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1.

Вид документа : Однотомное издание
Шифр издания :
Автор(ы) : Isakova V. G., Petrakovskaya E. A., Isakov V. P., Bayukov O. A., Velikanov D. A.
Заглавие : The research of powder fullerene and ultra-despersed diamond composites with metal and oxide nanoparicles
Место публикации : The Physics of Metals and Metallography. - 2006. - Vol. 102, Suppl.1. - С. S57-S60. - DOI 10.1134/S0031918X06140146
Примечания : Библиогр.: 7
Аннотация: Magnetic properties of new nanophase materials based on oxide and metal particles of dtransition metals included in the powder fullerite C60 and detonative ultradispersed diamonds (UDD) are investigated. The materials are obtained by an original method of catalytic combustion reaction.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev D. S., Shtareva, A., V, Kevorkyants R., Rudakova, A., V, Molokeev M. S., Bakiev, T., V, Bulanin K. M., Ryabchuk V. K., Serpone N.
Заглавие : Materials synthesis, characterization and DFT calculations of the visible-light-active perovskite-like barium bismuthate Ba1.264(4)Bi1.971(4)O4 photocatalyst
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]; Saint-Petersburg State University [39054581]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00855]
Место публикации : J. Mater. Chem. C. - 2020. - Vol. 8, Is. 10. - P.3509-3519. - ISSN 2050-7526, DOI 10.1039/c9tc06457e. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 42. - The current research was kindly funded by a grant from the Russian Science Foundation (project No. 19-73-10013). R. K., A. V. R., V. K. R. and T. V. B. acknowledge financial support from Saint-Petersburg State University (Pure ID 39054581). A. V. R. thanks the Russian Foundation for Basic Research for a Grant No. 18-03-00855 that supported studies into the photoinduced hydrophilicity of the bismuthate. The authors are further grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics of the Far Eastern Branch of the Russian Academy of Sciences, and the Resource Centers of the Research Park at the Saint-Petersburg State University: (i) the Center for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, (ii) the Center for Physical Methods of Surface Investigation, (iii) the Center for Optical and Laser Materials Research, and the laboratories of (iv) Nanotechnology and (v) Nanophotonics for their valuable assistance in carrying out the research and in providing the needed equipment. One of us (N.S.) is grateful to Prof. Angelo Albini and the staff of the PhotoGreen Laboratory at the University of Pavia, Italy, for their continued hospitality.
Предметные рубрики: OXIDE
NIO/SRBI2O4
SPECTRA
DRIVEN
CO2
LA
Аннотация: A perovskite-like barium bismuthate of the BaBi2O4 class, Ba1.264(4)Bi1.971(4)O4, has been prepared by solid-state synthesis and subsequently characterized by a number of experimental techniques (XPS, DRS, SEM, EDX and Raman spectroscopy), as well as by a DFT computational approach using the GGA Perdew–Burke–Ernzerhof (PBE) density functional to determine the energy band structure. XRD peaks were indexed to a rhombohedral cell (R[3 with combining macron]m) with parameters close to Ba0.156Bi0.844O1.422 (i.e., to Ba0.439Bi2.374O4), which upon Rietveld refinement gave Ba1.264(4)Bi1.971(4)O4. The Bi–O bond lengths determined from this refinement (1.86 and 2.31 Å) accorded with the bond lengths estimated from Raman spectra (1.97 and 2.26 Å). DFT calculations revealed the bismuthate to display two bandgaps that correspond to lower-energy indirect (2.28 eV) and to higher-energy direct (2.36 eV) electronic transitions in good agreement with the experimental bandgaps of 2.26 eV and 2.43 eV, respectively, from Tauc plots of DRS spectra. Relative to the indirect bandgap energy of 2.26 eV, the energies of the valence band and of the conduction band were, respectively, +1.14 eV and −1.12 eV. The photoactivity of Ba1.264(4)Bi1.971(4)O4 was examined toward the photoreduction of the greenhouse gas CO2 in aqueous media photoelectrochemically yielding alcohols and alkanes, while in the gas phase in an infrared cell reactor the products were carbon monoxide and alkanes.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrichkov V. A., Polukeev S. I., Ovchinnikov S. G.
