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    A novel Mn4+-activated fluoride red phosphor Cs30(Nb2O2F9)9(OH)3·H2O:Mn4+ with good waterproof stability for WLEDs / Y. Chen, F. Liu, Z. Zhang [et al.] // J. Mater. Chem. C. - 2022. - Vol. 10, Is. 18. - P. 7049-7057, DOI 10.1039/d2tc00132b. - Cited References: 56. - This work was financially supported by grants from the National Natural Science Foundation of China (NSFC) (No. 51802359), the Joint Funds of NSFC and Yunnan Province (No. U1702254), and Guangdong Basic and Applied Basic Research Foundation (No. 2020A1515010556) . - ISSN 2050-7534
   Перевод заглавия: Новый Mn4+-активированный фторидный красный люминофор Cs30(Nb2O2F9)9(OH)3ћH2O:Mn4+ с хорошей водонепроницаемостью для WLED
Кл.слова (ненормированные):
Crystal structure -- Fluorine compounds -- Gallium alloys -- III-V semiconductors -- Indium alloys -- Light emission -- Light emitting diodes -- Optical properties -- Phosphors -- Precipitation (chemical) -- Waterproofing
Аннотация: Red-light-emitting materials, as pivotal components of warm white light-emitting diodes (WLEDs), have drawn increasing public focus. Among these, Mn4+-doped red light-emitting fluorides have drawn considerable attention when combined with an InGaN chip; however, they suffer from poor water stability under humid conditions. In this work, a novel fluoride red phosphor, Cs30(Nb2O2F9)9(OH)3·H2O:xMn4+ (CNOFM), with good water resistance was synthesized for the first time using a facile co-precipitation method at ambient temperature. Experiments were implemented for the precise analysis of its crystal structure, optical properties, micro-morphology, thermal behavior, and waterproof properties. 6.66% Mn4+-doped CNOFM maintained a stable crystal structure and possessed strong PL intensity located at 633 nm with high color purity of 96%. CNOFM showed better thermal and waterproof stability compared with the commercial K2SiF6:Mn4+ red phosphor. Without any surface modifications, the PL intensity remained at about 83% of the initial value after immersion in water for 60 min, and the mechanism was investigated. Finally, a warm WLED with a CRI of 92.3 and CCT of 3271 K was fabricated using the CNOFM red phosphor.

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Держатели документа:
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Sun Yat-Sen University, School of Chemistry/School of Marine Sciences, 510275/Zhuhai, Guangzhou, 519082, China
Laboratory of Crystal Physics, Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna, 141980, Russian Federation
Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou, 510650, China

Доп.точки доступа:
Chen, Y.; Liu, F.; Zhang, Z.; Hong, J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bobrikov, I. A.; Shi, J.; Zhou, J.; Wu, M.
}
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    Aliovalent substitution toward reinforced structural rigidity in Ce3+-doped garnet phosphors featuring improved performance / T. Hu [et al.] // J. Mater. Chem. C. - 2019. - Vol. 7, Is. 46. - P. 14594-14600, DOI 10.1039/c9tc05354a. - Cited References: 38. - This work was supported by the National Natural Science Foundation of China (No. 51722202 and 51972118), the Guangdong Provincial Science & Technology Project (2018A050506004) and the Fundamental Research Funds for the Central Universities (D2190980). . - ISSN 2050-7534
   Перевод заглавия: Алиовалентное замещение с целью усиления структурной жесткости в люминофорных гранатах, легированных Ce3 + и имеющих улучшенные характеристики
Кл.слова (ненормированные):
Color -- Deterioration -- Efficiency -- Gallium alloys -- Garnets -- III-V semiconductors -- Indium alloys -- Photoluminescence -- Reinforcement -- Rigidity -- Semiconductor alloys -- Thermal Engineering -- Thermodynamic stability
Аннотация: Highly efficient phosphors with thermal stability and color-tunable emission are required for the fabrication of phosphor-converted white light-emitting diodes (pc-WLEDs). Currently developed engineering strategies are generally successful in photoluminescence tuning but, unfortunately, suffer severe deterioration in emission intensity/efficiency and/or thermal stability. Herein, an efficient aliovalent substitution strategy toward reinforced structural rigidity is proposed and demonstrated experimentally. By incorporating Be2+ ion into the garnet-type Lu2SrAl4SiO12:Ce3+ phosphor, the phosphor shows enhanced internal/external quantum efficiency, from 79.2%/26.7% to 84.5%/32.9%, photoluminescence tuning from green (peaking at ∼512 nm) to yellow (peaking at ∼552 nm), and zero thermal quenching, even up to 200 °C. The Be2+ substitution at the Al2/Si2 site enables stable and rigid local surroundings around the Ce3+ activator, which is responsible for the unprecedented performance. In addition, high-quality warm WLED devices with a luminous efficiency of 158.1 lm W-1, correlated color temperature of 3858 K and high color rendering index of 81.7, are obtained by combining Lu2SrAl4SiO12:Ce3+,Be2+ as the yellow emitter, CaAlSiN3:Eu2+ as the red emitter and a blue-emitting InGaN chip. These findings highlight a new strategy for performance optimization of LED phosphors by selecting rigid covalent compounds with further reinforced structural rigidity via aliovalent substitution.

