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Features of the pulsed magnetization switching in a high-coercivity material based on ε-Fe2O3 nanoparticles / S. I. Popkov, A. A. Krasikov, S. V. Semenov [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 3. - P. 445-453, DOI 10.1134/S1063783420030166. - Cited References: 44. - The study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240012 "Magnetization Switching of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields: New Approach to Studying the Dynamic Effects Related to the Magnetization of Magnetic Nanoparticles." . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
HIGH-TEMPERATURE
   WAVE ABSORBER
   OXIDE
   FIELD
   TRANSITION
   RESONANCE
Кл.слова (ненормированные):
ε-Fe2O3 nanoparticles -- dynamic magnetization switching -- coercivity
Аннотация: The magnetic structure of the ε-Fe2O3 iron oxide polymorphic modification is collinear ferrimagnetic in the range from room temperature to ~150 K. As the temperature decreases, ε-Fe2O3 undergoes a magnetic transition accompanied by a significant decrease in the coercivity Hc and, in the low-temperature range, the compound has a complex incommensurate magnetic structure. We experimentally investigated the dynamic magnetization switching of the ε-Fe2O3 nanoparticles with an average size of 8 nm in the temperature range of 80–300 K, which covers different types of the magnetic structure of this iron oxide. A bulk material consisting of xerogel SiO2 with the ε-Fe2O3 nanoparticles embedded in its pores was examined. The magnetic hysteresis loops under dynamic magnetization switching were measured using pulsed magnetic fields Hmax of up to 130 kOe by discharging a capacitor bank through a solenoid. The coercivity Нс upon the dynamic magnetization switching noticeably exceeds the Нс value under the quasi-static conditions. This is caused by the superparamagnetic relaxation of magnetic moments of particles upon the pulsed magnetization switching. In the range from room temperature to ~ 150 K, the external field variation rate dH/dt is the main parameter that determines the behavior of the coercivity under the dynamic magnetization switching. It is the behavior that is expected for a system of single-domain ferro- and ferrimagnetic particles. Under external conditions (at a temperature of 80 K) when the ε-Fe2O3 magnetic structure is incommensurate, the coercivity during the pulsed magnetization switching depends already on the parameter dH/dt and is determined, to a great extent, by the maximum applied field Hmax. Such a behavior atypical of systems of ferrimagnetic particles is caused already by the dynamic spin processes inside the ε-Fe2O3 particles during fast magnetization switching.

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Публикация на русском языке Особенности импульсного перемагничивания высококоэрцитивного материала на основе наночастиц ε-Fe2O3 [Текст] / С. И. Попков, А. А. Красиков, С. В. Семенов [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 3. - С. 395-402

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia.

Доп.точки доступа:
Popkov, S. I.; Попков, Сергей Иванович; Krasikov, A. A.; Красиков, Александр Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Yakushkin, S. S.; Kirillov, V. L.; Mart'yanov, O. N.; Balaev, D. A.; Балаев, Дмитрий Александрович; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Krai; Krasnoyarsk Territorial Foundation [18-42-240012]
}
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Structural, magnetic, electronic, and dilatation properties of the ordered solid solutions Ln0.2Sr0.8CoO3-δ (Ln = Sm, Gd, Dy) with the same oxygen nonstoichiometry index δ / V. A. Dudnikov, Y. S. Orlov, M. V. Bushinsky [et al.] // J. Alloy. Compd. - 2020. - Vol. 830. - Ст. 154629, DOI 10.1016/j.jallcom.2020.154629. - Cited References: 44. - The work was financially supported by Russian Foundation for Basic Research (grant No. 19-03-00017); RFBR and BRFFR as a part of scientific project No. 18-52-00017 and project F18R-119; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project: "New thermoelectric materials based on multi-scale spatially inhomogeneous substituted rare-earth cobalt oxides and the Ruddlesden-Popper phases " project No. 18-42-243004, Project of Basic Research SB RAS V.45.3.3. . - ISSN 0925-8388. - ISSN 1873-4669

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
LN(1-X)SR(X)COO(3-DELTA) LN
COBALTATE PEROVSKITES
Кл.слова (ненормированные):
Rare earth cobalt oxide solid solutions -- Layered perovskite-type cobalt oxides -- Structural -- Magnetic -- Electronic -- Dilatation properties
Аннотация: Single-phase samples of the layered perovskite-like cobalt oxides Ln0.2Sr0.8CoO3-δ (Ln = Sm, Gd, Dy) with the same oxygen nonstoichiometry index δ = 0.37 ± 0.01 were synthesized. All samples are characterized by a tetragonal unit cell with the space group I4/mmm. The structural, magnetic, electric transport and dilatation properties of the obtained samples are investigated. The studied samples are characterized by two anomalies in magnetic properties, a high-temperature maximum near Тm = 350 К with magnetic field hysteresis below Tm, and a diffuse peak in the intermediate temperature range, which shifts with ionic radius decrease of the rare-earth element to higher temperatures. The high-temperature maxima of the magnetic susceptibility correlate with anomalies in thermal expansion, heat capacity and the features in the temperature dependences of the electrical resistivity, pointing to a strong relationship between the structural, magnetic and electronic degrees of freedom. The given comparative analysis of the experimental data of various substituting rare-earth elements with the same oxygen nonstoichiometry has been carried out for the first time.

