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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov V. V., Karimov D.N.
Заглавие : Nature of magnetic circular dichroism and absorption spectra of f-f transitions in Na0.4Ho0.6F2.2 single crystal
Колич.характеристики :5 с
Место публикации : Chem. Phys. - 2024. - Vol. 581. - Ст.112257. - ISSN 03010104 (ISSN), DOI 10.1016/j.chemphys.2024.112257. - ISSN 18734421 (eISSN)
Примечания : Cited References: 25
Аннотация: We present first study of magnetic circular dichroism (MCD) spectra of Ho3+ ion in C4v local symmetry, which it has in fluorite Na0.4Ho0.6F2.2. Optical absorption and MCD spectra were studied in this single crystal in the region of 5I8 5F3, 5F2, 3K8 and 5G5 transitions in the temperature range 3.6–––90 K. It was revealed, that number of transitions observed in the MCD and absorption spectra coincides with the number of transitions only from the doublet E state to singlet excited states. The E-E type transitions are not active in MCD, but they are not observed in the absorption spectra either. Paramagnetic magneto-optical activities (MOA) of the absorption bands and their temperature dependences were measured and interpreted with the help of the theory based on the nature of f-f transitions allowance. The MCD spectra were also analyzed in approximation of the J,±MJ wave functions of the free atom. It was shown in particular, that the lowest initial state of the transitions observed at T ˃ 10 K had MJ = 7, but this is not the lowest state of the holmium ion in the crystal. A little lower there is a quasi-doublet with MJ = 8 and, accordingly, with a higher magneto-optical activity of transitions from it. However, the intensity of transitions from this state is low.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Rautskii M. V., Neznakhin D. S., Stepanova E. A., Edelman I. S., Chou, Hsiung
Заглавие : Particles–matrix bond in ZnCoO:H and ZnCoAlO:H films: Issues of magnetism and spin injection
Место публикации : Materials. - 2023. - Vol. 16, Is. 10. - Ст.3659. - ISSN 19961944 (eISSN), DOI 10.3390/ma16103659
Примечания : Cited References: 45. - This work was supported by the Russian Science Foundation [grant number 21-72-00061]
Аннотация: ZnCoO:H and ZnCoAlO:H films were synthesized by radio frequency magnetron sputtering in a (1 − x)Ar + xH2 mixed atmosphere with x = 0.2–0.5. The films contain different amounts of metallic Co particles (from 7.6% and higher) ~4–7 nm in size. The magnetic and magneto-optical (MO) behavior of the films was analyzed in combination with their structural data. The samples exhibit high values of magnetization (up to 377 emu/cm3) and MO response at room temperature. Two situations are considered: (1) the film magnetism is associated only with isolated metal particles and (2) magnetism is present both in the oxide matrix and in metal inclusions. It has been established that the formation mechanism of the magnetic structure of ZnO:Co2+ is due to the spin-polarized conduction electrons of metal particles and zinc vacancies. It was also found that in the presence of two magnetic components in the films, these components are exchange-coupled. In this case, the exchange coupling generates a high spin polarization of the films. The spin-dependent transport properties of the samples have been studied. A high value of the negative magnetoresistance of the films at room temperature (~4%) was found. This behavior was explained in terms of the giant magnetoresistance model. Thus, the ZnCoO:H and ZnCoAlO:H films with high spin polarization can be considered as sources of spin injection.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Edelman I. S., Chou, Hsiung, Petrov D. A., Zharkov S. M., Neznakhin, Dmitry, Stepanova, Elena, Stepanov, Andrey
Заглавие : Magnetic circular dichroism of Co nanoparticles localized in matrices of various types
Место публикации : Materialia. - 2023. - Vol. 28. - Ст.101759. - ISSN 25891529 (eISSN), DOI 10.1016/j.mtla.2023.101759
Примечания : Cited References: 28. - This work was supported by the Russian Science Foundation [grant number 21-72-00061]. Electron microscopic studies were carried out in the laboratory of electron microscopy of the Joint Scientific Center of the Siberian Federal University
Аннотация: Magnetic and magneto-optical properties of cobalt nanoparticles (Co-NPs) dispersed in a transparent dielectric SiO2 and semiconductor ZnO matrices have been investigated. Field and temperature dependences of the samples magnetization showed the typical behavior of an ensemble of superparamagnetic particles with a blocking temperature near and below room temperature. The spectroscopy of magnetic circular dichroism (MCD) in the visible and near-infrared light ranges has revealed a significant difference between the behavior of the Co-NPs and a solid Co film. It has been found that the MCD spectrum shape for the Co-NPs does not depend on the matrix type. The room temperature magneto-optical activity of the Co-NPs in the different matrices has been estimated as an indicator for practical applications.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Diab M., Gudim I. A., Popova M. N.
