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1.


   
    Efficiency of energy harvesting and storage using a multilayer capacitor based on BaTi0.86Sn0.14O3 ferroelectric lead-free ceramics / V. D. Fokina, V. S. Bondarev, E. I. Pogoreltsev, I. N. Flerov // Ceram. Int. - 2022. - Vol. 48, Is. 22. - P. 32966-32972, DOI 10.1016/j.ceramint.2022.07.227. - Cited References: 45 . - ISSN 0272-8842
Кл.слова (ненормированные):
Ferroelectric properties -- BaTiO3 and titanates -- Capacitors -- Energy harvesting/storage
Аннотация: The study of the parameters of energy harvesting and storage in the lead-free solid solution BaTi0.86Sn0.14O3 (BTSnO) was performed. The permittivity shows the behavior similar to a diffuse phase transition with the critical exponent γ = 1.84, which is close to the value characteristic of relaxors. Large values of the recoverable energy density, Wrec=(5.8–7.0)∙104 J/m3, and the energy storage efficiency coefficient, η=(82–94) %, are implemented in a wide temperature range, 30–87°С, at a low electric field, E = 18.5 kV/cm. For the first time, the analysis of the Olsen cycle was performed using two phase diagrams: polarization – electric field and entropy – temperature. A fairly good agreement was found between the values of the energy conversion density, ND ≈ 0.15 J/cm3, which was determined using two approaches. A universal parameter is proposed for comparing the energy harvesting density for the materials studied in different ranges of temperature and electric fields.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660074, Russian Federation

Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Flerov, I. N.; Флёров, Игорь Николаевич
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2.


   
    Multiple strategies to approach high-efficiency luminescence controllable in blue/cyan/green-emitting Bi3+-activated phosphors / P. Gao, Q. Li, S. Li [et al.] // J. Phys. Chem. C. - 2022. - Vol. 126, Is. 21. - P. 9195-9206, DOI 10.1021/acs.jpcc.2c02560. - Cited References: 53. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (grant no. 51974123), the Distinguished Youth Foundation of Hunan Province (grant no.2020JJ2018), the Key R&D projects in Hunan Province (2020WK2016, 2020SK2032, 2021SK2047, and 2022NK2044), the Natural Science Foundation of Hunan Province, China (grant no. 2021JJ40261), the Hunan High Level Talent Gathering Project (2019RS1077 and 2020RC5007), the Scientific Research Fund of Hunan Provincial Education Department (19C0903), the Natural Sciences Foundation of Hunan Agricultural University, China (grant no. 19QN11), the Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization Science Foundation (19KFXM12), the Changsha Science and Technology Plan (KH2005114, KH2201428), and the College Students’ Innovative Training (S202110537012) . - ISSN 1932-7447
   Перевод заглавия: Многочисленные стратегии достижения высокоэффективной управляемой люминесценции в синих/голубых/зеленых Bi3+-активированных люминофорах
Кл.слова (ненормированные):
Energy transfer -- Luminescence -- Blue phosphors -- Emitting phosphors -- High quality -- Higher efficiency -- Multiple strategy -- Optical tuning -- Performance -- Photoluminescence spectrum -- Red green blues -- White light emitting diodes
Аннотация: Cyan gap is a major block in achieving high-quality white light-emitting diodes (WLEDs). Hence, a novel cyan-emitting phosphor Sr2GdGaO5/0.02Bi3+ with optical tuning performance is synthesized based on the local crystal field regulation strategy surrounding the luminescence center. With the substitution of Al3+ for Ga3+, the photoluminescence (PL) spectra of Sr2GdGa1–xAlxO5/0.02Bi3+ (0 ≤ x ≤ 1) phosphors adjust from cyan (466 nm) to blue (450 nm). Moreover, such a Ba2+ doping adjusts the PL spectra of Sr2–xBaxGdGaO5/0.02Bi3+ (0 ≤ x ≤ 0.5) phosphors from cyan (466 nm) to green (482 nm). These phenomena are contributed to the crystal field splitting and nephelauxetic effect. The energy transfer from Bi3+ to Eu3+ is realized by co-doping Bi3+ and Eu3+ ions in the A2GdBO5/Bi3+ (A = Sr, Ba; B = Ga, Al) host materials, and two single-phase white phosphors Sr2GdGaO5/0.02Bi3+, 0.05Eu3+ and Sr1.5Ba0.5GdGaO5/0.02Bi3+, 0.05Eu3+ are obtained. Finally, a WLED with high color rendering index (Ra = 93.6) is prepared by using red/green/blue (RGB) phosphors and Sr2GdGaO5/0.02Bi3+ phosphor, which is higher than that of the WLED prepared by RGB phosphors (Ra = 86.7), indicating that Sr2GdGaO5/0.02Bi3+ phosphor can close the cyan gap. These results provide multiple strategies in achieving luminescence controllable and WLED.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha, 410128, China
College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Gao, P.; Li, Q.; Li, S.; Gai, S.; Li, Y.; Ma, Y.; Zhang, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Z.; Xia, M.
}
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3.


   
    Ligand engineering triggered efficiency tunable emission in zero-dimensional manganese hybrids for white light-emitting diodes / Q. Ren, J. Zhang, Y. Mao [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 18. - Ст. 3142, DOI 10.3390/nano12183142. - Cited References: 38. - This work was supported by the Natural Science Foundation of Shanxi Province (No. 20210302124054), National Natural Science Foundation of China (No. 21871167), Science and Technology Innovation Project of Colleges and Universities in Shanxi Province (No. 2021L262), 1331 Project of Shanxi Province and the Postgraduate Innovation Project of Shanxi Normal University (No.2021XSY040), and funded by RFBR according to the research project No. 19−52−80003 . - ISSN 2079-4991
   Перевод заглавия: Лигандная инженерия триггерной эффективности перестраиваемой люминесценции в нульмерных гибридах марганца для белых диодов
Кл.слова (ненормированные):
zero-dimensional manganese bromides -- steric configurations -- tunable emission -- white light-emitting diodes
Аннотация: Zero-dimensional (0D) hybrid manganese halides have emerged as promising platforms for the white light-emitting diodes (w-LEDs) owing to their excellent optical properties. Necessary for researching on the structure-activity relationship of photoluminescence (PL), the novel manganese bromides (C13H14N)2MnBr4 and (C13H26N)2MnBr4 are reported by screening two ligands with similar atomic arrangements but various steric configurations. It is found that (C13H14N)2MnBr4 with planar configuration tends to promote a stronger electron-phonon coupling, crystal filed effect and concentration-quenching effect than (C13H26N)2MnBr4 with chair configuration, resulting in the broadband emission (FWHM = 63 nm) to peak at 539 nm with a large Stokes shift (70 nm) and a relatively low photoluminescence quantum yield (PLQY) (46.23%), which makes for the potential application (LED-1, Ra = 82.1) in solid-state lighting. In contrast, (C13H26N)2MnBr4 exhibits a narrowband emission (FWHM = 44 nm) which peaked at 515 nm with a small Stokes shift (47 nm) and a high PLQY of 64.60%, and the as-fabricated white LED-2 reaches a wide colour gamut of 107.8% National Television Standards Committee (NTSC), thus highlighting the immeasurable application prospects in solid-state display. This work clarifies the significance of the spatial configuration of organic cations in hybrids perovskites and enriches the design ideas for function-oriented low-dimensional emitters.