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
RAS, Fed Res Ctr KSC SB, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Lebedev Phys Inst, Moscow 119991, Russia.
NAS Belarus, Sci Pract Mat Res Ctr, Minsk 220072, BELARUS.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Ioffe Inst, St Petersburg 194021, Russia.

Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Orlov, Yu. S.; Орлов, Юрий Сергеевич; Bushinsky, M. V.; Solovyov, L. A.; Vereshchagin, S. N.; Gavrilkin, S. Yu; Tsvetkov, A. Yu; Gorev, M. V.; Горев, Михаил Васильевич; Novikov, S. V.; Mantytskaya, O. S.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-03-00017]; RFBRRussian Foundation for Basic Research (RFBR) [18-52-00017, F18R-119]; BRFFR [18-52-00017, F18R-119]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory [18-42-243004, SB RAS V.45.3.3]
}
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    Materials synthesis, characterization and DFT calculations of the visible-light-active perovskite-like barium bismuthate Ba1.264(4)Bi1.971(4)O4 photocatalyst / D. S. Shtarev, A. V. Shtareva, R. Kevorkyants [et al.] // J. Mater. Chem. C. - 2020. - Vol. 8, Is. 10. - P. 3509-3519, DOI 10.1039/c9tc06457e. - Cited References: 42. - The current research was kindly funded by a grant from the Russian Science Foundation (project No. 19-73-10013). R. K., A. V. R., V. K. R. and T. V. B. acknowledge financial support from Saint-Petersburg State University (Pure ID 39054581). A. V. R. thanks the Russian Foundation for Basic Research for a Grant No. 18-03-00855 that supported studies into the photoinduced hydrophilicity of the bismuthate. The authors are further grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics of the Far Eastern Branch of the Russian Academy of Sciences, and the Resource Centers of the Research Park at the Saint-Petersburg State University: (i) the Center for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, (ii) the Center for Physical Methods of Surface Investigation, (iii) the Center for Optical and Laser Materials Research, and the laboratories of (iv) Nanotechnology and (v) Nanophotonics for their valuable assistance in carrying out the research and in providing the needed equipment. One of us (N.S.) is grateful to Prof. Angelo Albini and the staff of the PhotoGreen Laboratory at the University of Pavia, Italy, for their continued hospitality. . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Синтез, характеризация и DFT-расчеты для перовскитоподобного висмутата бария Ba1.264(4)Bi1.971(4)O4, обладающим фотокаталитическими свойствами при облучении видимым светом

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
OXIDE
   NIO/SRBI2O4
   SPECTRA
   DRIVEN
   CO2
   LA
Аннотация: A perovskite-like barium bismuthate of the BaBi2O4 class, Ba1.264(4)Bi1.971(4)O4, has been prepared by solid-state synthesis and subsequently characterized by a number of experimental techniques (XPS, DRS, SEM, EDX and Raman spectroscopy), as well as by a DFT computational approach using the GGA Perdew–Burke–Ernzerhof (PBE) density functional to determine the energy band structure. XRD peaks were indexed to a rhombohedral cell (R[3 with combining macron]m) with parameters close to Ba0.156Bi0.844O1.422 (i.e., to Ba0.439Bi2.374O4), which upon Rietveld refinement gave Ba1.264(4)Bi1.971(4)O4. The Bi–O bond lengths determined from this refinement (1.86 and 2.31 Å) accorded with the bond lengths estimated from Raman spectra (1.97 and 2.26 Å). DFT calculations revealed the bismuthate to display two bandgaps that correspond to lower-energy indirect (2.28 eV) and to higher-energy direct (2.36 eV) electronic transitions in good agreement with the experimental bandgaps of 2.26 eV and 2.43 eV, respectively, from Tauc plots of DRS spectra. Relative to the indirect bandgap energy of 2.26 eV, the energies of the valence band and of the conduction band were, respectively, +1.14 eV and −1.12 eV. The photoactivity of Ba1.264(4)Bi1.971(4)O4 was examined toward the photoreduction of the greenhouse gas CO2 in aqueous media photoelectrochemically yielding alcohols and alkanes, while in the gas phase in an infrared cell reactor the products were carbon monoxide and alkanes.

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Держатели документа:
Russian Acad Sci, YuA Kosygin Inst Tecton & Geophys, Far Eastern Branch, 65 Kim Yu Chen St, Khabarovsk 680063, Russia.
Far Eastern State Transport Univ, 47 Seryshev St, Khabarovsk 680021, Russia.
St Petersburg State Univ, Lab Photoact Nanocomposite Mat, Ulyanovskaya 1, St Petersburg 198904, Russia.
Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
St Petersburg State Univ, Dept Photon, Ulyanovskaya 1, St Petersburg 198904, Russia.
Univ Pavia, Dipartimento Chim, PhotoGreen Lab, Via Taramelli 12, I-27100 Pavia, Italy.