Заглавие : Cation spin and superexchange interaction in oxide materials below and above spin crossover under high pressure
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [18-12-00022]
Место публикации : Phys. Rev. B. - 2020. - Vol. 101, Is. 9. - Ст.094409. - ISSN 2469-9950, DOI 10.1103/PhysRevB.101.094409. - ISSN 2469-9969(eISSN)
Примечания : Cited References: 65. - We acknowledge the support of the Russian Science Foundation through Grant No. 18-12-00022
Предметные рубрики: EXCHANGE INTERACTION
PHASE-TRANSITIONS
STATE
ELECTRON
IRON
Аннотация: We derived simple rules for the sign of 180° superexchange interaction based on the multielectron calculations of the superexchange interaction in the transition metal oxides that are valid both below and above spin crossover under high pressure. The superexchange interaction between two cations in dn configurations is given by a sum of partial contributions related to the electron-hole virtual excitations to the different states of the dn+1 and dn−1 configurations. Using these rules, we have analyzed the sign of the 180° superexchange interaction of a number of oxides with magnetic cations in electron configurations from d2 until d8: the iron, cobalt, chromium, nickel, copper, and manganese oxides with increasing pressure. The most interesting result concerns the magnetic state of cobalt and nickel oxides CoO, Ni2O3 and also La2CoO4, LaNiO3 isostructural to well-known high-TC and colossal magnetoresistance materials. These oxides have a spin 12 at the high pressure. Change of the interaction from antiferromagnetic below spin crossover to ferromagnetic above spin crossover is predicted for oxide materials with cations in d5(FeBO3) and d7(CoO) configurations, while for materials with the other dn configurations spin crossover under high pressure does not change the sign of the 180∘ superexchange interaction.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Orlov Yu. S., Bushinsky M. V., Solovyov L. A., Vereshchagin S. N., Gavrilkin, S. Yu, Tsvetkov, A. Yu, Gorev M. V., Novikov S. V., Mantytskaya O. S., Ovchinnikov S. G.
Заглавие : Structural, magnetic, electronic, and dilatation properties of the ordered solid solutions Ln0.2Sr0.8CoO3-δ (Ln = Sm, Gd, Dy) with the same oxygen nonstoichiometry index δ
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-03-00017]; RFBRRussian Foundation for Basic Research (RFBR) [18-52-00017, F18R-119]; BRFFR [18-52-00017, F18R-119]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory [18-42-243004, SB RAS V.45.3.3]
Место публикации : J. Alloy. Compd. - 2020. - Vol. 830. - Ст.154629. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2020.154629. - ISSN 1873-4669(eISSN)
Примечания : Cited References: 44. - The work was financially supported by Russian Foundation for Basic Research (grant No. 19-03-00017); RFBR and BRFFR as a part of scientific project No. 18-52-00017 and project F18R-119; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project: "New thermoelectric materials based on multi-scale spatially inhomogeneous substituted rare-earth cobalt oxides and the Ruddlesden-Popper phases " project No. 18-42-243004, Project of Basic Research SB RAS V.45.3.3.
Предметные рубрики: LN(1-X)SR(X)COO(3-DELTA) LN
COBALTATE PEROVSKITES
Аннотация: Single-phase samples of the layered perovskite-like cobalt oxides Ln0.2Sr0.8CoO3-δ (Ln = Sm, Gd, Dy) with the same oxygen nonstoichiometry index δ = 0.37 ± 0.01 were synthesized. All samples are characterized by a tetragonal unit cell with the space group I4/mmm. The structural, magnetic, electric transport and dilatation properties of the obtained samples are investigated. The studied samples are characterized by two anomalies in magnetic properties, a high-temperature maximum near Тm = 350 К with magnetic field hysteresis below Tm, and a diffuse peak in the intermediate temperature range, which shifts with ionic radius decrease of the rare-earth element to higher temperatures. The high-temperature maxima of the magnetic susceptibility correlate with anomalies in thermal expansion, heat capacity and the features in the temperature dependences of the electrical resistivity, pointing to a strong relationship between the structural, magnetic and electronic degrees of freedom. The given comparative analysis of the experimental data of various substituting rare-earth elements with the same oxygen nonstoichiometry has been carried out for the first time.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Orlov Yu. S., Dudnikov V. A., Vereshchagin S. N., Volochaev M. N., Gavrilkin S. Y., Tsvetkov A. Y.
