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    Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: Structural and spectroscopic properties / C. S. Lim [et al.] // Dalton Trans. - 2016. - Vol. 45, Is. 39. - P. 15541-15551, DOI 10.1039/c6dt02378a. - Cited References: 71 . - ISSN 1477-9226
   Перевод заглавия: Тройной молибдат со структурой шеелита NaCaLa(MoO4)3:Er3+/Yb3+: структурные и спектроскопические свойства
Кл.слова (ненормированные):
Light emission -- Optical properties -- Phosphors -- Sol-gel process -- Sol-gels -- Tungstate minerals -- After-heat treatment -- Crystallized particles -- Homogeneous morphology -- Photoluminescence emission -- Spectroscopic property -- Triple molybdates -- Up-conversion emission -- Upconversion phosphors -- Optical emission spectroscopy
Аннотация: Triple molybdate NaCaLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.05 and y = 0.45, x = 0.1 and y = 0.2, x = 0.2 and y = 0) phosphors were successfully synthesized for the first time by the microwave sol-gel method. Well-crystallized particles formed after heat treatment at 900 °C for 16 h showed a fine and homogeneous morphology with particle sizes of 2-3 ?m. The structures were refined by the Rietveld method in the space group I41/a. The optical properties were examined comparatively using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the NaCaLa0.7(MoO4)3:0.1Er3+,0.2Yb3+ and NaCaLa0.5(MoO4)3:0.05Er3+,0.45Yb3+ particles exhibited a strong 525 nm emission band, a weaker 550 nm emission band in the green region, and three weak 655 nm, 490 nm and 410 nm emission bands in the red, blue and violet regions. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail. © 2016 The Royal Society of Chemistry.

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Держатели документа:
Department of Advanced Materials Science and Engineering, Hanseo University, Seosan, South Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation

Доп.точки доступа:
Lim, C. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Ikonnikov, D. A.; Atuchin, V. V.
}
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    Thermometry and up-conversion luminescence of Ln3+ (Ln = Er, Ho, Tm)-doped double molybdate LiYbMo2O8 / X. Y. Yun, J. Zhou, Y. H. Zhu [et al.] // J. Mater. Sci.: Mater. Electron. - 2020. - Vol. 31, Is. 21. - P. 18370-18380, DOI 10.1007/s10854-020-04382-8. - Cited References: 41. - This work is supported by the National Natural Science Foundation of China (No. 21576002 and 61705003) and Beijing Technology and Business University Research Team Construction Project (No. PXM2019_014213_000007) . - ISSN 0957-4522. - ISSN 1573-482X
   Перевод заглавия: Термометрия и апконверсионная люминесценции двойного молибдата LiYbMo2O8, легированного Ln (3+) (Ln = Er, Ho, Tm)

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
TEMPERATURE SENSING BEHAVIOR
   OPTICAL THERMOMETRY
   EMISSION
   PHOSPHOR
Аннотация: The discovery of stable and highly sensitive up-conversion (UC) phosphors using the fluorescence intensity ratio (FIR) is a significant challenge in the field of optical temperature sensor. Er3+/Ho3+/Tm3+-doped LiYbMo2O8 UC phosphors with excellent luminescence properties were successfully synthesized through a high-temperature solid-state reaction, and the crystal structure and UC luminescence properties were discussed in detail. The UC process has been investigated by spectra pump power dependence and further explained via the energy level diagram. All emission processes about Er3+ ions and Ho3+ ions are two-photon processes and the blue emission process about Tm3+ ions is a combination of two-photon process and three-photon process. Thermal sensing performances depended on FIR technology were estimated and the sensitivities of LiYb1−xMo2O8:xLn3+ included absolute sensitivity (Sa) and relative sensitivity (Sr) can produce particular change rules with the temperature, which can serve as excellent candidates for applications in optical temperature sensing. With the increase of temperature, the maximum values of Sr of LiYb1−xMo2O8:xLn3+ are 1.16% K−1 (0.05Er3+), 0.25% K−1 (0.01Ho3+), and 0.51% K−1 (0.01Tm3+), respectively. In addition, the Sa value of LiYb0.95Mo2O8:0.05Er3+ phosphor will reach the maximum (1.08% K−1) at 475 K, while the maximum values of Sa of LiYb0.99Mo2O8:0.01Ho3+ and LiYb0.99Mo2O8:0.01Tm3+ are 0.16% K−1, 0.14% K−1.

