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1.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Edelman I. S., Ivanova O. S., Zubavichus Y., Trofimova N. N., Zaikovskiy V. I., Artemenko A., Curely J., Kliava J.
Заглавие
: Magnetic nanoparticles in borate glasses: Identification and sizing
Коллективы
: Russian Foundation for Basic Research, Russian Foundation for Basic Research, International Conference on Optimization of Electrical and Electronic Equipmen (22 May - 24 May 2014; Bran, Romania)
Место публикации
: International Conference on Optimization of Electrical and Electronic Equipment (OPTIM 2014): IEEE Computer Society, 2014. - P.95-104. - ISBN 978-1-4799-5183-3,
DOI
10.1109/OPTIM.2014.6850939
Примечания
: Cited References: 60
Предметные рубрики:
Engineering, Electrical and Electronic
Ключевые слова
(''Своб.индексиров.''): superparamagnetic resonance--ferromagnetic-resonance--ferrite nanoparticles--oxide nanoparticles--faraday-rotation--ceramics--iron--
crystallization
--anisotropy--particles
Аннотация:
Heat treatment of borate glasses co-doped with low contents of iron and larger radius elements: Dy, Tb, Gd, Ho, Er, Y and Bi results in formation of magnetic nanoparticles, radically changing their physical properties. Transmission electron microscopy and synchrotron radiation-based techniques: XRD, EXAFS, XANES and SAXS, show a broad distribution of nanoparticle sizes with characteristic depending on the treatment regime; a crystalline structure of these nanoparticles is detected in heat treated samples. Magnetic circular dichroism (MCD) studies of samples subjected to heat treatment as well as of maghemite, magnetite and iron garnet allow to unambiguously assigning the nanoparticle structure to maghemite. Different features observed in the MCD spectra are related to different electron transitions in Fe3+ ions gathered in the nanoparticles. Variable-temperature electron magnetic resonance (EMR) studies confirm the formation of magnetic nanoparticles and the identification of their nature. Computer simulations of the EMR spectra corroborate the broad distribution of nanoparticle sizes found by 'direct' techniques. © 2014 IEEE.
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2.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Flerov I. N., Aleksandrov K. S., Tressaud A., Grannec J., Couzi M.
Заглавие
: Phase transitions in elpasolites (ordered perovskites)
Место публикации
: Materials Science and Engineering R: Reports. - 1998. - Vol. 24, Is. 3. - P.81-151. - ISSN 0927-796X
Примечания
: Cited References: 174
Предметные рубрики:
ELASTIC NEUTRON-DIFFRACTION
MII = CO
RAMAN-SCATTERING
THERMODYNAMIC PROPERTIES
CRYSTAL-STRUCTURE
SINGLE-CRYSTALS
RB2KMIIIF6 ELPASOLITES
CUBIC PEROVSKITES
TEMPERATURE FORM
HIGH-RESOLUTION
Ключевые слова
(''Своб.индексиров.''): crystal atomic structure--crystal growth--crystal lattices--
crystallization
--crystallography--ferroelectricity--hydrostatic pressure--order disorder transitions--single crystals--thermodynamics--elpasolites--landau theory--perovskite
Аннотация:
Many compounds with general chemical formula A2BB?X6 and with tolerance factor value t < 1 crystallize in the elpasolite (ordered perovskite) structure. Different preparative methods have been considered. For example, the Bridgman technique is the most suitable method of growing single crystals of halogenated elpasolites with monoatomic cations. Group-theory and symmetry analyses have allowed us to build a scheme of possible structural distortions connected with octahedral rotations and displacements of ions. Experimental observations have proven that ferroelastic phase transitions occurring most frequently in elpasolites are due to small octahedra tilts. Quantitative analysis allows the possibility of describing these transitions in the framework of the thermodynamic Landau theory. Hydrostatic pressure and the substitution of atoms in different crystallographic sites allow to change significantly the succession and the temperature of phase transitions. The hypothesis of bond stresses is able to predict the possible occurrence of a phase transition for a particular elpasolite and/or the role of the octahedra rotations in the transformation. The mechanism of phase transitions in elpasolites and related compounds has also been considered. One can assume that a displacive mechanism associated with a strong anharmonicity plays a large role in phase transitions occurring in compounds with monoatomic cations. On the other hand, for instance, in cryolites with ammonium cations, the transitions originate from an order-disorder phenomenon. В© 1998 Elsevier Science S.A. All rights reserved.
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3.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Kveglis L. I., Kuzovnikov A. V., Timofeev I. V.