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Держатели документа:
Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University, Taiyuan, 030031, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Key Laboratory of Interface Science and Engineering in Advanced Material (Ministry of Education), College of Chemistry Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, China

Доп.точки доступа:
Ren, Q.; Zhang, J.; Mao, Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, G.; Zhang, X. -M.
}
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4.


   
    High-efficiency continuous-luminescence-controllable performance and antithermal quenching in Bi3+-activated phosphors / P. Gao, Q. Li, C. Zhou [et al.] // Inorg. Chem. - 2022. - Vol. 61, Is. 33. - P. 13104-13114, DOI 10.1021/acs.inorgchem.2c01784. - Cited References: 52. - The authors gratefully acknowledge funds from the National Natural Science Foundation of China (Grant 51974123), the Distinguished Youth Foundation of Hunan Province (Grant 2020JJ2018), the Key R&D Projects in Hunan Province (2020WK2016, 2020SK2032, 2021SK2047, and 2022NK2044), the Natural Science Foundation of Hunan Province, China (Grant 2021JJ40261), the Hunan High Level Talent Gathering Project (2020RC5007), Changsha Science and Technology Plan (KH2005114 and KH2201428), Hunan Graduate Scientific Research Innovation Project (2022XC017), and the College Students’ Innovative Training (s202210537079x) . - ISSN 0020-1669
   Перевод заглавия: Высокоэффективная непрерывная контролируемая люминесценция и антитермическое тушение в Bi3+-активированных люминофорах
Аннотация: Recently, Bi3+-activated phosphors have been widely researched for phosphor-converted light-emitting diode (pc-LED) applications. Herein, novel full-spectrum A3BO7:Bi3+ (A = Gd, La; B = Sb, Nb) phosphors with a luminescence-tunable performance were achieved by a chemical substitution strategy. In the La3SbO7 host material, a new luminescent center was introduced, with Gd3+ replacing La3+. The photoluminescence (PL) spectra show a large blue shift from 520 to 445 nm, thus achieving regulation from green to blue lights. Moreover, a series of solid solution-phase phosphors La3Sb1-xNbxO7:Bi3+ were prepared by replacing Sb with Nb, and a PL spectral tunability from green (520 nm) to orange-red (592 nm) was realized. Temperature-dependent PL spectra show that La3-xGdxSbO7:Bi3+ phosphors have excellent thermal stability. Upon 350 nm excitation, the PL intensity of La3-xGdxSbO7:Bi3+ phosphors at 150 °C remained at more than 93% at room temperature. With Gd3+ doping, the thermal stability gradually improved, and LaGd2SbO7:0.03Bi3+ represents splendid antithermal quenching (135.2% at 150 °C). Finally, a full-visible spectrum for pc-LED with a high color-rendering index (Ra = 94.4) was obtained. These results indicated that chemical substitution is an effective strategy to adjust the PL of Bi3+, which is of great significance in white-light illumination and accurate plant lighting.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk Science Centre, Siberian Branch, Russian Academy of Science, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China

Доп.точки доступа:
Gao, P.; Li, Q.; Zhou, C.; Chen, K.; Luo, Z.; Zhang, S.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, J.; Zhou, Z.; Xia, M.
}
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5.


   
    Nanostructured photosensitive layer for Tamm-plasmon-polariton-based organic solar cells / R. G. Bikbaev, D. A. Pykhtin, S. Ya. Vetrov [et al.] // Appl. Opt. - 2022. - Vol. 61, Is. 17. - P. 5049-5054, DOI 10.1364/AO.456413. - Cited References: 47. - Council on Grants of the President of the Russian Federation (MK-46.2021.1.2) . - ISSN 1559-128X
Кл.слова (ненормированные):
Efficiency -- Nanoparticles -- Organic solar cells -- Phonons -- Photons -- Photosensitivity -- Plasmonics -- Refractive index -- Scattering parameters -- Transfer matrix method
Аннотация: The influence of the volume fraction of plasmonic nanoparticles on the efficiency of the Tamm-plasmon-polariton-based organic solar cell is investigated in the framework of temporal coupled mode theory and confirmed by the transfer matrix method. It is shown that, unlike a conventional plasmonic solar cell, in which the efficiency is directly proportional to the volume fraction of nanoparticles in the photosensitive layer, the efficiency of the proposed solar cell reaches the highest value at low volume fractions. This effect is explained by the fact that at these volume fractions, the critical coupling condition of the incident field with the Tamm plasmon polariton is fulfilled. Thus, for the incoming radiation range of 350 to 500 nm, a maximal cell efficiency of 28% is achieved with a volume fraction of nanoparticles equal to 10%. Additionally, the optical properties of the photosensitive layer are compared for the cases of determining its complex refractive index by effective medium theory and the S-parameter retrieval method. A good agreement between the results is demonstrated, which encourages the use of the effective medium theory for preliminary calculations.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Pykhtin, D. A.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Shabanov, V. F.; Шабанов, Василий Филиппович
}
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6.


