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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Gardymova A. P., Rudyak, Vladimir Yu., Barbashov, Vadim A., Zyryanov V. Ya.
Заглавие : Electrically induced transformation of cholesteric droplets under homeotropic boundary conditions
Колич.характеристики :7 с
Место публикации : J. Mol. Liq. - 2023. - Vol. 385. - Ст.122379. - ISSN 01677322 (ISSN), DOI 10.1016/j.molliq.2023.122379. - ISSN 18733166 (eISSN)
Примечания : Cited References: 37. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038. The research was carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University
Аннотация: Cholesteric droplets under homeotropic boundary conditions demonstrate a rich variety of possible orientational structures. We have implemented electrically controlled switching of such droplets between two classes of stable states: i) structures with cylindrical cholesteric layers and ii) layer-like structures with one or more λ+1/2-disclinations. Structure relaxation after switching off the voltage proceeded via the fast (less than 1 s), the slow (more than 1 s), and the stabilization stages (~10 hours). We investigated intermediate long-lived metastable states occurring in the relaxation process and explained the formation of various structures in cholesteric droplets. The fast and the slow stages of relaxation were found to be sensitive to the voltage reduction regime. We have determined the combinations of droplet size and voltage reduction regimes leading to the two types of structures after relaxation.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gardymova A. P., Krakhalev M. N., Rudyak V. Yu., Barbashov V. A., Zyryanov V. Ya.
Заглавие : Polymer-dispersed cholesteric liquid crystal under homeotropic anchoring: Electrically induced structures with λ1/2-disclination
Место публикации : Polymers. - 2022. - Vol. 14, Is. 7. - Ст.1454. - ISSN 20734360 (ISSN), DOI 10.3390/polym14071454
Примечания : Cited References: 44. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038
Аннотация: Orientational structures of polymer-dispersed cholesteric liquid crystal under homeotropic anchoring and their transformations under the action of an electric field are studied. The switching of cholesteric droplets between different topological states are experimentally and theoretically demonstrated. Structures with λ+1/2-disclination are found and considered. These structures are formed during the transformation of a twisted toroidal configuration induced by a decrease in the electric field when a relative chiral parameter N06.3. The transformation of the initial structure with a bipolar distribution of the helix axis into a twisted toroidal configuration and then into a structure with λ+1/2-disclination is investigated in detail. The behavior of these structures under the influence of an external electric field, as well as the appearance of structures with λ−1/2-disclination, are studied. Obtained results are promising for the development of optical materials with programmable properties.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Сутормин, Виталий Сергеевич, Крахалев, Михаил Николаевич, Прищепа, Оксана Олеговна, Зырянов, Виктор Яковлевич
Заглавие : Ориентационный переход в слое нематика с гомеотропно-коническими граничными условиями, индуцированный ионной модификацией поверхностного сцепления
Место публикации : Жидк. крист. и их практич. использ. - 2022. - Т. 22, № 3. - С. 105-110. - ISSN 1991-3966 (ISSN), DOI 10.18083/LCAppl.2022.3.105; Liq. Cryst. Appl. - ISSN 2499-9644 (eISSN)
Примечания : Библиогр.: 4. - В.С. Сутормин, М.Н. Крахалев и О.О. Прищепа благодарят за поддержку грант РФФИ, Правительства Красноярского края и Красноярского краевого фонда науки в рамках научного проекта № 20-42-240007
Аннотация: Исследована трансформация ориентационной структуры в слое нематика с гомеотропно-коническими граничными условиями, индуцированная электроуправляемой ионной модификацией поверхностного сцепления. Обнаружено, что изменение азимутального угла директора на подложке с коническим сцеплением возможно осуществить путем модификации граничных условий на второй подложке.The transformation of the orientational structure induced by the electrically controlled ionic modification of surface anchoring in the nematic layer with homeotropic-conical boundary conditions has been considered. It has been found that the change in the azimuthal angle of director at the substrate with conical anchoring can be realized by modification of boundary conditions at the second substrate.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Rudyak, Vladimir Yu., Prishchepa O. O., Gardymova, Anna P., Emelyanenko, Alexander V., Liu, Jui-Hsiang, Zyryanov V. Ya.
Заглавие : Orientational structures in cholesteric droplets with homeotropic surface anchoring
Коллективы : Russian Foundation for Basic Research Project [19-53-52011 MNT_a, RFMEFI62117X0011]
Место публикации : Soft Matter. - 2019. - Vol. 15, Is. 28. - P.5554-5561. - ISSN 1744-683X, DOI 10.1039/c9sm00384c. - ISSN 1744-6848(eISSN)
Примечания : Cited References: 67. - This work was supported by the Russian Foundation for Basic Research Project No. 19-53-52011 MNT_a. The research is carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University supported by the project RFMEFI62117X0011.