Заглавие
: The self-organization of tetrahedrally close-packed structures in magnetic nanocrystalline Tb-Fe and Co-Pd films
Коллективы
: International Conference on Mechanical Spectroscopy and Relaxation Phenomena in Solids (3; 2006; Cracow, Poland)
Место публикации
: Mechanical spectroscopy III: Mechanical spectroscopy and relaxation phenomena IN SOLIDS. Ser. Solid state phenomena: Trans tech publications LTD, 2006. - Vol. 115. - P.267-273. - ISBN 1012-0394. - ISBN 3-908451-24-8
Примечания
: Cited References: 19
Предметные рубрики:
AMORPHOUS FILMS
Ключевые слова
(''Своб.индексиров.''): dissipative structures--explosive
crystallization
--thermal conductivity--tb-fe films--co-pd films
Аннотация:
The self-organization of an atomic structure in Tb30Fe70 and Co50Pd50 films possessing of high values of the perpendicular magnetic anisotropy (PMA) constant (K perpendicular to similar to 10(6) erg/cm(3)) is investigated by transmission electron microscopy. The
crystallization
of the films is realized in an explosive way with formation of different dissipative structures from the initial nanocrystalline state. In present work the structural model of a thin film in mezzo-scale and the correlation of a structure with magnetic properties are discussed.
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4.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Balaev D. A., Bayukov O. A., Eremin E. V., Molokeev M. S., Pankrats A. I., Sablina K. A., Velikanov D. A., Vorotynov A. M.
Заглавие
: Synthesis and magnetic properties of β-Cu3Fe4(VO4)6 single crystals
Коллективы
: Moscow International Symposium on Magnetism
Место публикации
: Solid State Phenom.: Selected, peer reviewed papers/ ed.: N. Perov, A. Semisalova: Trans Tech Publications Ltd, 2015. - Vol. 233-234: Achievements in Magnetism. - P.137-140. - ISSN 1662-9779,
DOI
10.4028/www.scientific.net/SSP.233-234.137. - ISSN 978-3-03835-482-6
Предметные рубрики:
Achievements in magnetism
Ключевые слова
(''Своб.индексиров.''): lyonsite--spontaneous
crystallization
--spin glass--single crystal--magnetization
Аннотация:
β-Cu3Fe4(VO4)6 single crystals were synthesized. The X-ray, magnetic, Mössbauer, and EPR investigations of the crystals were fulfilled. It is established that single-crystal β-Cu3Fe4(VO4)6 is a spin glass at low temperatures. Freezing temperature varies considerably depending on the orientation of the magnetic field relative to the crystal axes. Spin-glass state is confirmed by the relaxation of the magnetization.
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5.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Frolov K. V., Lyubutin I. S., Smirnova E. S., Alekseeva O. A., Verin I. A., Artemov V. V., Kharlamova S. A., Bezmaternykh L. N., Gudim, I. A.
Заглавие
: Low-temperature structural and magnetic phase transitions in multiferroic GdFe3(BO3)4
Коллективы
: Russian Foundation for Basic Research [14-02-00483a, 13-02-12442]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-1130.2014.5, NSh-924.2014.2]; Russian Ministry of Education and Science [RFMEFI62114X0005]
Место публикации
: J. Alloys Compd.: Elsevier Science, 2016. - Vol. 671. - P.545-551. - ISSN 0925-8388,
DOI
10.1016/j.jallcom.2016.02.083. - ISSN 1873-4669(eISSN)
Примечания
: Cited References:36. - We thank Dr. A.P. Dudka for help in the low temperature XRD measurements. This study was supported in part by the Russian Foundation for Basic Research (projects # 14-02-00483a and 13-02-12442), and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools (grant # NSh-1130.2014.5 and # NSh-924.2014.2). This work was performed using the equipment of the Shared Research Center IC RAS and was supported by the Russian Ministry of Education and Science (project RFMEFI62114X0005).
