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1.
Antiferromagnetic resonance and
phase diagrams of
gadolinium
ferroborate GdFe3(BO3)(4) / A. I. Pankrats [et al.]> // J. Exp. Theor. Phys. - 2004. -
Vol. 99
,
Is. 4
. - P. 766-775,
DOI
10.1134/1.1826168. - Cited References: 16 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Кл.слова (ненормированные):
Anisotropy
--
Antiferromagnetic materials
--
Antiferromagnetism
--
Phase diagrams
--
Resonance
--
Single crystals
--
Antiferromagnetic resonance
--
Antiferromagnets
--
Crystal axis
--
Transition fields
--
Gadolinium
compounds
Аннотация:
Antiferromagnetic resonance in single crystals of rhombohedral
gadolinium
ferroborate GdFe3(BO3)(4) was studied. The frequency-field dependences of antiferromagnetic resonance over the frequency range 26-70 GHz and the temperature dependences of resonance parameters for magnetic fields oriented along the crystal axis and in the basal plane were determined. It was found that the iron subsystem, which can be treated as a two-sublattice antiferromagnet with anisotropy of the easy-plane type, experienced ordering at T = 38 K. At temperatures below 20 K, the
gadolinium
subsystem with the opposite anisotropy sign strongly influenced the anisotropic properties of the crystal. This resulted in a spontaneous spin-reorientation transition from the easy-plane to the easy-axis state at 10 K. Below 10 K, magnetic field-induced transitions between the states were observed. Experimental phase diagrams on the temperature-magnetic field plane were constructed for fields oriented along the crystal axis and in the basal plane. A simple model was used to calculate the critical transition fields. The results were in close agreement with the experimental values measured at T = 4.2 K for both field orientations. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, Siberian Div, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Bayukov, O. A.; Баюков, Олег Артемьевич
}
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2.
Biogenic ferrihydrite nanoparticles
doped with
gadolinium
[Текст] / S. V. Stolyar [и др.]> //
V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P232 . - ISBN 978-5-7444-3124-2
Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Ладыгина, Валентина Петровна; Ishchenko, L. A.; Ищенко Л. А.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
}
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3.
Coupled R and
Fe magnetic excitations in RFe 3(BO 3) 4 multiferroics / A. M. Kuzmenko [et al.]> //
Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. -
Vol. 190
. - P. 269-272,
DOI
10.4028/www.scientific.net/SSP.190.269 . - ISBN 9783037854365
Кл.слова (ненормированные):
Magnetic resonance
--
Rare-earth iron borates
--
Terahertz spectroscopy
--
Antiferromagnetics
--
Coupled mode
--
Exchange coupled
--
Frequency ranges
--
G factors
--
Iron borate
--
Magnetic excitations
--
Multiferroics
--
Resonance mode
--
Strong interaction
--
Transmission spectrums
--
Antiferromagnetism
--
Electron transitions
--
Gadolinium
--
Ions
--
Magnetic materials
--
Magnetic permeability
--
Magnetic resonance
--
Terahertz spectroscopy
--
Neodymium
Аннотация:
Various resonance modes were observed in the transmission spectra of rare-earth iron borates RFe 3(BO 3) 4 (R = Nd 3+, Sm 3+, Gd 3+) at the frequency range 100-600 GHz, which were attributed to collective magnetic excitations in the exchange coupled Fe- and R-subsystems, i.e. antiferromagnetic (Fe) resonance and electron transitions in the R-ions. Strong interaction of the Fe and R oscillations was revealed and theoretically analyzed taking into account feature of the R-ion ground state. Intensities of the coupled modes (contributions to magnetic permeability) strongly depend on a difference of Fe and R ions g-factors that allows defining the sign of the latter. In particular, an appreciable intensity of exchange (Nd) modes in NdFe 3(BO 3) 4 is caused by g Nd?,|| < 0 whereas in GdFe 3(BO 3) 4 with gGd ? gFe ? 2 the exchange (Gd) modes were hided due to compensation of Fe and Gd contributions. In SmFe 3(BO 3) 4, despite a negligible Sm g-factor, the Sm modes were clear observed due to their excitation via coupling with the Fe-subsystem. В© (2012) Trans Tech Publications.
Scopus
Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А.М.; Mukhin, A. A.; Ivanov, V.Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
}
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4.
Effect of
gadolinium
on magnetic circular dichroism and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses / I. Edelman [et al.]> // J. Non-Cryst. Solids. - 2019. -
Vol. 506
. - P. 68-79,
DOI
10.1016/j.jnoncrysol.2018.12.006. - Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030. . - ISSN 0022-3093
Кл.слова (ненормированные):
Iron oxides
--
ε-Fe2O3
--
Borate glasses
--
Nanoparticles
--
Magnetic circular dichroism
--
Electron magnetic resonance
Аннотация:
A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by
gadolinium
. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
LOMA, UMR 5798 Universite de Bordeaux-CNRS, Talence cedex, 33405, France
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, 630090, Russian Federation
NRC “Kurchatov Institute”, Moscow, 123182, Russian Federation
Vavilov State Optical Institute, St.-Petersburg, 199053, Russian Federation
Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Kliava, J.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zaikovskii, V.; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zubavichus, Y.; Stepanov, S.
}
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5.
