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Библиотека института физики им. Л.В. Киренского СО РАН
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Каталог книг и брошюр библиотеки ИФ СО РАН
Каталог журналов библиотеки ИФ СО РАН
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1.
Вид документа
: Статья из журнала
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Автор(ы)
: Li Y., Gai S., Zhu H., Yin J., Guo W., Molokeev M. S., Lu X., Xia M., Zhou Z.
Заглавие
: Abnormal Bi3+ activated NIR phosphor toward multifunctional LED applications
Колич.характеристики
:10 с
Место публикации
: Ceram. Int. - 2023. - Vol. 49, Is. 23, Pt. B. - P.39671-39680. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2023.09.322. - ISSN 18733956 (eISSN)
Примечания
: Cited References: 45. - This research was jointly supported by the National Natural Science Foundation of China (Grant No. 51974123 ), the Key R & D Projects in Hunan Province ( 2021SK2047 , 2022NK2044 ), the Natural Science Foundation of Hunan Province, China (Grant No. 2021JJ40261 ), Wangcheng Science and Technology Plan ( KJ221017 ), the Science and Technology Innovation Program of Hunan Province ( 2022WZ1022 ) and the Strategic Academic Leadership Program “Priority-2030” for the Siberian Federal University
Аннотация:
Herein, the strategy of replacing Ge4+ with smaller Si4+ was adopted to realize the site-selective occupation of Bi3+ activator in the small ring and obtain a near-infrared light-emitting in Zn2(Ge,Si)O4. The designed phosphor exhibits a broad NIR emission with FWHM ≈104 nm in the 650−860 nm region, with a center emission wavelength of about 750 nm. Interestingly, the more sensitive four-member ring sites gradually replaced the six-member ring sites and realized a large-scope photoluminescence regulation from blue to NIR by just after the crystal field engineering. The possible reasons for this phenomenon can be interpreted by centroid shift (εc) and crystal field splitting (εcfs). This work not only provides new insights for the development of Bi3+-activated NIR-emitting phosphors, but also provides thoughts for revealing the potential NIR luminous mechanism of Bi3+.
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2.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Pugachev A. M., Zaytseva I. V., Surovtsev N. V., Krylov A. S.
Заглавие
: Anharmonicity and local noncentrosymmetric regions in BaTiO3 pressed powder studied by the Raman line temperature dependence
Место публикации
: Ceram. Int. - 2020. - Vol. 46, Is. 14. - P.22619-22623. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2020.06.024
Примечания
: Cited References: 26. - The reported study was funded by RFBR , according to the research project No. 18-02-00399 and 19-42-543-016 , Government of Novosibirsk region No. 19-42-543-016 and State assignment No AAAA-A17-117052410033-9. The experiments were performed in the multiple-access center “High-Resolution Spectroscopy of Gases and Condensed Matter” in IA&E SB RAS (Novosibirsk, Russia) and Center for Common Use of the Krasnoyarsk Scientific Center, SB RAS (Krasnoyarsk, Russia)
Аннотация:
The temperature dependencies of position, width, and integral amplitude the E(TO) line near 307 cm−1 in Raman spectra in barium titanate powders with different non-hydrostatic pressure and temperature treatment were studied. It was found that parameters of the E(TO) line near 307 cm−1 are different in the crystal, the untreated powder, the powder treated by the non-hydrostatic pressure, and the powder annealed after the pressure treatment. The line width (FWHM) increase with temperature according to Klemens model. It indicates that the origin of the line broadening is the anharmonicity of the E(TO) phonons. The pressure treatment changes the anharmonicity of the phonon potential. It was found that the temperature dependence of the integral intensity of the E(TO) line is similar to that of the second optical harmonic signal and reflects the presence of the local polar regions. Thus, the E(TO) line in the Raman spectrum allows one to characterize the average polarity of local regions and their anharmonicity depending on non-hydrostatic pressures and thermal treatment.
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3.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Udod L. V., Sitnikov M. N.