Заглавие : Optical linear dichroism in the ab-plane of NdFe3(BO3)4 ferroborate
Колич.характеристики :6 с
Место публикации : J. Exp. Theor. Phys. - 2023. - Vol. 137, Is. 4: Special Issue dedicated to the 95th Anniversary of L. A. Prozorova. - P.486-491. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776123100011. - ISSN 10906509 (eISSN)
Примечания : Cited References: 16. - This study was supported by the Ministry of Science and Higher Education (project no. FFUU-2022-0003) and partially (K.N. B., dichroism measurements) by the Russian Science Foundation (grant no. 19-72-10132P)
Аннотация: The high-resolution optical absorption spectra of NdFe3(BO3)4 single crystals have been recorded at temperatures from 4 to 40 K in the IR range of f–f transitions in a Nd3+ ion. Light linearly polarized at different angles to the C2 axes in the basal plane has been passed along the trigonal C3 axis. Below the temperature of magnetic moment ordering into a collinear antiferromagnetic structure (TN ≈ 30 K), dichroism, that is, the absorption versus polarization dependence, arises. The temperature and angular dependences of dichroism indicate that the magnetic moments of iron are directed along the C2 axes up to about 17 K, the number of domains with variously directed C2 axes being different. The mechanism of linear dichroism has been discussed. Below 17 K, a smooth transition to the helicoidal magnetic phase has been observed, with the collinear phase coexisting with the helicoidal one. Data presented in this article contradict the earlier concept of magnetic moments fluctuating in the low-temperature phase near the C2 axis within the ±10° interval.
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5.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov V. V., Sukhachev A. L., Gudim I. A.
Заглавие : Magnetic circular dichroism of f-f transitions in multiferroic antiferromagnet Ho0.75Nd0.25Fe3(BO3)4
Коллективы : "Functional materials", International conference, Крымский федеральный университет имени В.И. Вернадского
Место публикации : Ovchinnikov S. G. International conference "Functional materials": book of abstracts/ ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2023. - P.100-101
Примечания : Cited References: 2
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Petrov D. A., Chou H.
