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A high thermal stability Cr3+-doped gallate far red phosphor for plant lighting: structure, luminescence enhancement and application prospect / C. Zhou, L. Peng, Z. H. Kong [et al.] // J. Mater. Chem. C. - 2022. - Vol. 10, Is. 15. - P. 5829-5839, DOI 10.1039/d2tc00614f. - Cited References: 39. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant no. 51974123), the Distinguished Youth Foundation of Hunan Province (Grant no. 2020JJ2018), Key R & D projects in Hunan Province (2020WK2016 & 2020SK2032), the Hunan High Level Talent Gathering Project (2019RS1077 & 2020RC5007), the Natural Sciences Foundation of Hunan Agricultural University (19QN11), the Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization Science Foundation (19KFXM12), the Changsha Science and technology plan (KH2005114), the Scientific Research Fund of Hunan Provincial Education Department (19C0903) and the Innovation Training Program for College Students of Hunan Province (No. S202010537012) . - ISSN 2050-7526. - ISSN 2050-7534

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
EMITTING PHOSPHOR
TUNING PHOTOLUMINESCENCE
LEDS
Аннотация: Cationic substitution is a common material modification strategy. Generally, it follows the principles of radius matching, valency equilibrium and stoichiometric substitution. However, radius-mismatched, nonstoichiometric-ratio ion substitution can achieve unexpected experimental results. Such unexpected results are very important for expanding the research of materials, but the modification mechanism is still unclear. In this work, the optical performance of ZnGa2O4:0.02Cr3+ (ZGO:0.02Cr3+) is effectively regulated by chemical unit cosubstitution (Ge4+–Li+/Na+ for Ga3+–Zn2+) and excess cation substitution synergetic strategies, and the thermal stability is retained at 97.7% at room temperature and 150 °C. Ge4+–Li+ and Ge4+–Na+ replace the lattice position of Ga3+–Zn2+ to enhance the photoluminescence (PL) intensity and quantum efficiency (QE) of ZGO:0.02Cr3+. The optimal doping contents of Ge4+–Li+ and Ge4+–Na+ are all 0.3 mol (PL intensity is 130.3% and 153.4% and QE = 77.4% and 85.1%). With further addition of Li+ ions, the emission intensity and QE continued to increase to 176.4% and 83.8%, respectively. The synergistic effect of the mechanism on optical properties is explained via Rietveld refinement, optical band gap energy and thermoluminescence. Finally, LED devices were fabricated by using the ZGO:0.02Cr3+,0.03Ge4+,0.11Li+ phosphor to investigate the effect on plant growth. The growth period was reduced and the fruit quality was improved in dwarf potted tomato, which shows the application prospect in plant growth of the ZGO:0.02Cr3+ phosphor.

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Держатели документа:
Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.
Hunan Opt Agr Engn Technol Res Ctr, Changsha 410128, Peoples R China.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Sun Yat Sen Univ, Sch Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China.