Заглавие
: Electronic transition, ferroelectric and thermoelectric properties of bismuth pyrostannate Bi2(Sn0.85Cr0.15)2O7
Место публикации
: Ceram. Int. - 2018. - Vol. 44, Is. 2. - P.1614-1620. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2017.10.082
Примечания
: Cited References: 41. - The authors would like to thank M. Molokeev for the clarification of x-ray spectra. The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project № 16–52-00045 bel_a.
Ключевые слова
(''Своб.индексиров.''): dielectric properties--ferroelectric properties--impedance--thermopower--electrical properties
Аннотация:
The ferroelectric properties of bismuth pyrostannate Bi2(Sn0.85Cr0.15)2O7 in the high-temperature region are established. The linear thermal expansion coefficient, electrical resistance, impedance, I−V characteristics, capacitance, loss-angle tangent, charge, and thermopower of the investigated material are measured in the temperature range of 300−700 K at frequencies of 102−106 Hz. Anomalies of the thermal expansion coefficient and hodograph spectrum variation in the region of polymorphic phase transitions are observed. The high resistance and change of the hopping conductivity for the tunnel-emission are found. The hysteresis in the electric field dependence of polarization is established. The change in the thermopower sign with temperature is revealed. The obtained experimental data are explained in the framework of the model of migration polarization by charged chromium ions.
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4.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Avramov P. V., Ovchinnikov S. G.
Заглавие
: Non-diagram transitions in polarized X-ray absorption CuL(3) spectra of HTSC-
ceramics
Место публикации
: Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1996. - Vol. 38, Is. 11. - P3226-3240. - ISSN 0367-3294
Примечания
: Cited References: 28
Предметные рубрики:
HIGH-TC SUPERCONDUCTIVITY
LA2CUO4
ALPHA
SATELLITES
STATES
OXIDES
XANES
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5.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Bormanis K., Gorev M. V., Flerov I. N., Sternberg A., Lace L., Ignatans R., Kalvane A., Antonova M.
Заглавие
: Behaviour of thermal expansion of (1-x)Pb(Ni1/3Nb2/3)O3-xPbTiO3 solid solutions
Место публикации
: Proc. Est. Acad. Sci. - 2017. - Vol. 66, Is. 4. - P.363-371. - ISSN 17366046 (ISSN),
DOI
10.3176/proc.2017.4.09
Примечания
: Cited References: 25. - The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.
Ключевые слова
(''Своб.индексиров.''): ferroelectrics--relaxors--
ceramics
--solid solutions--thermal expansion--phase diagram
Аннотация:
The features of the dependence of the bulk coefficient of thermal expansion of the (1-x)Pb(Ni1/3Nb2/3)O3-xPbTiO3 solid solution studied in the series of x = 0-0.8 in the temperature range from 100 to 750 K are reported. The obtained data and observed anomalies of thermal expansion are compared with dielectric properties, heat capacity, and the phase diagram of concentration. The anomalous and lattice constituents of deformation and of the coefficient of thermal expansion are analysed and the data on deformation are used to estimate the Burns temperature and the mean square polarization of the samples found to decrease with the decrease of the PbTiO3 concentration.
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Belyaev B. A., Drokin N. A., Poluboyarov V. A.
Заглавие
: Impedance spectroscopy study of the electrical properties of cation-substituted barium hexaaluminate
ceramics
Место публикации
: Phys. Solid State. - 2018. - Vol. 60, Is. 2. - P.274-280. - ISSN 1063-7834,
DOI
10.1134/S1063783418020063. - ISSN 1090-6460(eISSN)
Примечания
: Cited References:18
Предметные рубрики:
DIELECTRIC-RELAXATION
LIQUID-CRYSTALS
SPECTRA
Аннотация:
We report on the behavior of frequency and temperature dependences of the impedance of a measuring cell in the form of a parallel-plate capacitor filled with barium hexaaluminate
ceramics
with four aluminum cations replaced by iron (BaO · 2Fe2O3 · 4Al2O3). The measurements have been performed in the frequency range of 0.5–108 Hz at temperatures of 20-375°C. A technique for determining the electrical properties of the investigated
ceramics
is proposed, which is based on an equivalent electric circuit allowing the recorded impedance spectra to be approximated with sufficiently high accuracy. The established spectral features are indicative of the presence of two electric relaxation times different from each other by three orders of magnitude. This fact is explained by the difference between the charge transport processes in the bulk of crystallites and thin intercrystallite spacers, for which the charge activation energies have been determined.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Udod L. V., Sitnikov M. N., Shestakov N. P.
