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Aleksandrov, K. S.
Spectroscopic investigation of phase transitions in CsLiMoO//4 crystals. / K. S. Aleksandrov, Yu. N. Ivanov, A. D. Schafer // Ferroelectrics. - 1983. - Vol. 55, Is. 1. - P. 671-674 . - ISSN 0015-0193
Кл.слова (ненормированные):
CRYSTALS - Structure -- MAGNETIC RESONANCE -- SPECTROSCOPY, RAMAN -- CESIUM LITHIUM MOLYBDATE -- PHASE TRANSITIONS -- FERROELECTRIC MATERIALS
Аннотация: Raman and NMR spectra in cubic and two distorted phases of CsLiMoO//4 have been studied. Phase transitions in the crystal are shown to belong to order-disorder type.

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Доп.точки доступа:
Ivanov, Y. N.; Иванов, Юрий Николаевич; Schafer, A. D.; Александров, Кирилл Сергеевич; European Meeting on Ferroelectricity(5 ; 1983 ; Sept. ; 26-30 ; Malaga, Sp)
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    Electronic structure of β-RbNd(MoO4)2 by XPS and XES / V. V. Atuchin [et al.] // J. Phys. Chem. Solids. - 2015. - Vol. 77. - P. 101-108, DOI 10.1016/j.jpcs.2014.09.012. - Cited References: 52. - This study was partially supported by the Ministry of Education and Science of the Russian Federation and RFBR Grant 12-02-90806-mol_rf_nr. . - ISSN 0022-3697
   Перевод заглавия: Электронная структура b-RbNd(MoO4)2, исследованная при помощи РФЭС и РСМА

РУБ Chemistry, Multidisciplinary + Physics, Condensed Matter
Рубрики:
RAY-EMISSION-SPECTROSCOPY
   CRYSTAL-STRUCTURE
   PHOTOELECTRON-SPECTROSCOPY
   LUMINESCENCE PROPERTIES
   VIBRATIONAL PROPERTIES
   PHOTOEMISSION SPECTRA
   OPTICAL-PROPERTIES
   TERNARY MOLYBDATE
   AB-INITIO
   SYSTEM
Кл.слова (ненормированные):
Inorganic compounds -- Chemical synthesis -- Photoelectron spectroscopy -- X-ray diffraction -- Electronic structure
Аннотация: β-RbNd(MoO4)2 microplates have been prepared by the multistage solid state synthesis method. The phase composition and micromorphology of the final product have been evaluated by XRD and SEM methods. The electronic structure of β-RbNd(MoO4)2 molybdate has been studied employing the X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES). For the molybdate, the XPS core-level and valence-band spectra, as well as XES bands representing energy distribution of the Mo 4d- and O 2p-like states, have been measured. It has been established that the O 2p-like states contribute mainly to the upper portion of the valence band with also significant contributions throughout the whole valence-band region. The Mo 4d-like states contribute mainly to a lower valence band portion

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, UA-03142 Kiev, Ukraine
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia

Доп.точки доступа:
Atuchin, V. V.; Khyzhun, O. Y.; Chimitova, O. D.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Gavrilova, T. A.; Bazarov, B. G.; Bazarova, J. G.; Ministry of Education and Science of the Russian Federation; RFBR [12-02-90806-mol_rf_nr]
}
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    Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units / V. V. Atuchin, A. S. Aleksandrovsky, B. G. Bazarov [et al.] // J. Alloy. Compd. - 2019. - Vol. 785. - P. 692-697, DOI 10.1016/j.jallcom.2019.01.013. - Cited References: 42. - The reported study was funded by RFBR according to research projects 16-52-48010, 17-52-53031 and 18-03-00557. Besides, this study was supported by the Ministry of Science and Higher Education of the Russian Federation (project 0339-2016-0007). The work was supported by Act 211 Government of the Russian Federation, contract No 02.A03.21.0011. Additionally, the work was partially supported by the Ministry of Education and Science of the Russian Federation (4.1346.2017/4.6). . - ISSN 0925-8388. - ISSN 1873-4669
   Перевод заглавия: Исследование структурных, колебательных и спектроскопических свойств самоактивированного орторомбического двойного молибдата RbEu(MoO4)2 с изолированными группами MoO4

