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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Ovchinnikova T. M., Dyad'kov P. G., Plotkin V. V., Litasov K. D.
Заглавие : Metallic layer in the Earth's lower mantle
Место публикации : JETP Letters. - 2012. - Vol. 96, Is. 2. - P.129-132. - ISSN 0021-3640, DOI 10.1134/S002136401214010X
Примечания : Cited References: 25. - We are thankful to Dr. V. I. Anisimov for discussions. This work was supported by the Presidium of the Russian Academy of Sciences (project no. 2.16); Siberian Branch, Russian Academy of Sciences (project nos. 96 and 97); and Russian Foundation for Basic Research (project no. 12-02-90410).
Предметные рубрики: ELECTRICAL-CONDUCTIVITY
MAGNESIOWUSTITE
MECHANISM
CORE
Аннотация: We predict the insulator-metal-insulator transitions for the temperature and pressure of the lower mantle with the metal layer thickness Delta h a parts per thousand 400 km at the depth of 1400-1800 km. The insulator-metal transition has the Mott-Hubbard origin, while the second transition from metal to insulator results from spin crossover of the Fe2+ ions from high spin S = 2 to low spin S = 0 state. The conductivity in the metal layer may attain 250 S/m. The depth profile of the conductivity is also suggested.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Plotkin V. V., Dyad'kov P. G., Ovchinnikov S. G.
Заглавие : Detecting a magnesiowustite phase transition in the lower mantle by inversion of geomagnetic data
Коллективы : Siberian Branch of the Russian Academy of Sciences [96]
Место публикации : Russ. Geol. Geophys.: Elsevier Science, 2014. - Vol. 55, Is. 9. - P.1138-1145. - ISSN 1068-7971, DOI 10.1016/j.rgg.2014.08.009. - ISSN 1878-030X
Примечания : Cited References: 26. - The study was supported by the Siberian Branch of the Russian Academy of Sciences (interdisciplinary integration project no. 96).
Предметные рубрики: ELECTRICAL-CONDUCTIVITY
SATELLITE MEASUREMENTS
EARTHS MANTLE
GLOBAL MVS
INDUCTION
FIELD
METALLIZATION
Ключевые слова (''Своб.индексиров.''): magnesiowustite--metallic state--phase transition--lower mantle--conductivity--geomagnetic variations--global network
Аннотация: Global geomagnetic data are inverted for detecting a high-conductivity layer at depths of 1500-2000 km to test the hypothesis of a magnesiowustite phase transition in the lower mantle. We present the results of processing of both synthetic and global data-average monthly values of the geomagnetic field from 1920 to 2009. The inverted global data are consistent with the possible existence of a high-conductivity layer at great depths in the lower mantle.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Ovchinnikova T. M., Plotkin V. V., Dyad'kov P. G.
Заглавие : Spin crossover and Mott-Hubbard transition under high pressure and high temperature in the low mantle of the Earth
Коллективы : International conference on interaction of intense energy fluxes , International Conference on Interaction of Intense Energy Fluxes with Matter (XXX; 1–6 March 2015; Elbrus, Kabardino-Balkaria, Russia)
Место публикации : J. Phys.: Conf. Ser./ International conference on interaction of intense energy fluxes (30 ; 2015 ; March ; 01-06): IOP Publishing, 2015. - Vol. 653. - Ст.012095. - ISSN 1742-6588, DOI 10.1088/1742-6596/653/1/012095
Примечания : Cited References:22
Предметные рубрики: PHASE-TRANSITION
GEOMAGNETIC DATA
MAGNESIOWUSTITE
IRON
METALLIZATION
LAYER
Аннотация: Effect of high pressure induced spin crossover on the magnetic, electronic and structural properties of the minerals forming the Earth's low mantle is discussed. The low temperature P, T phase diagram of ferropericlase has the quantum phase transition point P = 56 GPa at T = 0 confirmed recently by the synchrotron Mossbauer spectroscopy. The LDA+GTB calculated phase diagram describes the experimental data. Its extension to the high temperature resulted earlier in prediction of the metallic properties of the Earth's mantle at the depth 1400 km h 1800 km. Estimation of the electrical conductivity based on the percolation theory is given. We discuss also the thermodynamic properties and structural anomalies resulting from the spin crossover and metal insulator transition and compare them with the experimental seismic and geomagnetic field data.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G.
Заглавие : Metallization and spin crossover in Magnesiowustite (Mg1-x Fe (x) O) at high pressures
Разночтения заглавия :авие SCOPUS: Metallization and spin crossover in Magnesiowustite (Mg 1 - xFe xO) at high pressures
Место публикации : JETP Letters. - 2011. - Vol. 94, Is. 3. - P.192-196. - ISSN 0021-3640, DOI 10.1134/S0021364011150094
Примечания : Cited References: 25. - The work was supported by the Division of Physical Sciences, Russian Academy of Sciences (program "Strong Electron Correlations"), the Siberian and Ural Branches, Russian Academy of Sciences (joint project no. 40), the Russian Foundation for Basic Research (project nos. 09-02-00171 and 10-02-00251), and the Ministry of Education and Sciences (project no. KG P891, federal program "Human Resources"). I am grateful to Yu.S. Orlov, N.V. Lishneva, and I.A. Makarov for their assistance in this work.
Предметные рубрики: EARTHS MANTLE
TRANSITION
Аннотация: The pressure-temperature phase diagram of magnesiowustite has been constructed using the many-electron LDA+GTB approach. The phase diagram includes a quantum critical point at P (c) = 55 GPa and has a symmetrical distribution of high-spin and low-spin states. The existence of a metallic state in a narrow temperature range above the critical point is predicted.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva Y., Palyanov Y., Borzdov Y., Bayukov O. A.
Заглавие : Processes and conditions of the origin for Fe3+-bearing magnesiowustite under lithospheric mantle pressures and temperatures
Место публикации : Minerals. - 2019. - Vol. 9, Is. 8. - Ст.474. - ISSN 2075163X (ISSN), DOI 10.3390/min9080474
Примечания : Cited References: 82. - This research was performed by state assignment of IGM SB RAS (project No. 0330-2016-0007).
Предметные рубрики: Mineral Geochemistry and Geochronology
Аннотация: An experimental study, implicated in the revealing of the conditions for the origin for Fe3+-bearing magnesiowüstite in the lithospheric mantle, was performed using Mössbauer spectroscopy of pre-synthesized samples. Experiments were carried out using a multi-anvil high-pressure split-sphere apparatus at 6.3–7.5 GPa, in the range of 1100–1650 °C in carbonate-metal, carbonate–oxide-metal, carbonate-oxide, carbide-oxide and carbonate–metal-sulphur systems. In three experimental series, oxygen fugacity gradient in the samples was created, which enabled the study of the processes of magnesiowüstite formation under oxidizing and reducing conditions (ΔlogfO2 (FMQ) values from −1 to −5). It was established that Fe3+-bearing magnesiowüstite can form both in assemblage with oxidized phases, such as carbonate or with reduced ones—metal, carbides, sulphides, graphite and diamond. According to the Mössbauer spectroscopy, the composition of synthesized magnesiowüstite varied within a range of Fe3+/ΣFe values from 0 to 0.3, with IV and VI coordination of Fe3+ depending on P, T, fO2, x-parameters. It was established that Fe3+-bearing magnesiowüstite formation processes under upper mantle P,T-conditions include redox reactions, with magnesiowüstite being (1) reductant or (2) product of interaction, (3) crystallization processes of magnesiowüstite from an oxidized melt, where magnesiowüstite acts as a sink for ferric iron and (4) iron disproportionation.
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