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Aver'yanov, E. M.
Anisotropy of the Local Field in Anisotropic Films of Conjugated Polymers / E. M. Aver'yanov // Phys. Solid State. - 2011. - Vol. 53, Is. 9. - P. 1933-1942, DOI 10.1134/S1063783411090046. - Cited References: 51 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
MOLECULAR-WEIGHT DEPENDENCE
   OPTICAL-PROPERTIES
   THIN-FILMS
   MEH-PPV
   POLY(P-PHENYLENE VINYLENE)
   CHAIN ORIENTATION
   REFRACTIVE-INDEX
   CONSTANTS
   POLYACETYLENE
   LIGHT
Аннотация: Using the data on dispersion of refractive indices in the visible region, the experimental values of the components L-j of the Lorentz tensor have been obtained for uniaxial (crystalline, oriented on a substrate, and stretched) films of conjugated polymers from nanometer to micrometer thicknesses. The dependence of the components L-j on the axial and planar orientations of macromolecules with respect to the optical axis of the film, technology of fabricating the films, and chemical structure of macromolecules has been elucidated. The correlation between the components L-j and the measured parameter. has been determined and the analytical dependence L-j(eta) for films with both types of macromolecular orientation has been established. In the visible region (0

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50-38, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Аверьянов, Евгений Михайлович
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Aver'yanov, E. M.
Effective refractive index of a two-dimensional polycrystal / E. M. Aver’yanov // JETP Letters. - 2015. - Vol. 101, Is. 10. - P. 685-689, DOI 10.1134/S0021364015100033. - Cited References: 28 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
SPECTROSCOPIC ELLIPSOMETRY
   CONJUGATED POLYMERS
   LOCAL-FIELD
   FILMS
   CONDUCTIVITY
   POLYFLUORENE
   ANISOTROPY
   DISPERSION
   MEDIA
Аннотация: A relation of the effective refractive index of a two-dimensional polycrystalline dielectric film in the transparency region to the refractive indices n1 and n2 of crystallites at the positions of axes 1 and 2, respectively, of refraction ellipsoids of the crystallites in the plane of the film has been obtained. This relation and the relation L* = (L1 + L2)/2 between the components of the Lorentz tensors for the film and crystallites have been confirmed by comparison with experimental data for conjugate-polymer films with uniaxial domains.

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Публикация на русском языке Аверьянов, Евгений Михайлович. Эффективный показатель преломления двумерного поликристалла [Текст] / Е. М. Аверьянов // Письма в Журн. эксперим. и теор. физ. : Наука, 2015. - Т. 101 Вып. 10. - С. 761-765