Доп.точки доступа:
Zhou, Cheng; Peng, L.u.; Kong, Zihui; Wu, Meihan; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Zhi; Wang, Jing; Xia, Mao
}
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    A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect / S. J. Gai, C. Zhou, L. Peng [et al.] // Mater. Today Chem. - 2022. - Vol. 26. - Ст. 101107, DOI 10.1016/j.mtchem.2022.101107. - Cited References: 50. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant No. 51974123), the Distinguished Youth Foundation of Hunan Province (Grant No.2020JJ2018), the Key R & D projects in Hunan Province (2020WK2016, 2020SK2032, 2021SK2047, 2022NK2044), the Natural Science Foundation of Hunan Province, China (Grant No. 2021JJ40261), the Hunan High Level Talent Gathering Project (2019RS1077&2020RC5007), the Scientific Research Fund of Hunan Provincial Education Department (19C0903), the Natural Sciences Foundation of Hunan Agricultural University, China (Grant No. 19QN11), Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization Science Foundation (19KFXM12), Changsha Science and technology plan (KH2005114 and KH2201428), the Hunan Graduate Scientific Research Innovation Project (2022XC017) and the College Students' Innovative Training (S202110537012 and s202210537079x) . - ISSN 2468-5194
   Перевод заглавия: Новый станнатный инфракрасный люминофор, легированный Cr3+, для освещения растений: решение структуры, настройка широкого спектра и перспективы применения
Кл.слова (ненормированные):
Mg2SnO4: Cr3+ -- Chemical unit cosubstitution -- Emission tuning -- Local structural modification -- Plant growth LEDs
Аннотация: Chemical unit cosubstitution is an effective strategy to regulate the luminescence properties of phosphors, and it has attracted huge attention in the last few years. Following the design principles of the match of effective ion radius, atomic valence equilibrium and stoichiometric substitution, the local structure of crystal can be well customized, which is beneficial to develop high-performance luminescent materials. In this work, Mg2+-Sn4+ sites were cosubstituted by Zn2+-Ti4+ ion pairs in Mg2SnO4: Cr3+, respectively, and the emission spectra was successfully serially tuned from broad-band to narrow-band along with a unique variation trend of blue shift first and then slightly red shift. The photoluminescence excitation (PLE), photoluminescence (PL) spectra, lifetime decay, Raman spectra and electron paramagnetic resonance (EPR) were used to analyze the mechanism of luminescence tuning. Based on the manipulation of local structure, the as-observed distinct luminescence tuning can be well understood by the crystal field theory, nephelauxetic effect and changed Cr3+ capacity in this phosphor. Moreover, the adjusted narrow-band far-red emission spectra peak at 732 nm, matching the characteristic absorption of plant phytochrome PFR, has broad application prospects in the field of plant growth lighting. In addition, light-regulated dwarf potted tomato experiments were carried out to verify the application of far-red light in plant growth.

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Держатели документа:
College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha, 410128, China
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk660036, Russian Federation

Доп.точки доступа:
Gai, S. J.; Zhou, C.; Peng, L.; Wu, M. H.; Gao, P. X.; Su, L. J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Z.; Xia, M.
}
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    A novel single-phase white light emitting phosphor Ca9La(PO4)5(SiO4)F2:Dy3+: Synthesis, crystal structure and luminescence properties / H. Liu [et al.] // RSC Adv. - 2016. - Vol. 6, Is. 29. - P. 24577-24583, DOI 10.1039/c5ra23348h. - Cited References: 33. - We gratefully acknowledge the financial support by the National Natural Science Foundations of China (Grant no. 41172053), the Fundamental Research Funds for the Central Universities (Grant no. 2652013043), and Science and Technology Innovation Fund of the China University of Geosciences (Beijing). . - ISSN 2046-2069
   Перевод заглавия: Новый однофазный люминофор Ca9La(PO4)5(SiO4)F2:Dy3+, излучающий белый свет: синтез, кристаллическая структура и люминесцентные свойства

РУБ Chemistry, Multidisciplinary
Рубрики:
Energy-transfer
   Diodes
   LEDs
   Emission
   Ions
   Excitation
   Ce3+
   Eu2+
   Ln
Аннотация: A novel single-phase white light emitting phosphor Ca9La(PO4)5(SiO4)F2:Dy3+ was prepared through traditional high-temperature solid state technology. The crystal structures of Ca9La(PO4)5(SiO4)F2 with or without Dy3+ ions were refined by the Rietveld method. The diffuse reflection spectra, excitation spectra, emission spectra, and decay times were characterized to investigate the photoluminescence properties for application in white light-emitting diodes. The results showed that the Ca9La(PO4)5(SiO4)F2:Dy3+ phosphor could efficiently assimilate n-UV light and emit blue (∼485 nm) and yellow light (∼580 nm), originating from the f-f transitions of Dy3+. The critical Dy3+ quenching concentration (QC) was determined to be about 15 mol%, and the corresponding QC mechanism was verified to be the dipole-dipole interaction. Additionally, the emission colors of all samples were located close to the ideal white light region, and the optimal chromaticity coordinates and correlated color temperature (CCT) were determined to be (x = 0.338, y = 0.336) and 5262 K. All the above results indicate that the as-prepared Ca9La(PO4)5(SiO4)F2:Dy3+ phosphor could serve as a promising candidate for white-light n-UV-LEDs. © The Royal Society of Chemistry 2016.