Effects of endohedral
Gd-containing fullerenols with a different number of oxygen substituents on bacterial bioluminescence / E. A. Stepin, E. S. Sushko, N. G. Vnukova [et al.]> // Int. J. Mol. Sci. - 2024. -
Vol. 25
,
Is. 2
. - Ст. 708,
DOI
10.3390/ijms25020708. - Cited References: 102. - This research was funded by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation, project No. 0287-2021-0020, and partly supported by the Russian Science Foundation No. 23-26-10018, Krasnoyarsk Regional Science Foundation . - ISSN 1661-6596. - ISSN 1422-0067
Перевод заглавия:
Влияние эндоэдральных Gd-содержащих фуллеренолов с различным числом кислородных заместителей на биолюминесценцию бактерий
Кл.слова (ненормированные):
endohedral fullerenol
--
gadolinium
--
bioluminescence
--
bacterial bioassay
--
toxicity
--
enzymatic bioassay
--
reactive oxygen species
--
density functional tight binding method
--
fourier-transform infrared spectroscopy
Аннотация:
Gadolinium
(Gd)-containing fullerenols are perspective agents for magnetic resonance imaging and cancer research. They combine the unique paramagnetic properties of Gd with solubility in water, low toxicity and antiradical activity of fullerenols. We compared the bioeffects of two Gd-containing fullerenols with a different number of oxygen groups—20 and 42: Gd@C82O20H14 and Gd@C82O42H32. The bioluminescent bacteria-based assay was applied to monitor the toxicity of fullerenols, bioluminescence was applied as a signal physiological parameter, and bacterial enzyme-based assay was used to evaluate the fullerenol effects on enzymatic intracellular processes. Chemiluminescence luminol assay was applied to monitor the content of reactive oxygen species (ROS) in bacterial and enzymatic media. It was shown that Gd@C82O42H32 and Gd@C82O20H14 inhibited bacterial bioluminescence at >10?1 and >10?2 gL?1, respectively, revealing a lower toxicity of Gd@C82O42H32. Low-concentration (10?3–10?1 gL?1) bacterial bioluminescence activation by Gd@C82O42H32 was observed, while this activation was not found under exposure to Gd@C82O20H14. Additional carboxyl groups in the structure of Gd@C82O42H32 were determined by infrared spectroscopy and confirmed by quantum chemical calculations. The groups were supposed to endow Gd@C82O42H32 with higher penetration ability through the cellular membrane, activation ability, lower toxicity, balancing of the ROS content in the bacterial suspensions, and lower aggregation in aqueous media.
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Держатели документа:
Biophysics Department, School of Fundamental Biology and Biotechnology, Siberian Federal University, 660041 Krasnoyarsk, Russia
Institute of Biophysics SB RAS, FRC KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Physics SB RAS, FRC KSC SB RAS, 660036 Krasnoyarsk, Russia
Department of Solid State Physics and Nanotechnology, School of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Department of Physical and Inorganic Chemistry, School of Non-Ferrous Metals and Materials Science, Siberian Federal University, 660025 Krasnoyarsk, Russia
Laboratory for Digital Controlled Drugs and Theranostics, FRC KSC SB RAS, 660036 Krasnoyarsk, Russia
Доп.точки доступа:
Stepin, E. A.; Sushko, E. S.; Сушко, Екатерина Сергеевна; Vnukova, N. G.; Внукова, Наталья Григорьевна; Churilov, G. N.; Чурилов, Григорий Николаевич; Rogova, A. V.; Tomilin, F. N.; Томилин, Феликс Николаевич; Kudryasheva, N. S.
}
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6.
Electrophysical properties of
hydroxylated endohedral metallofullerene with
gadolinium
/ A. I. Dudnik [et al.]> // J. Phys. Chem. Solids. - 2019. -
Vol. 135
. - Ст. 109094,
DOI
10.1016/j.jpcs.2019.109094. - Cited References: 35. - The reported study was funded by RFBR according to the research project No 18-29-19003. . - ISSN 0022-3697
Кл.слова (ненормированные):
Endohedral metallofullerene
--
Fullerenol
--
Impedance
--
Dielectric permittivity
--
Ionic and proton conductivity
--
Dielectric hysteresis
--
Polarizability
Аннотация:
The paper presents the results of experimental measurements of constitutive and electrophysical properties in hydroxylated endohedral metallofullerene with
gadolinium
sample. We extracted endohedral metallofullerene from carbon condensate, synthesized in high-frequency arc discharge plasma. Later hydroxyl groups were added. Via methods of infrared and x-ray photoelectronic spectroscopy, it was established that the molecules of hydroxylated endohedral metallofullerene have the Gd@C82Ox(OH)y, x + y=(40–42) composition. The method of measuring the electrical impedance in the frequency range from 100 Hz to 100 MHz shows that the resulting hydroxylated fullerene is an ion conductor. The measured frequency dependences of the dielectric permittivity and conductivity of hydroxylated fullerene are explained based on the assumption of an inhomogeneous distribution of electric charges in the material volume. Dielectric-hysteresis loops in the frequency range of 25 Hz–1 MHz and temperature range of 80–300 K, and volt-ampere characteristics were measured. The obtained results imply the appearance of residual polarization induced by the electric field in hydroxylated fullerene. However, the constant dipole moment is absent. © 2019
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Dudnik, A. I.; Дудник, Александр Иванович; Vnukova, N. G.; Внукова, Наталья Григорьевна; Drokin, N. A.; Дрокин, Николай Александрович; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Tomashevich, Y. V.; Churilov, G. N.; Чурилов, Григорий Николаевич
}
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7.
