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Chemistry of vinylidene complexes—XXVII—new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural and electrochemical study / V. V. Verpekin, O. S. Chudin, A. A. Kondrasenko [et al.] // Transition Met. Chem. - 2022. - Vol. 47. Is. 7-8. - P. 283-292, DOI 10.1007/s11243-022-00511-w. - Cited References: 46. - This work was conducted within the framework of the budget project 0287–2021-0012 for Institute of Chemistry and Chemical Technology SB RAS . - ISSN 0340-4285
Кл.слова (ненормированные):
Binary alloys -- Cyanides -- Ligands -- Manganese alloys -- Nuclear magnetic resonance spectroscopy -- Platinum compounds -- Redox reactions -- Chemical oxidation -- Electrochemical studies -- Isocyanide ligands -- Redox property -- Spectroscopic studies -- Structural studies -- Vinylidene complexes -- X-ray diffraction studies -- Platinum alloys
Аннотация: New binuclear MnPt µ-vinylidene complexes Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)(L) [L=PPh3 (1a), P(OPri)3 (2a)] bearing a terminal platinum-coordinated 1-adamantyl isocyanide ligand were prepared by the treatment of Cp(CO)2Mn(µ-C=CHPh)Pt(CO)(L) [L=PPh3 (1b), P(OPri)3 (2b)] with CN-Ad. At the same time the reaction between Cp(CO)2Mn(µ-C=CHPh)Pt(L)2 [L=PPh3 (1c), P(OPri)3 (2c)] and CN-Ad did not proceed. The new complexes were characterized by IR and 1H, 13C, 31P NMR spectroscopy. The molecular structure of Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)[P(OPri)3] (2a) was determined by an X-ray diffraction study. The redox properties of the new complexes and their reactions of chemical oxidation were studied. An influence of the platinum-coordinated 1-adamantyl isocyanide ligand on the properties of the synthesized µ-vinylidene compounds 1a and 2a was revealed.

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Держатели документа:
Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-24, Krasnoyarsk, 660036, Russian Federation
Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny Prospect, 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Verpekin, V. V.; Chudin, O. S.; Kondrasenko, A. A.; Burmakina, G. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Zimonin, D. V.; Rubaylo, A. I.
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Chemistry of vinylidene complexes. XXV. Synthesis and reactions of binuclear µ-vinylidene RePt complexes containing phosphite ligands. Spectroscopic, structural and electrochemical study / O. S. Chudin, V. V. Verpekin, A. A. Kondrasenko [et al.] // Inorg. Chim. Acta. - 2020. - Vol. 505. - Ст. 119463, DOI 10.1016/j.ica.2020.119463. - Cited References: 56. - This work was conducted within the framework of the budget project AAAA-A17-117021310221-7 for Institute of Chemistry and Chemical Technology SB RAS using the equipment of Krasnoyarsk Regional Research Equipment Centre of SB RAS . - ISSN 0020-1693
Кл.слова (ненормированные):
Vinylidene complexes -- Rhenium -- Platinum -- NMR -- X-ray diffraction -- Redox properties
Аннотация: Reactions of Cp(CO)2ReCCHPh with Pt[P(OR)3]4 (R = Pri, Et, Ph) gave binuclear μ-vinylidene complexes Cp(CO)2RePt(μ-CCHPh)[P(OR)3]2. Treatment of the previously synthesized Cp(CO)2Re(μ-CCHPh)Pt(PPh3)2 with triisopropylphosphite or triethylphosphite resulted in a stepwise substitution of PPh3 ligands, leading to the disubstituted Cp(CO)2RePt(μ-CCHPh)[P(OR)3]2 and monosubstituted Cp(CO)2RePt(μ-CCHPh)[P(OR)3](PPh3) (R = Pri or Et) species, while no triphenylphosphine ligand substitution in the reaction with P(OPh)3 occurs at all. The monosubstituted Cp(CO)2RePt(μ-CCHPh)[P(OR)3](PPh3) (R = Pri, Et, Ph) species were also obtained by reacting Cp(CO)2ReCCHPh with mixed-ligand complexes Pt(PPh3)3L (L = P(OPri)3, P(OEt)3, P(OPh)3). Reactions of Cp(CO)2RePt(μ-CCHPh)LL′ (L = L′ = P(OPri)3, P(OEt)3, P(OPh)3; L = P(OPri)3, P(OEt)3, P(OPh)3, L′ = PPh3) with Co2(CO)9 yield tricarbonyl vinylidene species Cp(CO)2RePt(μ-CCHPh)[P(OR)3](CO) (R = Pri, Et, Ph). The obtained compounds were characterized by IR and 1H, 13C, 31P NMR spectroscopy. The molecular structures of Cp(CO)2RePt(μ-CCHPh)[P(OPri)3]2, Cp(CO)2RePt(μ-CCHPh)[P(OPri)3](PPh3) and Cp(CO)2RePt(μ-CCHPh)[P(OPri)3](CO) were determined by X-ray diffraction study. The redox properties of the new complexes and their reactions of chemical oxidation were studied.