Предметные рубрики:
IRON BORATE GDFE3(BO3)4
BIFEO3 THIN-FILMS
MAGNETOELASTIC PROPERTIES
RM3(BO3)4 CRYSTALS
TRIGONAL GDFE3(BO3)4
ENHANCED POLARIZATION
HIGH-PRESSURES
CRYSTALLIZATION
BEHAVIOR
GROWTH
Ключевые слова
(''Своб.индексиров.''): multiferroics--rare earth compounds--x-ray diffraction--mossbauer--spectroscopy--crystal structure--spin dynamics
Аннотация:
X-ray analysis revealed that at temperature decreasing from room temperature to Tstr = 155 K the crystal unit cell GdFe3(BO3)4 is reduced only along the c axis (at 0.01 Å), while the a and b axes are unchanged within the error limits. The volume of the crystal decreases uniformly in the direction of all three axes at 155–80 K. At 80–30 K the crystal volume is decreased only by reduction of the parameters a and b, while the parameter c increases conversely. In the paramagnetic region Mössbauer spectra do not distinguish between the two structural positions of iron ions Fe1 and Fe2, appearing at T < Tstr. Below the temperature of the magnetic phase transition at TN = 38.0(1) K the Mössbauer data indicate quasi-one-dimensional magnetic ordering of iron moments in the sublattice Fe2 and a two-dimensional one in the iron sublattice Fe1. The dynamics of spin reorientation in sublattices Fe1 and Fe2 is studied in detail.Рентгеновский анализ показал, что при уменьшении температуры от комнатной до Tstr = 155 K изменение параметра элементарной ячейки кристалла GdFe3(BO3)4 происходит лишь вдоль оси с (при 0,01 Å), в то время как а и b оси остаются неизменными в пределах погрешности измерений. Объем кристалла уменьшается равномерно в направлении всех трех осей при 155-80 K. При 80-30 K объем кристалла уменьшается только уменьшением параметров a и b, в то время как параметр с наоборот увеличивается. В парамагнитной области Мессбауэровские спектры не различают двух структурных позиций ионов железа Fe1 и Fe2, появляющиеся при Т˂Tstr. Ниже температуры магнитного фазового перехода при TN = 38,0(1) К Мёссбауэрские данные указывают на квази-одномерный магнитное упорядочение моментов железа в подрешетке Fe2 и двумерное в железной подрешетке Fe1. Динамика спиновой переориентации в подрешетках Fe1 и Fe2 подробно изучается.
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Wang X., Li J. -G., Molokeev M. S., Zhu Q., Li X., Sun X.
Заглавие
: Layered hydroxyl sulfate: Controlled
crystallization
, structure analysis, and green derivation of multi-color luminescent (La,RE)2O2SO4 and (La,RE)2O2S phosphors (RE = Pr, Sm, Eu, Tb, and Dy)
Место публикации
: Chem. Eng. J.: Elsevier, 2016. - Vol. 302. - P.577-586. - ISSN 13858947 (ISSN),
DOI
10.1016/j.cej.2016.05.089
Примечания
: Cited References: 50. - This work is supported in part by the National Natural Science Foundation of China (Grants Nos. 51172038, 51302032, and U1302272), the Fundamental Research Fund for the Central Universities (Grant No. N140204002), Grants-in-Aid for Scientific Research (KAKENHI No. 26420686), and the Russian Foundation for Basic Research (15-52-53080). X.J. Wang acknowledges financial support from the China Scholarship Council for her overseas Ph.D. study (Contract No. 201406080035) and the assistance of Q. Q. Zhu (University of Science and Technology of China) for his help with calcination.
Предметные рубрики:
PHOTOLUMINESCENCE PROPERTIES
OXYSULFATE/OXYSULFIDE SYSTEMS
CRYSTAL-STRUCTURE
OXYGEN-STORAGE
Ln
NANOCOMPOSITES
EMISSION
CAPACITY
FAMILY
FABRICATION
Ключевые слова
(''Своб.индексиров.''): sulfate type layered rare earth hydroxide--luminescence--oxysulfate--oxysulfide
Аннотация:
The two important groups of Ln2O2SO4 and Ln2O2S compounds are traditionally synthesized with the involvements of environmentally harmful sulfur-containing reagents. We developed in this work a unique green approach for their synthesis, using Ln2(OH)4SO4·2H2O layered hydroxyl sulfate as the precursor (Ln-241 phase). Phase selective
crystallization
of La-241 under both atmospheric pressure and hydrothermal conditions was firstly optimized, followed by transformation into La2O2S and La2O2SO4 by controlled calcination. Rietveld structure refinement was performed for La-241, La(OH)SO4, La2O2SO4, and La2O2S, and the crystal structure and cell parameters of La-241 were originally reported. The photoluminescence performances of several important activators (Pr3+, Sm3+, Eu3+, Tb3+, and Dy3+) in the two hosts, in terms of excitation, emission, quantum yield, and color coordinates of emission, were thoroughly investigated, and multi-color luminescence including bright red, green, orange red, and yellow was obtained under ultraviolet excitation. Detailed investigations of Tb3+ photoluminescence revealed that the lack of 5D3 emission in La2O2S and the gradual quenching of 5D3 blue emission at a higher Tb3+ content (hence decreasing I488/I545 ratio and changing color coordinates) in La2O2SO4 were suggested to be due to thermal activation of the 5D3 electrons into the conduction band and cross relaxation between adjacent Tb3+, respectively. The synthesis approach developed in this work for La2O2SO4 and La2O2S, with water vapor as the only exhaust gas, is environmentally benign and holds great potential in the facile synthesis of analogous compounds of other lanthanides. © 2016 Elsevier B.V.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Volkov N. V., Eremin E. V., Sablina K. A., Sapronova N. V.