Доп.точки доступа:
Аверьянов, Евгений Михайлович
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Aver'yanov, E. M.
Local-field anisotropy in conjugated polymers / E. M. Aver'yanov // JETP Letters. - 2010. - Vol. 91, Is. 9. - P. 455-460, DOI 10.1134/S0021364010090055. - Cited References: 25 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
OPTICAL-CONSTANTS
THIN-FILMS
LASERS
Аннотация: The experimental values of the Lorentz tensor components L (j) have been obtained for uniaxial optically positive and negative films of conjugated polymers with thicknesses of tens of nanometers. The correlation between the components L (j) and the measurable parameter eta has been revealed and the analytical dependence L (j) (eta) has been derived in agreement with the experiment.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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Aver'yanov, E. M.
Local-Field Anisotropy of a Light Wave in Quasi-Two-Dimensional Soft-Matter Objects / E. M. Aver'yanov // J. Exp. Theor. Phys. - 2010. - Vol. 110, Is. 4. - P. 622-636, DOI 10.1134/S1063776110040102. - Cited References: 73. - This study was supported by the Presidium of the Russian Academy of Sciences within the Program of Basic Research (project no. 27.1) and the Siberian Branch of the Russian Academy of Sciences within the Program of Interdisciplinary Basic Research (project no. 5). . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
INTEGRATED OPTICAL TECHNIQUES
   LANGMUIR-BLODGETT-FILMS
   SMECTIC LIQUID-CRYSTALS
   UNIAXIAL POLYMER-FILMS
   MOLECULAR-ORIENTATION
   INTERNAL FIELD
   DIELECTRIC-CONSTANT
   SPECTRAL FEATURES
   REFRACTIVE-INDEX
   THIN-FILMS
Кл.слова (ненормированные):
Anisotropic films -- Bilayer lipid membrane -- Chemical structure -- Comblike polymers -- Conductive Polymer -- Discotics -- Dispersion of refractive index -- Experimental data -- Experimental values -- Hexatic-B phase -- Isotropization -- Langmuir films -- Light wave -- Lorentz -- Macromolecular polymers -- Model approach -- Molecular polarizabilities -- Optical axis -- Order parameter -- Orientational order parameters -- Orientational orderings -- Orientational orders -- Smectic layers -- Smectic-A -- Smectics -- Soft matter -- Structural unit -- Sub-micron films -- Substrate types -- Tensor components -- Visible range -- Anisotropy -- Cell membranes -- Conductive plastics -- Conjugated polymers -- Electronic structure -- Light measurement -- Liquid crystal polymers -- Molecules -- Multilayer films -- Organic polymers -- Phase transitions -- Polarization -- Polymers -- Refractive index -- Substrates -- Tensors -- Two dimensional -- Conductive films
Аннотация: Experimental values of the Lorentz tensor components L-j for uniaxial quasi-two dimensional "soft matter" objects on substrates (bilayer lipid membranes, multilayer Langmuir films, smectics A, hexatic smectics B, submicron films of discotics Col(hd), micron anisotropic films of liquid-crystal comblike polymers and macromolecular polymers, submicron films of conjugated conductive polymers), freely suspended sub-micron films of smectics A, and uniaxially stretched micron films of conjugated conductive polymers have been determined using dispersion of refractive indices in the visible range. The dependences of the components L-j on the type of orientation (axial, planar) of uniaxial molecules (structural units of the film) with respect to the optical axis of the film, the film thickness, the substrate type, the chemical structure of molecules, and their long-range orientational order are established. It is revealed that the smectic A-hexatic B phase transition and two-dimensional crystallization of the smectic layer lead to changes in the components L-j due to the change in the orientational ordering of molecules as a result of the relation between the orientational and hexatic order parameters. All the above objects are characterized by isotropization of the Lorentz tensor L and the local-field tensor f with a simultaneous decrease in the birefringence of the sample and in the anisotropy of the molecular polarizability due to the change in the electronic structure of molecules. The correction for the anisotropy of the local-field tensor f to the orientational order parameter or the anisotropy of the molecular polarizability increases. The existing model approaches to calculating the components L-j for the objects under consideration are compared with the experimental data.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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Biosynthesis and properties of a P(3HB-co-3HV-co-4HV) produced by Cupriavidus necator B-10646 / N. O. Zhila, K. Y. Sapozhnikova, E. G. Kiselev [et al.] // Polymers. - 2022. - Vol. 14, Is. 19. - Ст. 4226, DOI 10.3390/polym14194226. - Cited References: 77. - The study was funded by State Assignment of the Ministry of Science and Higher Education of the Russian Federation (project No. 0287-2021-0025) . - ISSN 2073-4360
Кл.слова (ненормированные):
Cupriavidus necator B-10646 -- γ-valerolactone -- biomass concentration -- content and composition of copolymers -- P(3HB-co-3HV-co-4HV) -- physicochemical properties -- films -- surface properties
Аннотация: Synthesis of P(3HB-co-3HV-co-4HV) copolymers by the wild-type strain Cupriavidus necator B-10646 on fructose or sodium butyrate as the main C-substrate with the addition of γ-valerolactone as a precursor of 3HV and 4HV monomers was studied. Bacterial cells were cultivated in the modes that enabled production of a series of copolymers with molar fractions of 3HV (from 7.3 to 23.4 mol.%) and 4HV (from 1.9 to 4.7 mol.%) with bacterial biomass concentration (8.2 ± 0.2 g/L) and PHA content (80 ± 2%). Using HPLC, DTA, DSC, X-Ray, SEM, and AFM, the physicochemical properties of copolymers and films prepared from them have been investigated as dependent on proportions of monomers. Copolymers are characterized by a reduced degree of crystallinity (Cx 38–49%) molecular weight characteristics Mn (45–87 kDa), and Mw (201–248 kDa) compared with P(3HB). The properties of the films surface of various composition including the porosity and surface roughness were studied. Most of the samples showed a decrease in the average pore area and an increase in their number with a total increase in 3HV and 4HV monomers. The results allow scaling up the productive synthesis of P(3HB-co-3HV-co-4HV) copolymers using Cupriavidus necator B-10646.

