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The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases / I. O. Yurev, A. S. Aleksandrovsky, D. N. Kamaev [et al.] // J. Therm. Anal. Calorim. - 2024. - Vol. 149, Is. 5. - P. 2057-2073, DOI 10.1007/s10973-023-12792-z. - Cited References: 90. - The authors thank Prof. P.P. Fedorov, Chief Researcher of Prokhorov Institute of General Physics, Russian Academy of Sciences, for scientific advices. The authors thank N.I. Lozhkin, engineer of the Department of Inorganic and Physical Chemistry, Tyumen State University for the technical support of the visual thermal analysis setup. The authors thank N.A. Shulaev, research engineer of the Center for Nature-Inspired Engineering, Tyumen State University, for determining the elemental composition of samples by scanning electron microscopy. The authors thank I.V. Palamarchuk, research engineer of the Center for Collective Use "Rational Nature Management and Physical and Chemical Research" of the Tyumen State University, for measuring the diffuse reflectance spectra. The authors thank Doctor of Philology O.V. Trofimova, Professor at the Institute of Social Sciences and Humanities of the Tyumen State University, for her advices on academic writing. - This study was funded by the Russian Science Foundation, Project No. 23–23-00488 “Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)” . - ISSN 1388-6150. - ISSN 1588-2926
Кл.слова (ненормированные):
Samarium sulfides -- Refractory system -- Thermal analysis -- Ternary eutectic -- Phase diagram -- Band gap
Аннотация: Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm3S4 and Sm2O2S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm2S3-X-SmS-Sm2O2S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm3S4, SmS, and Sm2O2S compounds were determined. Eutectic diagrams of Sm3S4-Sm2O2S, SmS-Sm2O2S, SmS-Sm3S4 systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm3S4, SmS, and Sm2O2S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm3S4-SmS-Sm2O2S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm2S3 → γ-Sm2S3 polymorphic transition and the dependence of the Sm2S3-X composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm2S3 sample is Sm2S2.95. The Sm10S14O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm2S3-X-Sm2O2S system was revisited. Optical band gaps of Sm10S14O and Sm2O2S phases were determined. The Sm10S14O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm2O2S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Volodarsky Str. 6, Tyumen, 625003, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya Str. 63/4, Kurgan, 640020, Russian Federation
Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Akademgorodok Str. 50, Building 38, Krasnoyarsk, 660036, Russia
Siberian Federal University, Svobodnyj Av. 79, Krasnoyarsk, 660079, Russia
Institute of Physical Materials Science, SB RAS, Sakhyanova Str. 6, Ulan-Ude, 670047, Russian Federation
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya Str. 91, Yekaterinburg, 620990, Russian Federation

Доп.точки доступа:
Yurev, I. O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kamaev, D. N.; Polkovnikov, A. A.; Grigorchenko, V. M.; Yarovenko, A. A.; Zelenaya, A. E.; Parfenova, M. D.; Andreev, O. V.
}
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    Synthesis and properties of the NdSF compound, phase diagram of the NdF3–Nd2S3 system / V. M. Grigorchenko, M. S. Molokeev, A. S. Oreshonkov [et al.] // J. Solid State Chem. - 2024. - Vol. 333. - Ст. 124640, DOI 10.1016/j.jssc.2024.124640. - Cited References: 48. - This research was funded by the Tyumen Oblast Government as part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3). - The studies ab initio simulation of electron band structure, analysis of optical properties, XRD analysis was partially supported by "Priority-2030" program for the Siberian Federal University, and the state assignment of Kirensky Institute of Physics . - ISSN 0022-4596. - ISSN 1095-726X
   Перевод заглавия: Синтез и свойства соединения NdSF, фазовая диаграмма системы NdF3–Nd2S3
Кл.слова (ненормированные):
Neodymium fluorosulfide -- Phase diagram -- Optical band gap -- Microhardness
Аннотация: The NdF3–Nd2S3 system attracts attention of researchers due to the possibility of using LnSF compounds (Ln = rare earth element) as possible new p- and n-type materials. The samples of this system were synthesized from NdF3 and Nd2S3. The NdSF compound belongs to the PbFCl structural type, P4/nmm space group, unit cell parameters: a = 3.9331(20) Å, c = 6.9081(38) Å. The experimentally determined direct and indirect NdSF bandgaps are equal to 2.68 eV and 2.24 eV. The electronic band structure was calculated via DFT simulation. The NdSF compound melts congruently at T = 1385 ± 10°С, ΔНm = 40.5 ± 10 kJ/mol, ΔS = 24.4 ± 10 J/mol. The NdSF microhardness is 455 ± 10 HV. Five phase transformations in the NdF3–Nd2S3 system were recorded by DSC; their balance equations were derived. The liquidus of the system calculated from the Redlich–Kister equation is fully consistent with the DSC data.