Заглавие
: Dielectric properties of a mixed-valence Pb3Mn7O15 manganese oxide
Коллективы
:
Разночтения заглавия
:авие SCOPUS: Dielectric properties of a mixed-valence Pb3Mn7O 15 manganese oxide
Место публикации
: J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2010. - Vol. 22, Is. 37. - Ст.375901. - ISSN 0953-8984,
DOI
10.1088/0953-8984/22/37/375901
Примечания
: Cited References: 14. - This study was supported by the Russian Foundation for Basic Research 'Siberia', project No. 09-02-98003, and the Siberian Branch of the Russian Academy of Sciences, integration project No. 101.
Ключевые слова
(''Своб.индексиров.''): cation--lead--manganese derivative--oxide--article--chemical model--chemistry--
crystallization
--electric conductivity--electronics--methodology--temperature--cations--
crystallization
--electric conductivity--electronics--lead--manganese compounds--models, chemical--oxides--temperature--ac electric field--analysis of resistivity--carrier hopping--charge ordering--complex dielectric constant--crystal site--debye models--dielectric constants--dielectric spectra--frequency windows--lattice sites--low frequency--manganese ions--mixed valence--mixed valence state--relaxation behaviors--temperature range--electric fields--manganese--manganese oxide--permittivity--single crystals--crystal symmetry
Аннотация:
We investigated the low-frequency dielectric properties of a Pb3Mn7O15 single crystal with manganese ions in the mixed-valence state (Mn3+/Mn4+). Dielectric relaxation was found in the frequency window from 20 to 100 kHz in the temperature range 110-180 K. The dielectric spectra of the crystal were analyzed using a Debye model. Estimations made within the model and analysis of resistivity data suggest that the relaxation behavior of the dielectric constant is related to polaronic charge carrier hopping. Around 250 K, charge ordering occurs in the crystal when the Mn3+ and Mn4+ ions are arranged in a specific order among the crystal sites. With a decrease in temperature, an ac electric field can induce a charge hop between the equivalent lattice sites available, related to crystal symmetry. This hopping is equivalent to the reorientation of an electric dipole that yields Debye-type behavior of the complex dielectric constant. The observed anisotropy in the behavior of the dielectric properties and resistivity can be attributed to a pronounced two-dimensional character of the crystal structure.
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8.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Ryabinkina L. I., Romanova O. B., Har'kov A. M., Gorev M. V., Balaev A. D., Eremin E. V., Bovina A. F.
Заглавие
: The magnetoelastic effect in CoxMn1-xS solid solutions
Коллективы
:
Разночтения заглавия
:авие SCOPUS: The magnetoelastic effect in Cox Mn1 - x S solid solutions
Место публикации
: Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 2010. - Vol. 150, Is. 13-14. - P564-567. - ISSN 0038-1098,
DOI
10.1016/j.ssc.2010.01.009
Примечания
: Cited References: 13. - This work was supported by the Russian Foundation for Basic Research projects no. 08-02-00364-a, no. 08-02-90031, no. F08037, F08-229, and no. 09-02-00554-a.
Предметные рубрики:
YVO3 SINGLE-CRYSTAL
SPIN-STATE
TRANSITION
TRANSPORT
PHYSICS
LACOO3
Ключевые слова
(''Своб.индексиров.''): semiconductors--x-ray scattering--galvanomagnetic effects--thermal expansion--semiconductors--x-ray scattering--galvanomagnetic effects--thermal expansion--semiconductors--x-ray scattering--coefficient of thermal expansion--magnetoelastic effects--orbital ordering--temperature hysteresis--temperature range--zero magnetic fields--
crystallization
--electric resistance--magnetic field effects--magnetoresistance--manganese--manganese compounds--neon--organic polymers--scattering--semiconductor quantum dots--solid solutions--solidification--thermal stress--x ray scattering--thermal expansion
Аннотация:
The magnetization of cation-substituted CoxMn(1-x)S sulfides upon cooling in zero magnetic field and in a field in the temperature range 4-300 K has been measured and the resistance versus magnetic field (up to 10 kOe) dependences have been obtained. Magnetoresistance and temperature hysteresis of magnetization versus prehistory are found at the magnetic field H 0.1 T and at T 240 K. The interrelation between the magnetic and elastic subsystems of the CoxMn1-xS solid solutions has been established. A jump in the coefficient of thermal expansion is observed at the Neel temperature. The features of the physical properties are explained by orbital ordering. (C) 2010 Elsevier Ltd. All rights reserved.
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9.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Romanova O. B., Ryabinkina L. I., Sokolov V. V., Pichugin A. Y., Velikanov D. A., Balaev D. A., Galyas A. I., Demidenko O. F., Makovetskii G. I., Yanushkevich K. I.