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
MORPHOLOGY-CONTROLLED SYNTHESIS
LUMINESCENCE PROPERTIES
Кл.слова (ненормированные):
Rubidium europium molybdate -- Solid state reaction -- Rietveld refinement -- DSC -- Raman luminescence
Аннотация: RbEu(MoO4)2 is synthesized by the two-step solid state reaction method. The crystal structure of RbEu(MoO4)2 is defined by Rietveld analysis in space group Pbcn with cell parameters a = 5.13502(5), b = 18.8581(2) and c = 8.12849(7) Å, V = 787.13(1) Å3, Z = 4 (RB = 0.86%). This molybdate possesses its phase transition at 817 K and melts at 1250 K. The Raman spectra were measured with the excitation at λ = 1064 and 514.5 nm. The photoluminescence spectrum is evaluated under the excitation at 514.5 nm. The absolute domination of hypersensitive 5D0→7F2 transition is observed. The ultranarrow 5D0→7F0 transition in RbEu(MoO4)2 is positioned at 580.2 nm being 0.2 nm blue shifted, with respect to that in Eu2(MoO4)3.

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Держатели документа:
SB RAS, Lab Opt Mat & Struct, Inst Semicond Phys, Novosibirsk, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
South Ural State Univ, Lab Single Crystal Growth, Chelyabinsk 454080, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
SB RAS, Kirensky Inst Phys, Lab Coherent Opt, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Ulan Ude 670000, Russia.
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys Fed Res Ctr KSC, Lab Mol Spect, Krasnoyarsk 660036, Russia.
SB RAS, Inst Inorgan Chem, Lab Funct Films & Coatings, Novosibirsk 630090, Russia.
SB RAS, Lab Crystal Phys, Kirensky Inst Phys, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Siberian Fed Univ, Krasnoyarsk 660079, Russia.
SB RAS, Inst Automat & Elect, Lab Condensed Matter Spect, Novosibirsk 630090, Russia.

Доп.точки доступа:
Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Chimitova, Olga D.; Denisenko, Yuriy G.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Maximovskiy, Eugene A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, Alexey M.; Surovtsev, Nikolay V.; RFBR [16-52-48010, 17-52-53031, 18-03-00557]; Ministry of Science and Higher Education of the Russian Federation [0339-2016-0007]; Act 211 Government of the Russian Federation [02.A03.21.0011]; Ministry of Education and Science of the Russian Federation [4.1346.2017/4.6]
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Exploration of the structural and vibrational properties of the ternary molybdate Tl5BiHf(MoO4)6with isolated MoO4 units and Tl+ conductivity / V. Grossman, S. V. Adichtchev, V. V. Atuchin [et al.] // Inorg. Chem. - 2020. - Vol. 59, Is. 17. - P. 12681-12689, DOI 10.1021/acs.inorgchem.0c01762. - Cited References: 69. - This study was supported by the Russian Science Foundation (19-42-02003, in the part of conceptualization). The study was also funded by the RFBR according to research projects 18-08-00985, 18-08-00799, and 18-03-00557. This study was carried out within the state assignment of the FASO of Russia (Theme No. 0339-2016-0007) . - ISSN 0020-1669
Аннотация: The phase relations in the subsolidus region of the Tl2MoO4–Bi2(MoO4)3–Hf(MoO4)2 system were studied with the “intersecting cuts” method. The formation of the novel ternary molybdate Tl5BiHf(MoO4)6 is found in this ternary system. The compound has a phase transition at Tpt = 731 K (ΔH = −3.15 J/g) and melts at Tm = 871 K (ΔH = −41.71 J/g), as determined by a thermal analysis. Tl5BiHf(MoO4)6 single crystals were obtained by the spontaneous nucleation method. The crystal structure of Tl5BiHf(MoO4)6 was revealed by structure analysis methods. This molybdate crystallizes in the trigonal space group R3̅c with the unit cell parameters a = 10.6801(4) Å, c = 38.5518(14) Å, V = 3808.3(2) Å3, and Z = 6. The vibrational characteristics of Tl5BiHf(MoO4)6 were determined by Raman spectroscopy. The Tl5BiHf(MoO4)6 conductivity was measured at frequencies of 0.1, 1.0, and 10 kHz in the temperature range of 293–773 K; in this temperature range, the conductivity level was 10–12–10–7 S/cm.