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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, Building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Pervomaiskaya str. 91, 620990, Russia
Saint-Petersburg State University, 7/9 Universitetskaya Emb., 199034, St. Petersburg, Russia

Доп.точки доступа:
Grigorchenko, V.M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kertman, A.V.; Abulkhaev, M.U.; Mereshchenko, A.S.; Yurev, I.O.; Shulaev, N.А.; Kamaev, D.N.; Elyshev, A.V.; Andreev, O.V.
}
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Chemical pressure as an effective tool for tuning the structural disordering and barocaloric efficiency of complex fluorides (NH4)3MF7 (M: Sn, Ti, Ge, Si) / I. N. Flerov, M. V. Gorev, E. V. Bogdanov, N. M. Laptash // J. Phys. D: Appl. Phys. - 2024. - Vol. 57, Is. 17. - Ст. 175301, DOI 10.1088/1361-6463/ad211b. - Cited References: 39. - The study was supported by a Grant from the Russian Science Foundation No. 23-22-00115, https://rscf.ru/project/23-22-00115/ . - ISSN 0022-3727. - ISSN 1361-6463
Кл.слова (ненормированные):
fluorides -- phase transformation -- phase diagram -- entropy -- pressure -- barocaloric effect
Аннотация: Double fluoride salts (NH4)3M4+F7 (M4+: Sn, Ti, Ge, Si) demonstrate a high efficiency of using chemical pressure as a tool for control and tuning structural ordering/disordering, sensitivity to hydrostatic pressure, successions of the phase transitions, etc and, as a result, for purposeful variation within a wide range of parameters of barocaloric effect (BCE). The conventional and inverse BCEs near the triple points were found on the T − p phase diagrams, combination of which can be used to construct original cooling cycle in narrow temperature and pressure ranges. Reconstructive transformation between two cubic phases, Pm3-m ↔ Pa3-, realized in (NH4)3SnF7 at atmospheric pressure and in (NH4)3TiF7 at p ˃ 0.4 GPa are characterized by rather low thermal hysteresis, δT0 = 1 K, and a great entropy change, ΔSBCE = 110–152 J (kg · K)−1, depending on the size of the central atom. At above 300–350 K, a contribution to BCE associated with the regular thermal expansion of the crystal lattice becomes comparable to entropy and temperature changes under pressure in the region of the phase transitions. An analysis of the absolute, relative and integral barocaloric characteristics of (NH4)3M4+F7 compounds showed their high competitiveness with respect to other barocaloric materials considered as promising solid-state refrigerants.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk, Russia
Institute of Chemistry, Far Eastern Department of RAS, 690022 Vladivostok, Russia

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.
}
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Thermal expansion, T – x phase diagram and polarization of (1-x)Na1/2Bi1/2TiO3-xBaTiO3 solid solutions / M. V. Gorev, I. N. Flerov, M. S. Molokeev [et al.] // J. Eur. Ceram. Soc. - 2024. - Vol. 44, Is. 15. - Ст. 116769, DOI 10.1016/j.jeurceramsoc.2024.116769. - Cited References: 40 . - ISSN 0955-2219. - ISSN 1873-619X
Кл.слова (ненормированные):
Ferroelectrics -- NaBiTiO -- Thermal expansion -- Polarization -- Phase diagram
Аннотация: The paper presents the results of detailed studies of thermal expansion of solid solutions (1-x)Na1/2Bi1/2TiO3-xBaTiO3 with x=0.04-0.97 in the temperature range from 100 to 900 K. A change in chemical pressure associated with the complex cationic substitution, (Na1/2Bi1/2)2+ → Ba2+, result in a very rapid decrease in the temperatures of the transformation P4 mm → C2 mm → R3m below 100 K which are characteristic of BaTiO3. Significant features in the behavior of thermal expansion were observed near two triple points in the T – x phase diagram where the phases Pm3¯m, P4 mm, P4bm (x≈0.15-0.20) and P4bm, P4 mm, R3c (x≈0,06) coexist, allow the studied solid solutions to be divided into three groups. The relationship between the effects of internal chemical pressure and external hydrostatic one is discussed. By analyzing the thermodynamic potential, the root-mean-square polarization Pd is determined, which increases by about 16% with a decrease in the BT content from 0.97 to 0.4.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036, Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074, Krasnoyarsk, Russia
Institute of Solid State Physics, University of Latvia, Riga, LV-1063, Latvia

