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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Sutormin V. S., Prishchepa O. O., Kuz'menok N. M., Mikhalyonok S. G., Bezborodov V. S., Zyryanov V. Ya.
Заглавие : Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals
Коллективы : International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018 , Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]
Место публикации : J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P.57-62. - ISSN 0167-7322, DOI 10.1016/j.molliq.2019.02.132. - ISSN 1873-3166(eISSN)
Примечания : Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
TRANSITION
DROPLETS
CONFIGURATION
LAYER
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Gardymova A. P., Prishchepa O. O., Rudyak V. Yu., Emelyanenko A. V., Liu J. -H., Zyryanov V. Ya.
Заглавие : Bipolar configuration with twisted loop defect in chiral nematic droplets under homeotropic surface anchoring
Место публикации : Sci. Rep. - 2017. - Vol. 7, Is. 1. - Ст.14582. - ISSN 20452322 (ISSN), DOI 10.1038/s41598-017-15049-6
Примечания : Cited References: 45. - We are grateful to Dr. Timofeev Ivan Vladimirovich for valuable comments and discussions. This work was supported by the Russian Foundation for Basic Research (RFBR) under Grants Nos 15-02-06924, 16-53-00073, and Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 16-42-240704, and by the Siberian Branch of the Russian Academy of Sciences under Complex Program II.2P 0358-2015-0010. The work of V.Y.R. and À.V.Å. on the simulation of droplet structure and texture was supported by the Russian Science Foundation (project No. 16-43-03010). The work of J.H.L. was supported by the Ministry of Science and Technology of Taiwan (contract No. MOST105-2923-E-006-007).
Аннотация: Optical textures and appropriate orientational structures have been studied within droplets of chiral nematic dispersed in polymer assigning the homeotropic anchoring. The helix axis of the chiral structure inside droplets forms the bipolar configuration. The optical droplet textures were analysed in the unpolarised light, analyser switching-off scheme and in crossed polarisers. The twisted loop defect reveals itself convincingly in all schemes. Its appearance at the optical patterns of the chiral nematic droplets has been examined depending on their size and the aspect direction. The existence of the defect has been verified by the structural and optical calculations. The effect of an electric field on both the defect line shape and the orientational structure of chiral nematic has been studied.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Gardymova A. P., Rudyak, Vladimir Yu., Barbashov, Vadim A., Zyryanov V. Ya.
Заглавие : Electrically induced transformation of cholesteric droplets under homeotropic boundary conditions
Колич.характеристики :7 с
Место публикации : J. Mol. Liq. - 2023. - Vol. 385. - Ст.122379. - ISSN 01677322 (ISSN), DOI 10.1016/j.molliq.2023.122379. - ISSN 18733166 (eISSN)
Примечания : Cited References: 37. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038. The research was carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University
Аннотация: Cholesteric droplets under homeotropic boundary conditions demonstrate a rich variety of possible orientational structures. We have implemented electrically controlled switching of such droplets between two classes of stable states: i) structures with cylindrical cholesteric layers and ii) layer-like structures with one or more λ+1/2-disclinations. Structure relaxation after switching off the voltage proceeded via the fast (less than 1 s), the slow (more than 1 s), and the stabilization stages (~10 hours). We investigated intermediate long-lived metastable states occurring in the relaxation process and explained the formation of various structures in cholesteric droplets. The fast and the slow stages of relaxation were found to be sensitive to the voltage reduction regime. We have determined the combinations of droplet size and voltage reduction regimes leading to the two types of structures after relaxation.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Shvetsov S. A., Emelyanenko A. V., Bugakov M. A., Boiko N. I., Zyryanov V. Ya.