Заглавие : Order–disorder transition in the Dy0.2Sr0.8CoO3-δ rare-earth cobalt oxide solid solutions: Structural and thermoelectric properties
Место публикации : J. Eur. Ceram. Soc. - 2020. - Vol. 40, Is. 15. - P.5559-5565. - ISSN 09552219 (ISSN), DOI 10.1016/j.jeurceramsoc.2020.06.066
Примечания : Cited References: 29. - This study was supported by the Russian Science Foundation, project no. 19-72-00097
Аннотация: By the example of the Dy0.2Sr0.8CoO3-δ compound undergoing an order–disorder phase transition with increasing temperature, we demonstrate a significant dependence of the kinetic properties on the morphology of the internal spatially inhomogeneous structure, which forms in the sample depending on the rate of its transition from the high-temperature disordered cubic phase to the ground tetragonal ordered phase upon cooling. The results of transmission electron microscopy visualization of the spatially inhomogeneous state in the Dy0.2Sr0.8CoO3-δ ceramic samples are presented and compared with the X-ray diffraction data.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Fedorov A. S., Orlov Yu. S., Solovyov L. A., Vereshchagin S. N., Gavrilkin, S. Yu, Tsvetkov, A. Yu, Gorev M. V., Novikov, S., V, Ovchinnikov S. G.
Заглавие : Thermoelectric properties of the SmCoO3 and NdCoO3 cobalt oxides
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [16-13-00060]
Место публикации : Ceram. Int. - 2020. - Vol. 46, Is. 11. - P.17987-17991. - ISSN 0272-8842, DOI 10.1016/j.ceramint.2020.04.113. - ISSN 1873-3956(eISSN)
Примечания : Cited References: 41. - This study was supported by the Russian Science Foundation, project no. 16-13-00060.
Предметные рубрики: MAGNETIC-PROPERTIES
SPIN
CONDUCTIVITY
TRANSITIONS
LACOO3
SITE
Аннотация: The thermoelectric properties of the NdCoO3 and SmCoO3 rare-earth cobalt oxides with a perovskite structure have been investigated in a wide temperature range. It is shown that, in the low-temperature region, the thermal conductivity of the compounds has a sharp maximum and the electrical conductivity of the samples increases with temperature, whereas the Seebeck coefficient behaves nonmonotonically with increasing temperature. The SmCoO3 oxide is characterized by the positive thermopower over the entire investigated range with a sharp growth in the low-temperature region, attaining the maximum value (S ≈ 1000 μV/K) near room temperature, and a further decrease. It has been established that, in the NdCoO3 oxide, the Seebeck coefficient changes its sign, which was rarely observed in the La-based compounds and is atypical of the undoped rare-earth cobalt oxides. The thermopower maximum obtained at a temperature of 450 K is 400 μV/K. The regions of the fastest growth of the thermoelectric power factor correspond to the anomalies caused by the spin transition of Со3+ ions and the dielectric–metal transition.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popkov S. I., Krasikov A. A., Semenov S. V., Dubrovskii A. A., Yakushkin S. S., Kirillov V. L., Mart'yanov O. N., Balaev D. A.
Заглавие : Features of the pulsed magnetization switching in a high-coercivity material based on ε-Fe2O3 nanoparticles
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Krai; Krasnoyarsk Territorial Foundation [18-42-240012]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 3. - P.445-453. - ISSN 1063-7834, DOI 10.1134/S1063783420030166. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 44. - The study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240012 "Magnetization Switching of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields: New Approach to Studying the Dynamic Effects Related to the Magnetization of Magnetic Nanoparticles."