Предметные рубрики: LIQUID-CRYSTAL DROPLETS
TOPOLOGICAL DEFECTS
NEMATIC DROPLETS
Аннотация: The dependency of orientational structures in cholesteric droplets with homeotropic surface anchoring on the helicity parameter has been studied by experiment and simulations. We have observed a sequence of structures, in which the director configurations and topological defects were identified by comparison of polarized microscopy pictures with simulated textures. A toron-like and low-symmetry intermediate layer-like structures have been revealed and studied in detail. The ranges of stability of the observed structures have been summarized in a general diagram and explained by the helicity parameter dependence of the free energy terms.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Rudyak, V. Yu., Gardymova A. P., Zyryanov V. Ya.
Заглавие : Toroidal Configuration of a Cholesteric Liquid Crystal in Droplets with Homeotropic Anchoring
Коллективы : Russian Science Foundation [18-72-10036]; Ministry of Education and Science of the Russian Federation [RFMEFI62117X0011]
Место публикации : JETP Letters. - 2019. - Vol. 109, Is. 7. - P.478-481. - ISSN 0021-3640, DOI 10.1134/S0021364019070075. - ISSN 1090-6487(eISSN)
Примечания : Cited References: 30. - This work was supported by the Russian Science Foundation (project no. 18-72-10036). The work was performed using the equipment of the Shared Usage Center of High-Capacity Computational Resources, Moscow State University, supported by the Ministry of Education and Science of the Russian Federation (project no. RFMEFI62117X0011).
Предметные рубрики: NEMATIC DROPLETS
SURFACE
Аннотация: Orientational structures formed in cholesteric droplets with homeotropic surface anchoring have been studied by means of polarization optical microscopy and computer simulations. It has been found that, when the ratio of the size of droplets to the pitch of a cholesteric helix ranges from 1.4 to 2.9, an axisymmetric toroidal cholesteric structure is formed with a topological linear defect in the form of an equatorially located surface ring. The features of the toroidal structure in cholesteric droplets and their optical textures for various observation schemes are examined in detail.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Shvetsov S. A., Emelyanenko A. V., Bugakov M. A., Boiko N. I., Zyryanov V. Ya.
Заглавие : Homeotropic to planar realignment of nematicliquid crystal cell induced by self-assembled photosensitive layer
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.PC-35
Примечания : Cited References: 4
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rudyak V. Yu., Krakhalev M. N., Gardymova A. P., Prishchepa O. O., Emelyanenko A. V., Zyryanov V. Ya.
Заглавие : Structures, topological defects and optical patterns of cholesteric droplets with homeotropic anchoring
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.PB-31
Примечания : Cited References: 4
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Sutormin V. S., Prishchepa O. O., Kuz'menok N. M., Mikhalyonok S. G., Bezborodov V. S., Zyryanov V. Ya.
Заглавие : Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals
Коллективы : International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018 , Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]
Место публикации : J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P.57-62. - ISSN 0167-7322, DOI 10.1016/j.molliq.2019.02.132. - ISSN 1873-3166(eISSN)
Примечания : Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
TRANSITION
DROPLETS
CONFIGURATION
LAYER
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shvetsov S. A., Emelyanenko, Alexander, V, Bugakov M. A., Boiko N. I., Zyryanov V. Ya.
Заглавие : Photo-orientation of nematic liquid crystal without preliminary cell surface treatment
Коллективы : Russian Science Foundation (RSF) [18-72-00242]
Место публикации : Opt. Mater. Express. - 2019. - Vol. 9, Is. 6. - P.2595-2600. - ISSN 2159-3930, DOI 10.1364/OME.9.002595
Примечания : Cited References: 28. - Russian Science Foundation (RSF) (18-72-00242).
Предметные рубрики: HOMEOTROPIC ALIGNMENT
INTERFACE
DYE
PHOTOALIGNMENT
NONLINEARITY
Аннотация: We propose a simple and effective method of liquid crystal photoalignment that does not require any preliminary treatment of the cell substrates. To this aim, a small amount (0.1 wt %) of azobenzene carboxylic acid is added into the nematic liquid crystal. After filling the liquid crystal cell, a part of the dopant molecules is spontaneously adsorbed and attached to the glass surface by hydrogen bonds. This allows one to switch the boundary conditions of liquid crystal between homeotropic and planar due to the reversible trans-cis photoizomerization. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krakhalev M. N., Rudyak V. Yu., Gardymova A. P., Prishchepa O. O., Emelyanenko A. V., Zyryanov V. Ya.
Заглавие : Structures, topological defects and optical patterns of cholesteric droplets with homeotropic anchoring
Коллективы : International Liquid Crystal Conference
Место публикации : Abstracts of 27th International Liquid Crystal Conference (ILCC 2018). - 2018. - Ст.1-Е-6
Примечания : Cited References: 5
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