   
    Nonlinear photonic crystals of strontium tetraborate: Properties and conversion of radiation / A. S. Aleksandrovsky [et al.] // Proceedings of SPIE - The International Society for Optical Engineering. - 2010. - Vol. 7728: Nonlinear Optics and Applications IV (12 April 2010 through 15 April 2010, Brussels, ) Conference code: 81010, DOI 10.1117/12.853713 . - ISBN 0277786X (ISSN); 9780819482013 (ISBN)
Кл.слова (ненормированные):
nonlinear photonic crystal -- second harmonic generation -- strontium tetraborate -- As-grown -- Average power -- Domain shape -- Efficiency enhancement -- Femtoseconds -- Fourth harmonics -- Nonlinear diffraction -- Nonlinear optical process -- Nonlinear photonic crystals -- Quasi-phase-matched -- Second harmonic generation -- Tetraborate -- Ti: Sapphire laser -- Ti:sapphire oscillators -- Ferroelectricity -- Harmonic analysis -- Nonlinear optics -- Optical materials -- Photonic crystals -- Sapphire -- Strontium -- Harmonic generation
Аннотация: Random nonlinear photonic crystal (NPC) structures formed by as-grown domains in a non-ferroelectric strontium tetraborate (SBO) are investigated. The domain shape and orientation are similar to those in ferroelectric KTP. Nonlinear diffraction is the simplest way to detect, evaluate and characterize these structures. Reciprocal superlattice vectors spectra of NPC in SBO are very wide and enable broadband efficiency enhancement of nonlinear optical processes. Second harmonic (SH) generation of femtosecond Ti:sapphire oscillator radiation with 1.9% efficiency is obtained using nonlinear diffraction geometry. Random quasi phase matched generation at the wavelengths of fourth harmonic of Ti:sapphire laser is obtained with average power up to 1 ?W. © 2010 Copyright SPIE - The International Society for Optical Engineering.

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Держатели документа:
Kirensky Institute of Physics, Akademgorodok 50/38, 660036, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodniy 79, 660041, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Aleksandrovsky, A. S.; Zaitsev, A. I.; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Vyunishev, A. M.; Rovsky, V. E.; Slabko, V. V.
}
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7.


   
    Broadband Tamm plasmons in chirped photonic crystals for light-induced water splitting / M. V. Pyatnov, R. G. Bikbaev, I. V. Timofeev [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 6. - Ст. 928, DOI 10.3390/nano12060928. - Cited References: 41 . - ISSN 2079-4991
Кл.слова (ненормированные):
water splitting -- plasmon catalysis -- solar-to-hydrogen efficiency -- photocurrent
Аннотация: An electrode of a light-induced cell for water splitting based on a broadband Tamm plasmon polariton localized at the interface between a thin TiN layer and a chirped photonic crystal has been developed. To facilitate the injection of hot electrons from the metal layer by decreasing the Schottky barrier, a thin n-Si film is embedded between the metal layer and multilayer mirror. The chipping of a multilayer mirror provides a large band gap and, as a result, leads to an increase in the integral absorption from 52 to 60 percent in the wavelength range from 700 to 1400 nm. It was shown that the photoresponsivity of the device is 32.1 mA/W, and solar to hydrogen efficiency is 3.95%.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Computer Modelling, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Pyatnov, M. V.; Пятнов, Максим Владимирович; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Timofeev, I. V.; Тимофеев, Иван Владимирович; Ryzhkov, I. I.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович
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8.


    Пятнов, Максим Владимирович.
    Фотоэлектрохимическое расщепление воды наноструктурированным электродом и зеленая водородная энергетика / М. В. Пятнов, И. В. Тимофеев // Фотоника. - 2022. - Т. 16, Вып. 2. - С. 116-125 ; Photonics Rus., DOI 10.22184/1993-7296.FRos.2022.16.2.116.125. - Библиогр.: 28. - Исследование выполнено за счет гранта Российского научного фонда и Красноярского краевого фонда поддержки научной и научно-технической деятельности № 22-22-20078, https://rscf.ru/project/22-22-20078 . - ISSN 1993-7296. - ISSN 2686-844X
   Перевод заглавия: Photoelectrochemical water splitting by a nanostructured electrode and green hydrogen energy
Кл.слова (ненормированные):
плазмонный катализ -- расщепление воды -- фототок -- эффективность преобразования света в водород -- plasmonic catalysis -- water splitting -- photo-induced current -- light-to-hydrogen conversion efficiency
Аннотация: В статье описан перспективный способ получения водорода – ​фотоэлектрохимическое расщепление воды. Этот подход сочетает непосредственное использование солнечной энергии и низкую стоимость производства фотоэлектрохимических ячеек из широко распространенных на Земле полупроводниковых материалов. Последние достижения в конструировании таких ячеек включают наноструктурирование полупроводниковых электродов плазмонными материалами.
This article describes a promising hydrogen formation method, namely the photoelectrochemical water splitting. This approach combines the direct use of solar energy and low production cost of photoelectrochemical cells using the widely used semiconductor materials. The latest advances in such cell design include nanostructuring of the semiconductor electrodes with plasmonic materials.

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Держатели документа:
Институт физики им. Л. В. Киренского СО РАН -обособленное подразделение ФИЦ КНЦ СО РАН
Сибирский федеральный университет

Доп.точки доступа:
Тимофеев, Иван Владимирович; Timofeev, I. V.; Pyatnov, M. V.

}
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9.


   
    Highly efficient Fe3+-doped A2 BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis / D. Liu, G. Li, P. Dang [et al.] // Light Sci. Appl. - 2022. - Vol. 11, Is. 1. - Ст. 112, DOI 10.1038/s41377-022-00803-x. - Cited References: 50. - This work was financially supported by the National Natural Science Foundation of China (NSFC Nos. 51720105015, 51932009, 51929201, 52072349), the Projects for Science and Technology Development Plan of Jilin Province (20210402046GH), and the Natural Science Foundation of Zhejiang Province (LR22E020004) . - ISSN 2095-5545
   Перевод заглавия: Высокоэффективные люминофоры A2BB'O6, легированные Fe3+ (A = Sr2+, Ca2+; B, B' = In3+, Sb5+, Sn4+), широкополосные люминофоры ближнего инфракрасного диапазона для спектроскопического анализа
Рубрики:
Optical properties of diamond
   Inorganic LEDs