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Держатели документа:
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, 670047, Russian Federation
Laboratory of Condensed Matter Spectroscopy, Institute of Automation and Electrometry, SB RAS, Novosibirsk, 630090, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
Buryat State University, Ulan-Ude, 670000, Russian Federation
Laboratory of Crystal Chemistry, Institute of Inorganic Chemistry, SB RAS, Novosibirsk, 630090, Russian Federation
Laboratory for Research Methods in Composition and Structure of Functional Materials, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660079, Russian Federation

Доп.точки доступа:
Grossman, V.; Adichtchev, S. V.; Atuchin, V. V.; Bazarov, B. G.; Bazarova, J. G.; Kuratieva, N.; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pervukhina, N. V.; Surovtsev, N. V.
}
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Ferroelectricity in caesium lithium molybdate CsLiMoO4 and related crystals CsLiWO4 and RbLiMoO4 / K. S. Aleksandrov [и др.] // Ferroelectrics. - 1981. - Vol. 36, Is. 1. - P. 399-402, DOI 10.1080/00150198108218138 . - ISSN 0015-0193
Кл.слова (ненормированные):
CESIUM COMPOUNDS -- RUBIDIUM COMPOUNDS -- CESIUM LITHIUM MOLYBDATE -- CESIUM LITHIUM TUNGSTATE -- PHASE TRANSITIONS -- RUBIDIUM LITHIUM MOLYBDATE -- FERROELECTRIC MATERIALS
Аннотация: Successive ferroelectric phase transitions were discovered in CsLiMoO//4, CsLiWO//4 and RbLiMoO//4 single crystals. Strong elastic and no dielectric anomalies were found with temperature lowering in the initial cubic phases. The phase transitions are qualitatively described as pseudoproper ferroelectric ones.

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Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; ANISTRATOV, A. T.; Melnikova, S. V.; Мельникова, Светлана Владимировна; Klevtsov, P. V.; Kruglik, A. I.; Voronov, V. N.; Воронов, Владимир Николаевич; International meeting on ferroelectricity(5 ; 1981 ; 17-21 Aug. ; Universal Park, USA)
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Ferroelectricity in CS-Li molybdate crystals / K. S. Aleksandrov [и др.] // Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 4. - P. 1094-1101. - Cited References: 9 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

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Публикация на русском языке Сегнетоэлектричество в кристаллах цезий-литий молибдата [Текст] / К. С. Александров [и др.] // Физ. тверд. тела. - 1982. - Т. 24 Вып. 4. - С. 1094-1101

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Anistratov, A. T.; Melnikova, S. V.; Мельникова, Светлана Владимировна; Kruglik, A. I.; Круглик, Анатолий Иванович; Zherebtsova, L. I.; Shabanova, L. A.; Шабанова Л. А.
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    Incommensurately modulated structure and spectroscopic properties of CaGd2(MoO4)4:Ho3+/Yb3+ phosphors for up-conversion applications / C. S. Lim [et al.] // J. Alloys Compd. - 2017. - Vol. 695. - P. 737-746, DOI 10.1016/j.jallcom.2016.06.134. - Cited References: 60. - This research was supported by the Basic Science Research Program through the National Research Foundation of Korea funded by the Ministry of Education (2015-058813) and the Russian Foundation for Basic Research (15-52-53080). VVA, ASA and ASO were partially supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 0925-8388
   Перевод заглавия: Несоразмерно модулированная структура и спектроскопические свойства люминофоров CaGd2(MoO4)4:Ho3+/Yb3+ для апконверсионного применения
Кл.слова (ненормированные):
Modulation -- Molybdate -- Raman -- Sol-gel synthesis -- Upconversion -- XRD
Аннотация: CaGd2(MoO4)4:Ho3+/Yb3+ phosphors doped by Ho3+ and Yb3+ (Ho3+ = 0 and 0.05, and Yb3+ = 0, 0.35, 0.40, 0.45 and 0.50) were successfully synthesized by the microwave sol-gel method. The synthesized particles, being formed after heat-treatment at 900 °C for 16 h, showed a well crystallized morphology. All compounds are (3 + 2)D incommensurately modulated with superspace group I41/a(α,β,0)00(-β,α,0)00. It was found that parameter (α2 + β2)1/2 is proportional to cell parameter a for all studied compositions and, therefore, modulation vector k is the same for all known CaRE2(MoO4)4 compounds. The modulation vector invariance is a specific and valuable feature of this type of the structure. Under the excitation at 980 nm, the doped particles exhibited the yellow emission composed of green (545-nm) and red (655-nm) emission bands due to frequency upconversion (UC). The pump power dependence and CIE chromaticity of the UC emission were evaluated. The shape of UC bands in CaGd2(MoO4)4:Ho3+/Yb3+ is dependent on the Yb content due to the influence of the crystal field affecting a holmium ion. 13 Raman-active modes of the CaGd2(MoO4)4 lattice were identified via a comparison of experimental Raman spectra and the lattice dynamics simulation results. Four additional Raman lines were found in the region of stretching vibrations and, at least, two additional modes are present in the bending mode region. These additional modes are ascribed to incommensurate crystal lattice modulation. Luminescence bands of Ho ions are severely broadened due to a statistical disorder in the CaGd2−xYby (MoO4)4 lattice.