Endohedral Gd-containing fullerenol:
Toxicity, antioxidant activity and regulation of reactive oxygen species in cellular and enzymatic systems / E. S. Sushko, N. G. Vnukova, G. N. Churilov, N. S. Kudryasheva> // Int. J. Mol. Sci. - 2022. -
Vol. 23
,
Is. 9
. - Ст. 5152,
DOI
10.3390/ijms23095152. - Cited References: 117. - This research was funded by Russian Foundation for Basic Research, N18-29-19003; Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, N20-44-243001; and partly supported by the Program of the Federal Service for Surveillance on Consumer Rights Protection and Human Wellbeing, Fundamental Study 2020-2025 (Russia) . - ISSN 1661-6596
Кл.слова (ненормированные):
endohedral fullerenol
--
gadolinium
--
toxicity
--
oxidative stress
--
antioxidant activity
--
reactive oxygen species
--
bioluminescence bioassay
--
hormesis
Аннотация:
The Gd-containing metallofullerene derivatives are perspective magnetic resonance imaging contrast agents. We studied the bioeffects of a water-soluble fullerene derivative,
gadolinium
-endohedral fullerenol, with 40–42 oxygen groups (Gd@Fln). Bioluminescent cellular and enzymatic assays were applied to monitor toxicity and antioxidant activity of Gd@Fln in model solutions; bioluminescence was applied as a signaling physiological parameter. The Gd@Fln inhibited bioluminescence at high concentrations (>2·10−1 gL−1), revealing lower toxicity as compared to the previously studied fullerenols. Efficient activation of bioluminescence (up to almost 100%) and consumption of reactive oxygen species (ROS) in bacterial suspension were observed under low-concentration exposure to Gd@Fln (10−3–2·10−1 gL−1). Antioxidant capability of Gd@Fln was studied under conditions of model oxidative stress (i.e., solutions of model organic and inorganic oxidizers); antioxidant coefficients of Gd@Fln were determined at different concentrations and times of exposure. Contents of ROS were evaluated and correlations with toxicity/antioxidant coefficients were determined. The bioeffects of Gd@Fln were explained by hydrophobic interactions, electron affinity, and disturbing of ROS balance in the bioluminescence systems. The results contribute to understanding the molecular mechanism of “hormetic” cellular responses. Advantages of the bioluminescence assays to compare bioeffects of fullerenols based on their structural characteristics were demonstrated.
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Держатели документа:
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Sushko, E. S.; Сушко, Екатерина Сергеевна; Vnukova, N. G.; Внукова, Наталья Григорьевна; Churilov, G. N.; Чурилов, Григорий Николаевич; Kudryasheva, N. S.
}
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8.
Gd3Ga5O12:Nd3+ crystals for
a continuous-wave diode-pumped laser operating in 4F3/2 4I11/2 and 4F3/2 4I13/2 channels / A. A. Kaminskii [et al.]> // Crystallogr. Rep. - 2002. -
Vol. 47
,
Is. 2
. - P. 308-312,
DOI
10.1134/1.1466508. - Cited References: 15 . - ISSN 1063-7745
Рубрики:
GALLIUM GARNET
EMISSION
Кл.слова (ненормированные):
gadolinium
--
gallium
--
neodymium
--
article
--
concentration response
--
crystal
--
pump
--
spectroscopy
--
X ray
--
x ray topography
Аннотация:
Garnet crystals of the composition Gd3Ga5O12:Nd3+ (concentration series CNd = 1-10 at. %) were grown from flux. In terms of spectroscopy, these crystals, unlike those grown from melts, form a medium with a single activator center. For the first time, continuous-wave lasing was excited by diode pumping with the use of Gd3Ga5O12:Nd3+ crystals at the wavelengths ?3 = 1.3315 and ?4 = 1.3370 ?m of the 4F3/2 > 4I13/2 channel and also the simultaneous generation at two wavelengths, ?1 = 1.0621 and ?2 = 1.0600 ?m, of the 4F3/2 > 4I11/2 channel. В© 2002 MAIK "Nauka/Interperiodica".
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Другая переводная версия
Crystals Gd3Ga5O12:Nd3+ for a continuous-wave diode-pumped laser operating in 4F3/24I11/2 and 4F3/24I13/2 channels [Текст] / A. A. Kaminskij [и др.] // Kristallogr. - 2002. - Vol. 47 Is. 2.- P.344-349 ; Crystallogr. Rep.
Публикация на русском языке
Раствор-расплавные кристаллы Gd3Ga5O12:Nd3+ для непрерывных лазеров (4F3/2→4I11/2 и 4F3/2→4I13/2 каналы) с диодно-лазерной накачкой [Текст] / А. А. Каминский [и др.] // Кристаллография. - 2002. - Т. 47 Вып. 2. - С. 344-348
Держатели документа:
Shubnikov Inst. of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow 117333, Russian Federation
Доп.точки доступа:
Kaminskii, A. A.; Butashin, A. V.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович; Kravtsov, N. V.; Firsov, V. V.; Seo, D. T.; Hommerich, U.; Temple, D.; Braud, A.
}
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9.