Кл.слова (ненормированные):
Antimony compounds -- Efficiency -- III-V semiconductors -- Light emission -- Near infrared spectroscopy -- Optical properties -- Phosphors -- Spectroscopic analysis
Аннотация: Near-infrared (NIR)-emitting phosphor-converted light-emitting diodes have attracted widespread attention in various applications based on NIR spectroscopy. Except for typical Cr3+-activated NIR-emitting phosphors, next-generation Cr3+-free NIR-emitting phosphors with high efficiency and tunable optical properties are highly desired to enrich the types of NIR luminescent materials for different application fields. Here, we report the Fe3+-activated Sr2−yCay(InSb)1−zSn2zO6 phosphors that exhibit unprecedented long-wavelength NIR emission. The overall emission tuning from 885 to 1005 nm with broadened full-width at half maximum from 108 to 146 nm was realized through a crystallographic site engineering strategy. The NIR emission was significantly enhanced after complete Ca2+ incorporation owing to the substitution-induced lower symmetry of the Fe3+ sites. The Ca2InSbO6:Fe3+ phosphor peaking at 935 nm showed an ultra-high internal quantum efficiency of 87%. The as-synthesized emission-tunable phosphors demonstrated great potential for NIR spectroscopy detection. This work initiates the development of efficient Fe3+-activated broadband NIR-emitting phosphors and opens up a new avenue for designing NIR-emitting phosphor materials.

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Держатели документа:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China
University of Science and Technology of China, Hefei, 230026, China
Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, China
Zhejiang Institute, China University of Geosciences, Hangzhou, 311305, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
School of Material Science and Engineering, Shandong University, Jinan, 266071, China

Доп.точки доступа:
Liu, D.; Li, G.; Dang, P.; Zhang, Q.; Wei, Y.; Qiu, L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lian, H.; Shang, M.; Lin, J.
}
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10.


   
    Efficiency of light modulation by a polymer dispersed ferroelectric liquid crystals / S. L. Smorgon, V. Ya. Zyryanov, V. F. Shabanov, E. P. Pozhidaev // V International Meeting on Optics of Liquid Crystals : abstracts. - 1993. - P. 117-118


Доп.точки доступа:
Smorgon, S. L.; Сморгон, Сергей Леонидович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Pozhidaev, E. P.; International Meeting on Optics of Liquid Crystals(5 ; 1993 ; Oct. 4-8 ; Siofok, Hungary)
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11.


   
    Chemical pressure as an effective tool for tuning the structural disordering and barocaloric efficiency of complex fluorides (NH4)3MF7 (M: Sn, Ti, Ge, Si) / I. N. Flerov, M. V. Gorev, E. V. Bogdanov, N. M. Laptash // J. Phys. D: Appl. Phys. - 2024. - Vol. 57, Is. 17. - Ст. 175301, DOI 10.1088/1361-6463/ad211b. - Cited References: 39. - The study was supported by a Grant from the Russian Science Foundation No. 23-22-00115, https://rscf.ru/project/23-22-00115/ . - ISSN 0022-3727. - ISSN 1361-6463
Кл.слова (ненормированные):
fluorides -- phase transformation -- phase diagram -- entropy -- pressure -- barocaloric effect
Аннотация: Double fluoride salts (NH4)3M4+F7 (M4+: Sn, Ti, Ge, Si) demonstrate a high efficiency of using chemical pressure as a tool for control and tuning structural ordering/disordering, sensitivity to hydrostatic pressure, successions of the phase transitions, etc and, as a result, for purposeful variation within a wide range of parameters of barocaloric effect (BCE). The conventional and inverse BCEs near the triple points were found on the T − p phase diagrams, combination of which can be used to construct original cooling cycle in narrow temperature and pressure ranges. Reconstructive transformation between two cubic phases, Pm3-m ↔ Pa3-, realized in (NH4)3SnF7 at atmospheric pressure and in (NH4)3TiF7 at p ˃ 0.4 GPa are characterized by rather low thermal hysteresis, δT0 = 1 K, and a great entropy change, ΔSBCE = 110–152 J (kg · K)−1, depending on the size of the central atom. At above 300–350 K, a contribution to BCE associated with the regular thermal expansion of the crystal lattice becomes comparable to entropy and temperature changes under pressure in the region of the phase transitions. An analysis of the absolute, relative and integral barocaloric characteristics of (NH4)3M4+F7 compounds showed their high competitiveness with respect to other barocaloric materials considered as promising solid-state refrigerants.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk, Russia
Institute of Chemistry, Far Eastern Department of RAS, 690022 Vladivostok, Russia

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.
}
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12.


   
    Luminescent studies of flexible [DUT-8 (Zn)] metal-organic frameworks / N. V. Slyusarenko, A. S. Krylov, M. V. Timofeeva [et al.] // Proc. SPIE. - 2023. - Vol. 12920: XVI International Conference on Pulsed Lasers and Laser Applications (10-15 September 2023, Tomsk, Russian Federation). - Ст. 1292014, DOI 10.1117/12.3005774. - Cited References: 10. - The reported study was funded by RFBR and DFG, project 21-52-12018
   Перевод заглавия: Изучение люминесценции гибкого DUT-8 (Zn) металлоорганического каркасного соединения
Кл.слова (ненормированные):
Förster resonance energy transfer -- FRET -- DUT-8 (Zn) -- metal-organic frameworks -- dye -- energy transfer -- efficiency -- steady-state luminescence -- time-resolved luminescence
Аннотация: An approach to the study of the porous structure of metal-organic frameworks (MOF) using guest luminescent molecules with specially selected spectral characteristics as acceptors of electronic excitation energy was suggested. If such molecules are adsorbed in MOF pores with sizes comparable to the Förster radius, Förster resonance energy transfer (FRET) from photoexcited linkers occurs. In this case quenching of luminescence of the linker can serve as analytical signals indicating open pore structure of the MOF. The developed approach was demonstrated by the example of DUT-8(Zn) MOF and Coumarin 1 as guest molecules by time-resolved luminescence methods.

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Держатели документа:
Siberian Federal University, Svobodny Prospect 79, 660041, Krasnoyarsk, Russia
Kirensky Institute of Physics FRC KSC SB RAS, Academgorodok 50/38, 660036, Krasnoyarsk, Russia
ITMO University, School of Physics and Engineering, Kronverksky Prospekt 49, bldg. A, 197101, St. Petersburg, Russia

Доп.точки доступа:
Slyusarenko, N. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Timofeeva, M. V.; Shipilovskikh, S. A.; Slyusareva, E. A.; International Conference on Pulsed Lasers and Laser Applications(16 ; 2023 : 10-15 Sept. ; Tomsk, Russian Federation)
}
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13.