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Держатели документа:
Beijing Technol & Business Univ, Sch Sci, Beijing 100048, Peoples R China.
RAS, Fed Res Ctr, Kirensky Inst Phys, Lab Crystal Phys,KSC,SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Yun, Xiangyan; Zhou, Jun; Zhu, Yaohui; Molokeev, M. S.; Молокеев, Максим Сергеевич; Jia, Yetong; Wei, Chao; Xu, Denghui; Sun, Jiayue
}
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    Thallium ionic conductivity of new thallium indium hafnium molybdate ceramics / V. G. Grossman, J. G. Bazarova, M. S. Molokeev, B. G. Bazarov // Ionics. - 2020. - Vol. 26. - P. 6157-6165, DOI 10.1007/s11581-020-03739-7. - Cited References: 60. - This study was carried out within the state assignment of FASO of Russia (Theme No 0339-2016-0007) as well was supported by RFBR Grants 18-08-00799 and 18-03-00557 . - ISSN 0947-7047. - ISSN 1862-0760
   Перевод заглавия: Таллий-ионная проводимость новой керамики на основе таллия, индия, гафния, молибдата

РУБ Chemistry, Physical + Electrochemistry + Physics, Condensed Matter
Рубрики:
POSITIVE ELECTRODE MATERIAL
CRYSTAL-STRUCTURE
TRIPLE MOLYBDATE
Кл.слова (ненормированные):
Synthesis -- Thallium -- Molybdates -- Phase diagram -- DSC -- Conducting material
Аннотация: In the process of studying the system Tl2MoO4–In2(MoO4)3–Hf(MoO4)2, a new thallium indium hafnium molybdate was found. The crystal structure of the molybdate Tl5InHf(MoO4)6 was determined in the centrosymmetric space group R3¯c (a = 10.63893 (5) Å, c = 38.1447(3) Å; V = 3739.04 (4) Å3, Z = 6). The structure is a three-dimensional framework consisting of alternating (Hf,In)O6-octahedra connected by МоО4-tetrahedra. Each octahedron has common vertices with tetrahedra. The atoms arranged in this way form channels extended along with the a and b axes, in which thallium atoms are located. The conductivity behavior of Tl5InHf(MoO4)6 ceramics was studied in the temperature range from 300 to 870 K. The conductivity of the heavy cations of thallium is activated with increasing temperature.

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Держатели документа:
Russian Acad Sci, Baikal Inst Nat Management, Siberian Branch, Sakhyanovoy St 6, Ulan Ude 670047, Buryat Republic, Russia.
Russian Acad Sci, Fed Res Ctr KSC, Kirensky Inst Phys, Siberian Branch, 50-38 Akademgorodok, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 82 Svobodniy Av, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Grossman, Victoria G.; Bazarova, J. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; RFBRRussian Foundation for Basic Research (RFBR) [0339-2016-0007]; [18-08-00799]; [18-03-00557]
}
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Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)(2) / V. V. Atuchin [et al.] // J. Cryst. Growth. - 2011. - Vol. 318, Is. 1. - P. 683-686, DOI 10.1016/j.jcrysgro.2010.09.076. - Cited References: 26 . - ISSN 0022-0248