Linear and nonlinear
optical spectroscopy of
gadolinium
iron borate GdFe3(BO3)(4) / A. M. Kalashnikova [et al.]> // JETP Letters. - 2004. -
Vol. 80
,
Is. 5
. - P. 293-297,
DOI
10.1134/1.1825108. - Cited References: 26 . - ISSN 0021-3640
РУБ
Physics, Multidisciplinary
Рубрики:
ORTHOFERRITES
Аннотация:
The optical spectra and the second-harmonic generation (SHG) are studied in a noncentrosymmetric GdFe3(BO3)(4) magnet. In the region of weak absorption (alpha similar to 20-400 cm(-1)) below similar to3 eV, three absorption bands are distinguished, which can be unambiguously assigned to forbidden electronic transitions from the ground (6)A(1) state of the Fe3+ ion to its excited states T-4(1) (similar to1.4 eV), T-4(2) (similar to2 eV), and (4)A(1), E-4 (similar to2.8 eV). Intense absorption begins in the region above 3 eV (alpha similar to 2-4 x 10(5) cm(-1)), where two bands at similar to4.0 and 4.8 eV are observed, which are caused by allowed electric dipole charge-transfer transitions. The spectral features of SHG in the 1.2-3.0-eV region are explained by a change in the SHG efficiency caused by a change in the phase mismatch. It is shown that in the weak absorption region, phase matching can be achieved for SHG. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Russian Acad Sci, Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Univ Dortmund, D-44227 Dortmund, Germany
Univ Nijmegen, NSRIM Inst, NL-6525 Nijmegen, Netherlands
ИФ СО РАН
Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, 194021, Russian Federation
Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Experimental Physics II, Dortmund University, Dortmund, 44227, Germany
NSRIM Institute, University of Nijmegen, 6525, Netherlands
Доп.точки доступа:
Kalashnikova, A. M.; Pavlov, V. V.; Pisarev, R. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Bayer, M.; Rasing, T.
}
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10.
Magnetic and optical
properties and electron paramagnetic resonance of
gadolinium
-containing oxide glasses / J. . Kliava [et al.]> // J. Phys.: Condens. Matter. - 2003. -
Vol. 15
,
Is. 40
. - P. 6671-6681,
DOI
10.1088/0953-8984/15/40/005. - Cited References: 30 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
ABSORPTION-SPECTRA
FARADAY-ROTATION
SPIN-RESONANCE
IONS
GD3+
SPECTROSCOPY
BEHAVIOR
GD-3
Кл.слова (ненормированные):
Doping (additives)
--
Electronic structure
--
Glass
--
Lanthanum compounds
--
Light absorption
--
Magnetic susceptibility
--
Oxides
--
Paramagnetic resonance
--
Positive ions
--
Rate constants
--
Substitution reactions
--
Absorption band
--
Gadolinium
containing oxide glasses
--
Positive Weiss constants
--
Gadolinium
compounds
Аннотация:
Magnetic susceptibility, electron paramagnetic resonance (EPR) and optical absorption have been studied in a glass system 20La(2)O(3)-22Al(2)O(3)-23B(2)O(3)-35(SiO2 + GeO2) with a part of La2O3 substituted by Gd2O3 in different concentrations. Positive Weiss constants have been found in more heavily doped glasses and ascribed to clustering of Gd3+ ions. Computer simulations of the EPR spectra show that the short-range ordering in the environment of the Gd3+ ions is well preserved. The relative distribution widths of the ligand coordinates are less than 2%. In the more heavily doped glasses the EPR spectra are superpositions of signals arising from isolated ions and ferromagnetic clusters. The increase of Gd3+ concentration is shown to change substantially the strong optical absorption edge while only small changes of f-f absorption band characteristics are observed. This difference is associated with the different effect of the Gd ion clustering on the mechanisms of the strong absorption in the ultraviolet region and the f-f absorption.
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Держатели документа:
Univ Bordeaux 1, CPMOH, F-33405 Talence, France
SI Vavilov State Opt Inst, St Petersburg 199034, Russia
Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
Bar Ilan Univ, Dept Phys, IL-52900 Ramat Gan, Israel
RAS, SB, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
CPMOH, Universite Bordeaux-I, 33405 Talence Cedex, France
L V Kirensky Inst. of Physics, SB RAS, Krasnoyarsk 660036, Russian Federation
Bar-Ilan University, Department of Physics, Ramat-Gan 52900, Israel
Bar-Ilan University, Department of Chemistry, Ramat-Gan 52900, Israel
S V Vavilov State Optical Institute, St Petersburg 199034, Russian Federation
Доп.точки доступа:
Kliava, J.; Edelman, I. S.; Эдельман, Ирина Самсоновна; Potseluyko, A. M.; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Berger, R.; Bruckental, I.; Yeshurun, Y.; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Zarubina, Y. V.
}
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11.