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Держатели документа:
State Key Laboratory of Luminescent Materials and Devices, Institute of Optical Communication Materials, South China University of Technology, Guangzhou, 510641, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Hu, T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xia, Z.; Zhang, Q.
}
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    Alloying Cs+ into Rb2ZrCl6:Te4+ toward highly efficient and stable perovskite variants / J. Zhou, X. M. Rong, M. S. Molokeev [et al.] // Mat. Chem. Front. - 2021. - Vol. 5, Is. 13. - P. 4997-5003, DOI 10.1039/d1qm00302j. - Cited References: 37. - This work is supported by Beijing Natural Science Foundation (No. 2214068), the National Natural Science Foundation of China (No. 61705003), and the Beijing Technology and Business University Research Team Construction Project (No. PXM2019_014213_000007 and PXM2020_014213_000017) . - ISSN 2052-1537
   Перевод заглавия: Легирование Cs+ в Rb2ZrCl6:Te4 + для получения высокоэффективного и стабильного перовскита

РУБ Chemistry, Multidisciplinary + Materials Science, Multidisciplinary
Рубрики:
TELLER
   PHOTOLUMINESCENCE
   TELLURIUM(IV)
   COMPLEXES
   PHOSPHORS
Аннотация: Doping or alloying in perovskites and perovskite variants provides a promising way for modulating the electronic and photoluminescence properties and the structural stability. In this work, a series of yellow-emitting Rb2−xCsxZrCl6:Te4+ solid solution phosphors were prepared by a hydrothermal method, and their broad emission is assigned to the triplet 3P1–1S0 self-trapped excitons (STEs). Upon increasing the alloying ion Cs+, the yellow emission can be greatly enhanced by a stronger Jahn–Teller distortion. Moreover, Cs2ZrCl6:Te4+ shows a high photoluminescence quantum yield (PLQY), and impressive thermal and anti-water stability. This doping–alloying strategy presents a new direction towards designing lead-free, high-performance and stable perovskite derivatives.