Заглавие
: Magnetic properties and the metal-insulator transition in GdXMn1-XS solid solutions
Коллективы
:
Разночтения заглавия
:авие SCOPUS: Magnetic properties and the metal-insulator transition in GdX Mn1 - X S solid solutions
Место публикации
: Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 2010. - Vol. 150, Is. 13-14. - P602-604. - ISSN 0038-1098,
DOI
10.1016/j.ssc.2009.12.042
Примечания
: Cited References: 13. - This study was supported by the Russian Foundation for Basic Research project No. 09-02-00554_a; No. 09-02-92001-NNS_a; No. 08-02-90031 Bel_a and Belarus Foundation for Basic Research project No. F04-182; ADTF "Development of scientific potential of the higher school" No. 2.1.1/401.
Ключевые слова
(''Своб.индексиров.''): insulator--metals--crystal growth--phase transitions--insulator--metals--crystal growth--phase transitions--insulator--metals--antiferromagnetic semiconductors--crystal growth--cubic lattice--metal-insulator phase transition--orders of magnitude--p-type--temperature range--thermoelectric properties--thermopowers--antiferromagnetic materials--antiferromagnetism--crystal growth--
crystallization
--electric properties--gadolinium--grain boundaries--magnetic fields--magnetic properties--manganese--manganese compounds--metal insulator boundaries--metals--semiconductor growth--semiconductor insulator boundaries--sodium chloride--solid solutions--solidification--metal insulator transition
Аннотация:
The structural, magnetic, electrical, and thermoelectric properties of GdXMn1-XS (0.01
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10.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Popova M. N., Chukalina E. P., Stanislavchuk T. N., Malkin B. Z., Zakirov A. R., Antic-Fidancev E., Popova E. A., Bezmaternykh L. N., Temerov V. L.
Заглавие
: Optical spectra, crystal-field parameters, and magnetic susceptibility of multiferroic NdFe3(BO3)(4)
Разночтения заглавия
:авие SCOPUS: Optical spectra, crystal-field parameters, and magnetic susceptibility of multiferroic Nd Fe3 (B O3) 4
Место публикации
: Phys. Rev. B: AMERICAN PHYSICAL SOC, 2007. - Vol. 75, Is. 22. - Ст.224435. - ISSN 1098-0121,
DOI
10.1103/PhysRevB.75.224435
Примечания
: Cited References: 22
Предметные рубрики:
IRON BORATE GDFE3(BO3)(4)
CRYSTALLIZATION
SPECTROSCOPY
LASER
ND3+
Аннотация:
We report high-resolution optical absorption spectra for NdFe3(BO3)(4) trigonal single crystal, which is known to exhibit a giant magnetoelectric effect below the temperature of magnetic ordering T-N=33 K. The analysis of the temperature-dependent polarized spectra reveals the energies and, in some cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We perform crystal-field calculations starting from the exchange-charge model, obtain a set of six real crystal-field parameters, and calculate wave functions and magnetic g factors. In particular, the values g(perpendicular to)=2.385 and g(parallel to)=1.376 were found for the Nd3+ ground-state doublet. We obtain B-loc=7.88 T and parallel to J(FN)parallel to=0.48 K for the values of the local effective magnetic field at liquid-helium temperatures at the Nd3+ site and the Nd-Fe exchange integral, respectively, using the experimentally measured Nd3+ ground-state splitting of 8.8 cm(-1). To check the reliability of our set of crystal-field parameters, we model the magnetic susceptibility data from literature. A dimer containing two nearest-neighbor iron ions in the spiral chain is considered to partly account for quasi-one-dimensional properties of iron borates, and then the mean-field approximation is used. The results of calculations with the exchange parameters for Fe3+ ions J(nn)=-6.25 K (intrachain interactions) and J(nnn)=-1.92 K (interchain interactions) obtained from fitting agree well with the experimental data.
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11.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Kazak N. V., Balaev A. D., Ivanova N. B., Ovchinnikov S. G.
