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1.
2-Thiobarbiturate complexes of
Ca(II): synthesis, crystal structure and thermal properties / N. N. Golovnev [et al.]> // 3 Int. Conf. on the Advancement of Mater. and Nanotechn. (ICAMN 2013) : Programme and abstracts book. - 2013. - P. 157
Перевод заглавия:
2-тиобарбитуровые комплексы Ca(II): синтез, кристаллическая структура и термические свойства
Кл.слова (ненормированные):
calcium
--
2-thiobarbituric acid
--
crystal structure
--
thermal
decomposition
--
IR spectroscopy
Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereschagin, S. N.; Верещагин, С. Н.; Atuchin, V. V.; Атучин, Виктор Валерьевич; International Conference on the Advancement of Materials and Nanotechnology (3 ; 2013 ; Nov. ; 19-22 ; Penang, Malaysia)
}
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2.
Calcium and strontium
thiobarbiturates with discrete and polymeric structures / N. N. Golovnev [et al.]> // J. Coordinat. Chem. - 2013. -
Vol. 66
. No. 23. - P. 4119–4130,
DOI
10.1080/00958972.2013.860450 . - ISSN 4119-4130
Перевод заглавия:
Кальциевый и стронциевый тиобарбитураты с дискретной и полимерной структурами
Кл.слова (ненормированные):
Calcium
--
2-Thiobarbituric acid IR
--
Crystal structure
--
Thermal
decomposition
--
Strontium
--
IR spectroscopy
Аннотация:
Three new alkaline earth metal complexes, [Ca2(H2O)8(μ2-HTBA-O,O′)2(HTBA-O)2] (1), [Ca(H2O)5(HTBA-O)2]·2H2O (2), and [Sr(H2O)4(μ2-HTBA-O,S)2]n (3) (H2TBA = 2-thiobarbituric acid, C4H4N2O2S), were synthesized and characterized by FT-IR spectroscopy, TG-DSC, and single-crystal and powder X-ray diffraction analysis. The single-crystal X-ray diffraction data revealed that 1 and 2 are discrete structures, whereas 3 is a polymer. In 1 and 2, Ca2+ is seven-coordinate and forms a monocapped trigonal prism. In 1, the prisms are pairwise connected with the assistance of two [μ2-HTBA-O,O′]− ligands. In 3, Sr2+ is coordinated by four monodentate HTBA− via S or O donors and four waters, with the formation of a distorted square antiprism. The antiprisms are connected by μ2-O,S bridging HTBA−. Hydrogen bonding involving coordinated water and π–π interactions plays an important role in construction of the supramolecular 3-D structures in 1–3. Infrared spectroscopic data supported the structural data. The thermal stability of 1–3 decreases in the order 1 > 2 > 3. Dehydration of 1–3 was a multi-step process, followed by exothermic oxidative degradation of the 2-thiobarbiturate moiety between 290 and 800 °C.
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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk, Russia
LV Kirenskii Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
Inst Chem & Chem Technol, Lab Catalyt Convers Small Mol, Krasnoyarsk, Russia
Russian Acad Sci, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia;
Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereshchagin, S. N.; Atuchin, V. V.
}
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3.
Crystal structure and
properties of polymeric hexaaqua-hexakis-(2-thiobarbiturato)-disamarium(III) / N. N. Golovnev [et al.]> // J. Struct. Chem. - 2017. -
Vol. 58
,
Is. 3
. - P. 539-543,
DOI
10.1134/S0022476617030155. - Cited References: 17 . - ISSN 0022-4766
Кл.слова (ненормированные):
structure
--
synthesis
--
complex
--
2-thiobarbituric acid
--
samarium(III)
--
thermal
decomposition
--
IR spectrum
Аннотация:
The structure (CIF file CCDC No. 1401886) of the hexaaqua-hexakis(2-thiobarbiturato)-disamarium [Sm2(H2O)6(HTBA)6]n polymeric complex (I), where H2ТВА is 2-thiobarbituric acid, is determined; its thermal
decomposition
and IR spectrum are studied. The crystals of I are monoclinic: a = 14.072(1) Å, b = 10.0842(6) Å, c = 15.323(1) Å, β = 110.408(2)°, V = 2037.9(2) Å3, space group P2/n, Z = 2. All three independent thiobarbiturate anions HTBA– coordinate to Sm3+ through oxygen atoms. To one of independent Sm3+ ions six (two terminal and four bridging) HTBA– ions and two water molecules are coordinated; the second is bonded with four bridging HTBA– and four water molecules, forming square antiprisms. The bridging HТВА–anions arrange antiprisms in layers. The structure is stabilized by hydrogen bonds and a π–π interaction between the HТВА– ions. The topology of the polymer network of I is analyzed.
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Публикация на русском языке
Кристаллическая структура и свойства полимерного гексааква-гексакис(2-тиобарбитурато)-дисамария(III) [Текст] / Н. Н. Головнев [и др.] // Журн. структ. химии. - 2017. - Т. 58 № 3. - С. 567-571
Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sterkhova, I. V.; Vereshchagin, S. N.; Golovneva, I. I.
}
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4.
Decomposition
in Ni-Co-Mn-In
functional Hensler alloys and its effect on shell-ferromagnetic and magnetocaloric effects / M. Sasmaz, F. Dreist, I. Iglesias [et al.]> // Phys. Rev. B. - 2020. -
Vol. 102
,
Is. 6
. - Ст. 064401,
DOI
10.1103/PhysRevB.102.064401. - Cited References: 38. - This work was supported by Deutsche Forschungsgemeinschaft (Project No. 405553726-CRC/TRR 270). The authors acknowledge support from the Turkish Scientific and Technological Research Council (Project No. 1059B191701241), the Deutsche Akademisches Austausch Dienst, and the Government of the Russian Federation (Grant No. 075-15-2019-1886). . - ISSN 2469-9950. - ISSN 2469-9969
РУБ
Materials Science, Multidisciplinary + Physics, Applied + Physics,
Рубрики:
FIELD-INDUCED STRAIN
MAGNETIC-FIELD
MARTENSITIC-TRANSFORMATION
Аннотация:
Ni-Co-Mn-In Heusler-based compounds are interesting for their magnetocaloric properties and have been widely investigated for this purpose. For Co compositions more than 5 at% in (Ni100-xCox)50Mn25+yIn25-y the material is no longer single phase, and for y 25, shell-ferromagnetic precipitation occurs. Our study is twofold: First we study here the shell-ferromagnetic properties of these systems and show that their ferromagnetic exchange can be strengthened by introducing Co into the precipitate. Second, we further show that both the multiphase character and shell-ferromagnetic precipitation have strong implications on the magnetocaloric properties.
