерения коэффициентов отражения была развита при поддержке проекта государственного задания № 0356-2019-0004 . - ISSN 2070-7401. - ISSN 2411-0280
   Перевод заглавия: Remote sensing of moisture profiles in the arable soil layer based on polarimetric observations of the reflection coefficient in the P- and C-bands. Experiment
Кл.слова (ненормированные):
радиолокация -- беспилотный летательный аппарат -- агропочвы -- влажность почвы -- пахотный слой -- диэлектрическая проницаемость -- Radar -- Unmanned aerial vehicle -- Agricultural soils -- Soil moisture -- Arable layer -- Dielectric constant
Аннотация: В данном сообщении экспериментально подтверждена принципиальная возможность дистанционного измерения профилей влажности в пахотном слое почвы с пригодной для практического применения точностью на основе поляриметрических измерений коэффициента отражения на двух частотах 630 МГц и 5,4 ГГц. Коэффициенты отражения измерялись под углом 35° импульсным методом в ходе естественных циклов испарения и увлажнения пахотного слоя почвы на участке сельскохозяйственного поля, находящегося под паром в районе пос. Минино, Красноярский край. Профили влажности почвы восстанавливались в ходе решения обратной задачи, информативным признаком в которой выступало отношение коэффициентов обратного радарного рассеяния на согласованных линейных поляризациях. Отношение коэффициентов обратного радарного рассеяния было оценено в скалярном приближении метода Кирхгофа в виде отношения коэффициентов отражения по мощности, измеренных на горизонтальной и вертикальной поляризациях. Среднеквадратическое отклонение и коэффициент детерминации между восстановленными и измеренными значениями объёмной влажности в поверхностном слое почвы толщиной 10 см оказались равны 2,2 % и 0,91 соответственно. Исследование показывает перспективность разработки поляриметрических многочастотных радиолокационных систем комбинированного сверхвысокочастотного и дециметрового диапазонов для дистанционного зондирования профилей влажности пахотного слоя почв.
This report experimentally confirmed the fundamental possibility of remote sensing of moisture profiles in the arable soil layer with practical acceptable accuracy based on polarimetric measurements of the reflection coefficient at two frequencies of 630 MHz and 5.4 GHz. Reflection coefficients were measured at an angle of 35° by the impulse method, during natural cycles of the evaporation and moistening of soil arable layer in a plot of an agricultural field under steam in the area of Minino village, Krasnoyarsk region. Soil moisture profiles were retrieved in the course of solving the inverse problem, in which cost function was the ratio of the backscattering coefficients taken on coincident linear polarizations. The ratio of the backscattering coefficients was estimated by the scalar Kirchhoff approximation in the form of a ratio of power reflection coefficients, which were measured on horizontal and vertical polarizations. The standard deviation and the determination coefficient between the retrieved and measured soil moisture in the 10 cm topsoil were 2.2 % and 0.91, respectively. The study shows the prospects of developing polarimetric multi-frequency radar systems of combined UHF and SHF bands for remote sensing of moisture profiles in the arable layer of soils.

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Держатели документа:
Kirensky Institute of Physics SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Muzalevskiy, K. V.
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Wüstite stability in the presence of a CO2-fluid and a carbonate-silicate melt: Implications for the graphite/diamond formation and generation of Fe-rich mantle metasomatic agents / Y. V. Bataleva [et al.] // Lithos. - 2016. - Vol. 244. - P. 20-29, DOI 10.1016/j.lithos.2015.12.001. - Cited References: 68. - This work was supported by the Russian Science Foundation under grant no. 14-27-00054. The authors thank A. Moskalev for his assistance in the work preparation, A. Khokhryakov for useful suggestions throughout the study, and S. Ovchinnikov for his assistance in implementation of Mössbauer spectroscopy measurements. The authors thank editor M. Scambelluri, and two anonymous reviewers for their useful comments, which helped to profoundly improve the manuscript. . - ISSN 0024-4937