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bormanis, K.; Birks, E.; Sapozhnikov, S. V.; Mikhaleva, E. A.; Михалева, Екатерина Андреевна
}
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    Влияние замещения в ортоферрите HoFe1-xMnxO3 на особенности фазовой диаграммы при малых концентрациях марганца (х0.1) / К. А. Шайхутдинов, С. В. Семенов, С. А. Скоробогатов, А. Л. Фрейдман // Новое в магнетизме и магнитных материалах : сборник трудов XXV международной конференции / прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2024. - Секция 7 [Сборник 7] : Магнитные фазовые переходы и критические явления. - С. 66-68. - Библиогр.: 4. - РНФ, Красноярский краевой фонд науки, грант № 23-22-10026 . - ISBN 978-5-4465-1869-2
   Перевод заглавия: Effect of substitution in orthoferrite HoFe1-xMnxO3 on the features of the phase diagram at low manganese concentrations (x0.1)
Аннотация: Ортоферриты редкоземельных элементов широко исследованы и проявляют спонтанные магнитные переходы. В то же время, соединения с замещением 3d-элементов исследованы достаточно слабо. В данной работе проведено исследование магнитных свойств монокристаллов ортоферрита гольмия с замещением ионов Fe3+ ионами Mn3+. Из магнитных измерений установлено, что при замещении железа на марганец изменяется тип магнитного ориентационного перехода от перехода II рода (AxFyGz ‒ CxGyFz) к переходу первого рода (AxFyGz ‒ GxCyAz) с наличием слабого ферромагнитного момента только в направлении b (для установки Рnma). Последнее позволяет использовать степень замещения, как инструмент создания материала с заданными магнитными свойствами. Кроме этого, установлено, что при малых концентрациях марганца (x0.1) на фазовой диаграмме HoFe1-xMnxO3 наблюдается более сложный переход AxFyGz ‒ GxCyAz‒ CxGyFz.

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Держатели документа:
Институт физики им. Л.В. Киренского Сибирского отделения Российской академии наук - обособленное подразделение ФИЦ КНЦ СО РАН

Доп.точки доступа:
Исхаков, Рауф Садыкович \прогр. ком.\; Iskhakov, R. S.; Овчинников, Сергей Геннадьевич \прогр. ком.\; Ovchinnikov, S. G.; Шайхутдинов, Кирилл Александрович; Shaikhutdinov, K. A.; Семенов, Сергей Васильевич; Semenov, S. V.; Скоробогатов, Станислав Алексеевич; Skorobogatov, S. A.; Фрейдман, Александр Леонидович; Freydman, A. L.; "Новое в магнетизме и магнитных материалах", международная конференция(25 ; 2024 ; 1-6 июля ; Москва); Научный совет по физике конденсированных сред РАН; МИРЭА - Российский технологический университет; Московский государственный университет им. М.В. Ломоносова; Магнитное общество России
}
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Properties of La2F4Se, B–LaFSe phases. Phase diagram of the LaF3–La2Se3 system / V. M. Grigorchenko, M. S. Molokeev, I. O. Yurev [et al.] // J. Solid State Chem. - 2024. - Vol. 338. - Ст. 124880, DOI 10.1016/j.jssc.2024.124880. - Cited References: 45. - This research was funded by the Tyumen Oblast Government as part of the West-Siberian Interregional Science and Education Center's project No. 89-DON (3). - This study was funded by the Russian Science Foundation, project No. 23-23-00488 "Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)". - The authors are grateful to I.V. Palamarchuk, a research engineer at the Center for Collective Use “Rational Nature Management and Physico-Chemical Research" of Tyumen State University, for measuring the diffusion spectrum of reflections of samples. A.S.A, A.S.O and A.S.K are grateful for the state assignment funding from Kirensky Institute of Physics . - ISSN 0022-4596. - ISSN 1095-726X
Кл.слова (ненормированные):
Lanthanum selenidofluoride -- Band gap -- Phase diagram -- Incongruent melting
Аннотация: Lanthanum selenidofluorides belong to wide-gap semiconductors and are promising for optoelectronics. La2F4Se, B–LaFSe compounds were obtained by the ampoule method from binary compounds. Crystals La2F4Se, R-3m, a = 4.18245(11) Å, c = 23.2939(6) Å, Z = 3, B–LaFSe P63/mmc, a = 4.21989(5) Å, c = 8.19140(10) Å, Z = 2 have a layered grain structure, their microhardnesses are 340 and 450 HV, which allows samples processing. The optical bandgap of La2F4Se is 4.5 eV. The optical bandgaps of La2F4Se and B–LaFSe were analyzed by comparing the calculated absorption spectra and the experimental Kubelka-Munk Functions. It was shown that this approach is attractive in explaining optical properties in the vicinity of fundamental absorption onset and in neighboring regions. In LaF3–La2Se3 system, temperatures and enthalpies of five phase transformations were determined, and their balance equations were obtained. It was shown that La2F4Se, B–LaFSe compounds melt incongruently and that an eutectic is formed between the phases. A phase diagram of LaF3–La2Se3 system was constructed. The liquidus calculated by Redlich-Kister polynomial agrees with the data of differential scanning calorimetry.

