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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Antipina L. Yu., Tomilin F. N., Vysotski E. S., Ovchinnikov S. G.
Заглавие : A quantum chemical study of the formation of 2-hydroperoxy-coelenterazine in the Сa2+-regulated photoprotein obelin
Место публикации : J. Struct. Chem.: Springer, 2011. - Vol. 52, Is. 5. - P.870-875. - ISSN 0022-4766
Примечания : Cited References: 19. - The work was supported by RFBR (07-04-00930-a), the "Molecular and Cell Biology" Program of the Presidium of the Russian Academy of Sciences, and the Program of the Siberian Division of the Russian Academy of Sciences (project No. 2) within the implementation of the Federal Targeted Program "Scientific and Scientific Pedagogical Personnel of Innovative Russia, 2010" (P333 and P213).
Предметные рубрики: CALCIUM-DISCHARGED OBELIN
SEMIEMPIRICAL METHODS
1.7 ANGSTROM
OPTIMIZATION
PARAMETERS
MECHANISM
FLUORESCENCE
ELEMENTS
PROTEIN
EMITTER
Ключевые слова (''Своб.индексиров.''): coelenterazine--2-hydroperoxy-coelenterazine--obelia longissima--renilla muelleri
Аннотация: The Ca2+-regulated photoprotein obelin determines the luminescence of the marine hydroid Obelia longissima. Bioluminescence is initiated by calcium and appears as a result of the oxidative decarboxylation related to the coelenterazine substrate. The luciferase of the luminescent marine coral Renilla muelleri (RM) also uses coelenterazine as a substrate. However, three proteins are involved in the in vivo bioluminescence of these animals: luciferase, green fluorescent protein, and Ca2+-regulated coelenterazine-binding protein (CBP). In fact, CBP that contains one strongly bound coelenterazine molecule is the RM luciferase substrate in the in vivo bioluminescent reaction. Coelenterazine becomes available for oxygen and the reaction with luciferase only after binding CBP with calcium ions. Unlike Ca2+-regulated photoproteins, the coelenterazine molecule is not activated by oxygen in the CBP molecule. In this work, by means of quantum chemical methods the behavior of substrates in these proteins is analyzed. It is shown that coelenterazine can form different tautomers: CLZ(2H) and CLZ(7H). The formation of 2-hydroperoxy-coelenterazine is studied. According to the obtained data, these proteins use different forms of the substrates for the reaction. In obelin, the substrate is in the CLZ(2H) form that affords hydrogen peroxide. In RM, coelenterazine is in the CLZ(7H) form, and therefore, CBP is not activated by oxygen.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lin C. -R., Ivanova O. S., Petrov D. A., Sokolov A. Е., Chen Y. -Z., Gerasimova M. A., Zharkov S. M., Tseng Y. -T., Shestakov N. P., Edelman I. S.
Заглавие : Amino-functionalized Fe3O4@SiO2 core-shell magnetic nanoparticles for dye adsorption
Место публикации : Nanomaterials. - 2021. - Vol. 11, Is. 9. - Ст.2371. - ISSN 20794991 (ISSN), DOI 10.3390/nano11092371
Примечания : Cited References: 35. - The authors are thankful for the financial support the Russian Foundation for Basic Research, Grant № 19-52-52002, Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3 and № 109-2112-M-153-003-, the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project number 19-42-240005: “Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe”. We thank also the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out
Аннотация: Fe3O4@SiO2 core-shell nanoparticles (NPs) were synthesized with the co-precipitation method and functionalized with NH2 amino-groups. The nanoparticles were characterized by X-ray, FT-IR spectroscopy, transmission electron microscopy, selected area electron diffraction, and vibrating sample magnetometry. The magnetic core of all the nanoparticles was shown to be nanocrystalline with the crystal parameters corresponding only to the Fe3O4 phase covered with a homogeneous amorphous silica (SiO2) shell of about 6 nm in thickness. The FT-IR spectra confirmed the appearance of chemical bonds at amino functionalization. The magnetic measurements revealed unusually high saturation magnetization of the initial Fe3O4 nanoparticles, which was presumably associated with the deviations in the Fe ion distribution between the tetrahedral and octahedral positions in the nanocrystals as compared to the bulk stoichiometric magnetite. The fluorescent spectrum of eosin Y-doped NPs dispersed in water solution was obtained and a red shift and line broadening (in comparison with the dye molecules being free in water) were revealed and explained. Most attention was paid to the adsorption properties of the nanoparticles with respect to three dyes: methylene blue, Congo red, and eosin Y. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for all three dyes. The equilibrium data were more compatible with the Langmuir isotherm and the maximum adsorption capacity was reached for Congo red.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Averyanov E. M., Gunyakov V. A.