Magnetic and thermophysical
properties of GdxMn1-xS solid solutions / S. S. Aplesnin [et al.]> // J. Phys.: Condens. Matter. - 2013. -
Vol. 25
,
Is. 2
. - Ст. 025802. - P. ,
DOI
10.1088/0953-8984/25/2/025802 . - ISSN 0953-8984
Кл.слова (ненормированные):
Antiferromagnetic orders
--
Band state
--
Face-centered cubic lattices
--
Magnetic phase transitions
--
Paramagnetic phase
--
Temperature dependence
--
Antiferromagnetism
--
Electron transitions
--
Gadolinium
--
Manganese
--
Paramagnetism
--
Sodium chloride
--
Specific heat
--
Organic polymers
Аннотация:
The structural, magnetic, and thermophysical properties of cation-substituted sulfides GdXMn1-XS (0.04 ? X ? 0.25) with the NaCl-type face-centered cubic lattice have been investigated. The range of existence of long-range antiferromagnetic order has been established. The anomalies observed in the temperature dependence of the specific heat correspond to the temperatures of the magnetic phase transition. The anomaly in the specific heat caused by electron transitions between the 4f levels and d band states has been observed. It has been found that the coefficient of thermal expansion decreases with increasing concentration of substituents in the magnetically ordered region and remains nearly invariable in the paramagnetic phase. В© 2013 IOP Publishing Ltd.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Daghestan Sci Ctr, Amirkhanov Inst Phys, Makhachkala 367003, Russia
Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Romanova, O.; Романова, Оксана Борисовна; Gorev, M. V.; Горев, Михаил Васильевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Gamzatov, A. G.; Aliev, A. M.
}
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12.
Magnetic and transport
properties of Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr) / N. V. Kazak [et al.]> // J. Magn. Magn. Mater. - 2009. -
Vol. 321
,
Is. 9
. - P. 1266-1271,
DOI
10.1016/j.jmmm.2008.11.087. - Cited Reference Count: 31. - Гранты: This study was supported by the Rosnauka (Project no. MK-4278.2008.2), Russian Foundation for Basic Research (Project no. 08-02-90708 mob_st) and "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS. - Финансирующая организация: Rosnauka [MK-4278.2008.2]; Russian Foundation for Basic Research [08-02-90708 mob_st]; "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS . - ISSN 0304-8853
Рубрики:
PEROVSKITE
PR
LA
EU
ND
LN
TRANSITION
SPIN
GD
SM
Кл.слова (ненормированные):
Perovskite structure
--
Doped cobaltite
--
Magnetic susceptibility
--
Metal-insulator transition
--
Doped cobaltite
--
Magnetic susceptibility
--
Metal-insulator transition
--
Perovskite structure
--
Antiferromagnetism
--
Barium
--
Cobalt compounds
--
Electric conductivity
--
Ferromagnetic materials
--
Ferromagnetism
--
Gadolinium
--
Magnetic susceptibility
--
Metal insulator boundaries
--
Oxide minerals
--
Paramagnetic materials
--
Perovskite
--
Phase separation
--
Semiconductor insulator boundaries
--
Transport properties
--
Antiferromagnetic
--
Doped cobaltite
--
Doped samples
--
Electrical conductivity measurements
--
Ferromagnetic transitions
--
Insulator-metal transitions
--
Magnetic and transport properties
--
Magnetic behaviors
--
Perovskite structure
--
Temperature ranges
--
Transport datum
--
X- ray diffractions
--
Metal insulator transition
Аннотация:
The X-ray diffraction, magnetization and electrical conductivity measurements for Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr) have been made. The complicated magnetic behavior, including the paramagnetic-ferromagnetic-antiferromagnetic and paramagnetic-ferromagnetic transitions, was found for Ba- and Sr-doped samples. The gradual insulator-metal transitions were observed in a wide temperature range T = 600-800 K. The complex magnetic and transport data could be explained on the basis of the structural phase separation. (C) 2009 Elsevier B.V. All rights reserved.
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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Polytech Inst, Krasnoyarsk 660074, Russia
Univ Guadalajara, CUCEI, Dept Fis, Guadalajara 44430, Jalisco, Mexico
Siberian Fed Univ, Inst Nat & Humanitary Res, Krasnoyarsk 660041, Russia
AA Galkin Donetsk Phystech Natl Acad Sci Ukraine, UA-83114 Donetsk, Ukraine
Доп.точки доступа:
Kazak, N. V.; Казак, Наталья Валерьевна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Balaev, A. D.; Балаев, Александр Дмитриевич; Ivanova, N.B.; Pashkevich, Yu. G.; Michel, C.R.; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич
}
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13.
Magnetic nanoparticles origin
in glasses co-doped with iron and
gadolinium
oxides / R. D. Ivantsov [et al.]> //
Third Asian school-conference on physics and technology of nanostructured materials (ASCO-NANOMAT 2015) : proceedings. - Vladivostok : Dalnauka, 2015. - Ст. VI.21.06p . - ISBN 978-5-8044-1556-4
Материалы конференции
Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Ivanova, O. S.; Иванова, Оксана Станиславовна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zubavichus, Y. V.; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Edelman, I. S.; Эдельман, Ирина Самсоновна; Asian School-Conference on Physics and Technology of Nanostructured Materials(3 ; 2015 ; Aug. ; 19-26 ; Vladivostok); Азиатская школа-конференция по физике и технологии наноструктурированных материалов(3 ; 2015 ; авг. ; 19-26 ; Владивосток)
}
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14.