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Держатели документа:
Adiyaman Univ, Golbasi Vocat Sch, Dept Elect & Energy, TR-02500 Adiyaman, Turkey.
Univ Duisburg Essen, Fac Phys, D-47048 Duisburg, Germany.
Univ Duisburg Essen, CENIDE, D-47048 Duisburg, Germany.
Mugla Univ, Dept Met & Mat Engn, TR-48000 Mugla, Turkey.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Sasmaz, M.; Dreist, F.; Iglesias, I.; Cakir, A.; Farle, M.; Фарле, Михаель; Acet, M.; Deutsche ForschungsgemeinschaftGerman Research Foundation (DFG) [405553726-CRC/TRR 270]; Turkish Scientific and Technological Research CouncilTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [1059B191701241]; Deutsche Akademisches Austausch Dienst; Government of the Russian Federation [075-15-2019-1886]
}
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5.
Effect of surfactants
on the structure, phase composition, and magnetic properties of FexSy nanoparticles synthesized by thermal
decomposition
/ R. D. Ivantsov, C.-R. Lin, Y.-Z. Chen [et al.]> // Nanobiotechnol. Rep. - 2022. -
Vol. 17
,
Is. 3
. - P. 336-344,
DOI
10.1134/S2635167622030089. - Cited References: 27. - This study was supported by the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project no. 19-42-240005: “Features of the Electronic Structure, Magnetic Properties, and Optical Excitations in Nanocrystals of Multifunctional Magnetic Chalcogenides Fe3S4 and FeSe” and the Russian Foundation for Basic Research and the Ministry of Science and Technology of Taiwan, joint projects nos. 19-52-52002 and 109-2112-M-153-003 and 108-2923-M-153-001-MY3. - The electron-microscopy study was carried out at the Laboratory of Electron Microscopy of the Center for Collective Use of the Siberian Federal University within the state assignment of the Ministry of Science and Higher Education of the Russian Federation (research code FSRZ-2020-0011). The magnetic measurements were carried out on a vibrating sample magnetometer at the Krasnoyarsk Regional Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences . - ISSN 2635-1676
Кл.слова (ненормированные):
Agglomeration
--
Crystal impurities
--
Fourier transform infrared spectroscopy
--
High resolution transmission electron microscopy
--
Magnetic properties
--
Magnetite
--
Magnetization
--
Nanomagnetics
--
Sulfur compounds
--
Synthesis (chemical)
--
Thermogravimetric analysis
--
Thermolysis
--
Electron diffraction analysis
--
Greigites
--
Hexadecylamine
--
Inverse spinel structures
--
Iron sulfide
--
Isostructural
--
Octadecyl amine
--
Organic shells
--
Structures phase
--
Synthesised
--
Surface active agents
Аннотация:
The effect of surfactants on the structure, morphology, and magnetic properties of FexSy iron-sulfide nanoparticles synthesized by thermal
decomposition
is studied. Oleylamine, hexadecylamine, and octadecylamine are used as surfactants. It is established by X-ray and electron-diffraction analysis combined with Mossbauer spectroscopy that, in samples 1 and 2 prepared using oleylamine and hexadecylamine, respectively, the Fe3S4 greigite phase dominates, with an inverse spinel structure isostructural to the iron oxide Fe3O4 magnetite with minor Fe9S11 impurities. Deviations in the distribution of iron cations over the tetrahedral and octahedral sites relative to the bulk greigite crystals are observed. The nanoparticles synthesized using octadecylamine (sample 3) are found to be multiphase with a greigite fraction of ~20%. In all three cases, as showed the results of transmission electron microscopy and Fourier transform infrared spectroscopy together with thermogravimetry analysis, the magnetic nanoparticles have an organic shell chemically bonded to their magnetic core, which prevents the agglomeration of the particles. This shell is much more massive in samples 2 and 3. The magnetization values for samples 1 and 2 are similar to those of greigite nanoparticles reported in publications, while the magnetization of sample 3 is several times lower, in accordance with the greigite fraction in it. The combination of fairly high magnetization with a massive organic shell allows one to consider hexadecylamine to be a promising surfactant for the synthesis of iron-sulfide nanoparticles protected from external impact and agglomeration.
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Публикация на русском языке
Влияние ПАВ на структуру, фазовый состав и магнитные свойства наночастиц FexSy, полученных методом термического разложения [Текст] / Р. Д. Иванцов, Ч. Р. Лин, Ю. Ж. Чэнь [и др.] // Рос. нанотехнол. - 2022. - Т. 17 № 3. - С. 358-367
Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Department of Applied Physics, National Pingtung University, Pingtung City, 90003, Taiwan
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Lin, C. -R.; Chen, Y. -Z.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Altunin, R. R.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Shestakov, N. P.; Шестаков, Николай Петрович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Edelman, I. S.; Эдельман, Ирина Самсоновна
}
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6.