РУБ Crystallography + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
MOLYBDENUM TRIOXIDE
   DOUBLE MOLYBDATES
   CRYSTAL-STRUCTURE
   GROWTH
   LASER
   MOO3
Кл.слова (ненормированные):
Crystal structure -- Solid state synthesis -- Molybdate
Аннотация: Rubidium neodymium dimolybdate, RbNd(MoO4)(2), microcrystals have been fabricated by solid state synthesis at T=550-600 degrees C by t=324 ks. Crystal structure of RbNd(MoO4)(2) has been refined by Rietveld method in space group Pbcn with cell parameters a = 5.1772(1) angstrom, b = 18.7293(4) angstrom, and c = 8.2774(1) angstrom (R-B=5.05%). The crystal structure of RbNd(MoO4)(2) consists of layers of MoO4 tetrahedrons cornersharing with NdO8 square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO4)(2) powder sample. (C) 2010 Elsevier B.V. All rights reserved.

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Доп.точки доступа:
Atuchin, V. V.; Chimitova, O. D.; Gavrilova, T. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kim, S. J.; Surovtsev, N. V.; Bazarov, B. G.; Базаров Б.Г.; Bazarova, Zh.G.; Базарова Ж.Г.; International Conference on Crystal Growth(16 ; 2010 ; Aug. ; 08-13 ; Beijing, China); International Conference on Vapor Growth and Epitaxy(14 ; 2010 ; Aug. ; 08-13 ; Beijing, China)
}
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    Synthesis, structural and spectroscopic properties of acentric triple molybdate Cs2NaBi(MoO4)3 / A. A. Savina [et al.] // J. Solid State Chem. - 2015. - Vol. 225. - P. 53–58, DOI 10.1016/j.jssc.2014.11.023. - Cited References: 66. - The authors are grateful to Dr. K.M. Khal'baeva and Dr. Irina A. Gudkova for their assistance in preparing the compound and taking X-ray single-crystal diffraction data. This study is partly supported by the Russian Foundation for Basic Research (Grants 13-03-01020 and 14-03-00298). V.V.A., A.S.K. and A.S.O. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for a partial financial support. . - ISSN 0022-4596. - ISSN 1095-726X
   Перевод заглавия: Синтез, структурные и спектроскопические свойства ацентричного тройного молибдата Cs2NaBi(MoO4)3

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
CRYSTAL-STRUCTURE
   SINGLE-CRYSTALS
   VIBRATIONAL PROPERTIES
   RAMAN-SPECTROSCOPY
   HYDROTHERMAL SYNTHESIS
   DIELECTRIC-PROPERTIES
   SELECTIVE OXIDATION;
   BISMUTH MOLYBDATES
   IONIC-CONDUCTIVITY
   OPTICAL-PROPERTIES
Кл.слова (ненормированные):
Triple molybdate -- Sodium -- Cesium -- Bismuth -- Crystal structure -- Raman spectroscopy -- CRYSTAL-STRUCTURE -- SINGLE-CRYSTALS -- VIBRATIONAL PROPERTIES -- RAMAN-SPECTROSCOPY -- HYDROTHERMAL SYNTHESIS -- DIELECTRIC-PROPERTIES -- SELECTIVE OXIDATION; -- BISMUTH MOLYBDATES -- IONIC-CONDUCTIVITY -- OPTICAL-PROPERTIES
Аннотация: New ternary molybdate Cs2NaBi(MoO4)3 is synthesized in the system Na2MoO4–Cs2MoO4–Bi2(MoO4)3. The structure of Cs2NaBi(MoO4)3 of a new type is determined in noncentrosymmetric space group R3c, a=10.6435(2), c=40.9524(7) Å, V=4017.71(13) Å3, Z=12 in anisotropic approximation for all atoms taking into account racemic twinning. The structure is completely ordered, Mo atoms are tetrahedrally coordinated, Bi(1) and Bi(2) atoms are in octahedra, and Na(1) and Na(2) atoms have a distorted trigonal prismatic coordination. The Cs(1) and Cs(2) atoms are in the framework cavities with coordination numbers 12 and 10, respectively. No phase transitions were found in Cs2NaBi(MoO4)3 up to the melting point at 826 K. The compound shows an SHG signal, I2w/I2w(SiO2)=5 estimated by the powder method. The vibrational properties are evaluated by Raman spectroscopy, and 26 narrow lines are measured.