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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Pervomaiskaya str. 91, 620990, Russia

Доп.точки доступа:
Grigorchenko, V.M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Yurev, I.O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Nesterova, N.V.; Kamaev, D.N.; Elyshev, A.V.; Andreev, O.V.
}
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Properties of GdSF and phase diagram of the GdF3 - Gd2S3 system / M. U. Abulkhaev, M. S. Molokeev, A. S. Oreshonkov [и др.] // J. Solid State Chem. - 2023. - Vol. 322. - Ст. 123991, DOI 10.1016/j.jssc.2023.123991. - Cited References: 44. - The authors of the article are grateful to P.P. Fedorov for valuable critical comments on the manuscript. - This research was funded by the Tyumen Oblast Government, as a part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3) . - ISSN 0022-4596. - ISSN 1095-726X
Кл.слова (ненормированные):
Gadolinium fluorosulfide -- Optical properties -- Electronic structure -- Thermal properties -- System phase diagram -- Tauc plot -- Direct and indirect bandgaps
Аннотация: The objectives of this study were to refine the phase diagram of the GdF3-Gd2S3 system and to calculate their liquidus, and to synthesize GdSF and to study their properties. The GdSF compound (ST PbFCl, P4/nmm, a (Å) 3.83006(17), c (Å) 6.8529(3), has an optical band gap for a direct interband transition of 2.56 eV and is characterized by a pronounced increase in the Kubelka-Munk function in the region of this transition. Direct optical bandgap of GdSF is measured to be equal to 2.77 eV. Two indirect bandgaps are detected to be 1.54 and 2.4 eV. Meta-GGA simulations of band structure predicting 1.481 eV direct bandgap of GdSF are in good agreement with these features of the experimental absorption spectrum. To explain this complicated case, we argue that formally direct optical transitions to highly dispersive subbands contribute not to direct but to indirect bandgaps measured by Tauc analysis. The GdSF compound melts incongruently with the formation of a melt and γ-Gd2S3 compound at t = 1280 ± 2°С, ΔН = 40.6 ± 2.8 kJ/mol, ΔS = 26.1 ± 1.8 J/mol∗K. The eutectic has a composition of 13 mol.% Gd2S3 (0.74 GdF3 + 0.26 GdSF), the melting characteristics of the eutectic are 1182 ± 2°С, ΔН = 36.2 ± 2.5 kJ/mol, ΔS = 24.9 ± 1.7 J/mol∗K. In the system GdF3 - Gd2S3 the balance equations for five phase transformations recorded by the DSC method were compiled. Convergence was achieved in the liquidus of the system constructed according to DSC data and calculated with the use of the Redlich-Kister equation.

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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, Building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Pervomaiskaya str. 91, 620990, Russia