   
    Machine-learning-driven discovery of Mn4+-doped red-emitting fluorides with short excited-state lifetime and high efficiency for mini light-emitting dIode displays / H. Ming, Ya. Zhou, M. S. Molokeev [et al.] // ACS Mater. Lett. - 2024. - Vol. 6. - P. 1790-1800, DOI 10.1021/acsmaterialslett.4c00263. - Cited References: 39. - This work was financially supported by the National Key Research and Development Program of China (No. 2022YFB3503800), National Natural Science Foundation of China (Grants Nos. 52202170 and 52322208), Natural Science Foundation of Guangdong Province (No. 2022A1515140032) and Distinguished Youth Foundation of Guangdong Scientific Committee (No. 2023B1515020059). This work was also supported by the Tyumen Oblast Government, as part of the West-Siberian Interregional Science and Education Center’s Project No. 89-DON (3). H. Ming acknowledges the fellowship support from the China Scholarship Council (CSC No. 202206150038) . - ISSN 2639-4979
   Перевод заглавия: Открытие на основе машинного обучения фторидов красного излучения, легированных Mn4+, с коротким временем жизни в возбужденном состоянии и высокой эффективностью для мини-светодиодных дисплеев
Аннотация: The discovery of high-efficiency Mn4+-activated fluoride red phosphors with short excited-state lifetimes (ESLs) is urgent and crucial for high-quality, wide-color-gamut display applications. However, it is still a great challenge to design target phosphors with both short ESL and high luminescence efficiency. Herein, we propose an efficient machine learning approach based on a small dataset to establish the ESL prediction model, thereby facilitating the discovery of new Mn4+-activated fluorides with short ESLs. Such a model can not only accurately predict the ESLs of Mn4+ in fluorides but also quantify the impact of structure features on ESLs, therefore elucidating the “structure-lifetime” correlations. Guided by the correlations, two new Mn4+-doped tetramethylammonium (TMA)-based hybrid fluorides (TMA)2BF6:Mn4+ (B = Sn or Hf) with both short ESLs (τ ≤ 3.7 ms) and high quantum efficiencies (internal QEs ˃ 92%, external QEs ˃ 55%) have been discovered successfully. A prototype displayer with excellent performance (∼124% National Television Standards Committee (NTSC) color gamut) is assembled by employing a (TMA)2SnF6:Mn4+-based white Mini-LED backlight module, demonstrating its practical prospects in high-quality displays. This work not only brings promising candidates for Mn4+-doped fluoride phosphors but also provides a valuable reference for accelerating the discovery of new promising phosphors.

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Держатели документа:
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, and Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices, South China University of Technology, Guangzhou 510641, China
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China
International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba 305-0047, Japan
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Laboratory of Theory and Optimization of Chemical and Technological Processes, University of Tyumen, Tyumen 625003, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk 660041, Russia
School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510641, China
Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials and College of Materials, Xiamen University, Xiamen 361005, China
Guangdong-Hong Kong-Macao Joint Laboratory for Intelligent Micro-Nano Optoelectronic Technology, School of Physics and Optoelectronic Engineering, Foshan University, Foshan 528225, China

Доп.точки доступа:
Ming, H.; Zhou, Ya.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhang, Ch.; Huang, L.; Wang, Yu.; Sun, H.-T.; Song, E.; Zhang, Q.
}
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14.


   
    Highly-efficiency far-red emission in Cr3+ activated Ca1.8Mg1.2Al2Ge3O12 toward plant precise lighting / Ch. Yang, D. Zheng, X. Zou [et al.] // Adv. Opt. Mater. - 2024. - Ст. 2303235, DOI 10.1002/adom.202303235. - Cited References: 48. - The work was supported by the National Natural Science Foundations of China (No. 12274144), the Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams (No. 2023KJ122), the Key Realm R&D Program of Guangdong Province (No. 2021B0707010003), the Guangdong Provincial Science and Technology Project (No. 2022A1515010229), and the Project of GDUPS (2018) for Prof. Bingfu LEI . - Article in press. - ISSN 2195-1071
Кл.слова (ненормированные):
cationic substitution -- Cr3+-doped phosphor -- far-red emission -- plant lighting
Аннотация: Far-red (FR) region (beyond 700 nm) lighting sources possess special potential for plant lighting. However, it remains a challenge to obtain high-performance Cr3+-doped FR phosphors. This study developed a FR phosphor, Ca1.8Mg1.2Al2Ge3O12:Cr3+ (CMAGG: Cr3+), using the cation substitution strategy. Under 438 nm blue light excitation, the phosphors display FR emission centered at 720 nm with a full width at half maximum (FWHM) of 91 nm. Benefit from the favorable match with the FR phytochrome (Pfr), the phosphor is combined with InGaN blue light chips to create a FR phosphor-converted light-emitting diode (pc-LED), which is used in Italian lettuce growth experiments and it results shown in a 15% increase in fresh weight and a 6.5% increase in dry weight. Notably, supplemental FR light modulated its growth morphology. The results of this study will be useful for further research on novel Cr3+-doped FR phosphors to meet the precise spectral requirements for plant growth.

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Держатели документа:
Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy, South China Agricultural University Guangzhou, Guangdong 510642, P. R. China
SBRAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
Maoming Branch Guangdong Laboratory for Lingnan Modern Agriculture Maoming, Guangdong 525100, P. R. China

Доп.точки доступа:
Yang, Ch.; Zheng, D.; Zou, X.; Dai, X.; Tang, B.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhang, X.; Zhang, H.; Liu, Y.; Lei, B.
}
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15.


