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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev D. S., Shtareva A. V., Ryabchuk V. K., Rudakova A. V., Murzin P. D., Molokeev M. S., Koroleva A. V., Blokh A. I., Serpone N.
Заглавие : Solid-state synthesis, characterization, UV-induced coloration and photocatalytic activity – The Sr6Bi2O11, Sr3Bi2O6 and Sr2Bi2O5 bismuthates
Место публикации : Catal. Today. - 2020. - Vol. 340. - P.70-85. - ISSN 09205861 (ISSN), DOI 10.1016/j.cattod.2018.09.035
Примечания : Cited References: 52. - The research was kindly funded by a grant from the Russian Science Foundation (project No. 17-73-00007). P.D. Murzin, A.V. Rudakova and V.K. Ryabchuk are grateful for financial support by the Mega-grant (No. 14.Z50.31.0016 ) from the Government of the Russian Federation within the Project “Establishment of the Laboratory of Photoactive Nanocomposite Materials” . The authors are very grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics FEB RAS, and the Resource Centers of the Research Park at the Saint-Petersburg State University: (i) Center for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, (ii) Center for Physical Methods of Surface Investigation, (iii) Center for Optical and Laser Materials Research, and (iv) the Nanophotonics Center for their valuable assistance in carrying out the research and in providing the needed equipment. One of us (NS) is grateful to Prof. Angelo Albini for his continued hospitality in the PhotoGreen Laboratory at the University of Pavia, Italy.
Аннотация: This article reports on two novel strontium bismuthate photocatalysts (Sr6Bi2O11 and Sr3Bi2O6) prepared by a solid-state synthesis for which the number of strontium atoms exceeds the number of bismuth atoms in the cation sublattice; for comparison, the bismuthate Sr2Bi2O5 was also re-examined. All three bismuthates were characterized by a variety of spectroscopic techniques (XRD, XPS, EDX, DR, Raman, SEM, and EIS). Direct bandgap energies for the three bismuthates were assessed from diffuse reflectance spectra: 2.61 eV for Sr6Bi2O11; 3.40 eV for Sr3Bi2O6; 3.17 eV for Sr2Bi2O5, while the flatband potentials (versus NHE) of the corresponding valence bands were estimated from XPS spectra: +2.22 eV for Sr6Bi2O11; +1.71 eV for Sr3Bi2O6; +1.61 eV for Sr2Bi2O5. The two novel bismuthates displayed photocatalytic activity toward the photodegradation of acetaldehyde in the gas phase and phenol in aqueous media, with the Sr6Bi2O11 system exhibiting significantly greater photoactivity vis-à-vis the Sr3Bi2O6 bismuthate; by comparison, Sr2Bi2O5 was photocatalytically inactive in this case; their photoactivity was also assessed from the photodegradation of phenol in aqueous media (in all cases using UV-Vis irradiation from a Xe light source). Detailed photocatalytic mechanisms are proposed based on UV-induced coloration studies (carried out using a high-pressure Hg lamp; 365 nm) and on the photodegradation in the presence of radical scavengers to explain how composition and structure of the three bismuthates affect their photocatalytic activity. The role of point defects (oxygen vacancies) in their crystal lattice is described as they affect photocatalytic activity by acting as electron traps and potentially as electron/hole recombination centers.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev D. S., Shtareva A. V., Molokeev M. S., Syuy A. V., Nashchochin E. O.
Заглавие : About photocatalytic properties of some heterostructures based on strontium bismuthate
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials
Место публикации : Key Eng. Mater. - 2019. - Vol. 806 KEM. - P.161-166. - ISSN 10139826 (ISSN); 9783035715682 (ISBN), DOI 10.4028/www.scientific.net/KEM.806.161
Примечания : Cited References: 9. - The research was carried out at the expense of a grant from the Russian Science Foundation (project No. 17-73-00007).
Аннотация: In the work, some heterostructures consisting of two different strontium bismuthates from the following series are investigated: Sr2Bi2O5, Sr3Bi2O6 and Sr6Bi2O11. It is shown that the creation of such heterostructures affects both optical and photocatalytic properties. The results obtained are promising for the further development and research of new heterostructures based on two different strontium bismuthates and for studying the characteristics of their photocatalytic activity. © 2019 Trans Tech Publications Ltd, Switzerland
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev D. S., Ryabchuk V. K., Rudakova A. V., Shtareva A. V., Molokeev M. S., Kirichenko E. A., Serpone N.