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Держатели документа:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing, China
Laboratory of Crystal Physics, Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Liu, H.; Liao, L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Guo, Q.; Zhang, Y.; Mei, L.
}
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    Blue-shift of Eu2+ emission in (Ba,Sr)3Lu(PO4)3:Eu2+ eulytite solid-solution phosphors resulting from release of neighbouring-cation-induced stress / Z. Y. Wang [et al.] // Dalton Trans. - 2014. - Vol. 43, Is. 44. - P. 16800-16804, DOI 10.1039/c4dt02319f. - Cited References: 16. - The present work was supported by the National Natural Science Foundations of China (grant no. 51002146, no. 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). V.V.A. is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1477-9226. - ISSN 1477-9234
   Перевод заглавия: Синее смещение излучения Eu2+ в твердых растворах (Ba,Sr)3Lu(PO4)3:Eu2 со структурой эулита, вызванное снятием напряжения, индуцированного соседними катионами

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
TUNABLE COLOR TONE
   EXCITED WHITE LEDS
   CRYSTAL-STRUCTURE
   TEMPERATURE
   IONS
Аннотация: A series of iso-structural eulytite-type (Ba,Sr)(3)Lu(PO4)(3):Eu2+ solid-solution phosphors with different Sr/Ba ratios were synthesized by a solid-state reaction. Crystal structures of (Ba,Sr)(3)Lu(PO4)(3):Eu2+ were resolved by the Rietveld method, which shows an eulytite-type cubic Bi-4(SiO4)(3) structure with cations disordered in a single C-3 site while the oxygen atoms were distributed over two partially occupied sites. The emission peaks of Ba(3-x)SrxLu(PO4)(3):Eu2+ (0

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Wang, Z. Y.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Liu, Q. L.
}
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    Ca6La4(SiO4)2(PO4)4O2:Eu2+: a novel apatite green-emitting phosphor for near-ultraviolet excited w-LEDs / Y. F. Xia [et al.] // J. Mater. Chem. C. - 2016. - Vol. 4, Is. 21. - P. 4675-4683, DOI 10.1039/c6tc01418f. - Cited References:37. - This study was sponsored by the National Natural Science Foundation of China (Grant No. 51472223), the Program for New Century Excellent Talents in University of Ministry of Education of China (Grant No. NCET-12-0951) and the Fundamental Research Funds for the Central Universities (Grant No. 2652015020 and Grant No. 2652015008). . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Ca6La4(SiO4)2(PO4)4O2:Eu2+: Новый зеленый люминофор со структурой апатита для белых люминесцентных ламп (w-LED), облучающихся ультрафиолетом

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
SOLID-SOLUTION PHOSPHORS
   PULSED-LASER DEPOSITION
   HIGH THERMAL-STABILITY
   WHITE-LIGHT
   LUMINESCENCE PROPERTIES
   ENERGY-TRANSFER
   SINGLE-PHASE
   CRYSTAL-STRUCTURE
   RED LUMINESCENCE
   EPITAXIAL-GROWTH
Аннотация: A novel apatite phosphor Ca6La4(SiO4)2(PO4)4O2:Eu2+ was prepared by conventional high-temperature solid-state reaction. Phase purity was examined by XRD and XPS analysis. The crystal structure information, such as space group, cell parameters and atomic coordinates, were refined by the Rietveld method, revealing that Eu2+ occupied the sites of Ca2+ ions. Moreover, low-temperature experiments, including low-temperature PL spectra and low-temperature decay curve, were used to prove the existence of two luminescence centers in Ca6La4(SiO4)2(PO4)4O2:Eu2+. With the increase in doping concentration of Eu2+, the emission wavelength shows a red shift from 498 nm to 510 nm, which is mainly caused by the increase in crystal-field splitting by Eu2+. The optimized concentration of Eu2+ was confirmed to be 0.01, the Rc was calculated to be 20.09 Å and the energy transfer between Eu2+ was demonstrated to be by exchange interaction. Moreover, good thermal stability has been proved by a temperature-dependence experiment; it shows that the phosphor can maintain 55% of emitting intensity at 150 °C compared to that at room temperature. Finally, the Ca6La4(SiO4)2(PO4)4O2:Eu2+ phosphor was fabricated with commercial red (CaAlSiN3:Eu2+) and blue (BAM:Eu2+) phosphor coating on a n-UV chip. This proves that this green phosphor has the potential to be used in a w-LED lamp.

