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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tetelbaum D., Nikolskaya A., Dorokhin M., Vasiliev V., Smolyakov D. A., Lukyanenko A. V., Baron F. A., Tarasov A. S.
Заглавие : Implanted gallium impurity detection in silicon by impedance spectroscopy
Место публикации : Mater. Lett. - 2022. - Vol. 308, Part B. - Ст.131244. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2021.131244
Примечания : Cited References: 11. - This study was supported by the Russian Foundation for Basic Research (grant No. 20-42-243007), Ministry of Science and Higher Education of the Russian Federation (project No. 075-03-2020-191/5), as well as the Government of the Russian Federation within the framework of the Megagrant for the creation of world-class laboratories (No. 075-15-2019-1886)
Аннотация: The results of determining the energy levels of boron-doped silicon implanted with gallium ions by impedance spectroscopy are reported. In the as-implanted sample the boron level remains the same and a second level appears close to the Ga-level reported in literature. In the sample annealed at 1000 °C, two levels are observed neither of which corresponds to the literature values for boron and gallium. It is assumed that in the as-implanted sample this method detects levels of gallium atoms located at a depth where ions penetrate due to the channeling effect, since a large concentration of defects at shallower depths does not allow detection of energy levels due to the Fermi level pinning. Explaining the results for the sample annealed after implantation requires additional research. The main result of this work is to establish the possibility of detecting impurity levels in ion-implanted silicon by impedance spectroscopy even in the absence of subsequent annealing.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen Y., Liu F., Zhang Z., Hong J., Molokeev M. S., Bobrikov I. A., Shi J., Zhou J., Wu M.
Заглавие : A novel Mn4+-activated fluoride red phosphor Cs30(Nb2O2F9)9(OH)3·H2O:Mn4+ with good waterproof stability for WLEDs
Место публикации : J. Mater. Chem. C. - 2022. - Vol. 10, Is. 18. - P.7049-7057. - ISSN 20507534 (ISSN), DOI 10.1039/d2tc00132b
Примечания : Cited References: 56. - This work was financially supported by grants from the National Natural Science Foundation of China (NSFC) (No. 51802359), the Joint Funds of NSFC and Yunnan Province (No. U1702254), and Guangdong Basic and Applied Basic Research Foundation (No. 2020A1515010556)
Аннотация: Red-light-emitting materials, as pivotal components of warm white light-emitting diodes (WLEDs), have drawn increasing public focus. Among these, Mn4+-doped red light-emitting fluorides have drawn considerable attention when combined with an InGaN chip; however, they suffer from poor water stability under humid conditions. In this work, a novel fluoride red phosphor, Cs30(Nb2O2F9)9(OH)3·H2O:xMn4+ (CNOFM), with good water resistance was synthesized for the first time using a facile co-precipitation method at ambient temperature. Experiments were implemented for the precise analysis of its crystal structure, optical properties, micro-morphology, thermal behavior, and waterproof properties. 6.66% Mn4+-doped CNOFM maintained a stable crystal structure and possessed strong PL intensity located at 633 nm with high color purity of 96%. CNOFM showed better thermal and waterproof stability compared with the commercial K2SiF6:Mn4+ red phosphor. Without any surface modifications, the PL intensity remained at about 83% of the initial value after immersion in water for 60 min, and the mechanism was investigated. Finally, a warm WLED with a CRI of 92.3 and CCT of 3271 K was fabricated using the CNOFM red phosphor.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moshkina E. M., Krylov A. S., Kokh D., Shabanova K., Molokeev M. S., Bovina A. F., Plyaskin M., Rostovtsev N., Bezmaternykh L. N.