Доп.точки доступа:
Shtarev, D. S.; Shtareva, A., V; Kevorkyants, R.; Rudakova, A., V; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bakiev, T., V; Bulanin, K. M.; Ryabchuk, V. K.; Serpone, N.; Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]; Saint-Petersburg State University [39054581]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00855]
}
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    The effect of microstructural features on the ferromagnetism of nickel oxide nanoparticles synthesized in a low-pressure arc plasma / A. V. Ushakov, I. V. Karpov, L. Y. Fedorov [et al.] // Physica E. - 2020. - Vol. 124. - Ст. 114352, DOI 10.1016/j.physe.2020.114352. - Cited References: 31. - The work was performed with a support of the grant of the Russian Science Foundation (Project No. 16-19-10054 ). The electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation . - ISSN 1386-9477
   Перевод заглавия: Влияние особенностей микроструктуры на ферромагнетизм наночастиц оксида никеля, синтезированных в дуговой плазме низкого давления
Кл.слова (ненормированные):
Nickel oxide -- Nanoparticles -- Band gap -- Magnetic properties
Аннотация: Nickel oxide nanoparticles were first synthesized by sputtering high-purity nickel in an oxygen plasma of a low-pressure arc discharge. The structure, morphology, and optical and magnetic properties of NiO nanoparticles were studied by XRD, TEM, FTIR, UV-VIS, and VSM. TEM images showed that the obtained NiO nanoparticles have a narrow particle size distribution and an average particle size of 12 nm. The XRD results and the processing of diffractograms by the Rietveld method showed that the obtained nanoparticles have a face-centered cubic lattice with an average particle size of 13 nm. With decreasing temperature, residual stresses increase and peaks corresponding to the superstructure appear. The band gap of NiO was determined from the optical absorption spectrum and amounted to 3.21 eV. Magnetic measurements showed that, at temperatures of 200 and 300 K, NiO nanoparticles, unlike bulk particles, exhibit ferromagnetic behavior, and at 5 K a magnetic hysteresis loop appears. Based on the studies, a dendritic model of the nanoparticle microstructure is proposed.

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Держатели документа:
Federal Research Center “Krasnoyarsk Scientific Center”, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center”, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Ushakov, A. V.; Karpov, I. V.; Fedorov, L. Y.; Demin, V. G.; Goncharova, E. A.; Shaihadinov, A. A.; Zeer, G. M.; Zharkov, S. M.; Жарков, Сергей Михайлович
}
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Order–disorder transition in the Dy0.2Sr0.8CoO3-δ rare-earth cobalt oxide solid solutions: Structural and thermoelectric properties / Y. S. Orlov, V. A. Dudnikov, S. N. Vereshchagin [et al.] // J. Eur. Ceram. Soc. - 2020. - Vol. 40, Is. 15. - P. 5559-5565, DOI 10.1016/j.jeurceramsoc.2020.06.066. - Cited References: 29. - This study was supported by the Russian Science Foundation, project no. 19-72-00097 . - ISSN 0955-2219
Кл.слова (ненормированные):
Substituted rare-earth cobalt oxides -- Thermoelectric oxide materials -- Ordered and disordered states -- Phase transition
Аннотация: By the example of the Dy0.2Sr0.8CoO3-δ compound undergoing an order–disorder phase transition with increasing temperature, we demonstrate a significant dependence of the kinetic properties on the morphology of the internal spatially inhomogeneous structure, which forms in the sample depending on the rate of its transition from the high-temperature disordered cubic phase to the ground tetragonal ordered phase upon cooling. The results of transmission electron microscopy visualization of the spatially inhomogeneous state in the Dy0.2Sr0.8CoO3-δ ceramic samples are presented and compared with the X-ray diffraction data.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Lebedev Physical Institute, Moscow, 119991, Russian Federation

Доп.точки доступа:
Orlov, Yu. S.; Орлов, Юрий Сергеевич; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Vereshchagin, S. N.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Gavrilkin, S. Y.; Tsvetkov, A. Y.
}
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Thermoelectric properties of the SmCoO3 and NdCoO3 cobalt oxides / V. A. Dudnikov, A. S. Fedorov, Y. S. Orlov [et al.] // Ceram. Int. - 2020. - Vol. 46, Is. 11. - P. 17987-17991, DOI 10.1016/j.ceramint.2020.04.113. - Cited References: 41. - This study was supported by the Russian Science Foundation, project no. 16-13-00060. . - ISSN 0272-8842. - ISSN 1873-3956