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Держатели документа:
China Univ Geosci, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing 100083, Peoples R China.
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Xia, Y. F.; Liu, Y. G.; Huang, Z. H.; Fang, M. H.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mei, L. F.
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    Cation substitution dependent bimodal photoluminescence in whitlockite structural Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors / H. P. Ji [et al.] // Inorg. Chem. - 2014. - Vol. 53, Is. 20. - P. 11119-11124, DOI 10.1021/ic501679f. - Cited References: 37. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), the Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), and Beijing Youth Excellent Talent Program (YETP0635). V.V.A. acknowledges the Ministry of Education and Science of the Russian Federation for financial support. . - ISSN 0020-1669. - ISSN 1520-510X
   Перевод заглавия: Катион зависимая бимодальная люминесценция в твердом растворе Ca3-xSrx(PO4)2:Eu2+ (0 ˂ x ˂ 2) со структурой витлокита

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
LIGHT-EMITTING-DIODES
   EFFICIENT ENERGY-TRANSFER
   EMISSION-TUNABLE PHOSPHOR
   EXCITED WHITE LEDS
   CRYSTAL-STRUCTURE
   LUMINESCENCE PROPERTIES
   Mn2+ PHOSPHOR
   COLOR TONE
   PHASE
   Eu2+
Аннотация: Cation substitution dependent tunable bimodal photoluminescence behavior was observed in the Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors. The Rietveld refinements verified the phase purity and whitlockite type crystal structure of the solid solutions. The tunable photoluminescence evolution was studied as a function of strontium content, over the composition range 0.1 ≤ x ≤ 2. In addition to the emission band peak at 416 nm in Ca3(PO4)2:Eu2+, the substitution of Ca2+ by Sr2+ induced the emerging broad-band peak at 493-532 nm. A dramatic red shift of the emission peak located in the green-yellow region was observed on an increase of x in the samples with 0.75 ≤ x ≤ 2.00. The two emission bands could be related to the EuOn-Ca9 and EuOn-Ca9-xSrx emitting blocks, respectively. The values for the two kinds of emitting blocks in the solid solutions can be fitted well with the observed intensity evolution of the two emission peaks.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
Univ Auckland, Dept Chem & Mat Engn, Auckland 1142, New Zealand

Доп.точки доступа:
Ji, H. P.; Huang, Z. H.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Huang, S. F.
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    Co-substitution in Ca1−xYxAl12−xMgxO19 phosphors: local structure evolution, photoluminescence tuning and application for plant growth LEDs / Y. Zheng [et al.] // J. Mater. Chem. C. - 2018. - Vol. 6, Is. 15. - P. 4217-4224, DOI 10.1039/c8tc00165k. - Cited References: 47. - The present work was supported by the National Natural Science Foundation of China (Grant No. 21671070), the Project for Construction of High-level University in Guangdong Province, and the Teamwork Projects funded by the Guangdong Natural Science Foundation (Grant No. S2013030012842), and the Guangzhou Science & Technology Projects (No. 201704030086, 201605030005), and the reported study was funded by the RFBR according to the research project 17-52-53031. Special Funds for the Cultivation of Guangdong College Students’ Scientific and Technological Innovation (‘‘Climbing Program’’ Special Funds) were granted for Dr Yinjian Zheng. . - ISSN 2050-7534
   Перевод заглавия: Созамещение в Ca1−xYxAl12−xMgxO19 люминофорах: локальная структура, настройка фотолюминесценции и применение светодиодов для роста растений
Кл.слова (ненормированные):
CO substitution -- Crystal structure transformation -- High temperature solid-state reaction -- Lighting systems -- Local structure -- Luminescence measurements -- Structural refinement -- Tunable luminescences
Аннотация: Herein, Mn4+-activated Ca1-xYxAl12-xMgxO19 (x = 0-0.50) solid solutions were prepared using a conventional high-temperature solid-state reaction. Crystal structure transformation via chemical co-substitution of Y3+/Mg2+ for Ca2+/Al3+ was investigated in detail. The optical properties of Ca1-xYxAl12-xMgxO19 (x = 0-0.50) have been reported for the first time using a combination of techniques including structural refinement and luminescence measurements. Co-doping of Mg and Y cations within the CaAl12O19 host in a controlled manner resulted in the as-prepared samples with red/far-red ratio-tunable luminescence properties. The emission bands well-matched with the absorption band of phytochrome. Interestingly, enhanced Mn4+ luminescence can be obtained upon the addition of Mg2+ and Y3+. Unexpectedly, the quantum yields exhibit a slight change when x is in the range from 0.05 to 0.40; this indicates that these solid solutions have significant potential as lighting systems for plant growth.