Заглавие : New features in the structural relaxation of a nematic liquid-crystal doped with luminescent impurity molecules
Место публикации : JETP Letters. - 1993. - Vol. 57, Is. 8. - P.492-496. - ISSN 0021-3640
Примечания : Cited References: 15
Предметные рубрики: FLUORESCENCE DEPOLARIZATION
ORIENTATIONAL RELAXATION
FLUOROPHORES
Аннотация: A new approach is proposed for interpreting the polarized fluorescence spectra of an impure liquid crystal in which the orientational order of excited impurity molecules has undergone relaxation. This approach has also been realized experimentally. The new experimental data demonstrate a new relaxation process with a time scale on the order of 10(-11)-10(-9) s.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : AVERYANOV E. M.
Заглавие : POLARIZED LUMINESCENCE SPECTRUM OF IMPURITY LIQUID-CRYSTAL - THE DEGENERATION LIFTED AND RENEWED BY RELAXATION
Место публикации : Zhurnal Eksperimentalnoi Teor. Fiz.: MEZHDUNARODNAYA KNIGA, 1993. - Vol. 103, Is. 6. - P2018-2038. - ISSN 0044-4510
Примечания : Cited References: 45
Предметные рубрики: RESOLVED FLUORESCENCE DEPOLARIZATION
UNIAXIAL MOLECULAR SAMPLES
NEMATIC ORDER PARAMETERS
EXCITED-STATES
SPECTROSCOPY
MEMBRANES
FLUOROPHORES
ORIENTATION
TRANSITION
DYES
Аннотация: The general molecular-statistical approach is proposed for the analysis or the polarized luminescence spectrum for impurity molecule of an arbitrary symmetry in the nematic liquid crystal matrix. On the particular example of uniaxial molecules the influence of features of the molecular electron structure, orientational statistics, molecular dynamics, and features of the anisotropic intermolecular coupling upon the positions of maxima v(if)(t) of impurity fluorescence polarized bands J(ij)(t) is studied. For the first time it is shown that all these factors significantly affect the degree of spectrum v(ij)(t) degeneration. For t not-equal 0, relaxation of excited impurity molecule subsystem toward the orientational distribution lifts a partial degeneration of spectrum v(ij), occuring at t not-equal 0, and renews partial or total degeneration of spectrum v(ij) in the limit t = infinity. In the lack of the spectrum v(ij) degeneration for t = 0 the relaxation may restore partial degeneration for t not-equal 0 as a function of the features of electron structure of molecules. The results of work explain the familiar experimental data on the number of independent component v(ij) and relation between them, on dependence of v(ij) upon the order of matrix and impurity subsystem, on the mutual relation in the positions of impurity band polarized component in the absorption and fluorescence spectra.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Averyanov E. M.
Заглавие : Splitting of polarized impurity fluorescence bands in the steady-state spectrum of an isotropic solution
Место публикации : JETP Letters. - 1994. - Vol. 59, Is. 1. - P.23-26. - ISSN 0021-3640
Примечания : Cited References: 12
Предметные рубрики: RELAXATION
Аннотация: A difference is predicted between the peaks, nu(VV) and nu(VH), Of the polarized components J(VV)(nu) and J(VH)(nu) in the steady-state spectrum of impurity fluorescence in an isotropic solution. This difference would result from a temporal correlation between an orientational Brownian diffusion of excited fluorescing molecules and a structural relaxation of the surrounding matrix molecules.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : AVERYANOV E. M.