Electron spin resonance
in Cu1−xFexCr2Se4 nanoparticles synthesized with the thermal
decomposition
method / I. S. Edelman [et al.]> // J. Magn. Magn. Mater. - 2017. -
Vol. 436
. - P. 21-30,
DOI
10.1016/j.jmmm.2017.04.006. - Cited References: 34. - The paper was partially supported by the President of Russia (Grant #NSh-7559.2016.2). We also thank the Ministry of Science and Technology of Taiwan, Taiwan, and the Siberian Branch of RAS, Russian Federation (MOST 102-2112-M-153-002-MY3) for the financial support. . - ISSN 0304-8853
Перевод заглавия:
Электронный парамагнитный резонанс в наночастицах Cu1-xFexCr2Se4, синтезированных методом термического разложения
Кл.слова (ненормированные):
Anisotropy
--
Association reactions
--
Chromium compounds
--
Decomposition
--
Electrospinning
--
Inorganic compounds
--
Magnetic moments
--
Magnetocrystalline anisotropy
--
Nanoparticles
--
Plates (structural components)
--
Resonance
--
Spin dynamics
--
Synthesis (chemical)
--
Temperature distribution
--
Thermolysis
--
Inter-particle interaction
--
Nanoparticle (NPs)
--
Resonance spectrum
--
Single-crystalline
--
Temperature behavior
--
Temperature decrease
--
Temperature dependence
--
Thermal
decomposition
methods
--
Electron spin resonance spectroscopy
Аннотация:
IIn this paper, we present a study of the electron spin resonance (ESR) of nanoparticles (NPs) of Cu1−xFexCr2Se4 chalcogenides with x = 0, 0.2, and 0.4. NPs were synthesized via the thermal
decomposition
of metal chloride salts and selenium powder in a high-temperature organic solvent. According to the XRD and HRTEM data, the NPs were single crystalline nearly hexagonal plates with the structure close to CuCr2Se4 (Fd-3m, a = 10.337 Å). For x = 0 and 0.2, the NPs tend to form long stacks consisting of the plates “face to face” attached to each other due to the magnetostatic interparticle interaction. Only separate NPs were observed in the case of x = 0.4. Peculiarities were revealed in the ESR temperature behavior for the NPs with x = 0 and 0.2 consistent with the features in the temperature dependences of the NPs magnetization. The non-monotonous dependence of the resonance field Hres on the temperature with a kink near 130 K and the energy gap in the resonance spectrum depending on the type of nanoparticle compacting are the distinct peculiarities. One of the main factors is discussed in order to explain the peculiarities: the coexistence of two types of anisotropy in the Cu1−xFexCr2Se4 NPs, in-plain shape anisotropy and magnetocrystalline anisotropy with four easy axes, which increases strongly with the temperature decrease.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
National Pingtung University, Pingtung City, Pingtung County, Taiwan
Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Zharkov, S. M.; Жарков, Сергей Михайлович; Pankrats, A. I.; Панкрац, Анатолий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Tugarinov, V. I.; Тугаринов, Василий Иванович; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Petrov, D. A.; Петров, Дмитрий Анатольевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Lin, C. -R.; Chen, C. -C.; Tseng, Y. -T.; Hsu, H. -S.
}
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7.
Exploration of the
structural, spectroscopic and thermal properties of double sulfate monohydrate NaSm(SO4)2·H2O and its thermal
decomposition
product NaSm(SO4)2 / Y. G. Denisenko, A. E. Sedykh, S. A. Basova [et al.]> // Adv. Powder Technol. - 2021. -
Vol. 32
,
Is. 11
. - P. 3943-3953,
DOI
10.1016/j.apt.2021.08.009. - Cited References: 81. - This work was partly supported by the Russian Science Foundation (21-19-00046) and Russian Foundation for Basic Research (Grant 19-33-90258\19). The use of the equipment of Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged . - ISSN 0921-8831
Перевод заглавия:
Исследование структурных, спектроскопических и термических свойств двойного сульфатного моногидрата NaSm(SO4)2·H2O и продукта его термического разложения NaSm(SO4)2
Кл.слова (ненормированные):
Sulfate
--
Thermal
decomposition
--
Crystal structure
--
Raman
--
Photoluminescence
Аннотация:
Samarium-sodium double sulfate crystalline hydrate NaSm(SO4)2·H2O was obtained by the crystallization from an aqueous solution containing equimolar amounts of ions. The anhydrous salt of NaSm(SO4)2 was formed by a thermally induced release of the equivalent of water from NaSm(SO4)2·H2O. The kinetic parameters of thermal
decomposition
were determined (Ea = 102 kJ/mol, A = 9·106). The crystal structures of both compounds were refined from the X-ray powder diffraction data. Sulfate hydrate NaSm(SO4)2·H2O crystallizes in the trigonal symmetry, space group P3121 (a = 6.91820(3) and c = 12.8100(1) Å, V = 530.963(7) Å3). The anhydrous salt crystallizes in the triclinic symmetry, space group P-1 (a = 6.8816(2), b = 6.2968(2) and c = 7.0607(2) Å, α = 96.035(1), β = 99.191(1) and γ = 90.986(1)°, V = 300.17(1) Å3). The vibrational properties of compounds are mainly determined by the sulfate group deformations. The luminescence spectra of both sulfates are similar and are governed by the transitions of samarium ions 4G5/2 → 6HJ (J = 5/2, 7/2, 9/2 and 11/2). The anhydrous sulfate is stable up to 1100 K and undergoes an almost isotropic expansion when heated. After 1100 K, the compound decomposes into Sm2(SO4)3 and Na2SO4.
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Держатели документа:
Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen, 625000, Russian Federation
Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, Giessen, 35392, Germany
Department of Inorganic and Physical Chemistry, Tyumen State University, Tyumen, 625003, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
Department of Applied Physics, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far-Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Photonics and Laser Technology, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Research Department, Northern Trans-Ural State Agricultural University, Tyumen, 625003, Russian Federation
Laboratory of the Chemistry of Rare Earth Compounds, Institute of Solid State Chemistry, UB RAS, Ekaterinburg, 620137, Russian Federation
Center for Materials Research (LaMa), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 16, Giessen, 35392, Germany
Доп.точки доступа:
Denisenko, Y. G.; Sedykh, A. E.; Basova, S. A.; Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Khritokhin, N. A.; Sal'nikova, E. I.; Andreev, O. V.; Muller-Buschbaum, K.
}
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8.
Golovnev, N. N.