Предметные рубрики: HIGH-TEMPERATURE
WAVE ABSORBER
OXIDE
FIELD
TRANSITION
RESONANCE
Аннотация: The magnetic structure of the ε-Fe2O3 iron oxide polymorphic modification is collinear ferrimagnetic in the range from room temperature to ~150 K. As the temperature decreases, ε-Fe2O3 undergoes a magnetic transition accompanied by a significant decrease in the coercivity Hc and, in the low-temperature range, the compound has a complex incommensurate magnetic structure. We experimentally investigated the dynamic magnetization switching of the ε-Fe2O3 nanoparticles with an average size of 8 nm in the temperature range of 80–300 K, which covers different types of the magnetic structure of this iron oxide. A bulk material consisting of xerogel SiO2 with the ε-Fe2O3 nanoparticles embedded in its pores was examined. The magnetic hysteresis loops under dynamic magnetization switching were measured using pulsed magnetic fields Hmax of up to 130 kOe by discharging a capacitor bank through a solenoid. The coercivity Нс upon the dynamic magnetization switching noticeably exceeds the Нс value under the quasi-static conditions. This is caused by the superparamagnetic relaxation of magnetic moments of particles upon the pulsed magnetization switching. In the range from room temperature to ~ 150 K, the external field variation rate dH/dt is the main parameter that determines the behavior of the coercivity under the dynamic magnetization switching. It is the behavior that is expected for a system of single-domain ferro- and ferrimagnetic particles. Under external conditions (at a temperature of 80 K) when the ε-Fe2O3 magnetic structure is incommensurate, the coercivity during the pulsed magnetization switching depends already on the parameter dH/dt and is determined, to a great extent, by the maximum applied field Hmax. Such a behavior atypical of systems of ferrimagnetic particles is caused already by the dynamic spin processes inside the ε-Fe2O3 particles during fast magnetization switching.
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Petrov D. A., Ivantsov R. D., Zharkov S. M., Yurkin G. Yu., Molokeev M. S., Knyazev Yu. V., Lin C.-R., Tseng Y.-T.
Заглавие : Core-shell iron oxide-carbon nanoparticles modified with Ag. synthesis, morphology, magnetic properties
Коллективы : Российская академия наук, Уральское отделение РАН, Институт физики металлов им. М. Н. Михеева Уральского отделения РАН, Уральский федеральный университет им. первого Президента России Б.Н. Ельцина, Российский фонд фундаментальных исследований, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : Euro-asian symposium "Trends in magnetism" (EASTMAG-2019): Book of abstracts/ чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст.J.P18. - P.220-221. - ISBN 978-5-9500855-7-4 (Шифр В33/E12-125657784)
Примечания : Cited References: 2. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project No. 18-42-243021 and by Joint Research Project of Russian Foundation for Basic Research and Ministry of Science and Technology, Taiwan MOST No. 19-52-52002
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9.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Balaev D. A., Dubrovskiy A. A., Semenov S. V., Krasikov A. A., Knyazev Yu. V., Bayukov O. A., Yakushkin S. S., Kirillov V. L., Bukhtiyarova G. A., Martyanov O. A.
Заглавие : Unusual magnetic behavior of polymorph iron oxide ϵ-Fe2O3 nanoparticles: magnetic phase diagram and surface effects
Коллективы : Российская академия наук, Уральское отделение РАН, Институт физики металлов им. М. Н. Михеева Уральского отделения РАН, Уральский федеральный университет им. первого Президента России Б.Н. Ельцина, Российский фонд фундаментальных исследований, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : Euro-asian symposium "Trends in magnetism" (EASTMAG-2019): Book of abstracts/ чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 2. - Ст.J.I2. - P.164-165. - ISBN 978-5-9500855-7-4 (Шифр В33/E12-125657784)
Примечания : Cited References: 15. - This work was supported by the Russian Science Foundation, project no. 17-12-01111
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dubrovskiy A. A., Semenov S. V., Knyazev Yu. V., Popkov S. I., Yakushkin S., Kirillov V., Martyanov O., Balaev D. A.
Заглавие : The Low-Temperature Magnetic State and Magnetic Ordering Temperature of ϵ-Fe2O3 Iron Oxide Nanoparticles
Место публикации : IEEE Magn. Lett. - 2019. - Vol. 10. - Ст.6110103. - ISSN 1949307X (ISSN), DOI 10.1109/LMAG.2019.2956674
Примечания : Cited References: 22
Предметные рубрики: Magnetic resonance
Magnetic hysteresis
Temperature distribution
Saturation magnetization
Nanoparticles
Perpendicular magnetic anisotropy
Аннотация: The ϵ-Fe2O3 iron oxide polymorph is a well-known magnetic material with a complex magnetic structure, which undergoes a series of magnetic transitions in different temperature ranges. However, the ϵ-Fe2O3 phase diagram is still unclear. We report on the magnetic properties of a sample consisting of ϵ-Fe2O3 nanoparticles with an average size of 8 nm embedded in a SiO2 xerogel matrix without an admixture of foreign phases. Along with the features typical of the well-known ϵ-Fe2O3 magnetic transition in the temperature range 80–150 K, the temperature dependence of magnetization M(T) of ϵ-Fe2O3 includes other low-temperature anomalies. In an external field of H = 70 kOe, there is a noticeable temperature hysteresis of magnetization at 50–90 K, and near T ≈ 50 K, the M(T) curves have a characteristic bending, which may be indicative of an additional magnetic transition. The ferromagnetic resonance spectra shows that, near 500 K, a magnetic phase transition occurs, which was previously thought to be a transition to the paramagnetic state. An analysis of the temperature dependence of the ferromagnetic resonance spectra shows that the magnetically ordered phase in ϵ-Fe2O3 exists up to about 800 K.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Semenov S. V., Dubrovskii A. A., Krasikov A. A., Popkov S. I., Yakushkin S. S., Kirillov V. L., Mart'yanov O. N.