Заглавие
: Bi2(Sn0.95Cr0.05)2O7: Structure, IR spectra, and dielectric properties
Место публикации
: Ceram. Int.: Elsevier, 2016. - Vol. 42, Is. 4. - P.5177-5183. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2015.12.040
Примечания
: Cited References: 45. - This work was supported by the Russian Foundation for Basic Research Projects no. 15-42-04099 r_siberia_a, Siberian Branch of Science and NAS of Belarus “Electronic and magnetic phase transitions in materials with magnetoelectric affect” and government work no. 114090470016.
Предметные рубрики:
BISMUTH PYROSTANNATE
PYROCHLORE STRUCTURE
MAGNETIC-PROPERTIES
PARTIAL OXIDATION
HIGH-TEMPERATURE
X-RAY
Bi2Sn2O7
SUBSTITUTION
CATALYSTS
DIFFRACTION
Ключевые слова
(''Своб.индексиров.''): bismuth pyrostannate--infrared absorption spectra--structural transition--permittivity--debye model
Аннотация:
Infrared absorption spectra of the bismuth pyrostannate Bi2(Sn0.95Cr0.05)2O7 were investigated in the frequency range 350-1100 cm-1 at temperatures of 110-525 K. Four frequency regions with split absorption lines are distinguished. Softening of frequencies at the structural transitions was observed. The maxima of permittivity measured in the frequency range 1-200 kHz at temperatures 100-400 K were determined. It was found that the magnetic susceptibility changes its sign in the low-temperature region. The correlation between anomalies in the magnetic susceptibility, permittivity, and absorption line intensity was established. Softening of frequencies is explained by the variation in the coefficient of thermal expansion of the lattice. The temperature behavior of permittivity is described using the Debye model. © 2015 Elsevier Ltd and Techna Group S.r.l.
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8.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Drokin N. A., Kiiko V. S., Pavlov A. V., Malkin A. I.
Заглавие
: BT-30 Ceramic Electrophysical Properties
Место публикации
: Refract. Ind. Ceram. - 2020. - Vol. 61, Is. 3. - P.341-348. - ISSN 1083-4877 (ISSN),
DOI
10.1007/s11148-020-00484-2. - ISSN 1573-9139 (eISSN)
Примечания
: Cited References: 12
Аннотация:
A total complex resistance (impedance) method is used to study the electrophysical characteristics of (BeO + TiO2)-
ceramics
modified with TiO2 micro- and nanoparticles in an amount of 30 wt.% (BT-30). Dispersion of the actual ε′ and imaginary ε′′ components of the dielectric permittivity component and specific conductivity in the frequency range from 100 Hz to 100 MHz from room temperature to the boiling point of liquid nitrogen are determined. High values of ε′ and ε′′ in the low-frequency range are typical for structurally inhomogeneous materials due to the accumulation of electric charges at the surface and within microcrystals. Two dielectric relaxation processes associated with electrical conductivity within the body and at the surface of
ceramics
are detected for the first time. An increase in conductivity with an increase in the microwave field frequency above 1 MHz is explained by the appearance of a current relaxation component. The activation energy of the static resistance of ceramic specimens is determined as a function of the reciprocal temperature that depends little on the weight content of TiO2 nanoparticles and varies in the range of 0.024 – 0.10 eV This also confirms the existence of two independent conduction processes, weakly dependent on the nanoparticle content in the ceramic composition. With placement of ceramic in a high-frequency electric field, spatial charges are formed, the field of which contributes to creation of additional polarization and dielectric losses.
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9.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Flerov I. N., Mikhaleva E. A., Gorev M. V., Kartashev A. V.