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Держатели документа:
Beijng Technol & Business Univ, Dept Phys, Beijing 100048, Peoples R China.
Shenzhen Univ, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen Engn Lab Adv Technol Ceram, Shenzhen Key Lab Special Funct Mat,Coll Mat Sci &, Shenzhen 518060, Peoples R China.
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Zhou, Jun; Rong, Ximing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, Yulong; Yun, Xiangyan; Xu, Denghui; Li, Xiong; Beijing Natural Science FoundationBeijing Natural Science Foundation [2214068]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [61705003]; Beijing Technology and Business University Research Team Construction Project [PXM2019_014213_000007, PXM2020_014213_000017]
}
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    Bismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting / Y. Wei, H. Yang, Z. Y. Gao [et al.] // Chem. Commun. - 2020. - Vol. 56, Is. 64. - P. 9170-9173, DOI 10.1039/d0cc03975f. - Cited References: 27. - This work was supported by the National Natural Science Foundation of China (Grant No. 51672259) and the Fundamental Research Funds for the National Universities, China University of Geosciences (Wuhan) (No. 1910491T02) . - ISSN 1359-7345. - ISSN 1364-548X
   Перевод заглавия: Активированные висмутом люминесцентные материалы двойных перовскитов, с полным спектром излучения, который получается за счет управления возбуждением и валентностью, для интеллектуального светодиодного освещения в будущем

РУБ Chemistry, Multidisciplinary
Рубрики:
PHOTOLUMINESCENCE
   PHOSPHORS
   Bi3+
   MODULATION
   CRYSTAL
Аннотация: A novel La2Mg1.14Zr0.86O6:Bi3+ double perovskite phosphor with excitation-induced blue/green photoluminescence tuning is reported. By designing Bi3+ → Eu3+ energy transfer, single-composition white light with wide-scale adjustable corrected color temperatures (CCTs) is successfully achieved. This work initiates a new insight to explore phosphors with excitation-induced photoluminescence tuning and wide CCT control for future intelligent LED lighting.

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Держатели документа:
China Univ Geosci, Engn Res Ctr Nanogeomat, Minist Educ, Fac Mat Sci & Chem, Wuhan 430074, Hubei, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Wei, Y.i.; Yang, Hang; Gao, Zhiyu; Xing, Gongcheng; Molokeev, M. S.; Молокеев, Максим Сергеевич; Li, Guogang
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    Blue-shift of Eu2+ emission in (Ba,Sr)3Lu(PO4)3:Eu2+ eulytite solid-solution phosphors resulting from release of neighbouring-cation-induced stress / Z. Y. Wang [et al.] // Dalton Trans. - 2014. - Vol. 43, Is. 44. - P. 16800-16804, DOI 10.1039/c4dt02319f. - Cited References: 16. - The present work was supported by the National Natural Science Foundations of China (grant no. 51002146, no. 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). V.V.A. is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1477-9226. - ISSN 1477-9234
   Перевод заглавия: Синее смещение излучения Eu2+ в твердых растворах (Ba,Sr)3Lu(PO4)3:Eu2 со структурой эулита, вызванное снятием напряжения, индуцированного соседними катионами

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
TUNABLE COLOR TONE
   EXCITED WHITE LEDS
   CRYSTAL-STRUCTURE
   TEMPERATURE
   IONS
Аннотация: A series of iso-structural eulytite-type (Ba,Sr)(3)Lu(PO4)(3):Eu2+ solid-solution phosphors with different Sr/Ba ratios were synthesized by a solid-state reaction. Crystal structures of (Ba,Sr)(3)Lu(PO4)(3):Eu2+ were resolved by the Rietveld method, which shows an eulytite-type cubic Bi-4(SiO4)(3) structure with cations disordered in a single C-3 site while the oxygen atoms were distributed over two partially occupied sites. The emission peaks of Ba(3-x)SrxLu(PO4)(3):Eu2+ (0