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Держатели документа:
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Dept Chem, Ulan Ude 670000, Russia.
SB RAS, Rzhanov Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Crystal Chem, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Mol Spectroscopy, Krasnoyarsk 660036, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Epitaxial Layers, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Res Methods Composit & Struct Funct Mat, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Crystal Struct, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
SB RAS, Inst Automat & Elect, Lab Condenced Matter Spectroscopy, Novosibirsk 630090, Russia.

Доп.точки доступа:
Savina, A. A.; Atuchin, V. V.; Solodovnikov, S. F.; Solodovnikova, Z. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Maximovsky, E. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, A. M.; Khaikina, E. G.; Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
}
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    Synthesis, crystal structures, and properties of new acentric glaserite-related compounds Rb7Ag5–3xSc2+x(XO4)9 (X = Mo, W) / T. S. Spiridonova, S. F. Solodovnikov, M. S. Molokeev [et al.] // J. Solid State Chem. - 2022. - Vol. 305. - Ст. 122638, DOI 10.1016/j.jssc.2021.122638. - Cited References: 71. - This research was supported by the Ministry of Science and Higher Education of the Russian Federation , projects No. 0273-2021-0008 (Baikal Institute of Nature Management, SB RAS), and No. 121031700313-8 (Nikolaev Institute of Inorganic Chemistry, SB RAS), as well as partial financial support from the Russian Foundation for Basic Research (project No. № 20-03-00533) . - ISSN 0022-4596
   Перевод заглавия: Синтез, кристаллическая структура и свойства новых ацентрических соединений Rb7Ag5–3xSc2+x(XO4)9 (X = Mo, W), родственных глазериту
Кл.слова (ненормированные):
Rubidium -- Silver -- Scandium -- Triple molybdate -- Triple tungstate -- Phase equilibria -- Synthesis -- Crystal structure -- Ionic conductivity
Аннотация: The subsolidus phase equilibria in the system Ag2MoO4–Rb2MoO4–Sc2(MoO4)3 were studied and two new triple molybdates, Rb9Ag3Sc2(MoO4)9 and Rb7Ag5Sc2(MoO4)9, were found. The structures of Rb7Ag5Sc2(MoO4)9 and isostructural Rb7Ag5Sc2(WO4)9 of the Cs7Na5Yb2(MoO4)9 type (the space group R32) were determined. The found composition of the triple tungstate crystal, Rb7Ag4.61Sc2.13(WO4)9, indicates a non-stoichiometric compound formula, Rb7Ag5–3xSc2+x(WO4)9. Both structures have one incompletely occupied Ag site, and structure Rb7Ag4.61Sc2.13(WO4)9 also contains two positions with mixed Ag and Sc. Both compounds contain ‘lanterns’ [M2(XO4)9] (M = (Sc, Ag), Sc; X = Mo, W), which are strengthened by three AgO2 dumbbells to give isolated building blocks [Ag3M2(XO4)9] forming two-story hexagonal layers resembling the structure of glaserite K3Na(SO4)2. Similar layers of [Ag3Sc2(WO4)9]9− building blocks were also found by us in the structure of Rb9–xAg3+xSc2(WO4)9, which is close to that of Rb9Ag3Sc2(MoO4)9. Similar layers of the [M2(TO4)9] units were also observed in Cs7Na5Yb2(MoO4)9 and Na13Sr2Ta2(PO4)9. The title compounds belong to the series of rhombohedral triple molybdates and tungstates with a ≈ 9–10 Å and large c-periods (more than 20 Å), which have layered or open 3D framework structures. Like many compounds of this series, Rb7Ag5Sc2(XO4)9 (Х = W, Mo) at elevated temperatures have significant ionic conductivity reaching values 6.1·10−3 S cm−1 at 703 K (X = Mo) and 1.4·10−3 S cm−1 at 733 K (X = W) with Еа = 0.7 eV and 0.6 eV, respectively.