РУБ Geochemistry & Geophysics + Mineralogy
Рубрики:
EARTHS LOWER MANTLE
   FERRIC IRON CONTENT
   DIAMOND FORMATION
   MINERAL INCLUSIONS
   NATURAL DIAMOND
   OXIDATION-STATE
   DEEP MANTLECRUST
   LITHOSPHERIC MANTLE
   OXYGEN FUGACITY
   OCEANIC-CRUST
Кл.слова (ненормированные):
Wustite -- CO2-fluid -- Carbonate-silicate melt -- Decarbonation -- Graphite formation -- HPHT experiment
Аннотация: Experimental simulation of the interaction of wüstite with a CO2-rich fluid and a carbonate-silicate melt was performed using a multianvil high-pressure split-sphere apparatus in the FeO-MgO-CaO-SiO2-Al2O3-CO2 system at a pressure of 6.3GPa and temperatures in the range of 1150°C-1650°C and with run time of 20h. At relatively low temperatures, decarbonation reactions occur in the system to form iron-rich garnet (Alm75Prp17Grs8), magnesiowüstite (Mg#≤0.13), and CO2-rich fluid. Under these conditions, magnesiowüstite was found to be capable of partial reducing CO2 to C0 that leads to the formation of Fe3+-bearing magnesiowüstite, crystallization of magnetite and metastable graphite, and initial growth of diamond seeds. At T≥1450°C, an iron-rich carbonate-silicate melt (FeO~56wt.%, SiO2~12wt.%) forms in the system. Interaction between (Fe,Mg)O, SiO2, fluid and melt leads to oxidation of magnesiowüstite and crystallization of fayalite-magnetite spinel solid solution (1450°C) as well as to complete dissolution of magnesiowüstite in the carbonate-silicate melt (1550°C-1650°C). In the presence of both carbonate-silicate melt and CO2-rich fluid, dissolution (oxidation) of diamond and metastable graphite was found to occur. The study results demonstrate that under pressures of the lithospheric mantle in the presence of a CO2-rich fluid, wüstite/magnesiowüstite is stable only at relatively low temperatures when it is in the absolute excess relative to CO2-rich fluid. In this case, the redox reactions, which produce metastable graphite and diamond with concomitant partial oxidation of wüstite to magnetite, occur. Wüstite is unstable under high concentrations of a CO2-rich fluid as well as in the presence of a carbonate-silicate melt: it is either completely oxidized or dissolves in the melt or fluid phase, leading to the formation of Fe2+- and Fe3+-enriched carbonate-silicate melts, which are potential metasomatic agents in the lithospheric mantle. © 2015 Elsevier B.V.

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Держатели документа:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug ave 3, Novosibirsk, Russian Federation
Novosibirsk State University, Pirogova str 2, Novosibirsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Y .N.; Sokol, A. G.; Borzdov, Y. M.; Bayukov, O. A.; Баюков, Олег Артемьевич
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The role of rocks saturated with metallic iron in the formation of ferric carbonate-silicate melts: experimental modeling under PT-conditions of lithospheric mantle / Y. V. Bataleva [et al.] // Russ. Geol. Geophys. - 2015. - Vol. 56, Is. 1-2. - P. 143-154, DOI 10.1016/j.rgg.2015.01.008. - Cited References:68. - This work was supported by Integration project 31 from the Siberian Branch of the Russian Academy of Sciences and by grant 12-05-00740 from the Russian Foundation for Basic Research. . - ISSN 1068. - ISSN 1878-030X. -