Заглавие : STATIONARY SPECTRUM OF ADMIXED LIQUID-CRYSTAL POLARIZED FLUORESCENCE
Место публикации : Zhurnal Eksperimentalnoi Teor. Fiz.: MEZHDUNARODNAYA KNIGA, 1994. - Vol. 106, Is. 3. - P767-779. - ISSN 0044-4510
Примечания : Cited References: 29
Предметные рубрики: LOCAL FIELD
SPECTROSCOPY
PARAMETERS
DYES
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Вид документа : Статья из сборника (выпуск монографической серии)
Шифр издания :
Автор(ы) : Bukhanov E. R., Gurevich Y. L., Shabanova K. A.
Заглавие : A study of wheat wax optical properties
Коллективы : Photonics and Electromagnetics Research Symposium - Fall
Место публикации : Photonics and Electromagnetics Research Symposium - Fall (2019 ; Dec 17-20 ; Xiamen, China). Photonics & Electromagnetics Research Symposium - Fall (PIERS - Fall): IEEE, 2019. - P.2890-2897. - (Progress in Electromagnetics Research Symposium). - , DOI 10.1109/PIERS-Fall48861.2019.9021781
Примечания : Cited References: 36
Предметные рубрики: DIMENSIONAL PHOTONIC CRYSTALS
BLUE-GREEN FLUORESCENCE
Аннотация: Epicuticular waxes are a multifunctional interface between a plant and the environment. In this paper wheat leaves wax has been studied. Wax isolation was carried out using the method of gradual freezing in water followed by slow thawing. The morphology of the samples obtained was observed with a Hitachi SU3500 electron microscope. The structure period is determined by the nanotubes diameter which equals 150-200 nm. Random orientation of their long axes in the layer allows using a one-dimensional model to calculate the transmission spectrum of a photonic crystal with the help of the transfer matrix method. While making the calculations a defect that may be caused by possible interlayer heterogeneity also must be taken into account. Numerical modeling made it possible to identify the stop zone and the defective mode. Intense fluorescence appears in the optical area of the wax layer under ultraviolet radiation, thus increasing the efficiency of photosynthesis.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova M. A., Tomilin F. N., Malyar E. Y., Varganov S. A., Fedorov D. G., Ovchinnikov S. G., Slyusareva E. A.
Заглавие : Fluorescence and photoinduced proton transfer in the protolytic forms of fluorescein: Experimental and computational study
Место публикации : Dyes Pigm. - 2020. - Vol. 173. - Ст.107851. - ISSN 01437208 (ISSN), DOI 10.1016/j.dyepig.2019.107851
Примечания : Cited References: 58. - This work is supported by the Russian Foundation for Basic Research, Russia (project 19-02-00450 ). S.A.V. thanks the National Science Foundation, United States for financial support through a CAREER Award ( CHE-1654547 ).
Аннотация: In contrast to the well-studied absorption spectra of different protolytic forms of fluorescein, the complex structure of the fluorescence spectra in a wide pH range is not completely understood because of the interplay between emission and photoinduced proton transfer in the electronic excited states. We provide insight into this interplay through a combined analysis of the experimental data, obtained by absorption and steady-state fluorescence spectroscopy at pH 0.3–10.5, and the time-dependent density functional theory (TD-DFT). The TD-DFT based computational model is validated on dianion and used to model the spectra of other protolytic forms. The protolytic/tautomeric forms of fluorescein are classified according to the partial charges on the triple chromophore ring, and electronic transitions are analyzed in terms of changes in molecular geometries and orbitals. A linear regression analysis between the calculated and experimental results based on both absorption and well-understood dianionic and cationic fluorescence peaks is used to assign the monoanionic (496 nm), neutral quinoid (550 nm) and neutral zwitterionic (483 nm) fluorescence peaks, whose positions were not clear prior to this work. The values of the excited-state dissociation microconstants pka* for different forms of fluorescein are calculated by means of the Forster cycle in conjunction with the spectroscopic measurements and computational data.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen M., Xia Z., Molokeev M. S., Liu Q.