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Держатели документа:
Department of Advanced Materials Science & Engineering, Hanseo University, Seosan, South Korea
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Lim, C. S.; Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич
}
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    Microwave sol-gel synthesis, microstructural and spectroscopic properties of scheelite-type ternary molybdate upconversion phosphor NaPbLa(MoO4)3:Er3+/Yb3+ / C. S. Lim [et al.] // J. Alloys Compd. - 2020. - Vol. 826. - Ст. 152095, DOI 10.1016/j.jallcom.2019.152095. - Cited References: 53. - This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2018R1D1A1A09082321). This study was supported by the Russian Science Foundation (19-42-02003, in part of conceptualization). Also, this study was supported by RFBR (18-32-20011, 18-03-00750). . - ISSN 0925-8388. - ISSN 1873-4669
   Перевод заглавия: Микроволновый золь-гель синтез, микроструктурные и спектроскопические свойства апконверсионного люминофора тройного молибдата NaPbLa(MoO4)3:Er3+/Yb3+ со структурой шеелита
Кл.слова (ненормированные):
Optical materials -- Chemical synthesis -- Molybdate -- Raman spectroscopy -- X-ray diffraction -- Phosphors
Аннотация: New ternary molybdate NaPbLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.05 and y = 0.35, 0.4, 0.45 and 0.5) phosphors were successfully fabricated by the MSG (microwave sol-gel) method, and the microstructural and spectroscopic properties were characterized. The crystal structure of NaPbLa(MoO4)3 (NPLM) was defined by Rietveld analysis in space group I41/a with unit cell parameters a = 5.3735(2) and c = 11.8668(4) Å, V = 342.65(3) Å3, Z = 4 (RB = 6.64%). The unit cell volume of NaPbLa(MoO4)3 (NPLM) was intermediate between those of NaLa(MoO4)2 and PbMoO4. Under the 980 nm excitation, upconverted yellowish-green emissions at transitions from 2H11/2 and 4S3/2 were observed. No concentration quenching in the subsystem of donor ions at the content up to 50 at.% and no cross-relaxation losses in the subsystem of acceptor ions at the concentrations as high as 5 at. % were verified. The individual chromaticity points for the NaPbLa(MoO4)3:Er3+,Yb3+ phosphors, corresponding to the equal-energy point in the standard CIE diagram, revealed yellowish-green emissions.