РУБ Materials Science, Ceramics
Рубрики:
MAGNETIC-PROPERTIES
   SPIN
   CONDUCTIVITY
   TRANSITIONS
   LACOO3
   SITE
Кл.слова (ненормированные):
Perovskite -- Thermoelectric oxide materials
Аннотация: The thermoelectric properties of the NdCoO3 and SmCoO3 rare-earth cobalt oxides with a perovskite structure have been investigated in a wide temperature range. It is shown that, in the low-temperature region, the thermal conductivity of the compounds has a sharp maximum and the electrical conductivity of the samples increases with temperature, whereas the Seebeck coefficient behaves nonmonotonically with increasing temperature. The SmCoO3 oxide is characterized by the positive thermopower over the entire investigated range with a sharp growth in the low-temperature region, attaining the maximum value (S ≈ 1000 μV/K) near room temperature, and a further decrease. It has been established that, in the NdCoO3 oxide, the Seebeck coefficient changes its sign, which was rarely observed in the La-based compounds and is atypical of the undoped rare-earth cobalt oxides. The thermopower maximum obtained at a temperature of 450 K is 400 μV/K. The regions of the fastest growth of the thermoelectric power factor correspond to the anomalies caused by the spin transition of Со3+ ions and the dielectric–metal transition.

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Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Lebedev Phys Inst, Moscow 119991, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Ioffe Inst, St Petersburg 194021, Russia.

Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Orlov, Yu. S.; Орлов, Юрий Сергеевич; Solovyov, L. A.; Vereshchagin, S. N.; Gavrilkin, S. Yu; Tsvetkov, A. Yu; Gorev, M. V.; Горев, Михаил Васильевич; Novikov, S., V; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Science FoundationRussian Science Foundation (RSF) [16-13-00060]
}
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Structure and thermodynamic properties of the SmGaGe2O7 oxide / L. T. Denisova, M. S. Molokeev, L. A. Irtyugo [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P. 384-387, DOI 10.1134/S1063783420020109. - Cited References: 10. - This study was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation to the Siberian Federal University in 2017–2019, project no. 4.8083.2017/8.9 “Formation of a Data Bank of Thermodynamic Characteristics of the Complex-Oxide Multifunctional Materials Containing Rare and Scattered Elements.” . - ISSN 1063-7834
Кл.слова (ненормированные):
samarium gallium germanate -- structure -- heat capacity
Аннотация: The SmGaGe2O7 oxide material has been obtained from initial Sm2O3, Ga2O3, and GeO2 oxides by solid-phase synthesis with annealing in air in the temperature range of 1273–1473 K. The structure of the investigated germanate (sp. gr. P21/c, a = 7.18610(9) Å, b = 6.57935(8) Å, and c = 12.7932(2) Å) has been established by X-ray diffraction and the high-temperature heat capacity has been determined by differential scanning calorimetry. Using the experimental data on Cp = f(T), the thermodynamic properties of the compound have been calculated.

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Публикация на русском языке Структура и термодинамические свойства SmGaGe2O7 [Текст] / Л. Т. Денисова, М. С. Молокеев, Л. А. Иртюго [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 2. - С. 332-335

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Irtyugo, L. A.; Beletskii, V. V.; Belousova, N. V.; Denisov, V. M.
}
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Core-shell iron oxide-carbon nanoparticles modified with Ag. synthesis, morphology, magnetic properties / D. A. Petrov, R. D. Ivantsov, S. M. Zharkov [et al.] // Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст. J.P18. - P. 220-221. - Cited References: 2. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project No. 18-42-243021 and by Joint Research Project of Russian Foundation for Basic Research and Ministry of Science and Technology, Taiwan MOST No. 19-52-52002 . - ISBN 978-5-9500855-7-4

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
National Pingtung University, Pingtung County, Taiwan

Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Petrov, D. A.; Петров, Дмитрий Анатольевич; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Lin, C.-R.; Tseng, Y.-T.; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
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Unusual magnetic behavior of polymorph iron oxide ϵ-Fe2O3 nanoparticles: magnetic phase diagram and surface effects / D. A. Balaev, A. A. Dubrovskiy, S. V. Semenov [et al.] // Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст. J.I2. - P. 164-165. - Cited References: 15. - This work was supported by the Russian Science Foundation, project no. 17-12-01111 . - ISBN 978-5-9500855-7-4

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Boreskov Institute of Catalysis, SB RAS

Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Krasikov, A. A.; Красиков, Александр Александрович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Bayukov, O. A.; Баюков, Олег Артемьевич; Yakushkin, S. S.; Kirillov, V. L.; Bukhtiyarova, G. A.; Martyanov, O. A.; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
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}
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10.

