1. ![](http://irbiscorp.spsl.nsc.ru/webirbis-htdocs/images/printer.jpg)
|
Вид документа : Статья из журнала Шифр издания :
Автор(ы) : Mel'nikova S. V., Bogdanov E. V., Molokeev M. S., Laptash N. M., Flerov I. N.
Заглавие : Optical and calorimetric studies of K2TaF7
Место публикации : J. Fluor. Chem. - 2019. - Vol. 222-223. - P.75-80. - ISSN 00221139 (ISSN) , DOI 10.1016/j.jfluchem.2019.04.016 Примечания : Cited References: 26. - The reported study was funded by RFBR according to the research project № 18-02-00269.
Аннотация: Optical and calorimetric experiments on K2TaF7 are performed in a wide temperature range. No features were found in the behavior of the birefringence Δnb(T), the angle of rotation of the indicatrix ϕ(T) and the heat capacity ΔCp(T) except for those associated with the Pnma↔P21/c phase transition. Structural transformation was characterized as strong first order “proper” ferroelastic accompanied by a huge angle ϕ ≈40° and strong pre-transition phenomena in Δnb(T). Two contributions to the anomalies of the optical properties were found associated with the photoelastic effect and the transition parameter related linearly to the spontaneous deformation. Thermal treatments cause correlated changes in temperature and enthalpy of the phase transition, which leads to the invariance of the large magnitude of the corresponding entropy ΔS = 22 J/mol·K which does not match the model with the absence of structural disorder in the Pnma phase.
Смотреть статью, Scopus, WOS, Читать в сети ИФ Найти похожие
|