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Держатели документа:
Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Sakh'yanova St. 6, Buryat Republic, Ulan-Ude, 670047, Russian Federation
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Akad. Lavrentyev Ave. 3, Novosibirsk630090, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok 50 bld.38, Krasnoyarsk, 660036, Russian Federation
Kemerovo State University, Krasnaya St., 6, Kemerovo, 650000, Russian Federation
Skolkovo Institute of Science and Technology, Moscow121205, Russian Federation

Доп.точки доступа:
Spiridonova, T. S.; Solodovnikov, S. F.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Solodovnikova, Z. A.; Savina, A. A.; Kadyrova, Y. M.; Sukhikh, A. S.; Kovtunets, E. V.; Khaikina, E. G.
}
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    Synthesis and spectroscopic properties of multiferroic β΄-Tb2(MoO4)3 / V. V. Atuchin [et al.] // Opt. Mater. - 2014. - Vol. 36, Is. 10. - P. 1631–1635, DOI 10.1016/j.optmat.2013.12.008. - Cited References: 43. - This study was partly supported by SB RAS under Projects 28.13 and 24.31, and by the PSB RAS Project No. 3.9.5b, and RFBR Projects . - ISSN 0925-3467. - ISSN 1873-1252
   Перевод заглавия: Синтез и спектроскопические свойства мультиферроика β'-Tb2(MoO4)3
Рубрики:
FERROELECTRIC-FERROELASTIC Tb2(MoO4)3
   STIMULATED RAMAN-SCATTERING
   TRANSITION-METAL MOLYBDATES
   RARE-EARTH MOLYBDATES
   CRYSTAL-STRUCTURE
   VIBRATIONAL PROPERTIES
   LUMINESCENCE PROPERTIES
   Tb-2(MoO4)3 CRYSTALS
   TERBIUM MOLYBDATE
   PHASE-TRANSITIONS
Кл.слова (ненормированные):
Terbium molybdate -- Raman spectrum -- Optical properties
Аннотация: Orthorhombic terbium molybdate, β΄-Tb2(MoO4)3, microcrystals have been fabricated by solid state synthesis at T = 750-1270 K for t = 290 h. The crystal structure β΄-Tb2(MoO4)3 has been refined by Rietveld method in space group Pba2 with cell parameters of a = 10.35387(6), b = 10.38413(6) and c = 10.65695(7) A (RB = 1.83%). About 40 narrow Raman lines have been observed in the Raman spectrum recorded for the β΄-Tb2(MoO4)3 powder sample. The luminescence spectrum of β΄-Tb2(MoO4)3 has been measured under the excitation at 355 nm, and the intensive photoluminescence band at 540-550 nm has been found. В© 2013 Elsevier Ltd. All rights reserved.

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Доп.точки доступа:
Grinberg, M. \ed.\; Bojarski, P. \ed.\; Suchocki, A. \ed.\; Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O. D.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Xia, Zhiguo; International Workshop on Advanced Spectroscopy and Optical Materials (4th ; 14–19 July 2013 ; Gdańsk, Poland)
}
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    Synthesis and spectroscopic properties of monoclinic α-Eu2(MoO4)3 / V. V. Atuchin [et al.] // J. Phys. Chem. C. - 2014. - Vol. 118, Is. 28. - P. 15404-15411, DOI 10.1021/jp5040739. - Cited References: 63. - This study is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1932-7447
   Перевод заглавия: Синтез и спектроскопические свойства моноклинного а-Eu2(MoO4)3

РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
RARE-EARTH MOLYBDATES
   VIBRATIONAL PROPERTIES
   LUMINESCENCE PROPERTIES
   CRYSTAL-STRUCTURE
   PHASE-TRANSITIONS
   TRIPLE MOLYBDATE
   SINGLE-CRYSTAL
   X-RAY
   PHOSPHORS
   EUROPIUM
Аннотация: The microcrystals of monoclinic europium molybdate, alpha-Eu-2(MoO4)(3), have been fabricated by solid-state synthesis at T = 753-1273 K for 300 h. The crystal structure of alpha-Eu-2(MoO4)(3) has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) angstrom, and beta = 109.278(1)degrees (R-B = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the alpha-Eu-2(MoO4)(3) powder sample. The luminescence spectra of alpha-Eu-2(MoO4)(3) under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition D-5(0) - F-7(2) and the presence of ultranarrow lines at D-5(0) - F-7(0) and D-5(1) - F-7(0) transitions.

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
SB RAS, Lab Coherent Opt, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
SB RAS, Lab Oxide Syst, Baikal Inst Nat Management, Ulan Ude 670047, Russia
SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia
SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk 660036, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia

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Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O. D.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Ministry of Education and Science of the Russian Federation
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Synthesis and electronic structure of orthorhombic molybdate RbNd(MoO4)2 / V. V. Atuchin [et al.] // The 3rd Int. Conf. on the Physics of Optical Materials and Devices. ICOM 2012 : book of abstracts. - 2012. - P. 209

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Базаров, Б.Г.; Chimitova, O. D.; Bekenev, V. L.; Khyzhun, O. Yu.; Bazarova, Zh. G.; Базарова, Ж. Г.; Vinča Institute of Nuclear Sciences,; University of Belgrade; Laboratoire de Chimie de la Matière Condensée de Paris; International Conference on the Physics of Optical Materials and Devices(3 ; 2012 ; Sept. ; 3-6 ; Belgrade, Serbia)
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10.

    Synthesis and electronic properties of β-RbNd(MoO4)2 / V. V. Atuchin [et al.] // Asian J. Chem. - 2014. - Vol. 26, No. 5. - P. 1284-1286, DOI 10.14233/ajchem.2014.17209. - Cited References: 26. - This study is partly supported by by the Ministry of Education and Science of the Russian Federation. . - ISSN 0970-7077
   Перевод заглавия: Синтез и электронные свойства бета-RbNd(MoO4)2

РУБ Chemistry, Multidisciplinary
Рубрики:
UP-CONVERSION PHOTOLUMINESCENCE
   VIBRATIONAL PROPERTIES
   CRYSTAL-STRUCTURE
   PARTICLES
   MOLYBDATE
   SPECTROSCOPY
   SYSTEM
   ER3+
Кл.слова (ненормированные):
β-RbNd(MoO4)2 -- Electronic structure -- Ab initio calculations -- X-Ray photoelectron spectroscopy
Аннотация: The electronic structure of β-RbNd(MoO4)2 has been evaluated from experimental and theoretical points of view. For the molybdate, X-ray photoelectron valence-band spectra have been measured. The total and partial densities of states of the constituent atoms of β-RbNd(MoO4)2 have been calculated using the FP-LAPW method. The FP-LAPW data reveal that main contributors in the valence-band region of β-RbNd(MoO4)2 are the Rb 4p-, Nd 4f-, Mo 4d- and O 2p-like states.

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Держатели документа:
SB RAS, Lab Opt Mat & Struct, Inst Semicond Phys, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Novosibirsk 630090, Russia
Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, UA-03142 Kiev, Ukraine
SB RAS, Lab Oxide Syst, Baikal Inst Nat Management, Ulan Ude 670047, Russia
SB RAS, Lab Crystal Phys, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Hanseo Univ, Dept Adv Mat Sci & Engn, Seosan 356706, South Korea

Доп.точки доступа:
Atuchin, V. V.; Bekenev, V. L.; Chimitova, O. D.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; Базаров Б. Г.; Bazarova, J. G.; Базарова Ж. Г.; Khuzhum, O. Y.; Lim, C. S.
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