Gavrichkov, V. A.
Cation spin and superexchange interaction in oxide materials below and above spin crossover under high pressure / V. A. Gavrichkov, S. I. Polukeev, S. G. Ovchinnikov // Phys. Rev. B. - 2020. - Vol. 101, Is. 9. - Ст. 094409, DOI 10.1103/PhysRevB.101.094409. - Cited References: 65. - We acknowledge the support of the Russian Science Foundation through Grant No. 18-12-00022 . - ISSN 2469-9950. - ISSN 2469-9969

РУБ Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
EXCHANGE INTERACTION
   PHASE-TRANSITIONS
   STATE
   ELECTRON
   IRON
Аннотация: We derived simple rules for the sign of 180° superexchange interaction based on the multielectron calculations of the superexchange interaction in the transition metal oxides that are valid both below and above spin crossover under high pressure. The superexchange interaction between two cations in dn configurations is given by a sum of partial contributions related to the electron-hole virtual excitations to the different states of the dn+1 and dn−1 configurations. Using these rules, we have analyzed the sign of the 180° superexchange interaction of a number of oxides with magnetic cations in electron configurations from d2 until d8: the iron, cobalt, chromium, nickel, copper, and manganese oxides with increasing pressure. The most interesting result concerns the magnetic state of cobalt and nickel oxides CoO, Ni2O3 and also La2CoO4, LaNiO3 isostructural to well-known high-TC and colossal magnetoresistance materials. These oxides have a spin 12 at the high pressure. Change of the interaction from antiferromagnetic below spin crossover to ferromagnetic above spin crossover is predicted for oxide materials with cations in d5(FeBO3) and d7(CoO) configurations, while for materials with the other dn configurations spin crossover under high pressure does not change the sign of the 180∘ superexchange interaction.

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Держатели документа:
Kirensky Inst Phys, Akadeingorodok 50,Bld 38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович; Russian Science FoundationRussian Science Foundation (RSF) [18-12-00022]
}
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11.

Synthesis and magnetic properties of the core-shell Fe3O4/CoFe2O4 nanoparticles / D. A. Balaev, S. V. Semenov, A. A. Dubrovskii [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P. 285-290, DOI 10.1134/S1063783420020043. - Cited References: 37. - This study was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
MOSSBAUER
ENSEMBLE
Кл.слова (ненормированные):
oxide nanoparticles -- core-shell structure -- coercivity
Аннотация: The Fe3O4/CoFe2O4 nanoparticles with a core-shell structure with an average size of 5 nm have been obtained by codeposition from the iron and cobalt chloride solutions. An analysis of the magnetic properties of the obtained system and their comparison with the data for single-phase Fe3O4 (4 nm) and CoFe2O4 (6 nm) nanoparticles has led to the conclusion about a noticeable interaction between the soft magnetic (Fe3O4) and hard magnetic (CoFe2O4) phases forming the core and shell of hybrid particles.

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Публикация на русском языке Синтез и магнитные свойства наночастиц Fe3O4/CoFe2O4 со структурой ядро/оболочка [Текст] / Д. А. Балаев, С. В. Семенов, А. А. Дубровский [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 2. - С. 235-240

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia.

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Popkov, S. I.; Попков, Сергей Иванович; Yakushkin, S. S.; Kirillov, V. L.; Mart'yanov, O. N.; Russian Science FoundationRussian Science Foundation (RSF) [17-12-01111]
}
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12.

Transport and magnetic phenomena in ZnO-С thin-film heterostructures / M. N. Volochaev, A. B. Granovsky, O. V. Zhilova [et al.] // Superlattices Microstruct. - 2020. - Vol. 140. - Ст. 106449, DOI 10.1016/j.spmi.2020.106449. - Cited References: 36. - The work was supported by the Ministry of Education and Science of Russia (project No. 3.1867.2017/4.6 ) and the RFBR (project No. 19-07-00471). The work was partially funded by the Academy of Finland . - ISSN 0749-6036
Кл.слова (ненормированные):
Zinc oxide -- Amorphous carbon -- Multi-layered structures -- Composites -- Hopping conductivity -- Weak localization -- Magnetoresistance
Аннотация: ZnO- and C-based heterostructures were fabricated by the layer-by-layer deposition technique using the ion-beam sputtering process. Structure, electrical and magnetic properties of fabricated heterostructures are discussed. The two-phase (ZnO and C) films are evolved into a multilayer structure, consisting of amorphous carbon and crystalline ZnO layers when the bilayer thickness increases. When carbon is added to ZnO, its electrical resistivity reduces. The conduction mechanism changes from the variable-range hopping in a narrow energy band to the nearest neighbors hopping in ZnO–C films with a thickness of h ˂ 150 nm. The temperature dependence of conductivity changes from the Arrhenius-like to logarithmic law, indicating that the strong charge localization turns into a weak one when the film thickness is about 150 nm. The negative magnetoresistance of up to 1% was detected at 77 K. The film ferromagnetism at the temperature of 10 K was not found.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk660036, Russian Federation
Lomonosov Moscow State University, Moscow119991, Russian Federation
Voronezh State Technical University, Voronezh394026, Russian Federation
National Research Centre ‘‘Kurchatov Institute”, Moscow123182, Russian Federation
Voronezh State University, Voronezh394003, Russian Federation
Lappeenranta-Lahti University of Technology, Lappeenranta FI53851, Finland

Доп.точки доступа:
Volochaev, M. N.; Волочаев, Михаил Николаевич; Granovsky, A. B.; Zhilova, O. V.; Kalinin, Y. E.; Ryl'kov, V. V.; Sumets, M. P.; Makagonov, V. A.; Pankov, S. Y.; Sitnikov, A. V.; Fadeev, E.; Lahderanta, E.; Foshin, V.
}
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13.