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Держатели документа:
Department of Aerospace Advanced Materials & Chemical Engineering, Hanseo University, Seosan, 356-706, Republic of Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russia
Functional Electronics Laboratory, Tomsk State University, Tomsk, 634050, Russia
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Lim, Chang Sung; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич
}
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    Microwave synthesis and spectroscopic properties of ternary scheelite-type molybdate phosphors NaSrLa(MoO4)3:Er3+,Yb3+ / C. S. Lim [et al.] // J. Alloys Compd. - 2017. - Vol. 713. - P. 156-163, DOI 10.1016/j.jallcom.2017.04.060. - Cited References: 87. - This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2016-944122) and by Project № 0356-2015-0412 of SB RAS Program №II.2P. The reported study was funded by RFBR according to the research project 16-52-48010 and 17-52-53031. Also, the work was supported by Act 211 Government of the Russian Federation, contract 02.A03.21.0011 and by the Ministry of Education and Science of the Russian Federation (4.1346.2017/PP). . - ISSN 0925-8388
   Перевод заглавия: Микроволновый синтез и спектроскопические свойства тройных шеелитоподобных молибденовых люминофоров NaSrLa(MoO4)3:Er3+,Yb3+
Кл.слова (ненормированные):
Microwave synthesis -- Crystal structure -- Molybdate phosphor -- Frequency up conversion
Аннотация: Ternary scheelite-type molybdate NaSrLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.1 and y = 0.2, x = 0.05 and y = 0.45, x = 0.2 and y = 0) phosphors were successfully synthesized by the microwave sol-gel method for the first time. Well-crystallized particles formed after the heat-treatment at 900 °C for 16 h showed a fine and homogeneous morphology with a particle size of 2–3 ?m. The crystal structures were refined by the Rietveld method in space group I41/a. The optical properties were examined comparatively using photoluminescence emission and Raman spectroscopy. Under the excitation at 980 nm, the NaSrLa0.7(MoO4)3:0.1Er3+,0.2Yb3+ and NaSrLa0.5(MoO4)3:0.05Er3+,0.45Yb3+ particles exhibited a strong 525-nm emission band, a weaker 550-nm emission band in the green region and weak 655-nm, 490-nm and 410-nm emission bands in the red, blue and violet regions. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail. The presence of Sr in NaSrLa(MoO4)3, in comparison with NaCaLa(MoO4)3 compound, leads to frequency shift mainly in the low region of Raman spectra. The MoO4 bending vibrations are most susceptible to changes in the distance between the nearest oxygen atoms in the nearest neighboring MoO4 groups.

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Держатели документа:
Department of Advanced Materials Science & Engineering, Hanseo University, Seosan, South Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian State University, Krasnoyarsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation
Laboratory of Single Crystal Growth, South Ural State University, Chelyabinsk, Russian Federation

Доп.точки доступа:
Lim, C. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Atuchin, V. V.
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10.

    Microwave-employed sol–gel synthesis of scheelite-type microcrystalline AgGd(MoO4)2:Yb3+/Ho3+ upconversion yellow phosphors and their spectroscopic properties / C. S. Lim, A. Aleksandrovsky, V. Atuchin [et al.] // Crystals. - 2020. - Vol. 10, Is. 11. - Ст. 1000. - P. 1-14, DOI 10.3390/cryst10111000. - Cited References: 58. - This study was supported by the Research Program through the Campus Research Foundation funded by Hanseo University in 2020 (201Yunghap09) . - ISSN 2073-4352
   Перевод заглавия: Микроволновый золь-гель синтез микрокристаллических апконверсионных желтых люминофоров AgGd(MoO4)2: Yb3+/ Ho3+ со структурой типа шеелита и их спектроскопические свойства
Кл.слова (ненормированные):
Microwave sol–gel -- Double molybdate -- Yellow phosphors -- Upconversion -- Spectroscopic properties
Аннотация: AgGd(MoO4)2:Ho3+/Yb3+ double molybdates with five concentrations of Ho3+ and Yb3+ were synthesized by the microwave employed sol–gel based process (MES), and the crystal structure variation, concentration effects, and spectroscopic characteristics were investigated. The crystal structures of AgGd1−x−yHoxYby(MoO4)2 (x = 0, 0.05; y = 0, 0.35, 0.4, 0.45, 0.5)at room temperature were determined in space group I41/a by Rietveld analysis. Pure AgGd(MoO4)2 has a scheelite-type structure with mixed occupations of (Ag,Gd) sites and cell parameters a = 5.24782 (11) and c = 11.5107 (3) Å, V = 317.002 (17) Å3, Z = 4. In doped samples, the sites are occupied by a mixture of (Ag,Gd,Ho,Yb) ions, which provides a linear cell volume decrease with the doping level increase. Under the excitation at 980 nm, AGM:0.05Ho,yYb phosphors exhibited a yellowish green emission composed of red and green emission bands according to the strong transitions 5F5 → 5I8 and 5S2/5F4 → 5I8 of Ho3+ ions. The evaluated photoluminescence and Raman spectroscopic results were discussed in detail. The upconversion intensity behavior dependent on the Yb/Ho ratio is explained in terms of the optimal number of Yb3+ ions at the characteristic energy transfer distance around the Ho3+ ion.

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Держатели документа:
Department of Aerospace Advanced Materials Engineering, Hanseo University, Seosan, 31962, South Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Lim, C. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Atuchin, V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич
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