Magnetic properties and
the metal-insulator transition in GdXMn1-XS solid solutions / O. B. Romanova [et al.]> // Solid State Commun. - 2010. -
Vol. 150
,
Is. 13-14
. - P. 602-604,
DOI
10.1016/j.ssc.2009.12.042. - Cited References: 13. - This study was supported by the Russian Foundation for Basic Research project No. 09-02-00554_a; No. 09-02-92001-NNS_a; No. 08-02-90031 Bel_a and Belarus Foundation for Basic Research project No. F04-182; ADTF "Development of scientific potential of the higher school" No. 2.1.1/401. . - ISSN 0038-1098
РУБ
Physics, Condensed Matter
Кл.слова (ненормированные):
Insulator
--
Metals
--
Crystal growth
--
Phase transitions
--
Insulator
--
Metals
--
Crystal growth
--
Phase transitions
--
Insulator
--
Metals
--
Antiferromagnetic semiconductors
--
Crystal growth
--
Cubic lattice
--
Metal-insulator phase transition
--
Orders of magnitude
--
P-type
--
Temperature range
--
Thermoelectric properties
--
Thermopowers
--
Antiferromagnetic materials
--
Antiferromagnetism
--
Crystal growth
--
Crystallization
--
Electric properties
--
Gadolinium
--
Grain boundaries
--
Magnetic fields
--
Magnetic properties
--
Manganese
--
Manganese compounds
--
Metal insulator boundaries
--
Metals
--
Semiconductor growth
--
Semiconductor insulator boundaries
--
Sodium chloride
--
Solid solutions
--
Solidification
--
Metal insulator transition
Аннотация:
The structural, magnetic, electrical, and thermoelectric properties of GdXMn1-XS (0.01 <= X <= 0.3) solid solutions synthesized for the first time on the basis of alpha-MnS have been studied experimentally in the temperature range 77-1000 K in magnetic fields up to 10 kOe. The synthesized samples are antiferromagnetic semiconductors with an NaCl-type cubic lattice typical of a-MnS. Both concentration (X-c = 0.3) and temperature (T-c = 450 K) metal-insulator phase transitions have been observed. The concentration metal-insulator transition is accompanied by a decrease in resistivity and thermopower by twelve and two orders of magnitude, respectively, with the change in conductivity from p-type to n-type. (C) 2010 Elsevier Ltd. All rights reserved.
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Держатели документа:
[Romanova, O. B.
Ryabinkina, L. I.
Velikanov, D. A.
Balaev, D. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Sokolov, V. V.
Pichugin, A. Yu.] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[Galyas, A. I.
Demidenko, O. F.
Makovetskii, G. I.
Yanushkevich, K. I.] Natl Acad Sci Belarus, GO NPTs Mat Sci Ctr, Minsk 220072, Byelarus
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk, Russian Federation
Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, 630090 Novosibirsk, Russian Federation
GO NPTs Materials Science Center, National Academy of Sciences of Belarus, 220072 Minsk, Belarus
Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Ryabinkina, L. I.; Рябинкина, Людмила Ивановна; Sokolov, V. V.; Pichugin, A. Y.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Galyas, A. I.; Demidenko, O. F.; Makovetskii, G. I.; Yanushkevich, K. I.
}
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15.
Magnetic structure of
the field-induced multiferroic GdFe3(BO3)(4) / H. D. Mo [et al.]> // Phys. Rev. B. - 2008. -
Vol. 78
,
Is. 21
. - Ст. 214407,
DOI
10.1103/PhysRevB.78.214407. - Cited References: 35. - We thank W. Schoenig, D. Coburn, S. Wilkins, and J. Hill for their support at X22C, S. LaMarra for his support at X21, and D. Connor for a critical reading of the manuscript. Use of the National Synchrotron Light Source, Brookhaven National Laboratory was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. . - ISSN 1098-0121
РУБ
Physics, Condensed Matter
Рубрики:
IRON BORATE GDFE3(BO3)(4)
X-RAY-SCATTERING
POLARIZATION DEPENDENCE
EXCHANGE SCATTERING
RESONANCE
FERROELECTRICITY
Кл.слова (ненормированные):
ferromagnetic materials
--
gadolinium
compounds
--
iron compounds
--
magnetic structure
--
multiferroics
--
Neel temperature
--
spin dynamics
--
X-ray scattering
Аннотация:
We report a magnetic x-ray scattering study of the field-induced multiferroic GdFe3(BO3)(4). Resonant x-ray magnetic scattering at the Gd L-II,L-III edges indicates that the Gd moments order at T-N approximate to 37 K. The magnetic structure is incommensurate below T-N, with the incommensurability decreasing monotonically with decreasing temperature until a transition to a commensurate magnetic phase is observed at T approximate to 10 K. Both the Gd and Fe moments undergo a spin reorientation transition at T-SR approximate to 9 K such that the moments are oriented along the crystallographic c axis at low temperatures. With magnetic field applied along the a axis, our measurements suggest that the field-induced polarization phase has a commensurate magnetic structure with Gd moments rotated similar to 45 degrees toward the basal plane, which is similar to the magnetic structure of the Gd subsystem observed in zero field between 9 and 10 K, and the Fe subsystem has a ferromagnetic component in the basal plane.
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Держатели документа:
[Mo, Haiding
Nelson, Christie S.] Brookhaven Natl Lab, Natl Synchrotron Light Source, Upton, NY 11973 USA
[Bezmaternykh, Leonard N.
Temerov, V. T.] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
National Synchrotron Light Source, Brookhaven National Laboratory, Upton, NY 11973, United States
L. V. Kirensky Institution of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Mo, H. D.; Nelson, C. S.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. T.
}
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16.