Заглавие : Multicomponent flux growth and composition control of Cu2MnBO5:Ga ludwigites
Место публикации : CrystEngComm. - 2022. - Vol. 24, Is. 19. - P.3565-3575. - ISSN 14668033 (ISSN), DOI 10.1039/d2ce00258b
Примечания : Cited References: 26. - This study was supported by the Russian Science Foundation (Grant No. 21-72-00130). The Raman, X-ray, and EDX data were obtained using the analytical equipment of the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center “Krasnoyarsk Science Center SB RAS”
Аннотация: To reach the concentration phase boundary between antiferromagnetic Cu2GaBO5 and ferrimagnetic Cu2MnBO5 ludwigites, solid solutions Cu2Mn1−xGaxBO5 (x = 0.05, 0.1, 0.15, 0.175) were grown by the flux technique using a multi-component solvent based on Bi2Mo3O12 with the addition of Na2B4O7 which significantly influenced the crystal formation and cation composition of the studied compounds. The content of the flux system was corrected taking into account the earlier established relationship of the partition coefficients of Mn2O3 and Ga2O3. The influence of the solvent components on the ludwigite crystallization was analyzed. The maximum size of the grown crystal was 1 × 1 × 4 mm3. The structure and cation composition of the grown compounds were studied using X-ray (X-ray diffraction, EDX (energy-dispersive X-ray spectroscopy)) and vibrational (Raman) spectroscopy techniques. The phase boundary of Cu2MnBO5–Cu2GaBO5 was found to be in the concentration range of x = 0.15–0.175, corresponding to a change in the monoclinic axis direction and a leap in the lattice parameters. The symmetry evolution of metal–oxygen octahedra for four nonequivalent cation positions was analyzed, and the unique crystal structure of Cu2MnBO5 demonstrated high rigidity relative to the introduction of Ga3+ cations. The polarized Raman spectra of monoclinic ludwigites were obtained and studied for the first time. A comparison of the spectra of the studied samples in both phases and orthorhombic ludwigites was made. A number of spectral features due to the monoclinic distortions in the crystal were found. In agreement with the Raman experiment, the concentration phase boundary was close to 0.15.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Volochaev M. N., Ishibashi T.
Заглавие : Coexistence of the electric polarization and conductive current in the bismuth–neodymium ferrite garnet films
Место публикации : J. Mater. Sci. Mater. Electron. - 2021. - Vol. 32. - P.3766-3781. - ISSN 09574522 (ISSN), DOI 10.1007/s10854-020-05121-9
Примечания : Cited References: 42
Аннотация: The Nd1Bi2Fe5O12/Nd2Bi1Fe4Ga1O12 polycrystalline films on the glass substrate and the Nd0.5Bi2.5Fe5O12 epitaxial films on the single-crystal gadolinium gallium garnet substrate have been investigated by impedance and dielectric spectroscopy. The inductive contribution to the impedance and two relaxation channels related to ferroelectric domains and migration polarization have been established. The magnetocapacitance and magnetoimpedance have been determined. The conductive and polarization currents and the phase difference between them for the films of two types have been determined. The critical temperatures of the polarization disappearance and hysteresis I–V have been found. A model of the polarization caused by the piezoelectric effect and flexoelectric interaction has been proposed. I–V hysteresis is explained by the presence of ferroelectric domains near the interface and is associated with the hysteresis of the electric polarization.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kulbakov A. A., Sarkar R., Janson O., Dengre S., Weinhold T., Moshkina E. M., Portnichenko P. Y., Luetkens H., Yokaichiya F., Sukhanov A. S., Eremina R. M., Schlender P., Schneidewind A., Klauss H. -H., Inosov D. S.