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Держатели документа:
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av, Krasnoyarsk, 660041, Russian Federation
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Zhila, N. O.; Sapozhnikova, K. Y.; Kiselev, E. G.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Shishatskaya, E. I.; Volova, T. G.
}
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Biosynthesis and properties of sulfur-containing polyhydroxyalkanoates (PHAs) produced by wild-type strain Cupriavidus necator B-10646 / N. O. Zhila, K. Yu. Sapozhnikova, A. V. Berezovskaya [et al.] // Polymers. - 2023. - Vol. 15, Is. 4. - Ст. 1005, DOI 10.3390/polym15041005. - Cited References: 53. - The study was funded by State Assignment of the Ministry of Science and Higher Education of the Russian Federation (project No. 0287-2021-0025) . - ISSN 2073-4360
Кл.слова (ненормированные):
biosynthesis -- different precursors -- sulfur-containing PHAs -- chemical composition -- 3MP monomers contents -- properties
Аннотация: The study addresses the growth of the wild-type strain Cupriavidus necator B-10646 and the synthesis of sulfur-containing polyhydroxyalkanoates (PHA) by this strain on media containing fructose and three different precursors (3-mercaptopropionic acid, 3′,3′-dithiodipropionic acid and 3′,3′-thiodipropionic acid). By varying the concentration and number of doses of the precursors added into the bacterial culture, it was possible to find conditions that ensure the formation of 3-mercaptopropionate (3MP) monomers from the precursors and their incorporation into the C-chain of poly(3-hydroxybutyrate). A series of P(3HB-co-3MP) copolymer samples with different content of 3MP monomers (from 2.04 to 39.0 mol.%) were synthesized and the physicochemical properties were studied. The effect of 3MP monomers is manifested in a certain decrease in the molecular weight of the samples and an increase in polydispersity. Temperature changes are manifested in the appearance of two peaks in the melting region with different intervals regardless of the 3MP content. The studied P(3HB-co-3MP) samples, regardless of the content of 3MP monomers, are characterized by equalization of the ratio of the amorphous and crystalline phases and have a close degree of crystallinity with a minimum of 42%, = and a maximum of 54%.

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Держатели документа:
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, 660036 Krasnoyarsk, Russia
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., 660041 Krasnoyarsk, Russia
Department of Medical Biology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., 660041 Krasnoyarsk, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, 660036 Krasnoyarsk, Russia
Basic Department of Solid State Physics and Nanotechnology, School of Engineering Physics and Radio Electronics, Siberian Federal University, 26 Kirensky St., 660074 Krasnoyarsk, Russia
International and Interuniversity Centre for Nano Science and Nano Technology, Mahatma Gandhi University, Kottayam 686560, India

Доп.точки доступа:
Zhila, Natalia O.; Sapozhnikova, Kristina Yu.; Berezovskaya, Arina V.; Kiselev, Evgeniy G.; Shishatskaya, Ekaterina I.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Thomas, Sabu; Volova, Tatiana G.
}
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    Chemical modification of films from biosynthetic poly-3-hydroxybutyrate aimed to improvement of their surface properties / A. N. Boyandin, A. A. Sukhanova, E. D. Nikolaeva, I. V. Nemtsev // Macromolecular Symposia. - 2021. - Vol. 395: 4th International Conference on Progress on Polymers and Composites (NOV 26-28, 2020, Electr. Network), Is. 1. - Ст. 2000281, DOI 10.1002/masy.202000281. - Cited References: 11. - This work was carried out by the team of the scientific laboratory "Smart Materials and Structures" within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project "Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions" (No. FEFE-2020-0015). The surface of the samples was investigated using a scanning electron microscope Hitachi TM3000 in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 1022-1360. - ISSN 1521-3900
   Перевод заглавия: Химическая модификация плёнок из биосинтетического поли-3-гидроксибутирата, направленная на улучшение их поверхностных свойств