Заглавие
: Caloric and multicaloric effects in oxygen ferroics and multiferroics
Коллективы
: Всероссийская конференция по физике сегнетоэлектриков
Место публикации
: Phys. Solid State/ Всероссийская конференция по физике сегнетоэлектриков (20 ; 2014 ; 18-22 авг. ; Красноярск): MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 3. - P.429-441. - ISSN 1063,
DOI
10.1134/S1063783415030075. - ISSN 10906460(eISSN)
Примечания
: Cited References:53. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-924.2014.2).
Предметные рубрики:
PHASE-TRANSITIONS
MAGNETOCALORIC MATERIALS
ELECTROCALORIC MATERIALS
REFRIGERATION
CERAMICS
OXYFLUORIDES
Аннотация:
The main problems of the current state-of-the-art research into the caloric effects observed in oxygen ferroics, multiferroics, and composites, as well as the influence of different factors (anisotropy, dimensional parameters, direct and indirect interferroic interactions) on these effects, have been considered. Possible ways to increase the caloric efficiency of materials have been analyzed.
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10.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Fomenko E. V., Akimochkina G. V., Knyazev Yu. V., Semenov S. V., Yumashev V. V., Solovyov L. A., Anshits A. G.
Заглавие
: Characterization and magnetic properties of sintered glass-
ceramics
from dispersed fly ash microspheres
Место публикации
: Magnetochemistry. - 2023. - Vol. 9, Is. 7. - Ст.177. - ISSN 23127481 (eISSN),
DOI
10.3390/magnetochemistry9070177
Примечания
: Cited References: 50. - Russian Science Foundation and the Krasnoyarsk Regional Science Foundation, grant number 22-27-20039, https://rscf.ru/project/22-27-20039/ (accessed on 15 March 2023)
Аннотация:
The recycling of hazardous industrial waste into high-tech materials with desired properties is of considerable interest since it provides optimal alternatives for its final disposal. Coal fly ash, the major waste generated by coal-fired power plants, contains significant quantities of dispersed microspheres with a diameter smaller than 10 μm, which are anthropogenic atmospheric pollutants PM10. Due to their composition and fine-grained powder morphology, they can be converted into sintered products. In this study, dispersed microspheres from class C fly ash were directly sintered without any additive to form high-strength glass-
ceramics
with magnetic properties. The optimum processing conditions were achieved at a temperature of 1200 °C, at which samples with a compressive strength of 100.6 MPa were obtained. Sintering reduces the quantity of the glass phase and promotes the formation of larnite, Fe-spinel, ye’elimite, and ternesite. Mössbauer measurements show that the relative concentration of the magnetic phase compared to the paramagnetic one rises almost in order. The sintered sample demonstrates a narrower distribution of the hyperfine magnetic field and a significantly lower value of the coercive field of 25 Oe, which allows proposing such materials as soft magnetic materials. The presented results demonstrate promising industrial applications of hazardous PM10 to minimize solid waste pollution.
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11.
Вид документа
: Статья из сборника (выпуск продолж. издания)
Шифр издания
:
Автор(ы)
: Dedova E. S., Pertushina M. U., Kondratenko A. I., Gorev M. V., Kulkov S. N.
Заглавие
: Complex oxide with negative thermal expansion for producing ceramic matrix composites with invar effect
Коллективы
: International Conference on Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2016
Место публикации
: AIP Conf. Proc. - 2016. - Vol. 1783: Advanced materials with hierarchical structure for new technologies and reliable structures 2016. - Ст.020037. - ,
DOI
10.1063/1.4966330
Примечания
: Cited References: 12. - The research was conducted with partial financial support by an agreement with the Ministry of Education No. 14.575.21.0040 (RFMEFI57514X0040). Authors are grateful to Institute of Physics for their help in the dilatometer investigation.