РУБ Geosciences, Multidisciplinary
Рубрики:
OXYGEN FUGACITY
   DIAMOND FORMATION
   OXIDATION-STATE
   EARTHS MANTLE
Кл.слова (ненормированные):
carbonate-silicate melt -- graphite -- CO2 fluid -- iron carbide -- garnet -- redox gradient -- high-pressure experiment
Аннотация: Experimental modeling of the processes of formation of ferric carbonate-silicate melts through the carbonate-oxide-metal interaction is performed in the (Mg,Ca)CO3-SiO2-Al2O3-Fe0 system at 6.3 and 7.5 GPa and within 1150-1650 °C, using a multianvil high-pressure apparatus of “split-sphere” type (BARS). Two parallel reactions run in the subsolidus region (1150-1450 °C): decarbonation, producing pyrope-almandine (Fe# = 0.40-0.75) and CO2 fluid, and redox interaction between carbonate and Fe0, resulting in the crystallization of iron carbide in assemblage with magnesiowustite (Fe# = 0.75-0.85). It is shown that the reduction of carbonate or CO2 fluid by iron carbide and parallel redox interaction of magnesiowustite with CO2 produce graphite in assemblage with Fe3 + -containing magnesiowustite. In the temperature range of 1450-1650 °C, generation of carbonate-silicate melts coexisting with pyrope-almandine, magnesiowustite, magnetite, ferrospinel, and graphite takes place. The composition of the produced melts is as follows: SiO2 - 10-15 wt.%, X(FeO + Fe2O3) = 36-43 wt.%, and Fe3+/XFe - 0.18-0.23. These Fe3 + -enriched carbonate-silicate melts/fluids are saturated with carbon and are the medium of graphite crystallization. Oxide and silicate phases (almandine, ferrospinel, and magnetite) coexisting with graphite are also characterized by high Fe3+/XFe values. It has been established that Fe3 + -enriched carbonate-silicate melts can result from the interaction of Fe0-containing rocks with carbonated rocks. In the reduced mantle (with the presence of iron carbides or oxides), melts of this composition can be the source of carbon and the medium of graphite crystallization at once. After separation and ascent, these ferric carbonate-silicate melts can favor oxidizing metasomatism in the lithospheric mantle.

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Публикация на русском языке Роль пород, содержащих самородное железо, в образовании железистых карбонатно-силикатных расплавов: экспериментальное моделирование при P-T-параметрах литосферной мантии [Текст] / Ю. В. Баталева [и др.] // Геол. и геофиз. - Новосибирск : Изд-во СО РАН, 2015. - Т. 56 № 1-2. - С. 188-203

Держатели документа:
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Novosibirsk State Univ, Novosibirsk 630090, Russia.

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Yu. N.; Sokol, A. G.; Borzdov, Yu. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Siberian Branch of the Russian Academy of Sciences [31]; Russian Foundation for Basic Research [12-05-00740]
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    Switchable ionic selectivity of membranes with electrically conductive surface: Theory and experiment / I. I. Ryzhkov, M. A. Shchurkina, E. V. Mikhlina [et al.] // Electrochim. Acta. - 2021. - Vol. 375. - Ст. 137970, DOI 10.1016/j.electacta.2021.137970. - Cited References: 67. - This work is supported by the Russian Foundation for Basic Research , Project 18-38-20046 . The physicochemical analysis of materials was carried out in Krasnoyarsk Regional Center of Research Equipment of Federal Research Center 'Krasnoyarsk Science Center SB RAS' . - ISSN 0013-4686. - ISSN 1873-3859
   Перевод заглавия: Переключаемая ионная селективность мембран с электропроводящей поверхностью: теория и эксперимент

РУБ Electrochemistry

Кл.слова (ненормированные):
Nanoporous membrane -- Carbon coating -- Switchable ionic selectivity -- Space charge model -- Uniform potential model
Аннотация: Nanoporous membranes with electrically conductive surface represent an important class of stimuli–responsive materials. The variation of surface potential provides a powerful tool for adjusting ionic selectivity, conductivity, and rejection. This work is devoted to the theoretical and experimental study of switchable ionic selectivity. The one–dimensional Space charge (SC) and two–dimensional Uniform potential (UP) models are first generalized to constant surface potential case taking into account the Stern layer with inner (iHp) and outer (oHp) Helmholtz planes. The ionic selectivity is investigated experimentally by measuring the membrane potential at zero current for C–Nafen membranes prepared from alumina nanofibers with conductive carbon coating. The evolution of charging current is used to determine the dependence of surface charge density and differential capacitance on the applied potential. These data are fitted by the UP and SC models to find the Stern layer capacitance. It is shown that the variation of surface potential results in a continuous change of ionic selectivity from anion to cation. The membrane potential data are fitted by the UP and SC models using the chemical charge density and concentration boundary layer thickness as fitting parameters. It allows to determine the potential, at which the membrane becomes non–selective. The SC and UP models provide close results for membrane potential and surface charge density and demonstrate a good agreement with the experimental data. The UP model overestimates the solution velocity and ion concentrations at the membrane surface, while it underestimates the ion fluxes and iHp/oHp potentials. This work essentially extends our understanding of ion transport in stimuli–responsive membranes operated by the electric field. The results can be applied in the area of nanofiltration, (reverse) electrodialysis, electrochemical sensors, and nanofluidic devices.