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Guangdong Provincial Engineering Technology Research Center for Optical Agricultural, College of Materials and Energy, South China Agricultural University, Guangzhou, China
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Zheng, Y.; Zhang, H.; Xia, Z.; Liu, Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lei, B.
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    Color tunable emission and energy transfer of Ce3+ and Tb3+ co-doped novel La6Sr4(SiO4)6F2 phosphors with apatite structure / Q. Guo [et al.] // Mater. Res. Bull. - 2015. - Vol. 72. - P. 245-251, DOI 10.1016/j.materresbull.2015.07.029. - Cited References: 37. - This present work is supported by the National Natural Science Foundations of China (Grant No. 41172053). . - ISSN 0025-5408
   Перевод заглавия: Излучение с управляемым цветом и энергетический переход ионов Ce3+ и Tb3+ при их совместном допировании нового люминофора La6Sr4(SiO4)6F2 со структурой апатита

РУБ Materials Science, Multidisciplinary
Рубрики:
LIGHT-EMITTING-DIODES
   LUMINESCENCE PROPERTIES
   PHOTOLUMINESCENCE PROPERTIES
   EU2+
   LEDS
Кл.слова (ненормированные):
Inorganic compounds -- Luminescence -- Phosphors -- Optical properties -- Crystal structure
Аннотация: Single-phase La6Sr4(SiO4)6F2: Ce3+, Tb3+ samples with apatite-like structure have been synthesized via solid-state reaction method. The phase structure, luminescence properties, lifetime, the PL thermal stability, as well as the fluorescence decay curves of the samples were investigated to characterize the resulting samples. Effective energy transfer occurs from Ce3+ to Tb3+ in La6Sr4(SiO4)6F2, which shows more intense Blue-Green light under UV light excitation. In addition, a possible mechanism of the energy-transfer from Ce3+ to Tb3+ ion is also proposed. The critical distance RC of Ce3+ to Tb3+ ions in La6Sr4(SiO4)6F2 host was calculated to be 11.878 Å. All the results indicate that La6Sr4(SiO4)6F2:Ce3+, Tb3+ phosphors have potential applications to be used as near UV-convertible phosphors for white light-emitting diodes. © 2015 Elsevier Ltd. All rights reserved.

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Держатели документа:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, School of Materials Sciences and Technology, China University of Geosciences, Beijing, China
Laboratory of Crystal Physics, Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Guo, Q.; Liao, L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mei, L.; Liu, H.
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    Competitive site occupation toward improved quantum efficiency of SrLaScO4:Eu red phosphors for warm white LEDs / Z. Y. Yang, G. C. Liu, Y. F. Zhao [et al.] // Adv. Opt. Mater. - 2022. - Vol. 10. Is. 6. - Ст. 2102373, DOI 10.1002/adom.202102373. - Cited References: 42. - This research was supported by the International Cooperation Project of National Key Research and Development Program of China (Program No. 2021YFE0105700), National Natural Science Foundation of China (Grant Nos. 51972118 and 51961145101), Guangzhou Science & Technology Project (Project No. 202007020005), the State Key Laboratory of Luminescent Materials and Devices (Grant No. Skllmd-2021-09), China Postdoctoral Science Foundation (Grant No. 2021M691053), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (Program No. 2017BT01X137). This work was also funded by RFBR according to the research Project No. 19-52-80003 and the NRF International: SA/China Joint Research Programme 2021 - CHIN2002265 06921 UID 132785 . - ISSN 2195-1071
   Перевод заглавия: Конкурентное заселение позиций для повышения квантовой эффективности красных люминофоров SrLaScO4:Eu для тепло-белых светодиодов