Ключевые слова
(''Своб.индексиров.''):
ceramics
--zirconium tungstate--negative thermal expansion coefficient--phase transformation--spinel
Аннотация:
The article investigates the phase composition of (Al2O3 – 20 wt % ZrO2)–ZrW2O8 ceramic composites obtained by cold-pressing and sintering processes. Using X-ray analysis it has been shown that composites mainly have monoclinic modification of zirconium dioxide and orthorhombic phase of aluminum oxide. After adding zirconium tungstate the phase composition of sintered
ceramics
changes, followed by the formation of tungsten-aluminates spinel such as Alx(WOy)z. It has been shown that thermal expansion coefficient of material decreases approximatly by 30%, as compared with initial
ceramics
.
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12.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Ma, Bin, Guo Q. F., Molokeev M. S., Lv, Zhenfei, Yao, Jun, Mei, Lefu, Huang, Zhaohui
Заглавие
: Crystal structure and luminescence properties of green-emitting Sr1−xAl12O19:xEu2+ phosphors
Место публикации
: Ceram. Int.: Elsevier Science, 2016. - Vol. 42, Is. 5. - P.5995-5999. - ISSN 0272-8842,
DOI
10.1016/j.ceramint.2015.12.149. - ISSN 1873-3956(eISSN)
Примечания
: Cited References: 30. - This work was supported by the National Natural Science Foundation of China (Grant nos. 51032007 and 51372232) and the Fundamental Research Funds for the Central Universities (Grant no. 2652015024).
Предметные рубрики:
COLOR-TUNABLE PHOSPHOR
ENERGY-TRANSFER
Dy3+ PHOSPHORS
NEAR-UV
Eu2+
DIODES
PHASE
STATE
Ce3+
Ключевые слова
(''Своб.индексиров.''): crystal structure--magnetoplumbite--phosphor
Аннотация:
In this paper, a series of novel luminescent Sr1−xAl12O19:xEu2+ phosphors were synthesized by a high temperature solid-state reaction. The phase structure, photoluminescence (PL) properties, as well as the decay curves were investigated. The quenching concentration of Eu2+ in SrAl12O19 was about 0.15 (mol). Upon excitation at 378 nm, the composition-optimized Sr0.85Al12O19:0.15Eu2+ exhibited strong broad-band green emission at 530 nm with the CIE chromaticity (0.2917, 0.5736). The results indicate that Sr1−xAl12O19:xEu2+ phosphors have potential applications as green-emitting phosphors for UV-pumped white-light LEDs.
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13.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Guo Q. F., Ma B., Liao L. B., Molokeev M. S., Mei L. F., Liu H. K.
Заглавие
: Crystal structure and luminescence properties of novel Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphor with apatite structure
Место публикации
: Ceram. Int.: Elsevier Science, 2016. - Vol. 42, Is. 10. - P.11687-11691. - ISSN 0272-8842,
DOI
10.1016/j.ceramint.2016.04.086. - ISSN 1873-3956(eISSN)
Примечания
: Cited References:26. - This present work is supported by the National Natural Science Foundation of China (Grant no. 41172053).
Предметные рубрики:
Light-Emitting-Diodes
Energy-transfer
Tunable phosphor
LEDs
Eu-2+
Ions
Ce3+
Ключевые слова
(''Своб.индексиров.''): crystal structure--apatite--phosphor
Аннотация:
In this paper, a series of novel luminescent Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors with apatite structure were synthesized by a high temperature solid-state reaction. The phase structure, photoluminescence (PL) properties, as well as the PL thermal stability were investigated. Sr9.92(SiO4)3(SO4)3O:0.08Eu2+ phosphor exhibits better thermal quenching resistance, retaining the luminance of 66.55% at 150 °C compared with that at 25 °C. The quenching concentration of Eu2+ in Sr10(SiO4)3(SO4)3O was about 0.08 (mol) with the dipole–quadrupole interaction. The Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors exhibited a broad-band green emission at 538 nm upon excitation at 396 nm. The results indicate that Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors have potential applications as near UV-convertible phosphors for white-light UV LEDs.
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14.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: PETRAKOVSKII G. A., PATRIN G. S., USTYUZHANIN Y. N., SABLINA K. A., STEPANOV G. N.
