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Direct and indirect studies of the electrocaloric effect in single crystalline ferrielectric (NH4)2SO4 / V. S. Bondarev, E. A. Mikhaleva, M. V. Gorev, I. N. Flerov> // J. Alloys Compd. - 2022. - Vol. 892. - Ст. 162130, DOI 10.1016/j.jallcom.2021.162130. - Cited References: 38. - The reported study was supported by the Russian Science Foundation (project no. 19-72-00023)
. - ISSN 0925-8388 Кл.слова (ненормированные): Ferrielectric -- Electrocaloric effect -- Phase transition -- Entropy Аннотация: The influence of an electric field on the phase transition parameters and the electrocaloric response in ferrielectric (NH4)2SO4 was studied using a universal multifunctional adiabatic calorimeter. The very low sensitivity of the phase transition temperature to the electric field, dT0/dE ≈ 5·10-3 K/(kV/cm), was shown to be the reason for the low maximum value of the intensive electrocaloric effect, ΔTAD, at E = 11 kV/cm: direct and indirect measurements gave the values of 0.01 K and 0.05 K, respectively. However, the extensive electrocaloric response revealed by an analysis of the entropy–temperature–electric field phase diagram was relatively large, with a value of ΔSECE ≈ − 19 J/kg K, due to the significant contribution of a jump in the excess entropy to the total value, δS0/ΔS0 ~ 0.37. An additional irreversible increase in temperature under the electric field was associated with the Joule effect and indicated a significant electrical conductivity of ammonium sulphate.
Смотреть статью, Scopus, WOS, Читать в сети ИФ Держатели документа: Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660074, Russian Federation Доп.точки доступа: Bondarev, V. S.; Бондарев, Виталий Сергеевич; Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич } Найти похожие
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