РУБ Polymer Science

Кл.слова (ненормированные):
biocompatibility -- polyhydroxyalkanoates -- polyhydroxybutyrate -- polymer modification
Аннотация: Films from biodegradable poly-3-hydroxybutyrate are treated with chemical reagents to improve their hydrophilicity and biocompatibility. Two approaches are tested: a single treatment with alkali, acids, oxidizing or reducing agents, and a step-by step treatment of the alkali pre-activated surface of polymer films with bromine water and amino-compounds (ammonia or triethylamine). The maximal level of hydrophilicity (the lowest water contact angle and the highest polar component of the surface free energy) is registered after a single treatment with NaOH and after the step-by-step treatment. These samples also showed the best adhesion of mouse fibroblasts of NIH 3T3 line on the film surface. So, the proposed methods can be used to enhance hydropilicity and biocompatibility of biopolymer surface.

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Держатели документа:
Reshetnev Siberian State Univ Sci & Technol, 31 Krasnoyarsky Rabochy Av, Krasnoyarsk 660037, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr, Inst Biophys,Krasnoyarsk Sci Ctr, 50,Build 50, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Int Sci Ctr Studying Extreme States Organism, Fed Res Ctr,Krasnoyarsk Sci Ctr, 50,Build 12-2, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Fed Res Ctr, 50 Akademgorodok, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Boyandin, A. N.; Sukhanova, Anna Alekseevna; Nikolaeva, Elena Dmitrievna; Nemtsev, I. V.; Немцев, Иван Васильевич; Ministry of Science and Higher Education of the Russian Federation [FEFE-2020-0015]; International Conference on Progress on Polymers and Composites(4th ; 26-28 Nov. 2020)
}
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Composite polymer granules based on poly-ε-caprolactone and montmorillonite prepared by solution-casting and melt extrusion / A. Sukhanova, A. Boyandin, N. Ertiletskaya [et al.] // Polymers. - 2023. - Vol. 15, Is. 20. - Ст. 4099, DOI 10.3390/polym15204099. - Cited References: 45. - This research was supported by a grant from the Russian Science Foundation, project No. 23-16-00184 . - ISSN 2073-4360
Кл.слова (ненормированные):
biodegradable polymers -- poly-ε-caprolactone -- montmorillonite -- polymer composites -- processing technologies
Аннотация: Eco-friendly polymer composites in the form of granules based on biodegradable polycaprolactone (PCL) with the inclusion of montmorillonite (MMT) from 5 to 50 wt% were prepared by solution-casting and melt extrusion. The physicochemical properties of the composite granules were studied using FTIR spectroscopy, XRDA, DSC, and TGA methods. The paper presents comparative values of crystallinity of composite granules which depend on the method of measuring (XRDA, DSC). It was shown that the crystallinity of PCL/MMT granules was affected by the preparation method and by the MMT content, and that with increase in MMT content, crystallinity increased by up to 61–67%. The change in crystallinity of the granules also affected its biodegradation in soil. At the end of exposure in soil, the mass loss for the granules prepared by solution-casting was more than 90%, whereas for the composite granules prepared by extrusion it was less than 60%. Applying melt extrusion enabled obtaining intercalated composites with predictable features, whereas only mixed-structure microcomposites could be prepared by solution-casting.

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Держатели документа:
Department of Biodegradable Polymers Materials, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarskiy Rabochiy Av., Krasnoyarsk 660037, Russia
Department of Analysis, Synthesis, Modeling and Digital Design of Smart Materials with Specified Properties, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarskiy Rabochiy Av., Krasnoyarsk 660037, Russia
Department of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, Krasnoyarsk 660036, Russia
Department Engineering Physics and Radio Electronics, Siberian Federal University, 79 Svobodny Av., Krasnoyarsk 660041, Russia
Department of Digital Design of Transformable Structures based on Smart Materials, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarskiy Rabochiy Av., Krasnoyarsk 660037, Russia
Department of Scientific Activities, Science and Technology, Siberian Federal University, 79 Svobodny Av., Krasnoyarsk 660041, Russia
Department of Intelligent Materials and Systems, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarskiy Rabochiy Av., Krasnoyarsk 660037, Russia