Заглавие : Homeotropic to planar realignment of nematicliquid crystal cell induced by self-assembled photosensitive layer
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.PC-35
Примечания : Cited References: 4
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Inverse mode of ion-surfactant method of director reorientation inside nematic droplets
Место публикации : Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P.1998-2003. - ISSN 1542-1406, DOI 10.1080/15421400903050814
Примечания : Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation.Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation
Ключевые слова (''Своб.индексиров.''): electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--applied voltages--crossed polarizers--director fields--director reorientation--droplet structure--electrically commanded surfaces--high concentration--homeotropic--initial state--ionic modification--liquid-crystal droplets--nematic droplets--nematic polymer--surface-active cations--surface-anchoring--trimethyl--ammonium compounds--cationic surfactants--crystals--drop formation--dyes--ionization of liquids--ions--liquid crystal displays--liquid crystals--liquids--nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zyryanov V. Ya., Myslivets S. A., Gunyakov V. A., Parshin A. M., Arkhipkin V. G., Shabanov V. F., Lee, Wei
Заглавие : Magnetic-field tunable defect modes in a photonic-crystal/liquid-crystal cell
Место публикации : Opt. Express. - 2010. - Vol. 18, Is. 2. - P.1283-1288. - JAN 18. - ISSN 1094-4087, DOI 10.1364/OE.18.001283
Примечания : Cited Reference Count: 15. - Гранты: This work was partially supported by the Russian Federal Grant No. 02.740.11.0220 and SB RAS Grant Nos. 5, 27.1 and 144. W. Lee gratefully acknowledges financial support from the National Science Council of the Republic of China (Taiwan) under Grant No. NSC 98-2923-M-033-001-MY3 dedicated to an internationally joint effort between Russia and Taiwan.Финансирующая организация: Russian Federal [02.740.11.0220]; SB RAS [5, 27.1, 144]; National Science Council of the Republic of China (Taiwan) [NSC 98-2923-M-033-001-MY3]
Предметные рубрики: NEMATIC LIQUID-CRYSTAL
BAND-GAP MATERIALS
SPONTANEOUS EMISSION
SPECTRUM
Ключевые слова (''Своб.индексиров.''): crystal defects--magnetic fields--photonic crystals--applied magnetic fields--crossed polarizers--crystal cells--defect mode--homeotropic--light transmission spectra--light wave--nematic director--optical cells--planar alignment--spectral shift--tunable defect--light transmission--article--artifact--chemistry--electromagnetic field--liquid crystal--materials--materials testing--radiation exposure--refractometry--artifacts--electromagnetic fields--liquid crystals--manufactured materials--materials testing--refractometry
Аннотация: Light transmission spectrum of a multilayer photonic crystal with a central liquid-crystal defect layer placed between crossed polarizers has been studied. Transmittance was varied due to the magnetically induced reorientation of the nematic director from homeotropic to planar alignment. Two notable effects were observed for this scheme: the spectral shift of defect modes corresponding to the extraordinary light wave and its superposition with the ordinary one. As a result, the optical cell allows controlling the intensity of interfering defect modes by applied magnetic field. (C) 2010 Optical Society of America
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prishchepa O. O., Zyryanov V. Ya., Gardymova A. P., Shabanov V. F.
Заглавие : Optical textures and orientational structures of nematic and cholesteric droplets with heterogeneous boundary conditions
Место публикации : Mol. Cryst. Liquid Cryst. - 2008. - Vol. 489, Is. 1. - P.84-93. - ISSN 1542-1406, DOI 10.1080/15421400802219817
Примечания : Cited Reference Count: 17. - Гранты: This work was supported in part by the grants of DSP, No 2.1.1.1814; RFBR, No 0803-01007; Council of the President of the RF for Support of Young Scientists and Leading Scientific Schools (projects NSh-3818-2008.3, MK-3624.2007.2); RAS, No 8.1, 2.10.2; SB RAS, No 33.Финансирующая организация: DSP [2.1.1.1814]; RFBR [0803-01007]; Young Scientists and Leading Scientific Schools [NSh-3818-2008.3, MK-3624.2007.2]; RAS [8.1, 2.10.2]; SB RAS [33]
Предметные рубрики: LIQUID-CRYSTAL DROPLETS
ELECTRIC-FIELD
BIPOLAR
Ключевые слова (''Своб.индексиров.''): director configuration--interfaces--nematic and cholesteric droplets--surfactant--director configuration--interfaces--nematic and cholesteric droplets--surfactant--boundary value problems--drop formation--drops--fluid mechanics--phospholipids--surface active agents--boundary conditioning--director configuration--homeotropic--interfaces--nematic and cholesteric droplets--nematic droplets--nematics--optical textures--orientational structures--surface anchoring--surfactant--boundary conditions
Аннотация: Brief review of the orientational structures within the droplets of chiral as well as achiral nematics with the heterogeneous boundary conditions is reported. The modification of boundary conditions in the 5CB/polyvinylbutyral and LN-396/cholesterylacetate/polyvinylbutyral compositions with the planar anchoring at the interface is created by addition of the homeotropic surfactant (lecithin). Sequences of the novel stable and non-stable orientational structures being realized within the droplets of achiral nematic are presented. For the LN-396 nematic droplets doped by cholesterylacetate the formation of a spherulite structure has been shown when the tangential surface anchoring is modified to the homeotropic one.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Rudyak, Vladimir Yu., Prishchepa O. O., Gardymova, Anna P., Emelyanenko, Alexander V., Liu, Jui-Hsiang, Zyryanov V. Ya.