Заглавие
: DC-EFFECT ON THE MICROWAVE RESPONSE IN THE SUPERCONDUCTING
CERAMICS
HO-BA-CU-O
Место публикации
: Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 1989. - Vol. 72, Is. 8. - P759-762. - ISSN 0038-1098,
DOI
10.1016/0038-1098(89)90903-4
Примечания
: Cited References: 18
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15.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Udod L. V., Sitnikov M. N., Romanova O. B.
Заглавие
: Dielectric and transport properties, electric polarization at the sequential structural phase transitions in iron-substituted bismuth pyrostannate
Место публикации
: Ceram. Int. - 2021. - Vol. 47, Is. 2. - P.1704-1711. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2020.08.287
Примечания
: Cited References: 33. - The reported study was funded by Russian Foundation for Basic Research project № 20-52-00005 Bel_a
Аннотация:
The electrical characteristics including the electrical resistance, impedance, I–V characteristics, capacitance, dissipation factor, and thermoelectric power of the Bi2Sn2-хFeхO7 (х = 0.1, 0.2) stannates have been investigated in the temperature range of 100–600 K at frequencies of 102–106 Hz. The paramagnetic contribution of electrons to the dynamic magnetic susceptibility has been established. The conductivity mechanism of the compounds has been found from the I–V characteristics and the change in the carrier sign has been determined from the thermoelectric power. The hysteresis of the I–V curves, charge transfer currents and polarization current have been observed in the Bi2Sn1·8Fe0·2O7 compound. A nonlinear field dependence of the polarization in the orthorhombic phase has been found. The correlation between the obtained characteristics and the phase structure transitions has been established. Two relaxation channels and activation energy have been found using the Debye model. The hysteretic I–V characteristics have been explained using a model of the electronic structure and the dipole and migration polarization.
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16.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Gao Q., Hu Q., Jin L., Gorev M. V., Chezganov D. S., Vlasov E. O., Zeng H., Zhao L., Cui Y., Xu Z., Wei X.
Заглавие
: Dielectric relaxation and phase transition behavior of (1–x)Pb(Zn1/3Nb2/3)O3-xBaTiO3 binary solid solutions
Место публикации
: Ceram. Int. - 2018. - Vol. 44, Is. 15. - P.18491-18498. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2018.07.069
Примечания
: Cited References: 53. - This work was supported by the National Basic Research Program of China (Grant No. 2015CB654602 ), the International Science & Technology Cooperation Program of China (Grant No. 2015DFA51100 ), the NSFC projects (Grant Nos. 51761145024 and 51772239 ), Shaanxi province project 2017 ktpt-21, the Joint fund of the Ministry of Education (Grant No. 6141A02033210 ) and the 111 Project under Grant No. B14040 . The SEM work was done at International Center for Dielectric Research (ICDR), Xi’an Jiaotong University, Xi’an, China.
Ключевые слова
(''Своб.индексиров.''): dielectric relaxation--phase transition--“u”-shaped variation--polarization mismatch
Аннотация:
Dielectric relaxation and phase transition behaviors in (1–x)Pb(Zn1/3Nb2/3)O3-xBaTiO3 (PZN-BT) binary solid solutions have been systematically studied in this paper. All the compositions display a pure pseudo-cubic perovskite structure. As the BT contents increase from 10 mol% to 70 mol%, the phase transition peak becomes broader and broader, accompanying with decreases of ɛm (the maximum dielectric permittivity) and Tm (the temperature corresponds to the ɛm). Nevertheless, an abnormal increase of ɛm and Tm occurs when the BT contents exceeds 70 mol%, forming a “U” shaped curve of the compositional dependence of ɛm and Tm. Moreover, it is indicated from the new glass model fitting results that the characteristic parameter p, which represents the degree of relaxation, also shows a similar “U” shaped variation curve. Similarly, as shown in polarization-electric field loops, both remnant polarizations (Pr) and coercive fields (Ec) display the “U” shaped curve as the BT content changes from 10 mol% to 80 mol%. Finally, according to the similar variation of these key parameters mentioned above, a polarization mismatched model, which describes the destruction and reestablishment of the long range order arrangement in solid solutions composed of two kinds of ferroelectrics, is proposed to illustrate the underlying mechanism. In this PZN-BT system or other similar ABO3-type perovskite relaxors, the competition between the A-O and B-O coupling plays an important role to form the “U” shaped evolution of these key parameters.