The Sr2.4Dy0.6Co2O7-δ Ruddlesden‒Popper Phase: Structural, thermoelectric, and magnetic properties / V. A. Dudnikov, Y. S. Orlov, L. A. Solovyov [et al.] // Ceram. Int. - 2021. - Vol. 47, Is. 7, Part A. - P. 9068-9074, DOI 10.1016/j.ceramint.2020.12.030. - Cited References: 39. - The study was supported by the Russian Foundation for Basic Research , project no. 19-03-00017 and the budget project #АААА-А17-117021310222-4 for the Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences . - ISSN 0272-8842
Кл.слова (ненормированные):
Rare-earth substituted cobalt oxides -- Ruddlesden-Popper phase -- Thermoelectric oxide materials -- Magnetic properties
Аннотация: A new anion-deficient Sr2.4Dy0.6Co2O7‒δ (δ = 0.33–1.1) perovskite phase with a structure of the A3B2O7 Raddlesden‒Popper homologous series has been obtained by the solid-state synthesis in the reducing/oxidizing atmosphere and its structural characterization has been performed by the Rietveld refinement of the X-ray powder diffraction data. It has been stablished that the Sr2.4Dy0.6Co2O7‒δ compound (sp. gr. I4/mmm) has parameters of a = b = 3.8526(1) and c = 19.9431(7) Å in the reduced form (δ = 1.1) and a = b = 3.8086(1) and c = 19.9190(6) Å in the oxidized form (δ ≈ 0.33) and oxygen vacancies occupy mainly the sites linking CoO5 polyhedra inside two perovskite layers. It has been established using differential scanning calorimetry and thermogravimetry that, at T < 530 K, the synthesized phase is stable against the inert and oxidizing atmosphere; at higher temperatures, the Sr2.4Dy0.6Co2O7-δ compound can reversibly absorb/release oxygen. The magnetic properties of the Sr2.4Dy0.6Co2O6.09 compound have been investigated in the temperature range of 10–400 K and described in terms of the formation of dimers, in which the Co3+‒Co3+ and Co2+‒Co2+ ion pairs antiferromagnetically interact and are in the nonmagnetic ground state. The electrical conductivity and the Seebeck coefficient have been measured in air in the temperature range from 300 to 800 K. An observed sharp decrease in the Seebeck coefficient of the Sr2.4Dy0.6Co2O7-δ compound and the change in its sign near 700 K have been attributed to the transition of cobalt ions to the Co3+ state and the charge disproportionation of Co3+ ions to Co2+ and Co4+ ones.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russian Federation

Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Orlov, Yu. S.; Орлов, Юрий Сергеевич; Solovyov, L. A.; Vereshchagin, S. N.; Gavrilkin, S. Y.
}
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14.

Magnetic properties of iron oxide nanoparticles to create aptamer bionanoconjugates / A. Е. Sokolov, V. N. Zabluda, A. V. Sherepa [et al.] // Molecular Therapy - Nucleic Acids : book of abstracts of the 1st Int. conf. "Aptamers in Russia 2019". - 2019. - Vol. 17, Suppl. 1. - P. 12

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Доп.точки доступа:
Sokolov, A. Е.; Соколов, Алексей Эдуардович; Zabluda, V. N.; Заблуда, Владимир Николаевич; Sherepa, A. V.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Kurilina, A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Goncharova, D. A.; Shabalina, A.; Шабалина Анастасия; Svetlichnyi, V.; Светличный В.; Aptamers in Russia, international conference(1 ; 2019 ; Aug. 27-30 ; Krasnoyarsk)
}
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15.

Magnetic and optical properties of the iron oxide nanoparticles obtained via pulsed laser ablation / A. V. Kurilova, A. Е. Sokolov, V. A. Svetlichniy [et al.] // The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials : Proceedings. - VLadivostok : Dalnauka Publishing, 2020. - Ст. IV.31.05p. - P. 114. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No.17-42-240080 . - ISBN 978-5-8044-1698-1

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Доп.точки доступа:
Kurilova, A. V.; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Svetlichniy, V. A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Sherepa, A. V.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Goncharova, D. A.; Shabalina, A. V.; Asian School-Conference on Physics and Technology of Nanostructured Materials(5 ; 2020 ; 30 Jul - 3 Aug ; Vladivostok); Азиатская школа-конференция по физике и технологии наноструктурированных материалов(5 ; 2013 ; 30 июля - 3 авг. ; Владивосток)
}
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16.