Заглавие : Destruction of long-range magnetic order in an external magnetic field and the associated spin dynamics in Cu2GaBO5 and Cu2AlBO5 ludwigites
Место публикации : Phys. Rev. B. - 2021. - Vol. 103, Is. 2. - Ст.024447. - ISSN 24699950 (ISSN), DOI 10.1103/PhysRevB.103.024447
Примечания : Cited References: 46. - We thank U. Nitzsche for technical assistance. This project was funded in part by the German Research Foundation (DFG) under Grant IN 209/9-1, via Project C03 of the Collaborative Research Center SFB 1143 (project-id 247310070) at the TU Dresden, and the Würzburg-Dresden Cluster of Excellence on Complexity and Topology in Quantum Matter—ct.qmat (EXC 2147, project-id 390858490). O.J. was supported by the Leibniz Association through the Leibniz Competition
Аннотация: The quantum spin systems Cu2M′BO5 (M′=Al,Ga) with the ludwigite crystal structure consist of a structurally ordered Cu2+ sublattice in the form of three-leg ladders, interpenetrated by a structurally disordered sublattice with a statistically random site occupation by magnetic Cu2+ and nonmagnetic Ga3+ or Al3+ ions. A microscopic analysis based on density-functional-theory calculations for Cu2GaBO5 reveals a frustrated quasi-two-dimensional spin model featuring five inequivalent antiferromagnetic exchanges. A broad low-temperature 11B nuclear magnetic resonance points to a considerable spin disorder in the system. In zero magnetic field, antiferromagnetic order sets in below TN≈4.1 K and ∼2.4 K for the Ga and Al compounds, respectively. From neutron diffraction, we find that the magnetic propagation vector in Cu2GaBO5 is commensurate and lies on the Brillouin-zone boundary in the (H0L) plane, qm=(0.45,0,−0.7), corresponding to a complex noncollinear long-range ordered structure with a large magnetic unit cell. Muon spin relaxation is monotonic, consisting of a fast static component typical for complex noncollinear spin systems and a slow dynamic component originating from the relaxation on low-energy spin fluctuations. Gapless spin dynamics in the form of a diffuse quasielastic peak is also evidenced by inelastic neutron scattering. Most remarkably, application of a magnetic field above 1 T destroys the static long-range order, which is manifested in the gradual broadening of the magnetic Bragg peaks. We argue that such a crossover from a magnetically long-range ordered state to a spin-glass regime may result from orphan spins on the structurally disordered magnetic sublattice, which are polarized in magnetic field and thus act as a tuning knob for field-controlled magnetic disorder.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Ryabov V. V., Kargin Y. F., Chumilina L. G., Denisov V. M.
Заглавие : Crystal structure and thermodynamic properties of titanate ErGaTi2O7
Место публикации : Russ. J. Inorg. Chem. - 2021. - Vol. 66, Is. 4. - P.532-537. - ISSN 00360236 (ISSN), DOI 10.1134/S0036023621040082
Примечания : Cited References: 29
Аннотация: Erbium gallium titanate was prepared by solid-phase synthesis via the sequential calcination of precursor oxides in an air atmosphere at 1273 and 1573 K. The crystal structure of ErGaTi2O7 was characterized by full-profile analysis for the X-ray diffraction pattern of the synthesized powder sample as follows: space group Pcnb, a = 9.77326(15) Å, b = 13.5170(2) Å, c = 7.33189(11) Å, V = 918.58(3) Å3, ρ = 6.10 g/cm3. The high-temperature heat capacity of erbium gallium titanate was measured by differential scanning calorimetry within a temperature range of 320–1000 K. Based on these data, the basic thermodynamic functions of ErGaTi2O7 were calculated.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Irtyugo L. A., Beletskii V. V., Belousova N. V., Denisov V. M.
Заглавие : Structure and thermodynamic properties of the SmGaGe2O7 oxide
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P.384-387. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783420020109
Примечания : Cited References: 10. - This study was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation to the Siberian Federal University in 2017–2019, project no. 4.8083.2017/8.9 “Formation of a Data Bank of Thermodynamic Characteristics of the Complex-Oxide Multifunctional Materials Containing Rare and Scattered Elements.”
Аннотация: The SmGaGe2O7 oxide material has been obtained from initial Sm2O3, Ga2O3, and GeO2 oxides by solid-phase synthesis with annealing in air in the temperature range of 1273–1473 K. The structure of the investigated germanate (sp. gr. P21/c, a = 7.18610(9) Å, b = 6.57935(8) Å, and c = 12.7932(2) Å) has been established by X-ray diffraction and the high-temperature heat capacity has been determined by differential scanning calorimetry. Using the experimental data on Cp = f(T), the thermodynamic properties of the compound have been calculated.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moshkina E. M., Krylova S. N., Gudim I. A., Molokeev M. S., Temerov V. L., Pavlovskiy M. S., Vtyurin A. N., Krylov A. S.