Заглавие : Low-hydrogenated ZnCoAlO films: structure, magneto-optical and magnetic behavior
Место публикации : Appl. Phys. A. - 2022. - Vol. 128, Is. 6. - Ст.519. - ISSN 09478396 (ISSN), DOI 10.1007/s00339-022-05665-z
Примечания : Cited References: 16. - This research was funded by the Russian Science Foundation Grant No. 21-72-00061
Аннотация: Morphology, chemical composition, crystal structure, and magnetic circular dichroism of ZnO films doped simultaneously with Co and Al (CAZO) have been studied. The films were deposited on glass substrates by the RF magnetron sputtering of the Zn0.93Co0.05Al0.02O target. Low hydrogen concentrations of 1–4% were used in mixed Ar + H2 atmosphere together with high enough substrate temperature of 450 °C. A tendency to a decrease in the Zn amount and an increase in the relative Co and Al content in the films has been revealed in the presence of hydrogen in the atmosphere. The structural data of the studied films correlate well with those for high-hydrogenated (20–50% H2) CAZO films deposited under the same conditions and studied earlier. The new data indicate the prospect of obtaining ferromagnetic samples based on ZnO without any secondary phases.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Samardak, Alexander S., Ognev, Alexey, V, Kolesnikov, Alexander G., Stebliy, Maksim E., Samardak, Vadim Yu, Iliushin, Ilia G., Pervishko, Anastasiia A., Yudin, Dmitry, Platunov M. S., Ono, Teruo, Wilhelm, Fabrice, Rogalev, Andrey
Заглавие : XMCD and ab initio study of interface-engineered ultrathin Ru/Co/W/Ru films with perpendicular magnetic anisotropy and strong Dzyaloshinskii-Moriya interaction
Коллективы : Russian Ministry of Science and Higher Education [075-15-2021-607, 0657-2020-0013]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-32-60020]; Russian Federation President Scholarship for Young Scientists [SP-1640.2021.5]; Russian Science FoundationRussian Science Foundation (RSF) [21-42-00041]; Russian Ministry of Science and Higher Education
Место публикации : Phys. Chem. Chem. Phys. - 2022. - Vol. 24, Is. 14. - P.8225-8232. - ISSN 1463-9076, DOI 10.1039/d1cp05456b. - ISSN 1463-9084(eISSN)
Примечания : Cited References: 47. - A. V. O., I. G. I. and T. O. thank the Russian Ministry of Science and Higher Education for state support of scientific research conducted under the supervision of leading scientists in Russian institutions of higher education, scientific foundations and state research centers (Project No. 075-15-2021-607) in parts of sample preparation and its magnetic characterization. The micromagnetic simulations performed by M. E. S. were supported by the Russian Ministry of Science and Higher Education under the state task (0657-2020-0013). A. A. P. (ab initio calculations) acknowledges the support from the Russian Foundation for Basic Research (Project No. 19-32-60020) and the Russian Federation President Scholarship for Young Scientists (SP-1640.2021.5). The work of A. S. S. related to the experimental and analytical study of DMI and skyrmion bubbles was supported by the Russian Science Foundation (Project No. 21-42-00041). The authors acknowledge the use of computational resources of the Skoltech supercomputer Zhores47 to obtain the theoretical results presented in this paper. The authors thank ID12 beamline staff for their help during the XMCD experiment and gratefully acknowledge the provision of beamtime (Proposal MA-3661) by the ESRF. The research contribution of M. P. (XMCD anaysis) was partially funded by the Russian Ministry of Science and Higher Education via the budget project of SRF SKIF, Boreskov Institute of Catalysis
Предметные рубрики: TOTAL-ENERGY CALCULATIONS
CIRCULAR-DICHROISM
MOLECULAR-DYNAMICS
Аннотация: Understanding the nature of recently discovered spin–orbital induced phenomena and a definition of a general approach for “ferromagnet/heavy-metal” layered systems to enhance and manipulate spin–orbit coupling, spin–orbit torque, and the Dzyaloshinskii–Moriya interaction (DMI) assisted by atomic-scale interface engineering are essential for developing spintronics and spin-orbitronics. Here, we exploit X-ray magnetic circular dichroism (XMCD) spectroscopy at the L2,3-edges of 5d and 4d non-magnetic heavy metals (W and Ru, respectively) in ultrathin Ru/Co/W/Ru films to determine their induced magnetic moments due to the proximity to the ferromagnetic layer of Co. The deduced orbital and spin magnetic moments agree well with the theoretically predicted values, highlighting the drastic effect of constituting layers on the system's magnetic properties and the strong interfacial DMI in Ru/Co/W/Ru films. As a result, we demonstrate the ability to simultaneously control the strength of magnetic anisotropy and intermixing-enhanced DMI through the interface engineered inversion asymmetry in thin-film chiral ferromagnets, which are a potential host for stable magnetic skyrmions.
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov V. V., Malakhovskii A. V., Sukhachev A. L., Gudim I. A.