Заглавие
: Mossbauer magnetization and resistivity studies of Fe1.91V0.09BO4
Разночтения заглавия
:авие SCOPUS: Mossbauer magnetization and resistivity studies of Fe1.91V 0.09BO4
Место публикации
: Physica B: ELSEVIER SCIENCE BV, 2005. - Vol. 359: International Conference on Strongly Correlated Electron Systems (SCES 04) (JUL 26-30, 2004, Karlsruhe, GERMANY). - P1324-1326. - ISSN 0921-4526,
DOI
10.1016/j.physb.2005.01.396
Примечания
: Cited References: 8
Предметные рубрики:
FE2OBO3
Ключевые слова
(''Своб.индексиров.''): mott-hubbard system--magnetism--new materials--magnetism--mott-hubbard system--new materials--
crystallization
--crystallography--fermi level--ferrimagnetism--magnetism--magnetization--mossbauer spectroscopy--phase transitions--single crystals--x ray diffraction analysis--charge ordering--electron-electron interactions--mott-hubbard system--new materials--iron compounds
Аннотация:
Single crystals of Fe1.91V0.09BO4 were prepared by spontaneous
crystallization
using a solution melt technology for the first time and its structure, electronic and magnetic properties were investigated by X-ray diffraction, Mossbauer spectroscopy, magnetization and electrical measurements. Room-temperature Mossbauer measurements indicate that "localized" (Fe2+, Fe3+) and "delocalized" (Fe2.5+) states in ratio 0.31:0.345:0.345 distributed over two crystallographically non-equivalent positions exist. The results of magnetic measurements show that warwickite is a P-type ferrimagnet below T = 130 K. Resistivity measurements show a variable-range-hopping when electron-electron interactions cause a soft Coulomb gap in the density of states at the Fermi energy. (c) 2005 Elsevier B.V. All rights reserved.
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12.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Kveglis L. I., Seredkin V. A., Kuzovnikov A. V.
Заглавие
: Scale invariance of the structure upon explosive
crystallization
of amorphous films
Место публикации
: JETP Letters. - 2005. - Vol. 82, Is. 1. - P.22-25. - ISSN 0021-3640,
DOI
10.1134/1.2045332
Примечания
: Cited References: 19
Аннотация:
Experimental results that are obtained in the process of the explosive
crystallization
of x-ray amorphous films Fe2Tb and CoPd with magnetic anisotropy perpendicular to the film plane are reported. The internal bending of thus obtained "single crystals" reaches 100 deg/mu m. An explanation of the mechanism and kinetics of explosive
crystallization
in the Fe2Tb and CoPd films is proposed in the framework of the shear transformation zone theory. (C) 2005 Pleiades Publishing, Inc.
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13.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Zharkov S. M., Kveglis L. I.
Заглавие
: Electron-beam-initiated
crystallization
of iron-carbon films
Место публикации
: Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2004. - Vol. 46, Is. 5. - P969-974. - ISSN 1063-7834,
DOI
10.1134/1.1744977
Примечания
: Cited References: 34
Предметные рубрики:
AMORPHOUS-GERMANIUM FILMS
EXPLOSIVE
CRYSTALLIZATION
PATTERN-FORMATION
TEMPERATURE
MICROSCOPY
MECHANISM
Аннотация:
A structure formed in nanocrystalline iron-carbon films exposed to an electron beam was studied. Explosive
crystallization
(EC) with the formation of dendrite and cellular-dendritic instabilities at a rate of up to 1 cm/s was observed. It was shown that the dependence between the growth rate of dendrite branches (or cells) during EC and the rounding radius of dendrite branch tips can be approximately described by equations used to calculate the crystal growth in supercooled melts. To explain the EC mechanism, a model of a liquid zone formed at the
crystallization
front was used. It was shown that the liquid zone arises due to energy accumulated in the film in the nanocrystalline state. It was assumed that this energy was accumulated due to the energy of elastic stresses. (C) 2004 MAIK "Nauka / Interperiodica".
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14.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Myagkov V. G.
Заглавие
: Oscillations of the
crystallization
front of adsorbed water
Место публикации
: JETP Letters. - 2000. - Vol. 72, Is. 1. - P.4-6. - ISSN 0021-3640,
DOI
10.1134/1.1311396
Примечания
: Cited References: 25
Предметные рубрики:
RAPID SOLIDIFICATION
PATTERN-FORMATION
INSTABILITIES
EQUILIBRIUM
ALLOYS
Аннотация:
Relaxation oscillations of the
crystallization
front in a gradient temperature field have been observed for water adsorbed on a metal film deposited on a glass substrate. The metal film plays an important role in heat removal from the
crystallization
front and determines the existence of oscillations. A possible mechanism is proposed for the development of oscillations. It is shown that the oscillations observed are similar to the oscillations of the front of self-propagating high-temperature synthesis. (C) 2000 MAIK "Nauka / Interperiodica".
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15.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Myagkov V. G., Bykova L. E., Bondarenko G. N.