Заглавие : Orientational structures in cholesteric droplets with homeotropic surface anchoring
Коллективы : Russian Foundation for Basic Research Project [19-53-52011 MNT_a, RFMEFI62117X0011]
Место публикации : Soft Matter. - 2019. - Vol. 15, Is. 28. - P.5554-5561. - ISSN 1744-683X, DOI 10.1039/c9sm00384c. - ISSN 1744-6848(eISSN)
Примечания : Cited References: 67. - This work was supported by the Russian Foundation for Basic Research Project No. 19-53-52011 MNT_a. The research is carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University supported by the project RFMEFI62117X0011.
Предметные рубрики: LIQUID-CRYSTAL DROPLETS
TOPOLOGICAL DEFECTS
NEMATIC DROPLETS
Аннотация: The dependency of orientational structures in cholesteric droplets with homeotropic surface anchoring on the helicity parameter has been studied by experiment and simulations. We have observed a sequence of structures, in which the director configurations and topological defects were identified by comparison of polarized microscopy pictures with simulated textures. A toron-like and low-symmetry intermediate layer-like structures have been revealed and studied in detail. The ranges of stability of the observed structures have been summarized in a general diagram and explained by the helicity parameter dependence of the free energy terms.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Huang K.-C., Hsiao Yu-Cheng, Timofeev I. V., Zyryanov V. Ya., Lee W.
Заглавие : Photo-manipulated photonic bandgap devices based on optically tristable chiral-tilted homeotropic nematic liquid crystal
Место публикации : Opt. Express: Optical Society of America, 2016. - Vol. 24, Is. 22. - P.25019-25025. - ISSN 10944087 (ISSN), DOI 10.1364/OE.24.025019
Примечания : Cited References: 22. - Ministry of Science and Technology (MOST), (103-2923-M-009-003-MY3); Ministry of Education and Science of the Russian Federation (3.1276.2014/K); Siberian Branch of the Russian Academy of Sciences under Complex Program II.2P (0358-2015-0010, 0358-2015-0011).
Ключевые слова (''Своб.индексиров.''): defects--energy gap--liquid crystals--nematic liquid crystals--photonic crystals--spontaneous emission--homeotropic nematic liquid crystals--intensity modulators--low-power consumption--multi-channel filter--one dimensional photonic crystal--photonic application--photonic bandgap devices--transmission characteristics--light transmission
Аннотация: We report on the spectral properties of an optically switchable tristable chiral-tilted homeotropic nematic liquid crystal (LC) incorporated as a tunable defect layer in one-dimensional photonic crystal. By varying the polarization angle of the incident light and modulating the light intensity ratio between UV and green light, various transmission characteristics of the composite were obtained. The hybrid structure realizes photo-tunability in transmission of defect-mode peaks within the photonic bandgap in addition to optical switchability among three distinct sets of defect modes via photoinduced tristable state transitions. Because the fabrication process is easier and less critical in terms of cell parameters or sample preparation conditions and the LC layer itself possesses an extra stable state compared with the previously reported bistable counterpart operating on the basis of biased-voltage dual-frequency switching, it has much superior potential for photonic applications such as a low-power-consumption multichannel filter and an optically controllable intensity modulator. © 2016 Optical Society of America.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shvetsov S. A., Emelyanenko, Alexander, V, Bugakov M. A., Boiko N. I., Zyryanov V. Ya.
Заглавие : Photo-orientation of nematic liquid crystal without preliminary cell surface treatment
Коллективы : Russian Science Foundation (RSF) [18-72-00242]
Место публикации : Opt. Mater. Express. - 2019. - Vol. 9, Is. 6. - P.2595-2600. - ISSN 2159-3930, DOI 10.1364/OME.9.002595
Примечания : Cited References: 28. - Russian Science Foundation (RSF) (18-72-00242).
Предметные рубрики: HOMEOTROPIC ALIGNMENT
INTERFACE
DYE
PHOTOALIGNMENT
NONLINEARITY
Аннотация: We propose a simple and effective method of liquid crystal photoalignment that does not require any preliminary treatment of the cell substrates. To this aim, a small amount (0.1 wt %) of azobenzene carboxylic acid is added into the nematic liquid crystal. After filling the liquid crystal cell, a part of the dopant molecules is spontaneously adsorbed and attached to the glass surface by hydrogen bonds. This allows one to switch the boundary conditions of liquid crystal between homeotropic and planar due to the reversible trans-cis photoizomerization. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
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