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
LUMINESCENCE
   EUROPIUM
   BLUE
   EU2+
   STABILIZATION
   EPR
Кл.слова (ненормированные):
light-emitting diodes -- photoluminescence -- red emission
Аннотация: The discovery of Eu2+-doped high-efficiency red phosphors remains a vital challenge for white light-emitting diode (WLED) applications. It is therefore urgent to find effective strategies managing the oxidation state to help reduce Eu3+ to Eu2+ and accordingly increase the photoluminescence quantum yield (PLQY). Herein, a new red-emitting SrLaScO4:Eu phosphor is designed, and the PLQY is enhanced from 13% to 67% under 450 nm excitation by employing (NH4)2SO4-assisted sintering. Combined structural analysis, optical spectroscopy, and theoretical calculation reveal that predominant Eu2+ prefers to occupy the Sr2+ sites in the SrLaScO4 enabling red emission, and a competitive site occupation of Eu3+ in La3+ can be restrained, and the reduction mechanism of Eu3+ to Eu2+ originating from the (NH4)2SO4 addition is analyzed. The fabricated WLED device using red-emitting SrLaScO4:Eu and yellow-emitting Y3(Al,Ga)5O12:Ce3+ exhibits a high color-rendering index of 86.7 at a low correlated color temperature of 4005 K. This work provides a feasible reduction strategy for guiding the development of high-efficiency Eu2+-doped red phosphor for WLED applications.

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Держатели документа:
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangdong Prov Key Lab Fiber Laser Mat & Appl Tec, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China.
City Univ Hong Kong, Dept Chem, Kowloon, Hong Kong 999077, Peoples R China.
KSC SB RAS, Lab Crystal Phys, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Univ Free State, Dept Phys, POB 339, ZA-9300 Bloemfontein, South Africa.
South China Univ Technol, Sch Phys & Optoelect, Guangzhou 510641, Peoples R China.

Доп.точки доступа:
Yang, Zhiyu; Liu, Gaochao; Zhao, Yifei; Zhou, Yayun; Qiao, Jianwei; Molokeev, M. S.; Молокеев, Максим Сергеевич; Swart, Hendrik C.; Xia, Zhiguo; International Cooperation Project of National Key Research and Development Program of China [2021YFE0105700]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51972118, 51961145101]; Guangzhou Science & Technology Project [202007020005]; State Key Laboratory of Luminescent Materials and Devices [Skllmd-2021-09]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2021M691053]; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01X137]; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]; NRF International: SA/China Joint Research Programme 2021 [CHIN2002265 06921 UID 132785]
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10.

    Crystal structure and luminescence properties of novel Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphor with apatite structure / Q. F. Guo [et al.] // Ceram. Int. - 2016. - Vol. 42, Is. 10. - P. 11687-11691, DOI 10.1016/j.ceramint.2016.04.086. - Cited References:26. - This present work is supported by the National Natural Science Foundation of China (Grant no. 41172053). . - ISSN 0272-8842. - ISSN 1873-3956
   Перевод заглавия: Кристаллическая структура и люминесцентные свойства нового люминофора Sr10-x(SiO4)3(SO4)3O:xEu2+ со структурой апатита

РУБ Materials Science, Ceramics
Рубрики:
Light-Emitting-Diodes
   Energy-transfer
   Tunable phosphor
   LEDs
   Eu-2+
   Ions
   Ce3+
Кл.слова (ненормированные):
Crystal structure -- Apatite -- Phosphor
Аннотация: In this paper, a series of novel luminescent Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors with apatite structure were synthesized by a high temperature solid-state reaction. The phase structure, photoluminescence (PL) properties, as well as the PL thermal stability were investigated. Sr9.92(SiO4)3(SO4)3O:0.08Eu2+ phosphor exhibits better thermal quenching resistance, retaining the luminance of 66.55% at 150 °C compared with that at 25 °C. The quenching concentration of Eu2+ in Sr10(SiO4)3(SO4)3O was about 0.08 (mol) with the dipole–quadrupole interaction. The Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors exhibited a broad-band green emission at 538 nm upon excitation at 396 nm. The results indicate that Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors have potential applications as near UV-convertible phosphors for white-light UV LEDs.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Beijing 100083, Peoples R China.
SB RAS, Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Guo, Q. F.; Ma, B.; Liao, L. B.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mei, L. F.; Liu, H. K.
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