Заглавие
: Multiple self-propagating high-temperature synthesis and solid-phase reactions in thin films
Место публикации
: J. Exp. Theor. Phys.: AMER INST PHYSICS, 1999. - Vol. 88, Is. 5. - P963-967. - ISSN 1063-7761,
DOI
10.1134/1.558878
Примечания
: Cited References: 28
Предметные рубрики:
DENSE BRANCHING MORPHOLOGY
SINGLE-CRYSTAL GROWTH
PATTERN-FORMATION
AL-GE
CHEMICAL-REACTIONS
CRYSTALLIZATION
SEPARATION
HEAT
Аннотация:
A variety of self-propagating high-temperature synthesis in thin films has been found and investigated. This modification, called multiple self-propagating high-temperature synthesis, occurs in the solid phase and is a reversible phase transition. Multiple self-propagating high-temperature synthesis is similar in many respects to a metal-insulator phase transition. It is shown that for eutectic systems it is equivalent to a repeated transition through the eutectic temperature of bulk samples. It is inferred that multiple self-propagating high-temperature synthesis in bilayer films is governed by phase separation mechanisms that take place during eutectic solidification and eutectoid decomposition. (C) 1999 American Institute of Physics. [S1063-7761(99)01705-9].
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16.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Fausti D., Nugroho A. A., van Loosdrecht PHM, Klimin S. A., Popova M. N., Bezmaternykh L. N.
Заглавие
: Raman scattering from phonons and magnons in RFe3(BO3)(4)
Разночтения заглавия
:авие SCOPUS: Raman scattering from phonons and magnons in RFe3 (BO3) 4
Место публикации
: Phys. Rev. B: AMER PHYSICAL SOC, 2006. - Vol. 74, Is. 2. - Ст.24403. - ISSN 1098-0121,
DOI
10.1103/PhysRevB.74.024403
Примечания
: Cited References: 26
Предметные рубрики:
IRON BORATE GDFE3(BO3)(4)
LIGHT-SCATTERING
CRYSTALS
ND
CRYSTALLIZATION
TRANSITIONS
GENERATION
LASER
Аннотация:
Inelastic light scattering spectra of several members of the RFe3(BO3)(4) family reveal a cascade of phase transitions as a function of temperature, starting with a structural, weakly first-order, phase transition followed by two magnetic phase transitions. Those consist of the ordering of the Fe-spin sublattice, revealed by all the compounds, and a subsequent spin-reorientational transition for GdFe3(BO3)(4). The Raman data evidence a strong coupling between the lattice and magnetic degrees of freedom in these borates. The Fe-sublattice ordering leads to a strong suppression of the low-energy magnetic scattering, and a multiple peaked two-magnon scattering continuum is observed. Evidence for short-range correlations is found in the "paramagnetic" phase by the observation of a broad magnetic continuum in the Raman data, which persists up to surprisingly high temperatures.
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17.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Gavriliuk A. P., Isaev I. L., Karpov S. V., Krasnov I. V., Shaparev N. Y.
Заглавие
: Brownian dynamic of laser cooling and
crystallization
of electron-ion plasma
Место публикации
: Phys. Rev. E. - 2009. - Vol. 80, Is. 5. - Ст.56404. - ISSN 1539-3755,
DOI
10.1103/PhysRevE.80.056404
Примечания
: Cited References: 29
Предметные рубрики:
ULTRACOLD NEUTRAL PLASMAS
OPTICAL MOLASSES
LIQUIDS
ATOMS
TRAP
Ключевые слова
(''Своб.индексиров.''): brownian motion--laser cooling--plasma collision processes--plasma light propagation--plasma nonlinear processes--plasma simulation--plasma transport processes--brownian dynamics--brownian dynamics simulations--electron ion plasma--electron subsystem--friction force--ionic structure--nonlinear dependence--plasma cooling--brownian movement--
crystallization
--ions--laser cooling--lasers--cooling
Аннотация:
Laser cooling and
crystallization
of electron-ion plasma is studied using the Brownian dynamics simulation technique and taking into consideration the interaction of ions with the electron subsystem. It has been shown that the nonlinear dependence of laser friction force on the velocity of ions has to be taken into account in order to simulate in an adequate manner the cooling dynamics and obtain a correct estimate for minimum temperatures. It has been found that times required for formation of an ordered ionic structure can be much longer than the typical plasma cooling time.
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18.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Edelman I., Kliava J.
Заглавие
: Oxide glasses with magnetic nanoparticles: transparent magnets (Faraday rotation and electron magnetic resonance studies)
Коллективы
: RFBR-CNRS [07-02-92174]
Разночтения заглавия
:авие SCOPUS: Oxide glasses with magnetic nanoparticles: Transparent magnets (Faraday rotation and electron magnetic resonance studies)
Место публикации
: Phys. Status Solidi B. - 2009. - Vol. 246, Is. 10. - P.2216-2231. - ISSN 0370-1972,
DOI
10.1002/pssb.200945169
Примечания
: Cited References: 87. - This work is supported in part by RFBR-CNRS joint project, grant No 07-02-92174. We are grateful to E. Petrakovskaja and O. Ivanova for measuring and discussing, respectively, the EMR spectra in thermally treated samples and the FR spectral and magnetic field dependences.