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Wang, Z. Y.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Liu, Q. L.
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    Broad luminescence tuning in Mn2+-doped Rb2Zn3(P2O7)2 via doping level control based on multiple synergies / Q. Liu, P. Dang, G. Zhang [et al.] // CrystEngComm. - 2022. - Vol. 24, Is. 31. - P. 5622-5629, DOI 10.1039/d2ce00719c. - Cited References: 31. - We acknowledge the financial support from the National Natural Science Foundation of China (NSFC No. 51932009, 51720105015, 51929201, 52072349, and 52172166), Projects for the Science and Technology Development Plan of Jilin Province (20210402046GH), and the Natural Science Foundation of Zhejiang Province (LR22E020004) . - ISSN 1466-8033
   Перевод заглавия: Широкая перестройка люминесценции в Rb2Zn3(P2O7)2, легированном Mn2+, посредством управления уровнем легирования на основе множественного синергизма
Кл.слова (ненормированные):
Binary alloys -- Color -- Energy transfer -- High temperature applications -- Light emission -- Solid state reactions -- Centrosymmetric structures -- Crystallographic sites -- Doping levels -- Emission color -- Energy-transfer -- High temperature solid-state reaction -- Luminescence tuning -- Multi band -- Non-centrosymmetric -- Orange-red -- Phosphors
Аннотация: Here we constructed a series of novel non-centrosymmetric structure phosphors [Rb2Zn3(P2O7)2:Mn2+] by a high-temperature solid-state reaction. The multiband emission can be designed by Mn2+ preferentially occupying three types of crystallographic sites in Rb2Zn3(P2O7)2:Mn2+. The emission color could be continuously tuned from yellow-green to orange-red via multiple synergies among crystallographic site engineering, energy transfer, and Mn-Mn dimmers alone through the dopant concentration. These color-tunable phosphors have good thermal stability (I150 °C/I25 °C = 91%). The as-prepared pc-WLED has a low corresponding color temperature (CCT = 4820 K) and a high color rendering index (Ra = 90.4) with CIE color coordinates of (0.351, 0.358). These results show that emission-tunable Rb2Zn3(P2O7)2:xMn2+ phosphors are potential candidates for application in n-UV-based pc-WLED devices. This study offers a new insight for wide-range tuning of PL properties by using crystallographic site engineering through changing the doping level in Mn-activated phosphors.

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Держатели документа:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun, 130022, China
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China
Faculty of Materials Science and Chemistry, China University of Geoscience, Wuhan, 430074, China
Zhejiang Institute, China University of Geosciences, Hangzhou, 311305, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Liu, Q.; Dang, P.; Zhang, G.; Lian, H.; Li, G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Cheng, Z.; Lin, J.
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    Ca/Sr ratio dependent structure and up-conversion luminescence of (Ca1-xSrx)In2O4 : Yb3+/Ho3+ phosphors / M. Guan [et al.] // RSC Adv. - 2015. - Vol. 5, Is. 73. - P. 59403-59407, DOI 10.1039/c5ra08467a. - Cited References:25. - This present work was supported by the National Natural Science Foundations of China (Grant no. 51202226), the Fundamental Research Funds for the Central Universities (Grant no. 2652014125, 2652013128, 2652013043), and the Research Fund for the Doctoral Program of Higher Education of China (Grant no. 20130022110006). . - ISSN 2046-2069
   Перевод заглавия: Структура зависящая от Ca/Sr соотношения и люминесценция с апконверсией в люминофоре (Ca1-xSrx)In2O4: Yb3+/Ho3+

РУБ Chemistry, Multidisciplinary
Рубрики:
CO-DOPED CAIN2O4
   ENERGY-TRANSFER
   PHOTOLUMINESCENCE
   EMISSION
   SRIN2O4
Аннотация: Up-conversion (UC) phosphors of (Ca1-xSrx)In2O4 : Yb3+/Ho3+ (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0) were prepared. Based on the crystal structure evolution of these series solid solution samples, which were characterized by Rietveld refinement, the variation of UC luminescent properties was discussed in detail. Sr and Ca occupied one position and Yb/Ho dissolved in the In ion site in the (Ca1-xSrx)In2O4 lattice. With increasing Sr substituting Ca atoms, the cell parameters and cell volumes of these samples increased linearly, and distortions of (Ca/Sr)O-8 polyhedron were formed. The distortions on crystal structures showed a negative relation with UC luminescent intensities in these series phosphors.

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Держатели документа:
China Univ Geosci, Natl Lab Mineral Mat, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Univ Auckland, Dept Chem & Mat Engn, Auckland 1142, New Zealand.