Structure and Thermal
Decomposition
of Nd(III), Gd(III) and Tb(III) 2-Thiobarbiturates / N. N. Golovnev, M. S. Molokeev, I. V. Sterkhova> // Russ. J. Inorg. Chem. - 2019. -
Vol. 64
,
Is. 9
. - P. 1146-1151,
DOI
10.1134/S0036023619090134. - Cited References: 21. - The work was performed as part of the State Assignment of the Ministry of Education and Science of the Russian Federation to the Siberian Federal University in 2017-2019. (4.7666.2017/BCh). The powder X-ray diffraction studies were performed using the equipment at the Baikal and Krasnoyarsk Centers for Collective Use of the Siberian Branch of the Russian Academy of Sciences. . - ISSN 0036-0236. - ISSN 1531-8613
РУБ
Chemistry, Inorganic & Nuclear
Рубрики:
CRYSTAL-STRUCTURE
TRANSFORMATION
Кл.слова (ненормированные):
lanthanide(III) 2-thiobarbiturates
--
structure
--
thermal stability
Аннотация:
Complexes [Ln2(H2O)6(μ2-Htba−O,O')4(Htba−O)2]n (Ln = Tb (I), Gd (II), Nd (III); and H2tba is thiobarbituric acid) have been synthesized. According to single-crystal X-ray diffraction, monoclinic crystals of I–III are isostructural. They contain three independent Htba– ions (one terminal and two bridging) and two independent Ln3+ ions. Six Htba– ligands (two terminal and four O,O'-bridging) and two water molecules are coordinated to one Ln3+ ion, and four O,O'-bridging Htba– ions and four water molecules are coordinated to the other Ln3+ ion to form square antiprisms. The antiprisms are bound by Htba– bridging ions into layers. Numerous hydrogen bonds and π–π interactions stabilize the structures of the compounds. Thermal
decomposition
of complexes I and II performed in air results in mixtures of oxides and oxysulfates, whereas complex III forms Nd2O2SO4.
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Публикация на русском языке
Головнев Н. Н. Структура и термическое разложение 2-тиобарбитуратов Nd(III), Gd(III) и Tb(III) [Текст] / Н. Н. Головнев, М. С. Молокеев, И. В. Стерхова // Журн. неорг. химии. - 2019. - Т. 64 № 9. - С. 965-970
Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Khabarovsk 680021, Russia.
Russian Acad Sci, Favorsky Inst Chem, Siberian Branch, Irkutsk 664033, Russia.
Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Sterkhova, I., V; Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [4.7666.2017/BCh]
}
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9.
Golovnev, N. N.
Structure of potassium and cesium barbiturates / N. N. Golovnev, M. S. Molokeev, M. K. Lesnikov> // Russ. J. Inorg. Chem. - 2018. -
Vol. 63
,
Is. 10
. - P. 1315-1321,
DOI
10.1134/S0036023618100078. - Cited References: 25. - This work was performed within the state task from the Ministry of Education and Science to the Siberian Federal University in 2017-2019 (4.7666.2017/BCh). . - ISSN 0036-0236. - ISSN 1531-8613
РУБ
Chemistry, Inorganic & Nuclear
Рубрики:
CRYSTAL-STRUCTURE
THERMAL-PROPERTIES
1,3-DIETHYL-2-THIOBARBITURATE
Кл.слова (ненормированные):
potassium and cesium barbiturates
--
synthesis
--
structure
--
thermal
decomposition
Аннотация:
The structures of catena-[K(μ6-Hba−O,O,O,O′,O′,O″)] (I) and catena-[Cs(μ6-Hba–O,O,O′,O′,O″,O″)] (II), where Н2ba is barbituric acid C4H4N2O3, were characterized by powder X-ray diffraction. Crystallographic data: a = 14.1603 (4) Å, b = 3.68977 (9) Å, c = 10.9508 (3) Å, β = 82.226 (1)°, V = 566.90 (3) Å3, space group P21/n, Z = 4 for I; a = 14.652 (1) Å, b = 11.7275 (7) Å, c = 3.8098 (3) Å, β = 79.140 (6)°, V = 642.90 (8) Å3, space group C2/m, Z = 4 for II. The structural topologies of alkali metal complexes with barbituric acid and some its derivatives were compared. The thermal stability of complexes I and II in an air atmosphere was studied.
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Публикация на русском языке
Головнев Н. Н. Структура барбитуратов калия и цезия [Текст] / Н. Н. Головнев, М. С. Молокеев, М. К. Лесников // Журн. неорг. химии. - 2018. - Т. 63 № 10. - С. 1299–1305
Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Khabarovsk 680021, Russia.
Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Ministry of Education and Science [4.7666.2017/BCh]
}
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10.
Hydrates of lanthanide(III)
2-thiobarbiturates: synthesis, structure, and thermal
decomposition
/ N. N. Golovnev, M. S. Molokeev, M. K. Lesnikov, A. S. Samoilo> // Russ. J. Inorg. Chem. - 2020. -
Vol. 65
,
Is. 7
. - P. 999-1005,
DOI
10.1134/S0036023620070098. - Cited References: 22. - This study was financially supported by the Russian Foundation for Basic Research within scientific project no. 19-52-80003 . - ISSN 0036-0236
Кл.слова (ненормированные):
lanthanides(III)
--
thiobarbiturates
--
hydrates
--
structure
--
stability
Аннотация:
The hydrates Ln(Htba)3 ∙ 3H2O (Ln = Yb (I), Er (II), Ho (III); Н2tba = 2-thiobarbituric acid), Ln(Htba)3 ∙ 2H2O and Ln(Htba)3 ∙ 8H2O were crystallized from aqueous solutions. According to single-crystal X-ray diffraction analysis data, the structure of monoclinic crystals of isostructural complexes I–III was [Ln2(H2O)6(μ2-Htba-О,O')4(Htba-О)2]n. The formation of isostructural Ln(Htba) ∙ 2H2O (Ln = La, Ce, Eu, Yb, Lu), Ln(Htba)3 ∙ 8H2O (Ln = Eu, Tb, Ho, Yb) and Y(Htba)3 ∙ nH2O (n = 2, 8) was confirmed by the comparison of X-ray diffraction patterns, and their composition was determined by elemental and thermal analyses. The stability of crystal hydrates under heating in an air atmosphere and in contact with their saturated solutions was studied.
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Публикация на русском языке
Гидраты 2-тиобарбитуратов лантаноидов(III): синтез, структура и термическое разложение [Текст] / Н. Н. Головнев, М. С. Молокеев, М. К. Лесников, А. С. Самойло // Журн. неорг. химии. - 2020. - Т. 65 № 7. - С. 915-921
Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirenskii Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center,” Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Samoilo, A. S.
}
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11.