Synthesis, Crystal Structure and Thermodynamic Properties of LuGaTi2O7 / L. T. Denisova, M. S. Molokeev, L. G. Chumilina [et al.] // Inorg. Mater. - 2020. - Vol. 56, Is. 12. - P. 1242-1247, DOI 10.1134/S0020168520120055. - Cited References: 25 . - ISSN 0020-1685
Кл.слова (ненормированные):
lutetium gallium titanate -- mixed oxide compounds -- high-temperature heat capacity -- thermodynamic properties
Аннотация: Single-phase LuGaTi2O7 samples have been prepared by solid-state reaction in a starting mixture of Lu2O3, Ga2O3, and TiO2 via sequential firing in air at temperatures of 1273 and 1573 K. The crystal structure of the lutetium gallium dititanate has been determined by the Rietveld method (profile analysis of X-ray diffraction patterns of polycrystalline powders): sp. gr. Pcnb; a = 9.75033(13) Å, b = 13.41425(17) Å, c = 7.29215(9) Å, V = 957.32(2) Å3, d = 6.28 g/cm3. The heat capacity of LuGaTi2O7 has been determined as a function of temperature by differential scanning calorimetry in the range 320–1000 K. The Cp(T) data thus obtained have been used to calculate the principal thermodynamic functions of the oxide compound.

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Публикация на русском языке Синтез, кристаллическая структура и термодинамические свойства LuGaTi2O7 [Текст] / Л. Т. Денисова, М. С. Молокеев, Л. Г. Чумилина [и др.] // Неорган. матер. - 2020. - Т. 56 № 12. - С. 1311-1316

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620016, Russian Federation

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Chumilina, L. G.; Kargin, Y. F.; Denisov, V. M.; Ryabov, V. V.
}
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17.

    Atomic layer deposition ZnO on porous Al2O3 nanofibers film / A. S. Voronin, A. N. Masiygin, M. S. Molokeev, S. V. Khartov // J. Phys. Conf. Ser. - 2020. - Vol. 1679, Is. 2. - Ст. 022072DOI 10.1088/1742-6596/1679/2/022072. - Cited References: 10. - Studies by scanning electron microscopy and X-ray powder diffraction were performed on the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS». The transmission electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
   Перевод заглавия: Нанесение атомного слоя ZnO на пленку из пористых нановолокон Al2O3
Кл.слова (ненормированные):
Alumina -- Aluminum oxide -- Atomic layer deposition -- Atoms -- Composite structures -- High resolution transmission electron microscopy -- II-VI semiconductors -- Nanofibers -- Oxide minerals -- Scanning electron microscopy
Аннотация: The paper presents the results of the formation and study of the morphological and structural characteristics of the mesoporous ZnO / Al2O3 nanofibers film (ZANF). The deposition of a ZnO layer on Al2O3 nanofibers film (ANF) ~ 1 µm thick was carried out by the method of atomic layer deposition. The morphology of the mesoporous composite layer ZnO / Al2O3 (ZANF) has been studied by scanning and transmission electron microscopy. It is shown that in the process of atomic layer deposition, the ZnO layer grows according to the Stranski-Krastanov mechanism. A ZnO layer less than 5 nm thick gives an island structure in which Al2O3 nanofibers are uniformly coated with ZnO particles, an increase in the ZnO layer thickness to 15 nm demonstrates a continuous coating of Al2O3 nanofibers. The system has a core-shell structure. The resulting composite structures are promising for applications in photocatalysis and gas sensing.

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Держатели документа:
Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences (KSC SB RAS), Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Reshetnev Siberian State University Science and Technology, Krasnoyarsk, 660037, Russian Federation
Kirensky Institute of Physics (FRC KSC SB RAS), Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Voronin, A. S.; Masiygin, A. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Khartov, S. V.; International Scientific Conference on Applied Physics, Information Technologies and Engineering(2nd ; 25 September - 4 October 2020 ; Krasnoyarsk, Russian Federation)
}
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18.

Magneto-optical properties of the iron oxide nanoparticles obtained by laser ablation / A. V. Kurilova, A. Е. Sokolov, A. V. Sherepa [et al.] // Pulsed lasers and laser applications (AMPL-2019) : abstracts of XIV Int. conf. - 2019. - Ст. B-12. - P. 61-62 . - ISBN 978-5-93629-634-5

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Доп.точки доступа:
Sokolov, A. Е.; Соколов, Алексей Эдуардович; Kurilova, A. V.; Sherepa, A. V.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Goncharova, D. A.; Shabalina, A. V.; Svetlichnyi, V.; Светличный В.; Pulsed Lasers and Laser Applications, International Conference(14 ; 2019 ; 15-20 Sept. ; Tomsk)
}
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19.