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Держатели документа:
Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-24, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny Prospect, 79, Krasnoyarsk, 660041, Russian Federation
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave., 3, Novosibirsk, 630090, Russian Federation
Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation
Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok, 50-38, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Chudin, O. S.; Verpekin, V. V.; Kondrasenko, A. A.; Burmakina, G. V.; Piryazev, D. A.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Pavlenko, N. I.; Zimonin, D. V.; Rubaylo, A. I.
}
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Ion exchange recovery of platinum(IV) from hydrochloric acid solutions in the presence of silver(I) / O. N. Kononova, E. V. Duba, A. S. Efimova [et al.] // Russ. J. Phys. Chem. A. - 2020. - Vol. 94, Is. 4. - P. 828-834, DOI 10.1134/S003602442004007X. - Cited References: 35 . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
GROUP METALS
   SORPTION
   PALLADIUM
   RESINS
Кл.слова (ненормированные):
platinum -- silver -- hydrochloric solutions -- anion exchangers -- sorption
Аннотация: The ion exchange sorption of the platinum(IV) chloride complexes in the presence of silver(I) chloro complexes from 2 and 4 M aqueous solutions of hydrochloric acid is studied on Purolite anion exchangers with different functional groups. The high selectivity of the investigated sorbents with respect to platinum during its recovery from individual hydrochloric acid solutions and in the presence of silver chloride complexes is determined. Since the latter are in this case virtually not sorbed in the presence of platinum(IV), they can be separated at the stage of sorption. The excellent kinetic properties of the investigated anion exchangers are revealed, allowing platinum to be eluted after its separation from silver chloro complexes in a dynamic mode.

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Публикация на русском языке Ионообменное извлечение платины(IV) в присутствии серебра(I) из солянокислых растворов [Текст] / О. Н. Кононова, Е. В. Дуба, А. С. Ефимова [и др.] // Журн. физ. химии. - 2020. - Т. 94 № 4. - С. 602-609

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Kirensky Inst Phys, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Kononova, O. N.; Duba, E. V.; Efimova, A. S.; Ivanov, A. I.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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Study of Co x Pt 1-x nanoalloy formation mechanism via single-source precursors / E. Y. Filatov [et al.] // Powder Diffr. - 2019. - Vol. 34, Suppl. S1. - P. S27-S31, DOI 10.1017/S0885715619000162. - Cited References: 13. - This work was supported by the Russian Foundation for Basic Research (Grant nos. 17-03-00950 and 18-03-00777). Aleksei Chepurov acknowledges support of the state assignment project 0330-2016-0012. . - ISSN 0885-7156
Кл.слова (ненормированные):
nanoalloy formation -- powder diffraction -- nanoparticles -- cobalt -- platinum
Аннотация: This paper is devoted to the study of formation mechanism of metal solid solutions during the thermolysis of single-source precursors in Co–Pt systems with a wide range of superstructural ordering. It is shown that the thermal decomposition of [Pt(NH3)4][Co(C2O4)2(H2O)2]·2H2O salt in helium is critically different from that under hydrogen atmospheres. Thermal degradation under the helium atmosphere is followed by a gradual reduction of platinum and cobalt, and at each thermolysis temperature only one phase is present. At 380 °C an equiatomic Co0.50Pt0.50 solid solution is formed (a = 3.749 (4) Å, Fm−3m space group, V/Z = 13.17 Å3, crystallite size: 5–7 nm). When the precursor is decomposed under a hydrogen atmosphere, the process proceeds mainly through the simultaneous reduction of the platinum and cobalt atoms, and at each temperature section two metal phases are present. The formation of the close to equiatomic Co0.50Pt0.50 solid solution (a = 3.782 (4) Å, Fm−3m space group, V/Z = 13.52 Å3, crystallite size: 7–9 nm) occurs at 450 °C. The calculations of crystallite sizes are confirmed by transmission electron microscopy data.

