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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovsianikov A. K., Usmanov O. V., Zobkalo I. A., Schmidt W., Maity A., Hutanu V., Ressouche E., Shaykhutdinov K. A., Terentjev K. Yu., Semenov S. V., Meven M., Roth G., Peters L.
Заглавие : Inelastic neutron studies and diffraction in magnetic fields of TbFeO3 and YbFeO3
Место публикации : J. Magn. Magn. Mater. - 2022. - Vol. 563. - Ст.170025. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2022.170025
Примечания : Cited References: 37. - This work is supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA 3688/1-1. The neutron Experiments were performed at the instruments PUMA (MLZ), IN12 (ILL) and D23 (ILL). The authors express their gratitude to A. Bykov for his assistance to the XRD measurements
Аннотация: Investigations of the orthoferrites TbFeO3 and YbFeO3 were performed by neutron inelastic scattering and neutron single crystal diffraction in magnetic fields. The low temperature evolution of energy gaps was explored for both compounds and considered from the point of view of changes of rare earth ion anisotropy. Exchange parameters between nearest neighbors for Fe3+ in TbFeO3 were obtained. The magnetic phase diagram for YbFeO3 was obtained and discussed as a result of the energy balance between Heisenberg exchange interactions, Dzyaloshinsky-Moriya interaction, anisotropy and external magnetic field.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Usmanov O. V., Ovsianikov A. K., Zobkalo I. A., Shaykhutdinov K. A., Terentjev K. Yu., Semenov S. V.
Заглавие : Crystal field parameters and magnetic properties correlations in rare-earth orthoferrite HoFeO3
Место публикации : J. Surf. Invest. - 2022. - Vol. 16, Is. 6. - P.1041-1047. - ISSN 10274510 (ISSN), DOI 10.1134/S1027451022060258. - ISSN 18197094 (eISSN)
Примечания : Cited References: 28. - This work was supported by the Russian Foundation for Basic Research grant no. 19-52-12 047, and DFG grant no. SA 3688/1-1
Аннотация: The crystal structure and magnetic properties investigations of holmium orthoferrite compound HoFeO3 were performed in temperature range 7–300 K. Obtained XRD data confirm that HoFeO3 retains the orthorhombic perovskite structure of Pbnm space group. The crystal electric field (CEF) parameters of Ho3+ ion subsystem has been revealed numerically on the base of point charge model in the same temperature range. By this set of parameters CEF the splitting of Ho3+ energy levels was calculated and their temperature evolution was obtained. Modelling of isothermal magnetization M(H) with obtained set of parameters was carried out. Ho3+ single ion anisotropy due to CEF effects was demonstrated. Bulk magnetization evaluated from CEF was compared to experimental data.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lyubutin I. S., Ovchinnikov S. G., Gavriliuk A. G., Struzhkin V. V.
Заглавие : Spin-crossover-induced Mott transition and the other scenarios of metallization in 3d(n) metal compounds
Разночтения заглавия :авие SCOPUS: Spin-crossover-induced Mott transition and the other scenarios of metallization in 3 dn metal compounds
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2009. - Vol. 79, Is. 8. - Ст.85125. - ISSN 1098-0121, DOI 10.1103/PhysRevB.79.085125
Примечания : Cited References: 41
Предметные рубрики: RARE-EARTH ORTHOFERRITES
NARROW ENERGY BANDS
HIGH-PRESSURE
MAGNETIC COLLAPSE
ELECTRON CORRELATIONS
PHASE-TRANSITION
STATE
Y3FE5O12
OXIDES
EQUATION
Ключевые слова (''Своб.индексиров.''): bismuth compounds--hubbard model--localised states--metal-insulator transition--metallisation--spin systems
Аннотация: A different "Hubbard energy control" mechanism of the insulator-metal transition (IMT) in Mott-Hubbard insulators is discussed. This mechanism can be initiated by the lattice compression and it is driven by a spin crossover of 3d(5) ions from the high-spin state to the low-spin state. The spin crossover suppresses the effective Hubbard parameter U-eff down to the value enabling the insulator-metal transition according to the Mott mechanism U-eff/W approximate to 1. The classification of possible scenarios of metallization in the other 3d(n) metal compounds is also performed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kalashnikova A. M., Pavlov V. V., Pisarev R. V., Bezmaternykh L. N., Bayer M., Rasing T.
Заглавие : Linear and nonlinear optical spectroscopy of gadolinium iron borate GdFe3(BO3)(4)
Разночтения заглавия :авие SCOPUS: Linear and nonlinear optical spectroscopy of gadolinium iron borate GdFe3(BO3)4
Место публикации : JETP Letters. - 2004. - Vol. 80, Is. 5. - P.293-297. - ISSN 0021-3640, DOI 10.1134/1.1825108
Примечания : Cited References: 26
Предметные рубрики: ORTHOFERRITES
Аннотация: The optical spectra and the second-harmonic generation (SHG) are studied in a noncentrosymmetric GdFe3(BO3)(4) magnet. In the region of weak absorption (alpha similar to 20-400 cm(-1)) below similar to3 eV, three absorption bands are distinguished, which can be unambiguously assigned to forbidden electronic transitions from the ground (6)A(1) state of the Fe3+ ion to its excited states T-4(1) (similar to1.4 eV), T-4(2) (similar to2 eV), and (4)A(1), E-4 (similar to2.8 eV). Intense absorption begins in the region above 3 eV (alpha similar to 2-4 x 10(5) cm(-1)), where two bands at similar to4.0 and 4.8 eV are observed, which are caused by allowed electric dipole charge-transfer transitions. The spectral features of SHG in the 1.2-3.0-eV region are explained by a change in the SHG efficiency caused by a change in the phase mismatch. It is shown that in the weak absorption region, phase matching can be achieved for SHG. (C) 2004 MAIK "Nauka / Interperiodica".
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