Magnetic properties and
L1 0 phase formation in CoPt nanoparticles / S. V. Komogortsev [et al.]> // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. -
Vol. 190
. - P. 159-162,
DOI
10.4028/www.scientific.net/SSP.190.159 . - ISBN 1012-0394. - ISBN 9783037854365
Кл.слова (ненормированные):
Hard magnetic
--
Magnetic anisotropy
--
Magnetic nanoparticles
--
Remnant magnetization
--
Annealing time
--
CoPt nanoparticles
--
Disorder-order
--
Domain formation
--
Hard magnetic
--
Magnetic anisotropy energy
--
Magnetic nanoparticles
--
Phase formations
--
Remnant magnetization
--
Decomposition
--
Magnetic anisotropy
--
Magnetic materials
--
Remanence
--
Nanoparticles
Аннотация:
The effect of the atomic disorder-order transformation on remanence, coercivity and magnetic anisotropy energy in CoPt nanoparticles prepared by thermal
decomposition
and annealed at 400oC for 4 and 16 hours has been studied. The observed remanence and magnetic anisotropy energy enhancement versus annealing time are discussed in the terms of ordering domain formation inside nanoparticles. В© (2012) Trans Tech Publications.
Scopus
Доп.точки доступа:
Komogortsev, S. V.; Комогорцев, Сергей Викторович; Chizhik, N. A.; Чижик Н.А.; Filatov, E. Yu.; Филатов Е.Ю.; Korenev, S. V.; Коренев С.В.; Shubin, Yu.V.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Yurkin, G.Yu.; Юркин, Глеб Юрьевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
}
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12.
Metal dusting as
a key route to produce functionalized carbon nanofibers / A. R. Potylitsyna, I. V. Mishakov, Y. I. Bauman [et al.]> // React. Kinet. Mech. Catal. - 2022. -
Vol. 135
,
Is. 3
. - P. 1387-1404,
DOI
10.1007/s11144-022-02169-y. - Cited References: 65. - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Project numbers AAAA-A21-121011390054-1 (ID: 0239-2021-0010) and 121031700315-2) . - ISSN 1878-5190. - ISSN 1878-5204
РУБ
Chemistry, Physical
Рубрики:
CHLORINATED HYDROCARBONS
NI-CU
DECOMPOSITION
NANOTUBES
CATALYST
Кл.слова (ненормированные):
Metal dusting
--
Ternary nickel-molybdenum-tungsten alloy
--
Trichloroethylene
--
Acetonitrile
--
Functionalized carbon nanofibers
Аннотация:
The present paper reports a new method of producing N-doped carbon nanofibers via metal dusting of a ternary NiMoW alloy in the atmosphere containing C2HCl3 and CH3CN vapors at 600 °C. The initial alloy was prepared by a co-precipitation technique. The carbon deposition was monitored gravimetrically. The early stages of the metal dusting process were studied in detail using scanning and transmission electron microscopies. It was established that the rapid disintegration of the microdispersed NiMoW alloy with the formation of nanosized particles catalyzing the growth of carbon filaments occurs within the first 5 min of the reaction. The presence of C2HCl3 vapors in the reaction medium was shown to be the urgent condition to provide efficient metal dusting. The effect of the CH3CN concentration in the trichloroethylene-containing reaction mixture on the carbon deposition is investigated. As observed, the CH3CN content noticeable affects the carbon yield (after 2 h of reaction). The dome-shaped dependence of carbon yield reaches its maximal value of ~ 200 g/g(cat) at a CH3CN concentration of 33 vol%. According to X-ray photoelectron spectroscopy, the obtained carbon filaments are functionalized with Cl (0.1–1.2 wt%), O (3–6 wt%), and N (0.5–1.3 wt%). The prepared carbon filaments possess a segmented secondary structure, which is typical for carbon nanomaterials derived via catalytic
decomposition
of chlorine-substituted hydrocarbons. Low-temperature nitrogen adsorption measurement revealed that the specific surface area of the N-containing samples varies in a range from 370 to 550 m2/g.
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Держатели документа:
Boreskov Inst Catalysis, Pr Ac Lavrentieva 5, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Str Pirogova 2, Novosibirsk 630090, Russia.
Nikolaev Inst Inorgan Chem, Ac Lavrentieva 3, Novosibirsk 630090, Russia.
Kirensky Inst Phys, Akad Gorodok 50-38, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Potylitsyna, A. R.; Mishakov, I. V.; Bauman, Y. I.; Kibis, L. S.; Shubin, Y. V.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Melgunov, M. S.; Vedyagin, A. A.; Ministry of Science and Higher Education of the Russian Federation [AAAA-A21-121011390054-1, 0239-2021-0010, 121031700315-2]
}
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13.
Modification of polycaproamide
composites based on 1H,1H,13H-rihydroperfluorotridecan-1-ol and montmorillonite / S. V. Kudashev, A. A. Kondrasenko, A. N. Maiulev [et al.]> // Fibre Chem. - 2022. -
Vol. 53
,
Is. 5
. - P. 291-295,
DOI
10.1007/s10692-022-10287-5. - Cited References: 24 . - ISSN 0015-0541
Кл.слова (ненормированные):
Decomposition
--
Nuclear magnetic resonance spectroscopy
--
Macromolecular chain
--
Macroradicals
--
NMR-spectroscopy
--
Organoclays
--
Paramagnetic centers
--
Polycaproamides
--
Polymer composite
--
Possible mechanisms
--
Stabilizing effects
--
X ray structure analysis
--
Clay minerals
Аннотация:
Modification of polycaproamide by 1H,1H,13H-trihydroperfluorotridecan-1-ol immobilized on montmorillonite produced an F-containing polymer composite. The structure of the resulting composite was investigated using x-ray structure analysis and solid-state 19F NMR spectroscopy. The polymorphous composition of this heterochain polymer was shown to reorganize to enhance its thermal stability and diminish its flammability. Possible mechanisms for the stabilizing effect of the used modifier that were related to the involvement of organo-clay paramagnetic centers in the binding of macroradicals formed during thermal
decomposition
of macromolecular chains were discussed.