Доп.точки доступа:
Sukhanova, Anna; Boyandin, Anatoly; Ertiletskaya, Natalya; Shalygina, Taisia; Shabanov, A. V.; Шабанов, Александр Васильевич; Vasiliev, Alexander; Obvertkin, Ivan; Brott, Valeria; Prokopchuk, Yulia; Samoilo, Alexander
}
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Correction: Volova et al. Laser processing of polymer films fabricated from PHAs differing in their monomer composition. Polymers 2021, 13, 1553 / T. G. Volova, A. I. Golubev, I. V. Nemtsev [et al.] // Polymers. - 2024. - Vol. 16, Is. 8. - Ст. 1075, DOI 10.3390/polym16081075. - Cited References: 1 . - ISSN 2073-4360

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., 660041 Krasnoyarsk, Russia
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, 660036 Krasnoyarsk, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, 660036 Krasnoyarsk, Russia
Special Design and Technological Bureau ‘Nauka’ Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/45 Akademgorodok, 660036 Krasnoyarsk, Russia
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences” 50 Akademgorodok, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Volova, T. G.; Golubev, A. I.; Голубев, Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.
}
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10.

Crystal structure and properties of the precursor [Ni(H2O)6](HTBA)2·2Н2О and the complexes M(HTBA)2(H2O)2 (M = Ni, Co, Fe) / N. N. Golovnev [et al.] // Polyhedron. - 2014. - Vol. 70. - P. 71-76, DOI 10.1016/j.poly.2013.12.021. - Cited References: 32 . - ISSN 0277-5387

РУБ Chemistry, Inorganic & Nuclear + Crystallography
Рубрики:
2-THIOBARBITURIC ACID
   THIOBARBITURIC ACID
   COLLECTION
   POLYMERS
Кл.слова (ненормированные):
2-Thiobarbiturate complexes -- 3D elements -- IR spectra -- Structure -- Synthesis -- Thermal stability
Аннотация: Four new compounds, the discrete complex [Ni(H2O) 6](HTBA)2 .2H2O (1) and the polymers Ni(H2O)2(HTBA-O,S)2 (2), Co(H 2O)2(HTBA-O,S)2 (3) and Fe(H2O) 2(HTBA-O,S)2 (4) (H2TBA = 2-thiobarbituric acid, C4H4N2O2S), have been synthesized and structurally characterized. The structure of 1 has been solved by X-ray single-crystal diffraction analysis. The Ni(H2O) 6 2+ cation has an almost ideal octahedral geometry, and there is no coordination of Ni(II) by HTBA- in 1. Complexes 2-4 have been characterized by powder XRD, TG-DSC and FT-IR. In the isostructural polymers 2-4, the metals are six-coordinated, and the octahedrons are connected by μ2-O,S bridging ligands. Each of the M(II) ions is surrounded by two water molecules, two O-coordinated HTBA- ions and two S-coordinated HTBA- ions, with all pairs being in trans-positions. Hydrogen bonding and π-π interactions play an important role for the construction of the supramolecular 3D structures of 2-4. The formation of the complexes has been evidenced by infrared spectroscopy. The thermal decomposition of 2-4 under oxidative conditions has been divided into three major stages: dehydration, oxidative degradation of the organic moiety and transformation of the inorganic residue. © 2013 Elsevier Ltd. All rights reserved.

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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk 660041, Russia
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Chem & Chem Technol, Lab Catalyt Convers Small Mol, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Tomsk 634050, Russia

Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereshchagin, S. N.; Atuchin, V. V.; Sidorenko, M. Y.; Dmitrushkov, M. S.
}
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11.

Degradable poly(3-hydroxybutyrate)—the basis of slow-release fungicide formulations for suppressing potato pathogens / T. G. Volova, E. G. Kiselev, S. V. Baranovskiy [et al.] // Polymers. - 2022. - Vol. 14, Is. 17. - Ст. 3669, DOI 10.3390/polym14173669. - Cited References: 118 . - ISSN 2073-4360
Кл.слова (ненормированные):
fungicides -- degradable P(3HB) -- slow-release formulations -- physico-chemical properties -- degradation in soil -- suppression of plant pathogens
Аннотация: Three-component slow-release fungicide formulations with different modes of action of the active ingredients for suppressing potato pathogens were constructed for the first time. The difenoconazole, mefenoxam, prothioconazole, and azoxystrobin fungicides were embedded in the degradable polymer P(3HB)/birch wood flour blend and examined using SEM, IR spectroscopy, X-ray analysis, DTA, and DSC. Results showed that no chemical bonds were established between the components and that they were physical mixtures that had a lower degree of crystallinity compared to the initial P(3HB), which suggested different crystallization kinetics in the mixtures. The degradation behavior of the experimental formulations was investigated in laboratory micro-ecosystems with pre-characterized field soil. The slow-release fungicide formulations were prolonged-action forms with a half-life of at least 50–60 d, enabling gradual and sustained delivery of the active ingredients to plants. All slow-release fungicide formulations had a strong inhibitory effect on the most common and harmful potato pathogens (Phytophthora infestans, Alternaria longipes, Rhizoctonia solani, and Fusarium solani).