Заглавие : Synthesis and magnetic properties of the core-shell Fe3O4/CoFe2O4 nanoparticles
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [17-12-01111]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P.285-290. - ISSN 1063-7834, DOI 10.1134/S1063783420020043. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 37. - This study was supported by the Russian Science Foundation, project no. 17-12-01111.
Предметные рубрики: MOSSBAUER
ENSEMBLE
Аннотация: The Fe3O4/CoFe2O4 nanoparticles with a core-shell structure with an average size of 5 nm have been obtained by codeposition from the iron and cobalt chloride solutions. An analysis of the magnetic properties of the obtained system and their comparison with the data for single-phase Fe3O4 (4 nm) and CoFe2O4 (6 nm) nanoparticles has led to the conclusion about a noticeable interaction between the soft magnetic (Fe3O4) and hard magnetic (CoFe2O4) phases forming the core and shell of hybrid particles.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volochaev M. N., Granovsky A. B., Zhilova O. V., Kalinin Y. E., Ryl'kov V. V., Sumets M. P., Makagonov V. A., Pankov S. Y., Sitnikov A. V., Fadeev E., Lahderanta E., Foshin V.
Заглавие : Transport and magnetic phenomena in ZnO-С thin-film heterostructures
Место публикации : Superlattices Microstruct. - 2020. - Vol. 140. - Ст.106449. - ISSN 07496036 (ISSN), DOI 10.1016/j.spmi.2020.106449
Примечания : Cited References: 36. - The work was supported by the Ministry of Education and Science of Russia (project No. 3.1867.2017/4.6 ) and the RFBR (project No. 19-07-00471). The work was partially funded by the Academy of Finland
Аннотация: ZnO- and C-based heterostructures were fabricated by the layer-by-layer deposition technique using the ion-beam sputtering process. Structure, electrical and magnetic properties of fabricated heterostructures are discussed. The two-phase (ZnO and C) films are evolved into a multilayer structure, consisting of amorphous carbon and crystalline ZnO layers when the bilayer thickness increases. When carbon is added to ZnO, its electrical resistivity reduces. The conduction mechanism changes from the variable-range hopping in a narrow energy band to the nearest neighbors hopping in ZnO–C films with a thickness of h ˂ 150 nm. The temperature dependence of conductivity changes from the Arrhenius-like to logarithmic law, indicating that the strong charge localization turns into a weak one when the film thickness is about 150 nm. The negative magnetoresistance of up to 1% was detected at 77 K. The film ferromagnetism at the temperature of 10 K was not found.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Irtyugo L. A., Beletskii V. V., Belousova N. V., Denisov V. M.
Заглавие : Structure and thermodynamic properties of the SmGaGe2O7 oxide
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P.384-387. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783420020109
Примечания : Cited References: 10. - This study was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation to the Siberian Federal University in 2017–2019, project no. 4.8083.2017/8.9 “Formation of a Data Bank of Thermodynamic Characteristics of the Complex-Oxide Multifunctional Materials Containing Rare and Scattered Elements.”
Аннотация: The SmGaGe2O7 oxide material has been obtained from initial Sm2O3, Ga2O3, and GeO2 oxides by solid-phase synthesis with annealing in air in the temperature range of 1273–1473 K. The structure of the investigated germanate (sp. gr. P21/c, a = 7.18610(9) Å, b = 6.57935(8) Å, and c = 12.7932(2) Å) has been established by X-ray diffraction and the high-temperature heat capacity has been determined by differential scanning calorimetry. Using the experimental data on Cp = f(T), the thermodynamic properties of the compound have been calculated.