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Держатели документа:
Volgograd State Technical University, Volgograd, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Sebryakovskii Filial, Volgograd State Technical University, Volgograd Region, Mikhailovka, Russian Federation
L. V. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
I. M. Sechenov First Moscow State Medical University (Sechenov University), Moscow, Russian Federation
Доп.точки доступа:
Kudashev, S. V.; Kondrasenko, A. A.; Кондрасенко, Александр Александрович; Maiulev, A. N.; Мацулев, Александр Николаевич; Babkin, V. A.; Belousova, V. S.; Andreev, D. S.; Zheltobryukhov, V. F.; Kuznetsova, N. V.
}
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14.
Morphology and magnetic
properties of iron sulphides nanoparticles synthesized by the thermal
decomposition
method with different surfactants / R. D. IvantsovChun-Rong Lin, Yu. V. Knyazev [et al.]> //
Новое в магнетизме и магнитных материалах : сборник трудов XXIV международной конференции / прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2021. -
Секция 11
: Магнитные наноструктуры. - Ст. 11-25-28. - Библиогр.: 4
Перевод заглавия:
Морфология и магнитные свойства наночастицы сульфидов железа, синтезированных методом термического разложения с различными сурфактантами
Аннотация:
Morphology, magnetic, and structural properties were investigated of the iron sulphides (FexSy) nanoparticles fabricated by the thermal
decomposition
method using oleylamine, 1-hexadecylamine and octadecylamine surfactants. The presence of surfactant layer is confirmed by FT-IR spectroscopy and thermo-gravimetric analysis. The structural analysis and Mцssbauer spectroscopy of synthesized nanoparticles showed in main Fe3S4 phase with inclusions of Fe9S11 in cases of OLA and HDA surfactants and significant admixture of FeS2 and even Fe2O3 in case of ODA surfactant. Deviations of iron ions distribution among crystal positions from that in bulk pure greigite and the pronounce changes in the magnetic circular dichroism (MCD) spectra are explained with the influence of surfactants on the particles formation process as well with the role of the boundary between magnetic core and organic shell.
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Доп.точки доступа:
Исхаков, Рауф Садыкович \прогр. ком.\; Iskhakov, R. S.; Овчинников, Сергей Геннадьевич \прогр. ком.\; Ovchinnikov, S. G.; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Chun-Rong Lin; Knyazev, Yu. V.; Князев, Юрий Владимирович; Ying Zhen Chen; Zharkov, S. M.; Жарков, Сергей Михайлович; Lin, E. S.; Chen, B.Y.; Yaw-Teng Tseng; Edelman, I. S.; Эдельман, Ирина Самсоновна; "Новое в магнетизме и магнитных материалах", международная конференция(24 ; 2021 ; 1-8 июля ; Москва); Научный совет по физике конденсированных сред РАН; МИРЭА - Российский технологический университет; Московский государственный университет им. М.В. Ломоносова; Магнитное общество России
}
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15.
Mossbauer and MCD
spectroscopy of the Fe3S4 nanoparticles synthesized by the thermal
decomposition
method with two different surfactants / R. D. Ivantsov, C.-R. Lin, O. S. Ivanova [et al.]> // Curr. Appl. Phys. - 2021. -
Vol. 25
. - P. 55-61,
DOI
10.1016/j.cap.2021.02.013. - Cited References: 30. - The reported study was funded by Joint Research Project of Russian Foundation for Basic Research № 19-52-52002 and Ministry of Science and Technology, Taiwan MOST № 108-2923-M-153-001-MY3 and № 106-2112-M-153-001-MY3 , and by Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science , the research project number 19-42-240005 : “Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe”. The electron microscopy and electron diffraction investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation. The thermal-gravity measurements were carried out with the differential Scanning Calorimeter DSC 204 F-1 Phoenix (NETZSCH) in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» . - ISSN 1567-1739
Перевод заглавия:
Мёссбауэровская и МКД-спектроскопия наночастиц Fe3S4, синтезированных методом термического разложения с двумя разными ПАВ
Кл.слова (ненормированные):
Greigite
--
Thermal
decomposition
--
Surfactants
--
Mössbauer effect
--
FT-IR spectra
--
Magnetic circular dichroism
Аннотация:
Greigite (Fe3S4) nanoparticles (NPs) were fabricated by the thermal
decomposition
method using two different surfactants: oleylamine (OLA) and 1-hexadecylamine (HDA). In both cases, the synthesized NPs were characterized as the Fe3S4 nanocrystals with minor inclusions of Fe9S11 phase. FT-IR spectroscopy and thermo-gravimetric analysis allow concluding about OLA or HDA shells covering magnetic core of NPs. Mossbauer spectra has revealed deviations of iron ions distribution among crystal positions from that presented in literature for pure greigite. In accordance with these deviations, the pronounce changes are observed in the magnetic circular dichroism (MCD) spectra which manifest themselves as the spectrum shift to higher energies of electromagnetic waves and redistribution of the MCD maximum intensities. These effects are associated with a change in the density of electronic states in the samples due to the redistribution of iron ions between octahedral and tetrahedral positions in nanocrystals under the influence of surfactants.
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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RASKrasnoyarsk 660036, Russian Federation
Department of Applied Physics, National Pingtung University, Pingtung City, Pingtung County 90003, Taiwan
Siberian Federal UniversityKrasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Lin, C. -R.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Altunin, R. R.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Chen, Y. -Z.; Lin, E. -S.; Chen, B. -Y.; Shestakov, N. P.; Шестаков, Николай Петрович; Edelman, I. S.; Эдельман, Ирина Самсоновна
}
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16.