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Держатели документа:
Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russian Federation
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentyev Ave. 3, Krasnoyarsk, 630090, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Sobolev Institute of Geology and Mineralogy SB RAS, Koptyuga Ave.3, Novosibirsk, 630090, Russian Federation

Доп.точки доступа:
Filatov, E. Y.; Zadesenets, A. V.; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Plyusnin, P. E.; Chepurov, A. A.; Korenev, S. V.
}
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Chemistry of vinylidene complexes. XXIV. A new μ-vinylidene complex containing RePt core, and platinum-bound carbonyl ligand. Spectroscopic, structural and electrochemical study / V. V. Verpekin [et al.] // J. Mol. Struct. - 2018. - Vol. 1163. - P. 308-315, DOI 10.1016/j.molstruc.2018.03.020. - Cited References: 45. - The reported study was funded by the State budget allocated to the fundamental research in the Russian Academy of Sciences in the framework of Project No. V.44.1.7 and was financially supported by Krasnoyarsk Region Science and Technology Support Fund (the junior scientists project no. 3/15). . - ISSN 0022-2860. - ISSN 1872-8014

РУБ Chemistry, Physical
Рубрики:
TRI-METAL COMPLEXES
   RAY CRYSTAL-STRUCTURE
   BRIDGING CARBENE
   CARBYNE
Кл.слова (ненормированные):
Rhenium -- Platinum -- Vinylidene complexes -- Heterometallic complexes -- Electrochemistry
Аннотация: The novel heterobinuclear μ-vinylidene complex [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)(CO)] (1) was isolated from the reaction mixture of [Cp(CO)2Re(μ-C=CHPh)Fe(CO)4] and Pt(PPh3)4 for the first time. Alternative high-yield synthetic approaches to 1 were developed including the reactions of [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)2] (2) with Co2(CO)8 and Rh(acac)(CO)2. The complex was characterized by IR and ¹H, ¹³C and ³¹P NMR spectroscopy, a molecular structure of 1 was determined by X-ray diffraction analysis. The electrochemical behavior of the new complex was studied by cyclic voltammetry at platinum or glassed carbon electrodes and by dc polarography at a dropping mercury electrode.

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Держатели документа:
RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia.
RAS, SB, Fed Res Ctr, Inst Phys,Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
RAS, Fed Res Ctr, SB, Krasnoyarsk Sci Ctr, Akademgorodok 50, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Verpekin, V. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Kondrasenko, A. A.; Burmakina, G. V.; Chudin, O. S.; Pavlenko, N. I; Zimonin, Dmitry V.; Rubaylo, Anatoly I.; Russian Academy of Sciences [V.44.1.7]; Krasnoyarsk Region Science and Technology Support Fund [3/15]
}
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Ion-exchange sorption of palladium(II) from hydrochloric acid solutions in the presence of silver(I) / O. N. Kononova [et al.] // Russ. J. Phys. Chem. A. - 2018. - Vol. 92, Is. 10. - P. 2053-2059, DOI 10.1134/S0036024418100138. - Cited References: 36 . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
PLATINUM-GROUP METALS
   RECOVERY
   COMPLEXES
   CHLORIDE
   PD(II)
Кл.слова (ненормированные):
palladium -- silver -- hydrochloric acid solutions -- sorption -- sorptive extraction
Аннотация: The sorptive extraction of palladium(II) chloride complexes in the presence of silver(I) chloride complexes from 2 and 4 M aqueous solutions of HCl with a series of Purolite anionites with different functional groups is studied. An anion exchange mechanism of sorption is identified from Raman spectroscopy data. Kinetic properties that are inherent to the investigated ionites and allow the elution of palladium(II) and silver(I) after their extraction in a dynamic mode are revealed.