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av, Krasnoyarsk, 660041, Russian Federation
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Department of Medical Biology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av, Krasnoyarsk, 660041, Russian Federation
Basic Department of Chemistry and Technology of Natural Energy Sources and Carbon Materials, School of Petroleum and Gas Engineering, Siberian Federal University, 82 Svobodny Pr, Krasnoyarsk, 660041, Russian Federation
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Basic Department of Solid State Physics and Nanotechnology, School of Engineering Physics and Radio Electronics, Siberian Federal University, 26 Kirensky St, Krasnoyarsk, 660074, Russian Federation
International and Interuniversity Centre for Nano Science and Nano Technology, Mahatma Gandhi University, Kottayam, 686560, India

Доп.точки доступа:
Volova, T. G.; Kiselev, E. G.; Baranovskiy, S. V.; Zhila, N. O.; Prudnikova, S. V.; Shishatskaya, E. I.; Kuzmin, A. P.; Nemtsev, I. V.; Немцев, Иван Васильевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Thomas, S.
}
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12.

Effect of monomers of 3-hydroxyhexanoate on properties of copolymers poly(3-hydroxybutyrate-co 3-hydroxyhexanoate) / T. G. Volova, M. V. Uspenskaya, E. G. Kiselev [et al.] // Polymers. - 2023. - Vol. 15, Is. 13. - Ст. 2890, DOI 10.3390/polym15132890. - Cited References: 99. - The study was funded by the Russian Science Foundation (project No 23-64-10007) . - ISSN 2073-4360
Кл.слова (ненормированные):
P(3HB-co-3HHx) copolymers -- P(3HB) homopolymer -- various synthesis conditions -- molecular weight -- crystallinity -- thermal properties -- isothermal crystallization -- spherulites
Аннотация: The properties of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) P(3HB-co-3HHx) copolymers with different ratios of monomers synthesized by the wild-type strain Cupriavidus necator B-10646 on sugars, and an industrial sample from Kaneka synthesized by the recombinant strain C. necator NSDG-ΔfadB1 on soybean oil, were studied in a comparative aspect and in relation to poly(3-hydroxybutyrate) P(3HB). The copolymer samples, regardless of the synthesis conditions or the ratio of monomers, had reduced values of crystallinity degree (50–60%) and weight average molecular weight (415–520 kDa), and increased values of polydispersity (2.8–4.3) compared to P(3HB) (70–76%, 720 kDa, and 2.2). The industrial sample had differences in its thermal behavior, including a lower glass transition temperature (−2.4 °C), two peaks in its crystallization and melting regions, a lower melting point (Tmelt) (112/141 °C), and a more pronounced gap between Tmelt and the temperature of thermal degradation (Tdegr). The process, shape, and size of the spherulites formed during the isothermal crystallization of P(3HB) and P(3HB-co-3HHx) were generally similar, but differed in the maximum growth rate of the spherulites during exothermic crystallization, which was 3.5–3.7 μm/min for P(3HB), and 0.06–1.25 for the P(3HB-co-3HHx) samples. The results from studying the thermal properties and the crystallization mechanism of P(3HB-co-3HHx) copolymers are important for improving the technologies for processing polymer products from melts.