Заглавие : Magnetic circular dichroism and absorption of a HoAl3(BO3)4 crystal in the region of 5I8 → 5I3 and 5F2 transitions
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect.: Magnetotransport, magnetooptics and magnetophotonics. - Ст.D.P16. - P.470-471. - ISBN 978-5-94469-051-7
Примечания : Cited References: 4
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Solodova O. V., Sokolov A. Е., Ivanova O. S., Volochaev M. N., Lapin I. N., Goncharova D. A., Svetlichnyi V. A.
Заглавие : Magneto-optical properties of nanoparticle dispersions based on Fe3O4, obtained by pulse laser ablation in a liquid
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 14. - P.2292-2299. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.14.54331.147. - ISSN 10906460 (eISSN)
Примечания : Cited References: 39. - The authors would like to thank Dr. Phys.-Math. Sci., Professor I.S. Edelman for participating in the discussion of the study results and significant comments when writing the article. This study was supported by the Russian Foundation for Basic Research, grant No. 19-52-52002
Аннотация: The structure, optical and magneto-optical properties of colloidal solutions of iron oxide nanoparticles obtained by pulsed ablation in distilled water, both without additives and with various functional additives: gold-hydrochloric acid, silicon oxide, and polyvinylpyrrolidone, have been studied. It is shown that the main magnetic phase is magnetite Fe3O4. The size distribution of nanoparticles and the degree of their agglomeration depend on the additives. In the absence of the latter, a very wide of size distributions and strong agglomeration of particles are observed. The narrowest distribution curve with a maximum corresponding to ~7 nm and an almost complete absence of agglomeration are observed for particles synthesized in the presence of polyvinylpyrrolidone. The shape of the spectral dependence of magnetic circular dichroism, which generally corresponds to the spectrum of magnetite, undergoes some modifications for various additives, which is associated with defects in the distribution of iron ions between different positions in the crystal.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivantsov R. D., Lin C. -R., Zharkov S. M., Velikanov D. A., Molokeev M. S., Zeer G. M., Chen Y. -Z., Spivakov A. A.
Заглавие : Evolution of morphology and magnetic properties of α-Fe2−xCrxO3 nanoparticles in dependence on Cr concentration
Место публикации : J. Magn. Magn. Mater. - 2022. - Vol. 564. - Ст.170101. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2022.170101
Примечания : Cited References: 69. - The work was supported financially by the Russian Foundation for Basic Research, Grant № 19-52-52002 and Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3, № 110-2811-M-153-001 and № 110-2112-M-153-005. The support was obtained also from the Joint Scientific Center of the Siberian Federal University supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the electron microscopy studies were carried out
Аннотация: Hematite, α-Fe2O3, one of the most widely studied magnetic compounds known to mankind since ancient times, has amazing properties and continues to puzzle researchers to this day. In this work, we found exceptionally strong changes in the morphology and magnetic properties of hematite nanoparticles upon doping with rather low concentrations of chromium. Nanoparticles α-Fe2−xCrxO3 with x varied from zero to 0.15 were prepared by solvothermal method using FeCl3·6H2O, CrCl3·6H2O, and 1,2-diaminopropane, (CH2)3(NH2)2, as precursors and temperature 180 °C for 6 h. The X-ray diffraction data showed the presence of only one crystal phase α-Fe2O3 for all x meanings with growing average crystalline size as the x increases. For the parent α-Fe2O3 powdered samples, the transmission electron microscopy revealed very long narrow nanorods with rounded ends that transform into spindles of increasing volume and cross section diameter as the Cr concentration increases. Vibrating sample magnetometry (VSM) and magnetic circular dichroism (MCD) study of the nanoparticles behavior in dependences on temperature and magnetic field revealed many unusual peculiarities. Among them there are strong increase of NPs magnetization with x increase (usually opposite picture is observed), the Morin transition temperature TM dependence on magnetic field, VSM sees the Morin transition in samples with small x only while MCD – in all samples, magnetization field dependences also are different when measured with VSM and MCD, and so on. Qualitative considerations were proposed to explain the observed phenomena.
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