Microstructure and magnetic properties of Co58Ni10Fe5B16Si11 and Co58Ni10Fe5B16Si11-Al2O3 bulk amorphous coatings prepared by plasma spraying / E. A. Denisova, I. V. Nemtsev, S. V. Telegin [et al.] // J. Phys.: Conf. Ser. - 2020. - Vol. 1582, Is. 1. - Ст. 012078DOI 10.1088/1742-6596/1582/1/012078. - Cited References: 18. - This work was funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 18-42-240006 Nanomaterials with magnetic properties determined by the topological features of the nanostructure). The authors thank the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” for the provided equipment
Кл.слова (ненормированные):
Alumina -- Aluminum oxide -- Cobalt alloys -- Composite coatings -- Deposits -- Glass -- Heat treatment -- Industrial research -- Iron alloys -- Magnetic properties -- Magnetism -- Microstructure -- Nanocrystalline materials -- Nanocrystals -- Plasma jets -- Plasma spraying -- Silicon -- Silicon alloys
Аннотация: The bulk soft magnetic glassy Co58Ni10Fe5B16Si11 alloy specimens have been prepared by plasma spray deposition. In order to increase resistivity of the material, the bulk Co58Ni10Fe5B16Si11-Al2O3 composite materials were fabricated. The investigations of structure and magnetic properties of the bulk samples were carried out by X-ray diffraction, electron microscopy and magnetic measurements. The relation of the structural features and magnetic characteristics of the bulk coating to the main parameters of the deposition regimes was determined. Optimized plasma spray deposition parameters allowed obtaining bulk glassy samples with magnetic parameters that are not inferior to the characteristics of a thermally treated rapidly quenched ribbon with the same composition. It was found that the bulk amorphous coatings can be characterized as a heterophase system. The relaxation annealing of the Co58Ni10Fe5B16Si11 bulk coating leads to a phase transition in this alloy in the precrystallization temperature range. The magnetic properties of the both kinds of coatings are correlated with changes in the microstructure. The appearance of nanocrystalline phase with TC640 K during relaxation heat treatment leads to a decrease of the coercivity and to an increase of the permeability. A comparison between the magnetic properties of the CoNiFe-BSi coating and (CoNiFe-BSi)-Al2O3, composite coating is carried out.

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Держатели документа:
Kirensky Institute of Physics, Sb Russian Academy of Sciences, 50/38, Akademgorodok str., Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 73 Svobodny ave., Krasnoyarsk, 660041, Russian Federation
Scientific Center, Federal Research Center Ksc Sb Ras, 50 Akademgorodok str., Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy ave., Krasnoyarsk, 660037, Russian Federation
Krasnoyarsk Institute of Railways Transport, Novaja Zarja str., Krasnoyarsk, Russian Federation

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Nemtsev, I. V.; Telegin, S. V.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Kuzovnikova, L. A.; Shepeta, N. A.; International Conference on High-Tech and Innovations in Research and Manufacturing(2020 ; 28 Feb. ; Krasnoyarsk)
}
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20.

    Magnetic and structure properties of CoPt-In2O3 nanocomposite films / L. E. Bykova, V. G. Myagkov, V. S. Zhigalov [et al.] // J. Sib. Fed. Univ. Math. Phys. - 2020. - Vol. 13, Is. 4. - P. 431-438 ; Журн. СФУ. Матем. и физика, DOI 10.17516/1997-1397-2020-13-4-431-438. - Cited References: 29. - This study was supported by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects no. 19-43-240003 . - ISSN 1997-1397. - ISSN 2313-6022
   Перевод заглавия: Магнитные и структурные свойства нанокомпозитных пленок CoPt-In2O3

РУБ Mathematics
Рубрики:
THIN-FILMS
TEMPERATURE
PHASE
Кл.слова (ненормированные):
thin films -- ferromagnetic nanocomposites -- CoPt alloy -- In2O3 oxide -- тонкие пленки -- ферромагнитные нанокомпозиты -- сплав CoPt -- оксид In2O3
Аннотация: The structural and magnetic properties of CoPt-In2O3 nanocomposite films formed by vacuum annealing of the In/(Co3O4 + Pt)/MgO film system in the temperature range of 100–800 °C have been investigated. The synthesized nanocomposite films contain ferromagnetic CoPt grains with an average size of 5nm enclosed in an In2O3 matrix, and have a magnetization of 600 emu/cm3, and a coercivity of 150 Oe at room temperature. The initiation 200 °C and finishing 800 °C temperatures of synthesis were determined, as well as the change in the phase composition of the In/(Co3O4 + Pt)/MgO film during vacuum annealing.
Исследованы структурные и магнитные свойства нанокомпозитных пленок CoPt- In2O3, полученных вакуумным отжигом пленочной системы In/(Co3O4 + Pt)/MgO в интервале температур 100 – 800 °C. Синтезированные нанокомпозитные пленки содержали ферромагнитные CoPt-кластеры со средним размером 5 nm, заключенные в матрицу In2O3, и имели намагниченность 600 emu/cm3, коэрцитивную силу 150 Oe при комнатной температуре. Определены температуры начала 200 °C и окончания 800 °C синтеза, а также изменение фазового состава пленки In/(Co3O4 + Pt)/MgO при вакуумном отжиге.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.
Fed Res Ctr KSC SB RAS, Inst Chem & Chem Technol, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.

Доп.точки доступа:
Bykova, L. E.; Быкова, Людмила Евгеньевна; Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Bondarenko, G. N.; Patrin, G. S.; Патрин, Геннадий Семёнович; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory [19-43-240003]

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