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Держатели документа:
Inst Computat Modelling SB RAS, Akademgorodok 50-44, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Svobodny 79, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Akademgorodok 50, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Ryzhkov, Ilya I.; Shchurkina, Margarita A.; Mikhlina, Elena, V; Simunin, Mikhail M.; Nemtsev, I. V.; Немцев, Иван Васильевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-38-20046]
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    Structural properties and high-temperature spin and electronic transitions in GdCoO3: Experiment and theory / Yu. S. Orlov [et al.] // Phys. Rev. B. - 2013. - Vol. 88, Is. 23. - Ст. 235105. - P. , DOI 10.1103/PhysRevB.88.235105 . - ISSN 1098-0121
   Перевод заглавия: Структурные свойства и высокотемпературные спиновые и электронные переходы в GdCoO3: эксперимент и теория
Аннотация: We have investigated the x-ray diffraction (XRD) structure, magnetic susceptibility, and heat capacity of GdCoO3 in a wide temperature range. A model of phase separation of the low-spin (LS) and high-spin (HS) states has been proposed based on the analysis of XRD peak shape anomalies in the temperature range 200-800 K. From magnetic measurements we separated the HS Co3+ contribution and fitted it with the temperature-dependent spin gap. We found a smooth LS-HS crossover at T=800 K. The possible contribution of the intermediate spin (IS) state to the thermodynamics is excluded by the calculation IS-LS excitation energy within the modified crystal-field approach. In the two-phase model, with HS/LS probabilities calculated from the found spin gap and the LS and HS volumes calculated by the DFT-GGA method, we were able to reproduce the temperature dependence of the unit-cell volume and thermal expansion. Thus, we conclude that in GdCoO3 the main mechanism of the lattice expansion is not the conventional lattice anharmonicity, but the HS/LS fluctuations. The electronic structure has been calculated by the LDA+GTB method. At zero temperature, we have obtained the charge-transfer insulator with the charge gap Eg=0.5 eV. The thermal population of the HS term results in the in-gap band formation inside the insulator gap and smooth insulator-metal transition at TIMT=780 K. Heat-capacity measurements revealed a smooth maximum near the TIMT. © 2013 American Physical Society.

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Держатели документа:
Russian Acad Sci, LV Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660049, Russia
Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia
Natl Acad Sci Ukraine, OO Galkin Donetsk Inst Phys & Engn, UA-83114 Donetsk, Ukraine
MF Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia;

Доп.точки доступа:
Orlov, Yu.S.; Орлов, Юрий Сергеевич; Solovyov, L. A.; Соловьев, Леонид Александрович; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Kazak, N. V.; Казак, Наталья Валерьевна; Voronov, V. N.; Воронов, Владимир Николаевич; Vereshchagin, S. N.; Shishkina, N. N.; Perov, N. S.; Lamonova, K. V.; Babkin, R.Yu.; Pashkevich, Yu.G.; Anshits, A. G.; Аншиц, Александр Георгиевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
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Structural properties and high temperature spin and electronic transitions in GdCoO[[d]]3[[/d]]: experiment and theory [Текст] / Yu. S. Orlov [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P200 . - ISBN 978-5-7444-3124-2