Photoluminescence of pefloxacindi-ium
manganese(II) and zinc(II) tetrahalides / N. N. Golovnev, M. A. Gerasimova, M. S. Molokeev [et al.]> // J. Mol. Struct. - 2022. -
Vol. 1248
. - Ст. 131468,
DOI
10.1016/j.molstruc.2021.131468. - Cited References: 42. - The research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-43-240007. Authors thank the Centre for Equipment Joint User of School of Petroleum and Natural Gas Engineering of Siberian Federal University, Institute of Chemistry and Chemical Technology SB RAS for their technical support . - ISSN 0022-2860
Перевод заглавия:
Фотолюминесценция тетрагалогенидов марганца(II) и цинка(II) пефлоксацина
Кл.слова (ненормированные):
Manganese and zinc halides
--
Pefloxacin
--
Ionic compounds
--
Photoluminescence
--
X-ray diffraction
--
Thermal
decomposition
Аннотация:
Mn2+-based hybrid materials have become the hotspot of current research studies owing to their high photoluminescence quantum yield (PLQY), low-cost, environmental friendliness and stability. For the first time, we report the hydrothermal synthesis of two lead-free zero-dimensional luminescent organic-inorganic hybrid compounds, PefH2[MnBr4] (1) and PefH2[MnCl4] (2) (Pef = pefloxacin). They were characterized by elemental analysis, TG-DSC, single-crystal and powder XRD. Compounds 1–2 exhibit a distorted tetrahedral geometry around the manganese(II) metal center, which is isolated from the same centers by bulky pefloxacindi-ium (PefH22+) ions with a Mn···Mn distance of 7.3 Å. Their structures are stabilized by N—H···O, O—H···X (X = Br, Cl), C—H···O and C—H···X hydrogen bands and π–π stacking interaction. Thermal
decomposition
starts at T › 230°С for 1 and T › 210°С for 2 and proceeds for several stages. Upon UV excitation compounds exhibit a bright green emission with a moderate PLQY of 45% for 1 and 30% for 2. The influence of the halide ion and metal ion on the photoluminescence properties of isostructural compounds PefH2[MX4] (M = Mn, Zn and X = Br, Cl) is discussed.
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Держатели документа:
Siberian Federal University, 79 Svobodny Prospect, Krasnoyarsk, 660041, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, bld. 38 Akademgorodok 50, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, 47 Seryshev Str., Khabarovsk, 680021, Russian Federation
Research and Development Department, Kemerovo State University, 6 Krasnaya Str., Kemerovo, 650000, Russian Federation
Доп.точки доступа:
Golovnev, N. N.; Gerasimova, M. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Plyaskin, M. E.; Baronin, M. E.
}
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17.
Properties of a
novel quaterpolymer P(3HB/4HB/3HV/3HHx) / T. G. Volova [et al.]> // Polymer. - 2016. -
Vol. 101
. - P. 67-74,
DOI
10.1016/j.polymer.2016.08.048 . - ISSN 0032-3861
Кл.слова (ненормированные):
Physicochemical and mechanical properties
--
Polyhydroxyalkanoates
--
Quaterpolymers
--
Biocompatibility
--
Cell culture
--
Chain length
--
Chains
--
Decomposition
--
3-Hydroxyhexanoate
--
Degrees of crystallinity
--
Elongation at break
--
Physico-chemical and mechanical properties
--
Polyhydroxyalkanoates
--
Quaterpolymers
--
Short chain lengths
--
Thermal
decomposition
temperature
--
Film preparation
Аннотация:
Cupriavidus eutrophus В10646 was used to synthesize a series of polyhydroxyalkanoate (PHA) quaterpolymers composed of the short-chain-length 3-hydroxybutyrate (3HB), 4-hydroxybutyrate (4HB), and 3-hydroxyvalerate (3HV) and the medium-chain-length 3-hydroxyhexanoate (3HHx). The molar fraction of 3HB in the quaterpolymers varied between 63.5 and 93.1 mol.%, 3HV – between 1.1 and 24.6 mol.%, 4HB – between 2.4 and 15.6 mol.%, and 3HHx – between 0.4 and 4.8 mol.%. The properties of PHA quaterpolymers were significantly different from those of the P(3HB) homopolymer: they had much lower degrees of crystallinity (up to 30–45%), and lower melting points and thermal
decomposition
temperatures, with the interval between these temperatures remaining practically unchanged. Films prepared from PHA quaterpolymers were rougher and more porous than P(3HB) films; they showed higher values of elongation at break (up to 6–113%), i.e. were more elastic. Films prepared from PHA quaterpolymers were biocompatible and had no toxic effect on mouse fibroblast NIH 3T3 cells. © 2016 Elsevier Ltd
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Держатели документа:
Siberian Federal University, 79 Svobodnyi Avenue, Krasnoyarsk, Russian Federation
Institute of Biophysics of Siberian Branch of Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology of Siberian Branch of Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics of Siberian Branch of Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Volova, T. G.; Волова, Татьяна Григорьевна; Vinogradova, O. N.; Zhila, N. O.; Жила, Наталья Олеговна; Peterson, I. V.; Петерсон, Иван Викторович; Kiselev, E. G.; Киселев, Евгений Геннадьевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Sukovatiy, A. G.; Суковатый, Алексей Григорьевич; Shishatskaya, E. I.; Шишацкая, Екатерина Игоревна
}
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18.
Raman study of
decomposition
of Na-bearing carbonates in water fluid at high P–T parameters / S. Goryainov, A. Krylov, U. Borodina [et al.]> // Spectrochim. Acta - A: Mol. Biomol. Spectrosc. - 2024. -
Vol. 322
. - Ст. 124801,
DOI
10.1016/j.saa.2024.124801. - Cited References: 74. - Authors thank V.S. Shevchenko, A.F. Shatskiy, A.G. Sokol and A.V. Golovin for fruitful discussion. We acknowledge I.N. Kupriyanov for discussion and measurements of FTIR spectra of the samples. This work was carried out within the framework of the Russian Federation state assignment of the Sobolev Institute of Geology and Mineralogy SB RAS (state registration number: 122041400176-0) and A.K., S.K and A.V. thanks for support the Russian Federation state assignment of Kirensky Institute of Physics, Federal Research Center KSC SB RAS (state registration number: FWES-2024-0003). Work partially supported by the Russian Foundation for Basic Researches (RFBR-21-55-14001 ANF a grant). Equipment and devices of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” were used for Raman experiments at high P–T conditions . - ISSN 1386-1425. - ISSN 1873-3557
Кл.слова (ненормированные):
Raman spectroscopy
--
Carbonates
--
High pressure
--
High temperature
--
Abiogenic formation of organics
--
Organic formates
--
Organic molecular crystals
Аннотация:
The study of Na-carbonates stability and their transformations in aqueous carbonate fluid under high P–T conditions is relevant from the point of view of the understanding geochemical processes of the Na-assisted carbon circulation in the Earth’s crust and subduction zones. In situ Raman study of Na-bearing carbonate-water-Fe-metal system in diamond anvil cell (DAC) at high P–T conditions revealed that carbonates decompose with abiogenic formation of formates and other organic compounds that differs from behavior of carbonates in dry system. XRD and FTIR methods have been used additionaly to determine the phase composition. Na-bearing carbonates (nahcolite NaHCO3, shortite Na2Ca2(CO3)3 and cancrinite Na7Ca[(CO3)1.5Al6Si6O24]·2H2O) in aqueous fluid decompose to form simple carbonates and formates (as dominant organic molecules) at moderate P–T parameters (above ∼0.2 GPa, 200°C). Our experimental results directly confirm the hypothesis of Horita and Berndt (Science, 1999) about possible yield of organic formates in the carbonate-water-metal system. Nahcolite NaHCO3 in aqueous fluid in the presence of Fe metal decomposes into anhydrous phases: natrite γ-Na2CO3, siderite, magnetite (due to dissolution of Fe steel gasket), Na-formate and likely organic molecular crystalline solvate of Na-formate and methyl formate. Shortite decays into anhydrous phases: aragonite CaCO3, Na-Ca-formates and an amorphous phase. Cancrinite decomposes to unidentified carbonate-alumonosilicate phases, Na-Ca-formates and unknown organic molecular crystal. Magnetite is also formed in this system due to dissolution of Fe steel gasket used in DAC. The present study provides a new insight in processes of abiogenic formation of organic matter from carbonates in the crust and upper mantle.