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. Е., Zabluda V. N., Sherepa A. V., Knyazev Yu. V., Volochaev M. N., Kurilina A., Velikanov D. A., Goncharova D. A., Shabalina A., Svetlichnyi V.
Заглавие : Magnetic properties of iron oxide nanoparticles to create aptamer bionanoconjugates
Коллективы : Aptamers in Russia, international conference
Место публикации : Aptamers in Russia, international conference (1 ; 2019 ; Aug. 27-30 ; Krasnoyarsk). Molecular Therapy - Nucleic Acids: book of abstracts of the 1st Int. conf. "Aptamers in Russia 2019". - 2019. - Vol. 17, Suppl. 1. - P.12
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kurilova A. V., Sokolov A. Е., Svetlichniy V. A., Velikanov D. A., Sherepa A. V., Volochaev M. N., Goncharova D. A., Shabalina A. V.
Заглавие : Magnetic and optical properties of the iron oxide nanoparticles obtained via pulsed laser ablation
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials: Proceedings. - VLadivostok: Dalnauka Publishing, 2020. - Ст.IV.31.05p. - P.114. - ISBN 978-5-8044-1698-1
Примечания : The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No.17-42-240080
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Krasitskaya V. V., Frank L. A., Yaroslavtsev R. N., Chekanova L. A., Gerasimova Yu. V., Volochaev M. N., Bairmani M. S., Velikanov D. A.
Заглавие : Polysaccharide-coated iron oxide nanoparticles: Synthesis, properties, surface modification
Место публикации : Mater. Lett. - 2021. - Vol. 284. - Ст.128920. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2020.128920
Примечания : Cited References: 12. - The reported study was carried out with the financial support of the Russian Foundation for Fundamental Research , the Government of the Krasnoyarsk Territory , the Krasnoyarsk Territory Fund for Support of Scientific and Technical Activity in the framework of scientific Project No. 18-43-243003. This work was supported by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3)
Аннотация: In this work, magnetite nanoparticles coated with polysaccharides were synthesized. Arabinogalactan and chitosan were used as polysaccharides. The possibilities of immobilization of biospecific molecules on the surface of the obtained composites were studied. Experiments on covalent immobilization of biospecific molecules on magnetic nanoparticles coated with a polysaccharide showed a high density of immobilized molecules. This suggests the use of such materials in bioanalytical systems or as affinity sorbents.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronin A. S., Masiygin A. N., Molokeev M. S., Khartov S. V.
Заглавие : Atomic layer deposition ZnO on porous Al2O3 nanofibers film
Коллективы : International Scientific Conference on Applied Physics, Information Technologies and Engineering
Место публикации : J. Phys. Conf. Ser. - 2020. - Vol. 1679, Is. 2. - Ст.022072. - DOI 10.1088/1742-6596/1679/2/022072
Примечания : Cited References: 10. - Studies by scanning electron microscopy and X-ray powder diffraction were performed on the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS». The transmission electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: The paper presents the results of the formation and study of the morphological and structural characteristics of the mesoporous ZnO / Al2O3 nanofibers film (ZANF). The deposition of a ZnO layer on Al2O3 nanofibers film (ANF) ~ 1 µm thick was carried out by the method of atomic layer deposition. The morphology of the mesoporous composite layer ZnO / Al2O3 (ZANF) has been studied by scanning and transmission electron microscopy. It is shown that in the process of atomic layer deposition, the ZnO layer grows according to the Stranski-Krastanov mechanism. A ZnO layer less than 5 nm thick gives an island structure in which Al2O3 nanofibers are uniformly coated with ZnO particles, an increase in the ZnO layer thickness to 15 nm demonstrates a continuous coating of Al2O3 nanofibers. The system has a core-shell structure. The resulting composite structures are promising for applications in photocatalysis and gas sensing.
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. Е., Kurilova A. V., Sherepa A. V., Volochaev M. N., Velikanov D. A., Goncharova D. A., Shabalina A. V., Svetlichnyi V.
Заглавие : Magneto-optical properties of the iron oxide nanoparticles obtained by laser ablation
Коллективы : Pulsed Lasers and Laser Applications, International Conference
Место публикации : Pulsed lasers and laser applications (AMPL-2019): abstracts of XIV Int. conf. - 2019. - Ст.B-12. - P.61-62. - ISBN 978-5-93629-634-5
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Orlov Yu. S., Solovyov L. A., Vereshchagin S. N., Gavrilkin S. Y.