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Публикация на русском языке Ионообменная сорбция палладия (II) в присутствии серебра (I) из солянокислых растворов [Текст] / О. Н. Кононова [и др.] // Журн. физ. химии. - 2018. - Т. 92 № 10. - С. 1641-1647

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660025, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Kononova, O. N.; Duba, E. V.; Medovikov, D. V.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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Decoration of carbon nanomaterial powders with dispersed platinum metal particles / V. G. Isakova [et al.] // Russ. J. Appl. Chem. - 2018. - Vol. 91, Is. 7. - P. 1209-1216, DOI 10.1134/S1070427218070212. - Cited References: 22. - The study was performed with the support and equipment of the Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. . - ISSN 1070-4272. - ISSN 1608-3296

РУБ Chemistry, Applied
Рубрики:
NANOPARTICLES
   PALLADIUM
   FULLERENE
   ELECTRODE
   NANOTUBES
   OXIDATION
Кл.слова (ненормированные):
carbon nanomaterials -- platinum metal nanoparticles -- in situ one-step method
Аннотация: Carbon nanomaterials (fullerite, detonation nanodiamonds, Taunit, fullerenol, fullerene-containing black) were decorated with platinum group metal nanoparticles in situ in one step by low-temperature combustion (~250–270°С) of a powdered mixture of platinum metal acetylacetonate [Pt-M(асас)n, Pt-М = Pt(II), Pd(II), Rh(III), Ir(III), acac = CH3COCHCOCH3, n is the oxidation state of Pt-М] with carbon nanomaterials in air. As shown by thermal analysis, the process is based on thermal oxidative degradation of the organometallic complex, catalyzed by carbon nanomaterials, with oxidation (combustion) of the organic moiety and release of the metal into the condensed phase. The thermal process in an open system occurs in the glowing mode (210–250°С); the size of the nanoparticles formed is 7–30 nm. Under the conditions restricting the air access to the reaction mixture and free outflow of gaseous products formed by oxidation of acac ligands, the nanoparticle size decreases to 3–10 nm. The particle size depends on the metal amount in the initial powder mixture and on the support morphology.

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Публикация на русском языке Декорирование порошков углеродных наноматериалов дисперсными частицами платиновых металлов [Текст] : статья / В. Г. Исакова [и др.] // Журн. прикл. химии. - 2018. - Т. 91 № 7. - С. 1040-1048

Держатели документа:
Russian Acad Sci, Kirenksy Inst Phys, Separate Dept, Fed Res Ctr,Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Fed Res Ctr, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Isakova, V. G.; Исакова, Виктория Гавриловна; Osipova, I. V.; Осипова, Ирина Владимировна; Dudnik, A. I.; Дудник, Александр Иванович; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Zharikova, N. V.; Nemtsev, I. V.; Volochaev, M. N.; Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences
}
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Structure of a trinuclear μ3-vinylidene cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 / O. S. Chudin [et al.] // J. Struct. Chem. - 2017. - Vol. 58, Is. 3. - P. 600-602, DOI 10.1134/S0022476617030234. - Cited References: 15 . - ISSN 0022-4766
Кл.слова (ненормированные):
heterometallic clusters -- iron -- manganese -- platinum -- single crystal X-ray diffraction analysis -- vinylidene complexes
Аннотация: The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å3, space group C2/c, Z = 8, dcalc = 1.741 g/cm3. The cluster molecule contains a bridging phenylvinylidene ligand coordinated to a metallic core in the form of a Mn–Fe–Pt chain (the Mn–Fe and Fe–Pt bond lengths are 2.6768(14) Å and 2.6280(11) Å respectively and the Mn⋯Pt distance is 3.6425(19) Å).