   
    Численная оценка приведенного сопротивления теплопередаче оконных блоков различных конфигураций / М . В. Драница, П. С. Пахомов, Н. Е. Киреев, А. С. Орешонков // Изв. вузов. Строительство. - 2022. - № 10. - С. 76-81 ; News High. Edu. Inst. Construct., DOI 10.32683/0536-1052-2022-766-10-76-81. - Библиогр.: 8 . - ISSN 0536-1052
   Перевод заглавия: Numerical estimation of reduced resistance to heat transfer for various window configurations
Кл.слова (ненормированные):
оконный блок -- межстекольное пространство -- энергосбережение -- энергоэффективность -- сопротивление теплопередаче -- window block -- inter-glass space -- energy saving -- energy efficiency -- heat transfer resistance
Аннотация: В работе обсуждаются вопросы энергоэффективности пластиковых окон при заполнении межстекольного пространства осушенным воздухом, аргоном, криптоном, ксеноном и элегазом. Для численного расчета приведенного сопротивления теплопередаче оконных блоков с различными конфигурациями светопрозрачной части использованы современные программные комплексы Them 7.6 и Window 7.6. На основе полученных результатов разработаны рекомендации по использованию конфигураций стеклопакетов с заполнением воздухом и газами, отличными от него.
This article discusses the energy efficiency of plastic windows with the filling the space between panes by dry air, argon, krypton, xenon and SF6 gas. Numerical calculation of reduced resistance to heat transfer of window blocks with different configurations of the transparent part were performed using Them 7.6 and Window 7.6 software. Finally, the results of this work can be used for developing recommendations of using the window block configurations filled with air and gases other than.

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Инженерно-строительный институт, Сибирский федеральный университет, Красноярск, Россия
Институт физики им. Л.В. Киренского Сибирского отделения Российской академии наук (обособленное подразделение ФИЦ КНЦ СО РАН), Красноярск, Россия

Доп.точки доступа:
Драница, М.В.; Пахомов, П. С.; Киреев, Н. Е.; Орешонков, Александр Сергеевич; Oreshonkov, A. S.

}
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16.


   
    Nucleic acid aptamers increase the anticancer efficiency and reduce the toxicity of cisplatin-arabinogalactan conjugates in vivo / T. N. Zamay, A. K. Starkov, O. S. Kolovskaya [et al.] // Nucleic Acid Ther. - 2022. - Vol. 32, Is. 6. - P. 497-506, DOI 10.1089/nat.2022.0024. - Cited References: 42 . - ISSN 2159-3337. - ISSN 2159-3345
Кл.слова (ненормированные):
cisplatin -- aptamer -- arabinogalactan -- cancer chemotherapy -- ascites carcinoma
Аннотация: Cisplatin is an effective drug for treating various cancer types. However, it is highly toxic for both healthy and tumor cells. Therefore, there is a need to reduce its therapeutic dose and increase targeted bioavailability. One of the ways to achieve this could be the coating of cisplatin with polysaccharides and specific carriers for targeted delivery. Nucleic acid aptamers could be used as carriers for the specific delivery of medicine to cancer cells. Cisplatin-arabinogalactan-aptamer (Cis-AG-Ap) conjugate was synthesized based on Cis-dichlorodiammineplatinum, Siberian larch arabinogalactan, and aptamer AS-42 specific to heat-shock proteins (HSP) 71?kDa (Hspa8) and HSP 90-beta (Hsp90ab1). The antitumor effect was estimated using ascites and metastatic Ehrlich tumor models. Cis-AG-Ap toxicity was assessed by blood biochemistry on healthy mice. Here, we demonstrated enhanced anticancer activity of Cis-AG-Ap and its specific accumulation in tumor foci. It was shown that targeted delivery allowed a 15-fold reduction in the therapeutic dose of cisplatin and its toxicity. Cis-AG-Ap sufficiently suppressed the growth of Ehrlich's ascites carcinoma, the mass and extent of tumor metastasis in vivo. Arabinogalactan and the aptamers promoted cisplatin efficiency by enhancing its bioavailability. The described strategy could be very promising for targeted anticancer therapy.

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Держатели документа:
Laboratory for Digital Controlled Drugs and Theranostics, Federal Research Center "Krasnoyarsk Research Center" of the Siberian Branch of the Russian Academy of Science, Krasnoyarsk, Russian Federation
Laboratory For Biomolecular and Medical Technologies, Krasnoyarsk State Medical University named after Prof. V.F. Voino-Yasenecky, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Science Center SB RAS, Krasnoyarsk660036, Russian Federation
Department of Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory for Physics of Magnetic Phenomena, Kirensky Institute of Physics, Federal Research Center Krasnoyarsk Science Center SB RAS, Krasnoyarsk, Russian Federation
Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, ON, Canada

Доп.точки доступа:
Zamay, T. N.; Starkov, A. K.; Kolovskaya, O. S.; Zamay, G. S.; Veprintsev, D. V.; Luzan, N.; Nikolaeva, E. D.; Lukyanenko, K. A.; Artyushenko, P. V.; Shchugoreva, I. A.; Glazyrin, Y. E.; Koshmanova, A. A.; Krat, A. V.; Tereshina, D. S.; Zamay, S. S.; Pats, Y. S.; Zukov, R. A.; Tomilin, F. N.; Томилин, Феликс Николаевич; Berezovski, M. V.; Kichkailo, A. S.
}
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17.