Доп.точки доступа:
Abulkhaev, M. U.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kertman, A. V.; Kamaev, D. N.; Trofimova, O. V.; Elyshev, A. V.; Andreev, O. V.
}
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Martynov, S. N.
Orbital structure and magnetic phase diagram of the four-sublattice ferromagnet PbMnBO4 / S. N. Martynov // J. Magn. Magn. Mater. - 2023. - Vol. 570. - Ст. 170520, DOI 10.1016/j.jmmm.2023.170520. - Cited References: 20. - The author thanks A.D. Balaev for useful discussions of the magnetic measurements . - ISSN 0304-8853. - ISSN 1873-4766
Кл.слова (ненормированные):
Ferromagnets -- Magnetic anisotropy -- Noncollinear magnetic structures
Аннотация: A role of quadric and quartic single-ion anisotropy (SIA) of Mn3+-ions, dipole–dipole and Dzyaloshinsky–Moriya (DM) interactions for the magnetic ordering of the four-sublattice ferromagnet PbMnBO4 is investigated. A phase diagram of low-lying magnetic phases on the plane of the DM exchange components is obtained for different values of the SIA parameters. An effect of the isotropic interchain exchange on the spin orientation and, as a result, on the SIA energy in different magnetic phases is considered at the comparable values of the interactions. The determinative role of DM exchange for the magnetic anisotropy of PbMnBO4 is discussed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Мартынов, Сергей Николаевич
}
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Phase diagram and soft modes behavior TbFe3–xGax(BO3)4 solid solutions with huntite structure / A. S. Krylov, A. N. Vtyurin, I. A. Gudim [et al.] // Opt. Spectrosc. - 2023. - Vol. 131, Is. 9. - P. 840-848, DOI 10.1134/S0030400X23070081. - Cited References: 40. - The authors are grateful to the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Krasnoyarsk Regional Science Foundation for funding within the framework of the scientific project, grant no. 20-42-240009 r_a_Krasnoyarsk, as well as the Russian Foundation for Basic Research and the German Scientific Research Community (Deutsche Forschungsgemeinschaft) for financial support within the project no. 21-52-12018 NNIO_a . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
Raman spectroscopy -- temperature dependence -- soft modes -- ferroborates -- phase diagramm
Аннотация: The Raman spectra of four crystals of TbFe3–xGax(BO3)4 solid solutions (x from 0 to 0.54) were studied in the temperature range from 8 to 350 K. The temperatures of structural phase transitions were determined. The observed spectral behavior is characteristic to condensation and restoration of soft modes. Soft modes are associated with a structural phase transition from the R32 phase to the P3121 phase. The Compositions-Temperature phase diagram was constructed.

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Публикация на русском языке Фазовая диаграмма и особенности поведения мягких мод в твердых растворах со структурой хантита TbFe3-xGax(BO3)4 [Текст] / А. С. Крылов, А. Н. Втюрин, И. А. Гудим [и др.] // Опт. и спектроскоп. - 2022. - Т. 130 Вып. 1. - С. 84-91

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Siberian Federal University, 660041, Krasnoyarsk, Russia
Federal Research Center KSC SB, Russian Academy of Sciences, “Krasnoyarsk Scientific Center of the Siberian Branch of RAS”, 660036, Krasnoyarsk, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Krylova, S. N.; Крылова, Светлана Николаевна
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10.

    Gamov, Alexander.
    Fermion parity of phases supporting multiple Majorana modes in a superconducting nanowire / A. Gamov, A. O. Zlotnikov // J. Sib. Fed. Univ. Math. Phys. - 2023. - Vol. 16, Is. 6. - P. 820-829 ; Журн. СФУ. Матем. и физ. - Cited References: 22. - Gamov A. acknowledges the support of the Theoretical Physics and Mathematics Advancement Foundation "BASIS" . - ISSN 1997-1397. - ISSN 2313-6022
   Перевод заглавия: Фермионная четность в фазах с множеством майорановских мод в сверхпроводящей нанопроволоке
Кл.слова (ненормированные):
Fermion parity -- superconducting nanowire -- Majorana modes -- topological invarian -- topological phase diagram -- фермионная четность -- сверхпроводящая нанопроволока -- майорановские моды -- топологический инвариан -- топологическая фазовая диаграмма
Аннотация: The fermion parity of the ground state is determined in various topological phases of the semiconducting nanowire under external magnetic field with proximity-induced superconductivity and strong spin-orbit interaction. Electron hopping as well as spin-flip hopping due to spin-orbit coupling and superconducting pairings in the second coordination sphere are taken into account. The connection between the fermion parity and the parity of the BDI topological invariant is shown. The formation of topological phases with three and four pairs of Majorana modes has been demonstrated.
Для полупроводниковой нанопроволоки, помещенной во внешнее магнитное поле, с наведенной сверхпроводимостью и сильным спин-орбитальным взаимодействием определена фермионная четность основного состояния в различных топологических фазах при учете перескоков электронов, включая перескоки с переворотом спина за счет спин-орбитальной связи, и сверхпроводящих спариваний во второй координационной сфере. Показана связь фермионной четности и четности BDI топологического инварианта. Продемонстрировано формирование топологических фаз с тремя и четырьмя парами майорановских мод.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Zlotnikov, A. O.; Злотников, Антон Олегович

}
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