Предметные рубрики:
SPIN-HAMILTONIAN PARAMETERS
SINGLE-DOMAIN PARTICLES
SUPERPARAMAGNETIC RESONANCE
CRYSTALLIZATION
BEHAVIOR
FERRIMAGNETIC RESONANCE
PARAMAGNETIC-RESONANCE
TEMPERATURE-DEPENDENCE
COMPUTER-SIMULATIONS
FINE PARTICLES
BORATE GLASSES
Аннотация:
In the first part of this paper we outline the state of the art in the field of magnetic nanoparticles in oxide glasses. We describe the theoretical background of two complementary techniques used for the studies of the state of paramagnetic ions, clusters and magnetic particles in a diamagnetic matrix, viz., magnetooptical Faraday rotation (FR) and electron magnetic resonance (EMIR) and we overview previous results obtained with these techniques for several glass systems. In the second part, we highlight the case of potassium-alumina-borate glasses - a glassy system where doping with paramagnetic oxides results in formation of magnetic particles at very low contents of paramagnetic additions: Fe(2)O(3) and MnO. In the special case when the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles with characteristics close to those of manganese ferrite are formed already at the first stage of the glass preparation. After thermal treatment all glasses show FR and EMR spectra attesting to the presence of superparamagnetic nanoparticles, characterized by relatively broad size and shape distributions. The formation of magnetic nanoparticles confers to these glasses magnetic and magnetooptical properties typical of magnetically ordered substances. At the same time, the glasses remain transparent in a part of the visible and near infrared spectral range and display a high FR value. Such properties make them particularly interesting for use as new media for various magneto-optical devices. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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19.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: NESTEROV A. I., Ovchinnikov S. G.
Заглавие
: ACOUSTIC-WAVE AMPLIFICATION IN FAST
CRYSTALLIZATION
Место публикации
: Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1988. - Vol. 30, Is. 1. - P184-186. - ISSN 0367-3294
Примечания
: Cited References: 14
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20.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Ji H., Wang L., Cho Y., Hirosaki N., Molokeev M. S., Xia Z., Huang Z., Xie R.-J.
Заглавие
: New Y2BaAl4SiO12:Ce3+ yellow microcrystal-glass powder phosphor with high thermal emission stability
Место публикации
: J. Mater. Chem. C: Royal Society of Chemistry, 2016. - Vol. 4, Is. 41. - P.9872-9878. - ISSN 20507534 (ISSN),
DOI
10.1039/c6tc03422e
Примечания
: Cited References: 32. - This study was partially supported by the National Natural Science Foundation of China (Grant No. 51272259, 51572232 and 51561135015). R. X. was also partially supported by the JSPS KAKENHI (No. 15K06448). M. M. and Z. X. were also partially supported by the Russian Foundation for Basic Research (No. 15-52-53080). H. J. thanks the China Scholarship Council (CSC) for scholarship support.
Ключевые слова
(''Своб.индексиров.''): aluminum--crystal structure--
crystallization
--glass--laser applications--light emission--microcrystals--phosphors--precipitation (chemical)--quenching--silicon--silicon oxides--single crystals--structural design--crystalline nature--
crystallization
behavior--emission intensity--microcrystal glass--morphology structures--phase formation behavior--structure analysis--temperature increase--cerium
Аннотация:
To decrease the rare earth element usage and synthesis cost of Y3Al5O12:Ce phosphor, the Y2BaAl4SiO12 compound is developed as a new host for Ce3+ employing the solid solution design strategy. The design uses polyhedron substitution where YO8/AlO4 are partially replaced by BaO8/SiO4, respectively. Structure analysis of Y2BaAl4SiO12 proves that it successfully preserves the garnet structure, crystallizing in the cubic Iad space group with a = b = c = 12.00680(5) Å. Barium (Ba) atoms occupy the Y site and silicon (Si) atoms occupy the Al site in the AlO4 tetrahedrons. An expanded study on Y2MAl4SiO12 (M = Ba, Ca, Mg, Sr) series shows a cation size (of M)-dependent phase formation behavior. The lattice stability can be related with the M type in the M–Si pair and substitution level of M–Si for Y–Al. Doping Ce3+ into Y2BaAl4SiO12 yields bright yellow photoluminescence peaking at around 537 nm upon excitation by 460 nm light. The emission intensity is quite stable against thermal quenching whereas the peak wavelength shows a slight red-shift as the ambient temperature increases. The
crystallization
behavior of Y2BaAl4SiO12 is suggested as melt-assisted precipitation/growth based on cathodoluminescence analysis. The highly crystalline nature of the microcrystals explains the stable emission against thermal quenching. This study may provide an inspiring insight into preparing phosphor with new morphology-structure of “microcrystal-glass powder phosphor”, which distinguishes it from conventional “ceramic powder phosphor” or “single-crystal phosphor”.
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