Заглавие : Insights into Ba4Si6O16 structure and photoluminescence tuning of Ba4Si6O16:Ce3+,Eu2+ phosphors
Место публикации : J. Mater. Chem. C: Royal Society of Chemistry, 2015. - Vol. 3, Is. 48. - P.12477-12483. - ISSN 20507534 (ISSN), DOI 10.1039/c5tc03271g
Примечания : Cited References: 39. - This work was supported by the National Natural Science Foundations of China (Grant No. 51572023 and 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1).
Предметные рубрики: LIGHT-EMITTING-DIODES
ENERGY-TRANSFER
LUMINESCENCE PROPERTIES
WHITE-LIGHT
GLASS-CERAMICS
BA PHOSPHORS
EMISSION
GREEN
EU2+
FLUORESCENCE
Аннотация: The versatile polymorphism and chemical compositions of barium silicates have been studied for a long time and their crystal structures have been established. Herein, we focused on the understanding of the crystal structure of the Ba4Si6O16 phase and the structural correlation of Ba4Si6O16 and Ba2Si3O8; moreover, the luminescence properties of Ce3+,Eu2+-co-activated Ba4Si6O16 phosphors have been discussed. Ba4Si6O16:Ce3+,Eu2+ phosphors show tunable blue-green emission upon excitation with 365 nm ultraviolet (UV) light. The blue emission originates from Ce3+, whereas the bluish-green emission is ascribed to Eu2+, and variation in the emission peak wavelength from 442 to 497 nm can be achieved by properly tuning the Ce3+/Eu2+ ratio. Energy transfer from Ce3+ to Eu2+ in the Ba4Si6O16 host has been validated by the variation of emission spectra as well as the variation of Ce3+ decay lifetimes with increasing Eu2+ concentration, and the energy transfer mechanism is demonstrated to be a resonant type via a dipole-dipole process. The results suggest that Ba4Si6O16:Ce3+,Eu2+ phosphors are potential candidates as a blue-green component for UV-excited white light-emitting diodes. © 2015 The Royal Society of Chemistry.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chilom C. G., Sandu N., Iftimie S., Balasoiu M., Rogachev A., Orelovich O., Stolyar S. V.
Заглавие : Interactions of chemically synthesized ferrihydrite nanoparticles with human serum transferrin: Insights from fluorescence spectroscopic studies
Место публикации : Int. J. Mol. Sci. - 2021. - Vol. 22, Is. 13. - Ст.7034. - ISSN 16616596 (ISSN), DOI 10.3390/ijms22137034
Примечания : Cited References: 39. - The work was accomplished with the financial support of the RO-JINR Projects No. 365/11.05.2021, items 8, 87 and 98 and respectivelly, No. 366/11.05.2021, items 7, 86 and 97
Аннотация: Human serum transferrin (HST) is a glycoprotein involved in iron transport that may be a candidate for functionalized nanoparticles to bind and target cancer cells. In this study, the effects of the simple and doped with cobalt (Co) and copper (Cu) ferrihydrite nanoparticles (Fh-NPs, Cu-Fh-NPs, and Co-Fh-NPs) were studied by spectroscopic and molecular approaches. Fluorescence spectroscopy revealed a static quenching mechanism for all three types of Fh-NPs. All Fh-NPs interacted with HST with low affinity, and the binding was driven by hydrogen bonding and van der Waals forces for simple Fh-NPs and by hydrophobic interactions for Cu-Fh-NPs and Co-Fh-NPs binding, respectively. Of all samples, simple Fh-NPs bound the most to the HST binding site. Fluorescence resonance energy transfer (FRET) allowed the efficient determination of the energy transfer between HST and NPs and the distance at which the transfer takes place and confirmed the mechanism of quenching. The denaturation of the HST is an endothermic process, both in the case of apo HST and HST in the presence of the three types of Fh-NPs. Molecular docking studies revealed that Fh binds with a low affinity to HST (Ka = 9.17 × 103 M−1) in accord with the fluorescence results, where the interaction between simple Fh-NPs and HST was described by a binding constant of 9.54 × 103 M−1.
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