Заглавие : Gallium composition-dependent structural phase transitions in HoFe3-xGax(BO3)4 solid solutions: crystal growth, structure, and Raman spectroscopy study
Место публикации : Cryst. Growth Des. - 2020. - Vol. 20, Is. 2. - P.1058-1069. - ISSN 15287483 (ISSN), DOI 10.1021/acs.cgd.9b01387
Примечания : Cited References: 30. - The reported study was funded by the Russian Foundation for Basic Research No. 18-02-00754. The experiments were performed using equipment of Center for Common Use, Krasnoyarsk Scientific Center, FSC SB RAS
Аннотация: Single crystals of solid solutions of HoFe3–xGax(BO3)4 with x = 0, 0.5, 1, 1.5, and 3 were obtained using flux synthesis. The conditions of the synthesis are described in detail. The structural properties of each of the synthesized samples were studied using X-ray powder diffraction analysis at several temperature points (303, 403, and 503 K). The structural parameters of the obtained samples and the “pure” compounds HoFe3(BO3)4 and HoGa3(BO3)4 were compared. The Raman spectra of the obtained solid solutions HoFe3–xGax(BO3)4 were studied in a wide temperature range (T = 10–400 K). The vibrational spectra and eigenvectors of the HoFe3Ga(BO3)4 and HoGa3(BO3)4 in R32 phase and HoFe3Ga(BO3)4 in P3121 phase were calculated within density functional theory. The features of the Raman spectra of HoFe2Ga(BO3)4, HoFe2.5Ga0.5(BO3)4, HoFe3(BO3)4 crystals associated with the R32 → P3121 structural phase transition, which have a strong dependence on the degree of substitution x, were investigated. Peculiarities of the Raman spectra, which are associated with magnetic ordering in HoFe1.5Ga1.5(BO3)4, HoFe2Ga(BO3)4, and HoFe2.5Ga0.5(BO3)4 crystals, were detected.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Chumilina L. G., Kargin Y. F., Denisov V. M., Ryabov V. V.
Заглавие : Synthesis, Crystal Structure and Thermodynamic Properties of LuGaTi2O7
Место публикации : Inorg. Mater. - 2020. - Vol. 56, Is. 12. - P.1242-1247. - ISSN 00201685 (ISSN), DOI 10.1134/S0020168520120055
Примечания : Cited References: 25
Аннотация: Single-phase LuGaTi2O7 samples have been prepared by solid-state reaction in a starting mixture of Lu2O3, Ga2O3, and TiO2 via sequential firing in air at temperatures of 1273 and 1573 K. The crystal structure of the lutetium gallium dititanate has been determined by the Rietveld method (profile analysis of X-ray diffraction patterns of polycrystalline powders): sp. gr. Pcnb; a = 9.75033(13) Å, b = 13.41425(17) Å, c = 7.29215(9) Å, V = 957.32(2) Å3, d = 6.28 g/cm3. The heat capacity of LuGaTi2O7 has been determined as a function of temperature by differential scanning calorimetry in the range 320–1000 K. The Cp(T) data thus obtained have been used to calculate the principal thermodynamic functions of the oxide compound.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Irtyugo L. A., Beletskii V. V., Kargin, Yu. F., Denisov V. M.
Заглавие : Synthesis, structure, and thermophysical properties of EuGaGe2O7
Место публикации : Inorg. Mater. - 2020. - Vol. 56, Is. 8. - P.854-858. - ISSN 0020-1685, DOI 10.1134/S002016852008004X. - ISSN 1608-3172(eISSN)
Примечания : Cited References: 18
Предметные рубрики: TEMPERATURE HEAT-CAPACITY
THERMODYNAMIC PROPERTIES
CRYSTAL-STRUCTURE
Аннотация: The europium gallium germanate EuGaGe2O7 has been prepared by solid-state reaction in air in the temperature range 1273–1473 K using a stoichiometric mixture of Eu2O3, Ga2O3, and GeO2. Its crystal structure has been determined by X-ray diffraction (sp. gr. P21/c, a = 7.1693(7) Å, b = 6.57008(6) Å, c = 12.7699(1) Å, β = 117.4522(5)°, V = 533.768(8) Å3). The heat capacity of polycrystalline samples has been determined by differential scanning calorimetry in the temperature range 350–1053 K and the experimental data have been used to calculate the thermodynamic properties (enthalpy increment, entropy change, and reduced Gibbs energy change) of EuGaGe2O7.
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