Заглавие : The Sr2.4Dy0.6Co2O7-δ Ruddlesden‒Popper Phase: Structural, thermoelectric, and magnetic properties
Место публикации : Ceram. Int. - 2021. - Vol. 47, Is. 7, Part A. - P.9068-9074. - ISSN 02728842 (ISSN), DOI 10.1016/j.ceramint.2020.12.030
Примечания : Cited References: 39. - The study was supported by the Russian Foundation for Basic Research , project no. 19-03-00017 and the budget project #АААА-А17-117021310222-4 for the Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences
Аннотация: A new anion-deficient Sr2.4Dy0.6Co2O7‒δ (δ = 0.33–1.1) perovskite phase with a structure of the A3B2O7 Raddlesden‒Popper homologous series has been obtained by the solid-state synthesis in the reducing/oxidizing atmosphere and its structural characterization has been performed by the Rietveld refinement of the X-ray powder diffraction data. It has been stablished that the Sr2.4Dy0.6Co2O7‒δ compound (sp. gr. I4/mmm) has parameters of a = b = 3.8526(1) and c = 19.9431(7) Å in the reduced form (δ = 1.1) and a = b = 3.8086(1) and c = 19.9190(6) Å in the oxidized form (δ ≈ 0.33) and oxygen vacancies occupy mainly the sites linking CoO5 polyhedra inside two perovskite layers. It has been established using differential scanning calorimetry and thermogravimetry that, at T 530 K, the synthesized phase is stable against the inert and oxidizing atmosphere; at higher temperatures, the Sr2.4Dy0.6Co2O7-δ compound can reversibly absorb/release oxygen. The magnetic properties of the Sr2.4Dy0.6Co2O6.09 compound have been investigated in the temperature range of 10–400 K and described in terms of the formation of dimers, in which the Co3+‒Co3+ and Co2+‒Co2+ ion pairs antiferromagnetically interact and are in the nonmagnetic ground state. The electrical conductivity and the Seebeck coefficient have been measured in air in the temperature range from 300 to 800 K. An observed sharp decrease in the Seebeck coefficient of the Sr2.4Dy0.6Co2O7-δ compound and the change in its sign near 700 K have been attributed to the transition of cobalt ions to the Co3+ state and the charge disproportionation of Co3+ ions to Co2+ and Co4+ ones.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bykova L. E., Myagkov V. G., Zhigalov V. S., Matsynin A. A., Velikanov D. A., Bondarenko G. N., Patrin G. S.
Заглавие : Magnetic and structure properties of CoPt-In2O3 nanocomposite films
Коллективы : Russian Foundation for Basic Research, Government of Krasnoyarsk Territory [19-43-240003]
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2020. - Vol. 13, Is. 4. - P.431-438. - ISSN 1997-1397, DOI 10.17516/1997-1397-2020-13-4-431-438; Журн. СФУ. Матем. и физика. - ISSN 2313-6022(eISSN)
Примечания : Cited References: 29. - This study was supported by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects no. 19-43-240003
Предметные рубрики: THIN-FILMS
TEMPERATURE
PHASE
Аннотация: The structural and magnetic properties of CoPt-In2O3 nanocomposite films formed by vacuum annealing of the In/(Co3O4 + Pt)/MgO film system in the temperature range of 100–800 °C have been investigated. The synthesized nanocomposite films contain ferromagnetic CoPt grains with an average size of 5nm enclosed in an In2O3 matrix, and have a magnetization of 600 emu/cm3, and a coercivity of 150 Oe at room temperature. The initiation 200 °C and finishing 800 °C temperatures of synthesis were determined, as well as the change in the phase composition of the In/(Co3O4 + Pt)/MgO film during vacuum annealing.Исследованы структурные и магнитные свойства нанокомпозитных пленок CoPt- In2O3, полученных вакуумным отжигом пленочной системы In/(Co3O4 + Pt)/MgO в интервале температур 100 – 800 °C. Синтезированные нанокомпозитные пленки содержали ферромагнитные CoPt-кластеры со средним размером 5 nm, заключенные в матрицу In2O3, и имели намагниченность 600 emu/cm3, коэрцитивную силу 150 Oe при комнатной температуре. Определены температуры начала 200 °C и окончания 800 °C синтеза, а также изменение фазового состава пленки In/(Co3O4 + Pt)/MgO при вакуумном отжиге.
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