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Держатели документа:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, prospect Acad. Koptyug 3, Novosibirsk, 630090, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok, 50, bld. 38, Krasnoyarsk, 660036, Russia
Доп.точки доступа:
Goryainov, S.; Krylov, A. S.; Крылов, Александр Сергеевич; Borodina, U.; Likhacheva, A.; Krylova, S. N.; Крылова, Светлана Николаевна; Seryotkin, Yu.; Bogdanov, N.; Vtyurin, A. N.; Втюрин, Александр Николаевич; Grishina, S.
}
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19.
Raman study of
thaumasite and its
decomposition
at simultaneously high P-T parameters / A. S. Krylov [и др.]> //
XII Int. conf. "GeoRaman-2016" : abstract volume / compiled and edited by T.A. Alifirova, S.V. Rashchenko, A.V. Korsakov. - Novosibirsk : Офсет, 2016. - P. 22. - References: 1. - This work was supported by the Russian Foundation for Basic Research (projects No. 14-05-00616 and 15-55-45070-IND) and the Russian Science Foundation (project No. 15-17-30012). . - ISBN 978-5-85957-124-6
Аннотация:
Thaumasite Ca3Si(OH)6(SO4)(CO3)12H2O is extraordinary mineral that possibly plays particular role in silicate-sulfate-carbonate balance of the Earth‟s interiors. High pressure behavior of thaumasite was studied only in He medium at room T [1]. We present Raman spectroscopy study of thaumasite compressed in water at simultaneously high P-T conditions up to ~300 °C and ~2 GPa, in order to elucidate possible non-quenchable states (polymorphism, overhydration, reversible amorphization and dehydration), as well as its
decomposition
. Raman bands of thaumasite diminish in intensity and widen in the range of 200-300 °C (Fig. 1). Thaumasite crystals are partly dissolved in water. After the release of high P-T, strong band at 991 cm–1 shifts to 985 cm –1, corresponding to partly disordered thaumasite. The stability range of thaumasite is extended up to ~250 °C at ~2 GPa. At 300 °C and ~2 GPa, thaumasite is decomposed to aragonite, gypsum and partly amorphous silicate within 30 min.
Материалы конференции
,
Читать в сети ИФ
Доп.точки доступа:
Alifirova, T. A. \ed.\; Rashchenko, S. V. \ed.\; Korsakov, A. V. \ed.\; Goryainov, S. V.; Горяйнов, Сергей Владимирович; Krylov, A. S.; Крылов, Александр Сергеевич; Likhacheva, A. Y.; Лихачева, Анна Юрьевна; Prasad, P. S. R.; Vtyurin, A. N.; Втюрин, Александр Николаевич; "GeoRaman", International conference(12 ; 2016 ; June ; 9-15 ; Novosibirsk); Российская академия наук; Сибирское отделение РАН; Институт геологии и минералогии им. В.С. Соболева Сибирского отделения РАН
}
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20.
State of iron
in nanoparticles prepared by impregnation of silica gel and aluminum oxide with FeSO4 solutions / G. A. Bukhtiyarova [et al.]> // Phys. Solid State. - 2010. -
Vol. 52
,
Is. 4
. - P. 826-837,
DOI
10.1134/S1063783410040268. - Cited References: 27. - This study was supported by the Presidium of the Russian Academy of Sciences within the framework of the Program no. 27 "Principles of Basic Research of Nanotechnologies and Nanomaterials," Project no. 46 "Magnetically Ordered Nanoparticles in Catalytic Systems: Synthesis, Evolution, and Physicochemical Properties." . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
THERMAL-
DECOMPOSITION
BETA-FEOOH
MOSSBAUER
FERRIHYDRITE
EPSILON-FE2O3
FE-2(SO4)(3)
SULFATE
FE-57
Аннотация:
The state of iron in nanoparticles prepared by impregnating silica gel and aluminum oxide with iron(II) sulfate solutions has been investigated using Mossbauer spectroscopy. It has been revealed that the state of iron depends on the nature of the support. Iron(III) hydroxysulfate and iron(III) oxysulfate nanoparticles are formed on the surface of silica gel, and iron oxide nanoparticles are formed on the surface of aluminum oxide. An increase in the concentration of iron ions or in the size of iron-containing particles leads to hydration of the nanoparticle surface. The calcination of the samples results in the formation of E -Fe2O3 oxide in a strongly disordered or amorphous state in iron-containing particles on the surface of silica gel.
WOS
,
Scopus
,
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Держатели документа:
[Bukhtiyarova, G. A.
Mart'yanov, O. N.
Yakushkin, S. S.
Shuvaeva, M. A.] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[Bayukov, O. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, Novosibirsk 630090, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Bukhtiyarova, G. A.; Mart'yanov, O. N.; Yakushkin, S. S.; Shuvaeva, M. A.; Bayukov, O. A.; Баюков, Олег Артемьевич
}
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