   
    Влияние структуры хлоропластов на плотность фотонных состояний и эффективность преобразования солнечной энергии / К. А. Шабанова, Ю. Ю. Логинов, Е. Р. Буханов [и др.] // Сиб. аэрокосм. журн. - 2021. - Т. 22, № 4. - С. 708-717 ; Sib. Aerospace J., DOI 10.31772/2712-8970-2021-22-4-708-717. - Библиогр.: 22 . - ISSN 2712-8970
   Перевод заглавия: The chloroplast structure nfluence on photon states density and efficiency of solar energy conversion
Кл.слова (ненормированные):
биофотонный кристалл -- плотность фотонных состояний -- электронная микроскопия -- фотосинтез -- biophotonic crystal -- density of photon states -- electron microscopy -- photosynthesis
Аннотация: Благодаря поглощению солнечной энергии в хлоропластах – зелёных пластидах – происходит преобразование солнечной энергии в энергию химических связей. Изучение процессов фотосинтеза и увеличение его эффективности актуально для разработки замкнутых систем жизнеобеспечения, в том числе, при длительных полетах в космосе. Хлоропласты в свою очередь наполнены стопками высокоупорядоченных тилакоидных мембран (гранами). На границе этих мембран и располагаются пигмент-белковые фотосинтетические комплексы. Долгое время структурным характеристикам хлоропластов не уделялось должного внимания и они изучались как изотропные вещества, однако в последние годы было показано, что они обладают анизотропными свойствами и высоким коэффициентом преобразования при разделении зарядов. В данной работе был предложен подход к более точному пространственному определению гран в хлоропластах растений и определению размеров единичного блока. Тилакоидные мембраны и границы состоящей из них граны отчетливо видны в электронном микроскопе, если пучок электронов направлен строго перпендикулярно. Было замечено, что при повороте столика разные области мембран становятся либо расплывчатыми, либо более четкими, что говорит о том, что граны в хлоропластах располагаются не в одной плоскости. Также проведено сравнение влияния разных внешних условий на структуру хлоропласта растения не только через сравнение морфологических характеристик, но и посредством численного моделирования и сравнения спектральных свойств объектов. Для численного моделирования были определены периодические решетки для основных структурных единиц хлоропластов разных образцов. На основе этих решеток были рассчитаны спектры пропускания с помощью метода трансфер матриц. Также полученные значения электромагнитной волны вдоль решетки позволили рассчитать графики плотности фотонных состояний. Результаты расчетного метода графиков плотности фотонных состояний на основе структуры хлоропластов позволили не просто оценить возможную эффективность фотосинтеза, но и напрямую связать эти модели с внешними условиями, влияющими на растение.
Due to the absorption of solar energy in chloroplasts - green plastids, solar energy is converted into the energy of chemical bonds. Studying the processes of photosynthesis and increasing its efficiency is relevant for the development of closed life support systems, including during long flights in space. Chloroplasts are filled with stacks of highly ordered tilakoid membranes (granas). Pigment-protein photosynthetic complexes are located on the border of these membranes. For a long time, the structural characteristics of chloroplasts were not given due attention and they were studied as isotropic substances, but in recent years it has been shown that they have anisotropic properties and a high conversion coefficient during charge separation. In this work, an approach was proposed for a more accurate spatial determination of grains in plant chloroplasts and determination the single unit. Thylakoid membranes and the boundaries of the facet consisting of them are clearly visible in an electron microscope if the electron beam is directed strictly perpendicularly. It was noticed that when the stage is rotated, different regions of the membranes become either blurred or more distinct, which suggests that the granules in chloroplasts are not located in the same plane. Also, a comparison was made of the influence of different external conditions on the chloroplast structure of a plant, not only through a comparison of morphological characteristics, but also through numerical modeling and comparison of the objects spectral properties. For numerical simulation, periodic lattices were determined for the main structural units of chloroplasts of different samples. On the basis of these gratings, the transmission spectra were calculated using the transfer matrix method. Also, the obtained values of the electromagnetic wave along the lattice made it possible to calculate the graphs of the density of photon states. The results of the calculation method of plots of the density of photon states based on the structure of chloroplasts made it possible not only to assess the possible efficiency of photosynthesis, but also to directly relate these models to the external conditions affecting the plant.

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Сибирский государственный университет науки и технологий имени академика М. Ф. Решетнева, Российская Федерация, 660037, г. Красноярск, просп. им. газ. «Красноярский рабочий», 31
Институт физики им. Л. В. Киренского СО РАН, Российская Федерация, 660036, г. Красноярск, ул. Академгородок, 50, стр. 38
Федеральный исследовательский центр «Красноярский научный центр СО РАН», Российская Федерация, 660036, г. Красноярск, ул. Академгородок, 50
Сибирский федеральный университет, Институт фундаментальной биологии и биотехнологии, Российская Федерация, 660041, г. Красноярск, Свободный просп., 79, корп. 4

Доп.точки доступа:
Шабанова, К. А.; Логинов, Ю. Ю.; Буханов, Евгений Романович; Bukhanov, E. R.; Волочаев, Михаил Николаевич; Volochaev, M. N.; Пятина, С. А.; Pyatina, S. A.

}
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18.


   
    Apatite oxynitride phosphor (Mg,Y)5Si3(O,N)13:Ce3+,Mn2+: A single-phased host with solar-like and efficient emission / Y. Wu, W. Li, Y. Zheng [et al.] // J. Am. Ceram. Soc. - 2023. - Vol. 106, Is. 5. - P. 2985-2996, DOI 10.1111/jace.18981. - Cited References: 35. - This work was supported by the National Natural Science Foundation of China (Project No. 10804099, 21804119), Key projects of Zhejiang Natural Science Foundation (Project No. LZ18B050002), GDAS’ Project of Science and Technology Development (Nos. 2021GDASYL-20210103069, 2021GDASYL-20210103071) . - ISSN 0002-7820. - ISSN 1551-2916
   Перевод заглавия: Люминофор на основе оксинитрида апатита (Mg,Y)5Si3(O,N)13:Ce3+,Mn2+: однофазная матрица с эффективным излучением почти солнечного спектра
Кл.слова (ненормированные):
apatite oxynitride -- color rendering index -- full-color-emitting phosphor -- quantum efficiency -- thermal stability
Аннотация: During pursuing high color rendering index for full-color-emitting phosphor, low quantum efficiency (QE) is usually accompanying. We intend to elevate the luminescence efficiency when realizing a solar-like spectra distribution, by constructing apatite structure oxynitride, inheriting high covalence and rigidity from oxynitride, and suitable multiple cation sites from oxyapatite compounds. Full-color-emitting apatite structure oxynitride phosphor (Mg,Y)5Si3(O,N)13:Ce3+,Mn2+ has been prepared, and the crystal sites’ occupancies of activators in this host were favorable for white emission. (Mg,Y)5Si3(O,N)13:Ce3+,Mn2+ phosphor shows whole visible light with emission wavelength ranging from 370 to 750 nm, matching the spectra of sunlight quite well. The fabricated white light-emitting diode lamp demonstrated the distinctive overall performance of QE and chromaticity properties (Ra and R9). Furthermore, correlated color temperature is tunable from cool nature to warm white. The obtained lamp possesses the feature of less blue light hazard and high saturation of red degree, compared with the commercial YAG-based lamp.

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Держатели документа:
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China
Research Center of Analysis and Measurement, Zhejiang University of Technology, Hangzhou, China
Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, China
School of Applied Physics and Materials, Wuyi University, Jiangmen, Guangdong, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia

Доп.точки доступа:
Wu, Yanzheng; Li, Weiqiang; Zheng, Yifan; Xu, Yiqin; Wen, Dawei; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pan, Zaifa
}
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19.