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Публикация на русском языке Структура трехъядерного μ3-винилиденового кластера CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 [Текст] / О. С. Чудин [и др.] // Журн. структ. химии. - 2017. - Т. 58 № 3. - С. 628-630

Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Chudin, O. S.; Verpekin, V. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Rubaylo, A. I.
}
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Antitumor effect of arabinogalactan and platinum complex / A. K. Starkov [et al.] // Dokl. Biochem. Biophys. - 2016. - Vol. 467, Is. 1. - P. 92-94, DOI 10.1134/S1607672916020046. - Cited References: 7. - This study was supported by the Ministry of Education and Science of the Russian Federation (agreement no. 14.607.21.0104). This study was performed using the shared-access equipment center of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. . - ISSN 1607-6729

РУБ Biochemistry & Molecular Biology + Biophysics

Аннотация: The article presents the results of investigation of antitumor properties of platinum–arabinogalactan complex. We showed the ability of the complex to inhibit the growth of Ehrlich ascites tumor cells. It is found that the distribution of the platinum–arabinogalactan complex is not specific only for tumor cells in mice. The complex was found in all tissues and organs examined (ascites cells, embryonic cells, kidney, and liver). The mechanism of action of the arabinogalactan–platinum complex may be similar to cisplatin as the complex is able to accumulate in tumor cells. © 2016, Pleiades Publishing, Ltd.

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Публикация на русском языке Противоопухолевый эффект комплекса арабиногалактана с платиной [Текст] / А. К. Старков [и др.] // Докл. Акад. наук : Наука, 2016. - Т. 467 № 1. - С. 112-114

Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Voino-Yasenetskii State Medical University, Ministry of Health of the Russian Federation, ul. Partizana Zheleznyaka 1, Krasnoyarsk, Krasnoyarsk krai, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, Russian Federation
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Starkov, A. K.; Zamay, T. N.; Замай, Т. Н.; Savchenko, A. A.; Ingevatkin, E. V.; Titova, N. M.; Kolovskaya, O. S.; Коловская, О. С.; Luzan, N. A.; Silkin, P. P.; Kuznetsova, S. A.; Кузнецова, Светлана Алексеевна
}
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10.

Rhodium(III) speciation in concentrated nitric acid solutions / D. Vasilchenko [et al.] // Eur. J. Inorg. Chem. - 2016. - Vol. 2016, Is. 23. - P. 3822-3828, DOI 10.1002/ejic.201600523. - Cited References:31. - This work was supported by the Russian Foundation for Basic Research (grant number 16-03-00549 A). D. V. thanks the Ministry for Education and Science of the Russian Federation for the award of a President of the Russian Federation for Young Scientists Fellowship. . - ISSN 1434-1948. - ISSN 1099-0682

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
MAGNETIC-RESONANCE
   FISSION PLATINOIDS
   AQUEOUS-SOLUTIONS
   PT-195 NMR
   RH(III)
   SPECTROSCOPY
   CHEMISTRY
   DISSOCIATION
   PLATINUM(IV)
   COMPLEXES
Кл.слова (ненормированные):
Rhodium -- NMR spectroscopy -- Nitrates
Аннотация: The interaction of rhodium(III) aqua ions with nitrate ions in 3–16 m nitric acid solutions has been studied by 103Rh and 15N NMR and Raman spectroscopy. The mononuclear complexes [Rh(H2O)6–n(NO3)n]3–n (n = 1–4) were found to be the only form of rhodium(III) existing in the solutions with the metal concentration in the range 0.2–1.3 m. The dynamics of the H2O → NO3– substitution process was studied at 80 °C. An increase in the average number of nitrate groups bonded to rhodium with increasing concentration of nitric acid was also determined. The fine crystalline salt Rb4trans-[Rh(H2O)2(NO3)4][Rh(NO3)6] was obtained by solvothermal concentration of the rhodium nitric acid solution on addition of rubidium nitrate. The structure of the salt was solved by the powder X-ray diffraction method, with monodentate coordination of nitrato ligands found for both the [Rh(NO3)6]3– and trans-[Rh(H2O)2(NO3)4]– anions.

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Держатели документа:
Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Novosibirsk 630090, Russia.
RAS, Inst Chem & Chem Technol, SB, Krasnoyarsk 660049, Russia.
RAS, Kirensky Inst Phys, SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Vasilchenko, D.; Vorob'eva, S.; Tkachev, S.; Baidina, I. A.; Belyaev, A.; Korenev, S.; Solovyov, L.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Russian Foundation for Basic Research [16-03-00549 A]; Ministry for Education and Science of the Russian Federation
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