Доп.точки доступа:
Orlov, Yu.S.; Орлов, Юрий Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
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    Single crystal growth and the electronic structure of Rb2Na(NO3)3: Experiment and theory / K. E. Korzhneva, V. L. Bekenev, O. Y. Khyzhun [et al.] // J. Solid State Chem. - 2021. - Vol. 294. - Ст. 121910, DOI 10.1016/j.jssc.2020.121910. - Cited References: 54. - This work was done on state assignment of IGM SB RAS, Ministry of Science and Higher Education of the Russian Federation; NSU BCH-2020-0036-4 (10988) (XRD analysis), and was supported by Russian Foundation for Basic Research (grants Nos. 18-32-00359 , 19-42-540012) . - ISSN 0022-4596
   Перевод заглавия: Рост монокристалла и электронная структура Rb2Na(NO3)3: эксперимент и теория
Кл.слова (ненормированные):
Double nitrates -- Crystal growth -- Electronic structure -- Nonlinear optical materials -- X-ray photoelectron spectroscopy
Аннотация: Rb2Na(NO3)3 crystals demonstrate nonlinear optical properties and can be used as a converter of laser radiation in the shortwave region. The crystals were grown in the present work by the Bridgman–Stockbarger method in a ratio of 75 wt%(RbNO3) and 25 wt%(NaNO3). After the growth, a transparent centimeter size single crystal (6 cm long) was obtained for the first time that is very important for its practical application. The unit cell volume of double Rb2Na(NO3)3 nitrate is intermediate between the cell volumes of simple rubidium and sodium nitrates, RbNO3 and NaNO3. Electronic structure of Rb2Na(NO3)3 was studied in the present work from both experimental and theoretical viewpoints. In particular, employing X-ray photoelectron spectroscopy, we have measured binding energies of core electrons and energy distribution of the electronic states within the valence band region of the Rb2Na(NO3)3 crystal and established rather big binding energies for N 1s and O 1s core-level electrons. The bombardment of middle-energy Ar+ ions induces transformation of some nitrogen atoms of the analyzing topmost layers of the Rb2Na(NO3)3 crystal surface from the NO3– group to the NO2– group. To explore in detail the filling of the valence band of Rb2Na(NO3)3 by electronic states associated with constituting atoms, we use first-principles calculations within a density functional theory (DFT) framework. The DFT calculations reveal that O 2p states are the principal contributors to the valence band bringing the main input in its upper portion. The theoretical finding is supported experimentally by fitting the X-ray photoelectron valence band spectrum and the X-ray emission O Kα band on the total energy scale. The conduction band bottom of Rb2Na(NO3)3 is composed by unoccupied O 2p and N 2p states in almost equal proportion.

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Держатели документа:
Novosibirsk State University, Novosibirsk, 630090, Russian Federation
V.S. Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk, 630090, Russian Federation
Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, 3 Krzhyzhanovsky StreetKyiv UA-03142, Ukraine
Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Korzhneva, K. E.; Bekenev, V. L.; Khyzhun, O. Y.; Goloshumova, A. A.; Tarasova, A. Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Isaenko, L. I.; Kurus, A. F.
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Raman spectroscopy of SrLnCuS3 (Ln = La, Nd, Tm): experiment and ab initio calculation / S. N. Krylova, V. А. Chernyshev, A. V. Ruseikina [et al.] // XVIII International Feofilov symposium on spectroscopy of crystals doped with rare earth and transition metal ions (IFS-2022) : book of abstracts : Aug. 22-27, 2022, Moscow, Russia. - 2022. - P. 71-72. - Библиогр.: 8. - The work of Krylova S. was financially supported by the Russian Foundation for Basic Research and DFG project number No 21-52-12018. The research of Ruseikina A. was supported by the Tyumen region within the framework of the grant agreement in the form of a grant to non-profit organizations no. 89-don dated 07.12.2020. Chernyshev V. thanks the Ministry of Science and Higher Education of the Russian Federation (project no. FEUZ-2020-0054) for financial support. . - ISBN 978-5-89513-513-6
Аннотация: The Raman spectra of SrLaCuS3, SrNdCuS3, SrTmCuS3 compounds have been investigated. Ab initio calculations of the crystal structure and phonon spectrum of the compounds have been carried out. The types and wave numbers of the fundamental modes have been determined. The experimental Raman spectra have been interpreted.

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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russia
Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, 620002, Russia
Institute of Chemistry, University of Tyumen, Tyumen, 625003, Russia

Доп.точки доступа:
Krylova, S. N.; Крылова, Светлана Николаевна; Chernyshev, V. А.; Ruseikina, A. V.; Grigoriev, M. V.; Aleksandrovskiy, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; International Feofilov symposium on spectroscopy of crystals doped with rare earth and transition metal ions(18 ; 2022 ; Aug. ; Moscow); Физический институт им. П.Н. Лебедева РАН; Институт спектроскопии РАН
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Quasi-bound States in the Continuum in a Finite Chain of Dielectric Scatterers: Theory and Experiment / M. Balyzin [et al.] ; ed.: W. C. Chew, S. . He // Progress in Electromagnetics Research Symposium (PIERS-Toyama) : IEEE, 2018. - Vol. 2018-August. - P. 2516-2519. - (Progress in Electromagnetics Research Symposium), DOI 10.23919/PIERS.2018.8598011. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research (16-37-60064, 17-02-01234, 16-02-00314), the Ministry of Education and Science of the Russian Federation (3.1668.2017/4.6), the President of Russian Federation (MK-403.2018.2). . -