Доп.точки доступа:
Guan, Ming; Zheng, Hong; Huang, Zhaohui; Ma, Bin; Molokeev, M. S.; Молокеев, Максим Сергеевич; Huang, Saifang; Mei, Lefu
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    Ca6La4(SiO4)2(PO4)4O2:Eu2+: a novel apatite green-emitting phosphor for near-ultraviolet excited w-LEDs / Y. F. Xia [et al.] // J. Mater. Chem. C. - 2016. - Vol. 4, Is. 21. - P. 4675-4683, DOI 10.1039/c6tc01418f. - Cited References:37. - This study was sponsored by the National Natural Science Foundation of China (Grant No. 51472223), the Program for New Century Excellent Talents in University of Ministry of Education of China (Grant No. NCET-12-0951) and the Fundamental Research Funds for the Central Universities (Grant No. 2652015020 and Grant No. 2652015008). . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Ca6La4(SiO4)2(PO4)4O2:Eu2+: Новый зеленый люминофор со структурой апатита для белых люминесцентных ламп (w-LED), облучающихся ультрафиолетом

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
SOLID-SOLUTION PHOSPHORS
   PULSED-LASER DEPOSITION
   HIGH THERMAL-STABILITY
   WHITE-LIGHT
   LUMINESCENCE PROPERTIES
   ENERGY-TRANSFER
   SINGLE-PHASE
   CRYSTAL-STRUCTURE
   RED LUMINESCENCE
   EPITAXIAL-GROWTH
Аннотация: A novel apatite phosphor Ca6La4(SiO4)2(PO4)4O2:Eu2+ was prepared by conventional high-temperature solid-state reaction. Phase purity was examined by XRD and XPS analysis. The crystal structure information, such as space group, cell parameters and atomic coordinates, were refined by the Rietveld method, revealing that Eu2+ occupied the sites of Ca2+ ions. Moreover, low-temperature experiments, including low-temperature PL spectra and low-temperature decay curve, were used to prove the existence of two luminescence centers in Ca6La4(SiO4)2(PO4)4O2:Eu2+. With the increase in doping concentration of Eu2+, the emission wavelength shows a red shift from 498 nm to 510 nm, which is mainly caused by the increase in crystal-field splitting by Eu2+. The optimized concentration of Eu2+ was confirmed to be 0.01, the Rc was calculated to be 20.09 Å and the energy transfer between Eu2+ was demonstrated to be by exchange interaction. Moreover, good thermal stability has been proved by a temperature-dependence experiment; it shows that the phosphor can maintain 55% of emitting intensity at 150 °C compared to that at room temperature. Finally, the Ca6La4(SiO4)2(PO4)4O2:Eu2+ phosphor was fabricated with commercial red (CaAlSiN3:Eu2+) and blue (BAM:Eu2+) phosphor coating on a n-UV chip. This proves that this green phosphor has the potential to be used in a w-LED lamp.

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Держатели документа:
China Univ Geosci, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing 100083, Peoples R China.
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Xia, Y. F.; Liu, Y. G.; Huang, Z. H.; Fang, M. H.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mei, L. F.
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    Cation substitution dependent bimodal photoluminescence in whitlockite structural Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors / H. P. Ji [et al.] // Inorg. Chem. - 2014. - Vol. 53, Is. 20. - P. 11119-11124, DOI 10.1021/ic501679f. - Cited References: 37. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), the Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), and Beijing Youth Excellent Talent Program (YETP0635). V.V.A. acknowledges the Ministry of Education and Science of the Russian Federation for financial support. . - ISSN 0020-1669. - ISSN 1520-510X
   Перевод заглавия: Катион зависимая бимодальная люминесценция в твердом растворе Ca3-xSrx(PO4)2:Eu2+ (0 ˂ x ˂ 2) со структурой витлокита