   
    Towards understanding the triggering of the malignant cell death in high-efficiency magneto-mechanical anticancer therapy / P. N. Semina, I. L. Isaev, S. K. Komogortsev [et al.] // J. Phys. D. - 2023. - Vol. 56, Is. 6. - Ст. 065401, DOI 10.1088/1361-6463/acb0dd. - Cited References: 146. - P N S, A S K, D E K, S P P, S V K acknowledge the support by the Ministry of Science and High Education of Russian Federation (Project No. FSRZ-2020-0008). Experimental analyses were funded by the Ministry of Science and Higher Education of the Russian Federation (Project FWES-2022-0005) – A S K, T N Z. The authors thank Dr S V Saikova for providing the TEM image in figure (b) . - ISSN 0022-3727. - ISSN 1361-6463
Кл.слова (ненормированные):
magnetic nanoparticle -- malignant cell membrane -- apoptosis -- anticancer therapy -- aptamer
Аннотация: The paper discusses schemes for the implementation of magneto-mechanical anticancer therapy and the most probable scenarios of damaging mechanical effects on the membranes of malignant cells by targeted magnetic nanoparticles selectively bound to membrane mechanoreceptors employing aptamers. The conditions for selective triggering of the malignant cell apoptosis in a low-frequency non-heating alternating magnetic field, corresponding to the exceeding threshold value of the force acting on the membrane and its mechanoreceptors, are established using a nanoparticle dynamic simulation. The requirements for the functionality of magnetic nanoparticles and their suitability for biomedical applications are analysed. Attention is paid to the possibility of the formation of magnetite nanoparticle aggregates in an external magnetic field and their localization near tumor cell membranes. It is shown that the scenario involving the process of aggregation of magnetite nanoparticles provides a sufficient magneto-mechanical impact to achieve a therapeutic effect. A possible explanation for the experimentally established fact of successful application of magneto-mechanical therapy using magnetite nanoparticles is presented, in which complete suppression of the Ehrlich carcinoma in an alternating magnetic field as a response to a magnetome-chanical stimulus was demonstrated. This result confirmed the possibility of using the method for high efficiency treatment of malignant neoplasms. The paper is provided with an extensive review of key publications and the state of art in this area.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry—IRC SQC, Siberian Federal University, Krasnoyarsk 660041, Russia
Institute of Computational Modelling of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk 660036, Russia
L. V. Kirensky Institute of Physics, Federal Research Center KSC the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk 660036, Russia
Prof. V.F. Voino-Yasenetsky Krasnoyarsk State Medical University, Krasnoyarsk 660022, Russia
Federal Research Center "Krasnoyarsk Science Center" of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk 660036, Russia
Siberian Federal University, Krasnoyarsk 660041, Russia
Tomsk State University, Tomsk 634050, Russia
Federal Siberian Research Clinical Center, Federal Medical Biological Agency of Russian Federation, Krasnoyarsk 660037, Russia

Доп.точки доступа:
Semina, P. N.; Семина, Полина Николаевна; Isaev, I. L.; Исаев, Иван Леонидович; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Klyuchantsev, A. B.; Ключанцев, А. Б.; Kostyukov, A. S.; Blagodatova, A. V.; Khrennikov, D. E.; Kichkailo, A. S.; Кичкайло, Анна Сергеевна; Zamay, T. N.; Замай, Т. Н.; Lapin, I. N.; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Polyutov, S. P.; Полютов, Сергей Петрович; Karpov, S. V.; Карпов, Сергей Васильевич
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20.


   
    The crystal structure and luminescence properties of a novel green-yellow emitting Ca1.5Mg0.5Si1-xLixO4- δ:Ce3+ phosphor with high quantum efficiency and thermal stability / W. Ji [et al.] // Dalton Trans. - 2018. - Vol. 47, Is. 29. - P. 9834-9844, DOI 10.1039/c8dt02241k. - Cited References: 42 . - ISSN 1477-9226
   Перевод заглавия: Кристаллическая структура и люминесцентные свойства нового, излучающего зеленый свет люминофора Ca1.5Mg0.5Si1-xLixO4-δ:Ce3+ , с высокой квантовой эффективностью и термической стабильностью
Аннотация: A novel green-yellow emitting Ca1.5Mg0.5Si1−xLixO4−δ:Ce3+ phosphor with high quantum efficiency and thermal stability was discovered for applications in near ultraviolet pumped white light-emitting diodes. Its crystal structure was determined with a single-particle diagnosis approach. The Si sites in the SiO4 tetrahedra are reported for the first time to accommodate Li+ ions. This substitution, confirmed by 6Li solid-state NMR and T.O.F. neutron powder diffraction, causes a disordered occupation of Ca/Mg in the Ca3MgSi2O8 host and favors a phase transformation at ∼330 °C, which results in the formation of the novel phosphor. The produced phosphor was efficiently excited by near UV light peaking at 365 and 410 nm and produced broad green-yellow emission with peaks at 500 and 560 nm, respectively. Its quantum efficiency reached 88.4% (internal) and 55.7% (external) under excitation at 365 nm, and 80.5% (internal) and 42.7% (external) under excitation at 410 nm, while the decrease of luminescence intensity at 200 °C was small (∼26%). A WLED lamp with a high color rendering index of Ra = 92.8 was produced with the combination of a 365 nm emitting chip with blue emitting BaMgAl10O17:Eu2+, green-yellow emitting CMSL:0.01Ce, and red emitting Sr2Si5N8:Eu2+ phosphors.

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Держатели документа:
Chinese Academy of Sciences, Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui, China
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
School of Energy Science and Engineering, University of Electronic Science of China, 2006 Xiyuan Road, Chengdu, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center, KSC, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Department of Materials Science and Engineering, University of Ioannina, Ioannina, Greece
State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing, China
Department of Nuclear Physics, China Institute of Atomic Energy, Beijing, China
STFC-RAL, ISIS Facility Harwell Science and Innovation Campus, Didcot, United Kingdom

Доп.точки доступа:
Ji, W.; Xia, Z.; Liu, K.; Ali Khan, S.; Hao, L.; Xu, X.; Yin, L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Agathopoulos, S.; Yang, W.; Ma, X.; Sun, K.; Da Silva, I.
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