Magneto-optical properties of
Dy3+ in oxide glasses: The origin of the magneto-optical activity of f-f transitions and its anomalous temperature dependence / A. V. Malakhovskii [et al.]> // Phys. Solid State. - 2007. -
Vol. 49
,
Is. 4
. - P. 701-707,
DOI
10.1134/S1063783407040178. - Cited References: 28 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
MAGNETIC CIRCULAR-DICHROISM
FLUOROZIRCONATE ZBLAN GLASS
OPTICAL-ABSORPTION SPECTRA
DOPED SODA GLASS
SPECTROSCOPIC PROPERTIES
FLUOROBORATE GLASSES
LITHIUM BORATE
IONS
PR3+
GADOLINIUM
Аннотация:
The temperature dependence of the absorption spectra and magnetic circular dichroism due to f-f transitions from the H-6(15/2) to F-6 (5/2) and (6)(F (7/2) + H (5/2)) states in the Dy3+ ion in (Dy2O3-P2O5-SiO2-GeO2) and (Dy2O3-La2O3-Al2O3-B2O3-SiO2-GeO2) glasses and the temperature dependence of the Faraday effect were studied. The temperature dependence of the Faraday effect caused by f-d transitions was found to differ from that of the magnetic circular dichroism due to f-f transitions. It was shown that f-f transitions occur preferentially in Dy3+ ions associated into clusters. The origin of the paramagnetic magneto-optical activity of f-f transitions was analyzed. It was shown that the contributions to this activity can differ in value and sign and that the ratio between these contributions depends on the transition type. In some cases, this difference results in an anomalous temperature dependence of the magneto-optical activity.
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Публикация на русском языке
Магнитооптические свойства Dy3+ в оксидных стеклах. Природа магнитооптической активности f-f-переходов и ее аномальной температурной зависимости [Текст] / А. В. Малаховский [et al.] // Физика твердого тела. - Санкт-Петербург : Федеральное государственное унитарное предприятие "Академический научно-издательский, производственно-полиграфический и книгораспространительский центр Российской академии наук "Издательство "Наука", 2007. - Т. 49 № 4. - С. 667-673
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
SI Vavilov State Opt Inst, St Petersburg 192371, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk State University, Krasnoyarsk, 660041, Russian Federation
Vavilov State Optical Institute, Birzhevaya liniya 12, St. Petersburg, 192371, Russian Federation
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Isachenko, V. A.; Sukhachev, A. L.; Сухачев, Александр Леонидович; Potseluyko, A. M.; Zabluda, V. N.; Заблуда, Владимир Николаевич; Zarubina, T. V.; Edelman, I. S.; Эдельман, Ирина Самсоновна
}
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17.
Magnetoelectric effects in
gadolinium
iron borate GdFe3(BO3)(4) / A. K. Zvezdin [et al.]> // JETP Letters. - 2005. -
Vol. 81
,
Is. 6
. - P. 272-276,
DOI
10.1134/1.1931014. - Cited References: 23 . - ISSN 0021-3640
РУБ
Physics, Multidisciplinary
Рубрики:
OPTICAL SPECTROSCOPY
TRANSITIONS
POLARIZATION
PHASE
Аннотация:
Magnetoelectric interactions have been investigated in a single crystal of
gadolinium
iron borate GdFe3(BO3)(4), whose macroscopic symmetry is characterized by the crystal class 32. Using the results of this study, the interplay of magnetic and electric orderings occurring in the system has been experimentally revealed and theoretically substantiated. The electric polarization and magnetostriction of this material that arise in spin-reorientation transitions induced by a magnetic field have been investigated experimentally. For H parallel to c and H perpendicular to c, H-T phase diagrams have been constructed, and a strict correlation between the changes in the magnetoelectric and magnetoelastic properties in the observed phase transitions has been ascertained. A mechanism of specific noncollinear antiferroelectric ordering at the structural phase transition point was proposed to interpret the magnetoelectric behavior of the system within the framework of the symmetry approach in the entire temperature range. This ordering provides the conservation of the crystal class of the system when the temperature decreases to the antiferroelectric ordering point. The expressions that have been obtained for the magnetoelectric and magnetoelastic energy describe reasonably well the behavior of
gadolinium
iron borate observed experimentally. (C) 2005 Pleiades Publishing, Inc.
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Держатели документа:
Moscow MV Lomonosov State Univ, Moscow 119992, Russia
Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siverian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Moscow State University, Vorob'evy gory, Moscow, 119992, Russian Federation
Institute of General Physics, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation
Доп.точки доступа:
Zvezdin, A. K.; Krotov, S. S.; Kadomtseva, A. M.; Vorob'ev, G. P.; Popov, Y. F.; Pyatakov, A. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, E. A.
}
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18.
Magnetoelectric interactions in
rare-earth ferroborates / A. M. Kadomtseva [et al.]> // J. Exp. Theor. Phys. - 2007. -
Vol. 105
,
Is. 1
. - P. 116-119,
DOI
10.1134/S1063776107070254. - Cited References: 14 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
Кл.слова (ненормированные):
Gadolinium
compounds
--
Magnetoelectric effects
--
Phase transitions
--
Polarization
--
Single crystals
--
Magnetic control
--
Magnetoelectric interactions
--
Rare earth ferroborates
--
Torque curves
--
Rare earths
Аннотация:
Magnetic-field-induced phase transitions in single crystals of the rare-earth ferroborates GdFe3(BO3)(4) and NdFe3(BO3)(4) have been studied by measuring magnetoelectric dependences and torque curves. These phase transitions can serve as one of the possible mechanisms for magnetic control of electric polarization. Magnetic phase transitions in GdFe3(BO3)(4) are analyzed theoretically.