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
LIGHT-EMITTING-DIODES
   EFFICIENT ENERGY-TRANSFER
   EMISSION-TUNABLE PHOSPHOR
   EXCITED WHITE LEDS
   CRYSTAL-STRUCTURE
   LUMINESCENCE PROPERTIES
   Mn2+ PHOSPHOR
   COLOR TONE
   PHASE
   Eu2+
Аннотация: Cation substitution dependent tunable bimodal photoluminescence behavior was observed in the Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors. The Rietveld refinements verified the phase purity and whitlockite type crystal structure of the solid solutions. The tunable photoluminescence evolution was studied as a function of strontium content, over the composition range 0.1 ≤ x ≤ 2. In addition to the emission band peak at 416 nm in Ca3(PO4)2:Eu2+, the substitution of Ca2+ by Sr2+ induced the emerging broad-band peak at 493-532 nm. A dramatic red shift of the emission peak located in the green-yellow region was observed on an increase of x in the samples with 0.75 ≤ x ≤ 2.00. The two emission bands could be related to the EuOn-Ca9 and EuOn-Ca9-xSrx emitting blocks, respectively. The values for the two kinds of emitting blocks in the solid solutions can be fitted well with the observed intensity evolution of the two emission peaks.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
Univ Auckland, Dept Chem & Mat Engn, Auckland 1142, New Zealand

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Ji, H. P.; Huang, Z. H.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Huang, S. F.
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10.

    Chemical group substitution enables highly efficient Mn4+ luminescence in heterovalent systems / H. Ming, Y. Zhao, Y. Zhou [et al.] // Adv. Optical Mater. - 2023. - Vol. 11, Is. 10. - Ст. 2300076, DOI 10.1002/adom.202300076. - Cited References: 36. - This work was financially supported by the National Key Research and Development Program of China (2022YFB3503800), the National Science Foundation of China (Grant Nos. 52202170 and 51972117). This work was also funded by RFBR according to the research project No. 19-52-80003 . - ISSN 2195-1071
   Перевод заглавия: Замена химической группы обеспечивает высокоэффективную люминесценцию Mn4+ в гетеровалентных системах
Кл.слова (ненормированные):
defects -- heterovalent substitution -- Mn4+ -- oxyfluoride -- phosphors
Аннотация: Defects are a double-edged sword for heterovalent metal-ion doping phosphors. Along with the luminescence tunability of phosphors bestowed by defects, their expected luminescence efficiency would also be inevitably lowered due to the presence of these quenching sites. Herein, a chemical group substitution strategy is proposed, where inorganic polyhedrons act as the smallest chemical units during the structural evolution of the doping process. Such a method can not only effectively prevent the defect generation for charge compensation in heterovalent doping systems, but also facilitate the incorporation of activators into the matrix, leading to extremely high luminescence efficiency. The concept is first confirmed energetically favorable by first-principles simulations. As a robust experimental proof, two newly reported Mn4+-incorporated hexavalent organic-inorganic hybrid oxyfluorides (TMA)2BO2F4:Mn4+ (where TMA stands for tetramethylammonium, and B = W6+ or Mo6+) present high quantum efficiency (up to 94.4%) and short lifetime (down to 2.26 ms) that are superior to the commercial red phosphor K2SiF6:Mn4+ (≈84.8%, ≈8.06 ms). Utilizing the differences in decay lifetimes and thermal quenching behaviors of (TMA)2BO2F4:Mn4+ and K2SiF6:Mn4+, a time- and temperature-resolved single-color multiplexing mode with high-safety and easy-access is developed for information security. This work offers an effective strategy to manipulate defect generation in luminescent materials.

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Держатели документа:
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, and Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices, South China University of Technology, Guangzhou, 510641 P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036 Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041 Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021 Russia
School of Physics and Optoelectronics, South China University of Technology, Guangzhou, 510641 P. R. China

Доп.точки доступа:
Ming, Hong; Zhao, Yifei; Zhou, Yayun; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, Yuanjing; Song, Enhai; Zhang, Qinyuan
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