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17.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Drokina T. V., Petrakovskii G. A.
Заглавие
: Spin glasses state in zirconolites LnFeTi207 (Ln = Sm, Gd, Dy)
Коллективы
: China-Russia Symposium on Advaced Materials and Technologies (12; 2013 ; Nov. 18-22; Kunming, China)
Место публикации
: Adv. metals,
ceramics
and composites: 12th China-Russia Symposium on Advaced Materials and Technologies. - 2013. - Pt. 1. - P.143-146: Proceedings. - ISBN 978-7-5415-7650-5
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18.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Vtyurin A. N., Krylov A. S., Krylova S. N., Wei, Xiaoyong, Feng, Yujun, Xu, Ran, Zhao, Tian
Заглавие
: Dumping soft modes in Raman spectra of antiferroelectric (Pb-La)(Zr-Sn-Ti)O3
ceramics
Коллективы
: IEEE International Symposium on Applications of Ferroelectrics, International Conference on ElectroCeramics, European Meeting on Ferroelectricity, International Workshop on PiezoMEMS, Piezoresponse Force Microscopy Workshop
Место публикации
: Joint Conference of the IEEE ISAF, EMF, ICE, IWPM and PFM: Abstract book. - 2019. - P.694
Примечания
: Cited References: 3
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19.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Edelman I. S.
Заглавие
: Tranparent glass-
ceramics
containing nanoparticles of transition and rare earth elements
Коллективы
: "Trends in Nanomechanics and Nanoengineering", workshop, Сибирский федеральный университет, Институт физики им. Л.В. Киренского Сибирского отделения РАН
Место публикации
: Workshop "Trends in Nanomechanics and Nanoengineering": book of abstracts/ предс. сем. K. S. Aleksandrov ; зам. предс. сем.: G. S. Patrin, S. G. Ovchinnikov ; чл. лок. ком.: N. N. Kosyrev, A. S. Fedorov [et al]. - 2009. - P.25
Материалы семинара
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20.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Dudnikov V. A., Orlov Yu. S., Kazak N. V., Fedorov A. S., Solov'yov L. A., Vereshchagin S. N., Burkov A. T., Novikov S. V., Gavrilkin S. Yu., Ovchinnikov S. G.
Заглавие
: Effect of A-site cation ordering on the thermoelectric properties of the complex cobalt oxides Gd1-xSrxCoO3-δ (x = 0.8 and 0.9)
Место публикации
: Ceram. Int. - 2018. - Vol. 44, Is. 9. - P.10299-10305. - ISSN 02728842 (ISSN),
DOI
10.1016/j.ceramint.2018.03.037
Примечания
: Cited References: 38. - This work was supported by the Russian Science Foundation , project no. 16-13-00060.
Ключевые слова
(''Своб.индексиров.''): substituted rare earth cobalt oxides--thermoelectric oxide materials--ordered and disordered states
Аннотация:
The effect of substitution of Sr2+ ions for Gd3+ ions on the phase composition, electrical resistivity, thermoelectricity, and thermal conductivity of rare-earth cobalt oxides Gd1-xSrxCoO3-δ (x = 0.8 and 0.9) has been investigated. It has been determined that at the investigated strontium concentrations, the single-phase disordered nonstoichiometric cubic perovskites and superstructures with ordered Sr2+/Gd3+ ions and anion vacancies can be formed. The influence of ordering/disordering of Gd and Sr cations over crystal-lattice A- sites on the thermoelectric figure of merit and sample stability at high temperatures has been studied. The thermoelectric figure of merit of the disordered samples was found to exceed by far the analogous parameter of the ordered samples, which allows us to consider the disordering as a way of improving the thermoelectric parameters. Two contributions to the conductivities are discussed: high-temperature thermoactivation and low-temperatures variable range hopping. The parameters of the Mott electronic structure, including DOS N(εF), hopping energy ε (the energy of hopping conductivity activation), and hopping length Rh, have been estimated.
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