Заглавие : Phenomenological rule from correlations of conduction/valence band energies and bandgap energies in semiconductor photocatalysts: calcium bismuthates versus strontium bismuthates
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]; Saint-Petersburg State University [39054581]
Место публикации : ChemCatChem. - 2020. - Vol. 12, Is. 6. - P.1551-1555. - ISSN 1867-3880, DOI 10.1002/cctc.201902236. - ISSN 1867-3899(eISSN)
Примечания : Cited References: 13. - The research was supported from a grant from the Russian Science Foundation (project No. 19-73-10013). We are very grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics FEB RAS, and of the Research Center on Nanophotonics and the Center for Physical Methods of Surface Investigation (to Dr. Alexandra Koroleva) of the Research Park at Saint-Petersburg State University for their valuable assistance in carrying out the research and in providing the needed equipment. VKR and AVR acknowledge financial support from a grant by the Saint-Petersburg State University (Pure ID 39054581). One of us (NS) thanks Prof. A. Albini and the staff of the PhotoGreen Laboratory of the University of Pavia for their continued hospitality
Предметные рубрики: STRUCTURAL-PROPERTIES
Аннотация: A number of calcium bismuthates were synthesized (25 to 50 mol% in Ca) and characterized by XRD, SEM, EDX, XPS and DRS techniques; the latter provided an estimate of the bandgap energies (Ebg=2.41 to 3.29 eV) via Tauc plots for indirect transitions, whereas XPS established the potentials (vs NHE) of their respective valence bands (and thus the conduction bands). Linear correlations existed between EVB/ECB and Ebg that when compared with those of strontium bismuthates (reported earlier) showed that differences in energies at Ebg=0 eV are related to the difference in the absolute electronegativities of Ca and Sr, from which the following empirical phenomenological rule is postulated: replacing one alkaline earth metal in bismuthates by another causes the points of intersection of the linear correlations ECB(Ebg) and EVB(Ebg) to be displaced by an amount equal to twice the difference in absolute electronegativities of these metals.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Markovskaya, Dina, V, Zhurenok, Angelina, V, Kurenkova, Anna Yu, Kremneva, Anna M., Saraev, Andrey A., Zharkov S. M., Kozlova, Ekaterina A., Kaichev, Vasily V.
Заглавие : New titania-based photocatalysts for hydrogen production from aqueous-alcoholic solutions of methylene blue
Место публикации : RSC Adv. - 2020. - Vol. 10, Is. 56. - P.34137-34148. - ISSN 2046-2069(eISSN), DOI 10.1039/d0ra07630a
Примечания : Cited References: 57. - The XPS and XRD experiments were performed using facilities of the shared research center "National center for investigation of catalysts" at Boreskov Institute of Catalysis. The authors are grateful to Dr S. Cherepanova for the XRD study and Dr T. Larina and Dr D. Selishchev for the UV-vis measurements. The TEM investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Предметные рубрики: Ray absorption-edge
In-situ
Ag nanoparticles
Chemical-states
XPS analysis
Аннотация: A series of CuOx–TiO2 photocatalysts were prepared using fresh and thermally activated Evonik Aeroxide P25 titanium dioxide. The photocatalysts were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, XANES, diffuse reflectance spectroscopy, and N2 adsorption technique. Photocatalytic activity of the samples was tested in hydrogen production from aqueous-alcoholic solutions of methylene blue under UV radiation (λ = 386 nm). It was found for the first time the synergistic effect of hydrogen production from two substrates—dye and ethanol. The maximum hydrogen production rate in the system water–ethanol–methylene blue was 1 μmol min−1, which is 25 times higher than a value measured in a 10% solution of ethanol in water. The thermal activation of titania also leads to a change in the rate of hydrogen production. The highest catalytic activity was observed for a CuOx–TiO2 photocatalyst based on titania thermally-activated at 600 °C in air. A mechanism of the photocatalytic reaction is discussed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kholtobina A. S., Kovaleva E. A., Melchakova J., Ovchinnikov S. G., Kuzubov A. A.
Заглавие : Theoretical investigation of the prospect to tailor ZnO electronic properties with VP thin films
Место публикации : Nanomaterials. - 2021. - Vol. 11, Is. 6. - Ст.1412. - ISSN 20794991 (ISSN), DOI 10.3390/nano11061412
Примечания : Cited References: 75. - This research was funded by the Russian Science Foundation, grant number 20-73-00179. The authors would like to thank the Information Technology Centre, Novosibirsk State University for providing access to their supercomputers
Аннотация: The atomic and electronic structure of vanadium phosphide one-to four-atomic-layer thin films and their composites with zinc oxide substrate are modelled by means of quantum chemistry. Favorable vanadium phosphide to ZnO orientation is defined and found to remain the same for all the structures under consideration. The electronic structure of the composites is analyzed in detail. The features of the charge and spin density distribution are discussed.
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