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Держатели документа:
Moscow MV Lomonosov State Univ, Moscow 119992, Russia
Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Moscow State University, Moscow 119992, Russian Federation
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow 119991, Russian Federation
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Kadomtseva, A. M.; Zvezdin, A. K.; Pyatakov, A. P.; Kuvardin, A. V.; Vorob'ev, G. P.; Popov, Y. F.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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19.
Optical transitions in
GdFe3(BO3)(4) and FeBO3 under high pressures / A. G. Gavriliuk [et al.]> // J. Phys.: Condens. Matter. - 2005. -
Vol. 17
: 2nd International Symposium on Physics of Solids Under High Presure Using Nuclear Probes (JUL 22-25, 2004, Cologne, GERMANY),
Is. 48
. - P. 7599-7604,
DOI
10.1088/0953-8984/17/48/011. - Cited References: 8 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
ELECTRONIC-STRUCTURE
Кл.слова (ненормированные):
Band structure
--
Coulomb blockade
--
High pressure effects
--
Iron compounds
--
Magnetic moments
--
Mathematical models
--
Optical properties
--
Relaxation processes
--
Coulomb correlations
--
Electron correlations
--
Insulator-semiconductor transitions
--
Optical transitions
--
Gadolinium
compounds
Аннотация:
The optical properties of GdFe3(BO3)(4) under high pressures have been investigated experimentally and theoretically, and the results are compared with the properties of FeBO3. A model of the GdFe3(BO3)(4) band structure is derived within the multielectron model taking into account the strong electron correlations. Crossover of the Fe3+ ion high-spin and low-spin states, collapse of the magnetic moment, the relaxation Coulomb correlations, and insulator-semiconductor transition are predicted. Optical transitions in GdFe3(BO3)(4) and FeBO3 under high pressures were discovered.
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Держатели документа:
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
RAS, Inst Crystallog, Moscow 119333, Russia
RAS, Inst High Pressure Phys, Troitsk 142190, Russia
ИФ СО РАН
Institute of Crystallography, RAS, 119333, Moscow, Russian Federation
Institute for High Pressure Physics, RAS, 142190, Troitsk, Russian Federation
L V Kirensky Institute of Physics, Siberian Branch, RAS, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Gavriliuk, A. G.; Kharlamova, S. A.; Lyubutin, I. S.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Potseluyko, A. M.; Trojan, I. A.; Zabluda, V. N.; Заблуда, Владимир Николаевич
}
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20.
Properties of GdSF
and phase diagram of the GdF3 - Gd2S3 system / M. U. Abulkhaev, M. S. Molokeev, A. S. Oreshonkov [и др.]> // J. Solid State Chem. - 2023. -
Vol. 322
. - Ст. 123991,
DOI
10.1016/j.jssc.2023.123991. - Cited References: 44. - The authors of the article are grateful to P.P. Fedorov for valuable critical comments on the manuscript. - This research was funded by the Tyumen Oblast Government, as a part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3) . - ISSN 0022-4596. - ISSN 1095-726X
Кл.слова (ненормированные):
Gadolinium
fluorosulfide
--
Optical properties
--
Electronic structure
--
Thermal properties
--
System phase diagram
--
Tauc plot
--
Direct and indirect bandgaps
Аннотация:
The objectives of this study were to refine the phase diagram of the GdF3-Gd2S3 system and to calculate their liquidus, and to synthesize GdSF and to study their properties. The GdSF compound (ST PbFCl, P4/nmm, a (Å) 3.83006(17), c (Å) 6.8529(3), has an optical band gap for a direct interband transition of 2.56 eV and is characterized by a pronounced increase in the Kubelka-Munk function in the region of this transition. Direct optical bandgap of GdSF is measured to be equal to 2.77 eV. Two indirect bandgaps are detected to be 1.54 and 2.4 eV. Meta-GGA simulations of band structure predicting 1.481 eV direct bandgap of GdSF are in good agreement with these features of the experimental absorption spectrum. To explain this complicated case, we argue that formally direct optical transitions to highly dispersive subbands contribute not to direct but to indirect bandgaps measured by Tauc analysis. The GdSF compound melts incongruently with the formation of a melt and γ-Gd2S3 compound at t = 1280 ± 2°С, ΔН = 40.6 ± 2.8 kJ/mol, ΔS = 26.1 ± 1.8 J/mol∗K. The eutectic has a composition of 13 mol.% Gd2S3 (0.74 GdF3 + 0.26 GdSF), the melting characteristics of the eutectic are 1182 ± 2°С, ΔН = 36.2 ± 2.5 kJ/mol, ΔS = 24.9 ± 1.7 J/mol∗K. In the system GdF3 - Gd2S3 the balance equations for five phase transformations recorded by the DSC method were compiled. Convergence was achieved in the liquidus of the system constructed according to DSC data and calculated with the use of the Redlich-Kister equation.
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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, Building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Pervomaiskaya str. 91, 620990, Russia
Доп.точки доступа:
Abulkhaev, M. U.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kertman, A. V.; Kamaev, D. N.; Trofimova, O. V.; Elyshev, A. V.; Andreev, O. V.
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