РУБ Engineering, Electrical & Electronic + Physics, Applied
Рубрики:
LIGHT
Аннотация: In this work we experimentally observe a symmetry protected optical bound state in the continuum (BIC) with zero angular momentum in 1D array of ceramic disks at GHz frequencies. We analyze the dependence of Q factor of BIC on the number of the disks and the level of the material losses. We confirmed theoretical prediction about quadratic growth of the Q factor with the number of the disks and its following saturation due to material losses.

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Держатели документа:
ITMO Univ, Dept Nanophoton & Metamat, St Petersburg, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.

Доп.точки доступа:
Balyzin, M.; Sadrieva, Z.; Belyakov, M. A.; Kapitanova, P.; Sadreev, A. F.; Садреев, Алмаз Фаттахович; Bogdanov, A. A.; Chew, W.C. \ed.\; He, S... \ed.\; Russian Foundation for Basic Research [16-37-60064, 17-02-01234, 16-02-00314]; Ministry of Education and Science of the Russian Federation [3.1668.2017/4.6]; Russian Federation [MK-403.2018.2]; Progress in Electromagnetics Research Symposium 2018(Aug 01-04, 2018 ; Toyama, Japan)
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10.

    Processes and conditions of the origin for Fe3+-bearing magnesiowustite under lithospheric mantle pressures and temperatures / Y. Bataleva [et al.] // Minerals. - 2019. - Vol. 9, Is. 8. - Ст. 474, DOI 10.3390/min9080474. - Cited References: 82. - This research was performed by state assignment of IGM SB RAS (project No. 0330-2016-0007). . - ISSN 2075-163X
   Перевод заглавия: Процессы и условия зарождения магнезиовюстита, несущего Fe3+, при давлении и температуре литосферной мантии
Рубрики:
Mineral Geochemistry and Geochronology
Кл.слова (ненормированные):
Fe3+-bearing magnesiowustite -- Mantle oxides -- Experimental modeling -- High-pressure experiment -- Redox reactions -- Lithospheric mantle -- Diamond -- Graphite
Аннотация: An experimental study, implicated in the revealing of the conditions for the origin for Fe3+-bearing magnesiowüstite in the lithospheric mantle, was performed using Mössbauer spectroscopy of pre-synthesized samples. Experiments were carried out using a multi-anvil high-pressure split-sphere apparatus at 6.3–7.5 GPa, in the range of 1100–1650 °C in carbonate-metal, carbonate–oxide-metal, carbonate-oxide, carbide-oxide and carbonate–metal-sulphur systems. In three experimental series, oxygen fugacity gradient in the samples was created, which enabled the study of the processes of magnesiowüstite formation under oxidizing and reducing conditions (ΔlogfO2 (FMQ) values from −1 to −5). It was established that Fe3+-bearing magnesiowüstite can form both in assemblage with oxidized phases, such as carbonate or with reduced ones—metal, carbides, sulphides, graphite and diamond. According to the Mössbauer spectroscopy, the composition of synthesized magnesiowüstite varied within a range of Fe3+/ΣFe values from 0 to 0.3, with IV and VI coordination of Fe3+ depending on P, T, fO2, x-parameters. It was established that Fe3+-bearing magnesiowüstite formation processes under upper mantle P,T-conditions include redox reactions, with magnesiowüstite being (1) reductant or (2) product of interaction, (3) crystallization processes of magnesiowüstite from an oxidized melt, where magnesiowüstite acts as a sink for ferric iron and (4) iron disproportionation.

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Держатели документа:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug ave 3, Novosibirsk, 630090, Russian Federation
Department of Geology and Geophysics, Novosibirsk State University, Pirogova str 2, Novosibirsk, 630090, Russian Federation
Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Bataleva, Y.; Palyanov, Y.; Borzdov, Y.; Bayukov, O. A.; Баюков, Олег Артемьевич
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