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Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok 50/50, 660036 Krasnoyarsk, Russia
School of Fundamental Biology and Biotechnology, Siberian Federal University, Svobodnyi Av. 79, 660041 Krasnoyarsk, Russia
Chemical Engineering Center, Research Institute «Bioengineering» ITMO University, Kronverksky Pr. 49, 197101 Saint Petersburg, Russia
L. V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok 50/38, 660036 Krasnoyarsk, Russia
Basic Department of Solid State Physics and Nanotechnology, School of Engineering Physics and Radio Electronics, Siberian Federal University, Kirensky St. 26, 660074 Krasnoyarsk, Russia

Доп.точки доступа:
Volova, Tatiana G.; Uspenskaya, Mayya V.; Kiselev, Evgeniy G.; Sukovatyi, Aleksey G.; Zhila, Natalia O.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Shishatskaya, Ekaterina I.
}
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13.

    Influence of alkyl substituents in 1,3-diethyl-2-thiobarbituric acid on the coordination environment in M(H2O)2(1,3-diethyl-2-thiobarbiturate)2 M = Ca2+, Sr2+ / N. N. Golovnev [et al.] // J. Coord. Chem. - 2016. - Vol. 69, Is. 6. - P. 957-965, DOI 10.1080/00958972.2016.1149168. - Cited References: 42. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation for research engineering of the Siberian Federal University in 2015-2016. V.V.A. is grateful to the Ministry of Education and Science of the Russian Federation for the financial support of the investigation. . - ISSN 0095-8972
   Перевод заглавия: Влияние алкильных заместителей в 1,3-диэтил-2-2тиобарбитуровой кислоты на координационное окружение в M(H2O)2(1,3-диэтил-2-тиобарбутурат)2 M = Ca2+, Sr2+

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
CRYSTAL-STRUCTURE
   2-THIOBARBITURIC ACID
   STRUCTURAL-CHARACTERIZATION
   THIOBARBITURIC ACID
   THERMAL-PROPERTIES
   HYDROGEN-BOND
   COMPLEXES
   DIFFRACTION
   NETWORKS
   POLYMERS
Кл.слова (ненормированные):
1,3-Diethyl-2-thiobarbituric acid -- alkaline earth metals -- coordination compound -- X-ray diffraction -- thermal analysis
Аннотация: Two new isostructural complexes, [Ca(H2O)2(μ2-Detba-O,O′)2]n (1) and [Sr(H2O)2(μ2-Detba-O,O′)2]n (2) (HDetba = 1,3-diethyl-2-thiobarbituric acid), were synthesized and characterized by single-crystal and powder X-ray diffraction analysis, TG-DSC, FT-IR, and emission spectroscopy. The single-crystal X-ray diffraction data revealed that 1 and 2 are polymeric where M2+ (M = Ca, Sr) is a six-coordinate octahedral binding four Detba− ions and two water molecules. The octahedra are linked through bridging Detba− ions forming a 2-D layer. Two intermolecular hydrogen bonds O–H…S in the crystal form a 3-D net. The comparison of M(Detba)2 and M(Htba)2 (H2tba = 2-thiobarbituric acid) structures showed that the coordination number of metals in M(Detba)2 does not exceed six and there are no π–π interactions, unlike compounds with Htba−; Detba− ions are only bridges in HDetba coordination compounds. Thermal decomposition of 1 and 2 includes dehydration, which mainly ends at 200 °C, and organic ligand oxidation at 300–350 °C with a release of CO2, SO2, H2O, NH3, and isocyanate. Upon excitation at 220 nm, 1 and 2 exhibit an intense emission maximum at 557 nm.

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Держатели документа:
Department of Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation

Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Samoilo, A. S.; Atuchin, V. V.
}
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14.

    Influence of the filler particles’ surface morphology on the polyurethane matrix’s structure formation in the composite / T. A. Shalygina, M. S. Rudenko, I. V. Nemtsev [et al.] // Polymers. - 2021. - Vol. 13, Is. 22. - Ст. 3864, DOI 10.3390/polym13223864. - Cited References: 32. - This work was carried out by the team of the scientific laboratory “Intelligent Materials and Structures” within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project “Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions” (Project No. FEFE-2020-0015) . - ISSN 2073-4360
   Перевод заглавия: Влияние морфологии поверхности частиц наполнителя на формирование структуры полиуретановой матрицы в композите
Кл.слова (ненормированные):
polyurethane -- surface morphology -- nanoparticles -- nanowires -- core-shell -- molecular mobility -- molecular heterogeneity -- interfacial layers -- boundary layer -- transition layer
Аннотация: This article presents the surface morphology effect of silicon carbide (SiC) particles on the polyurethane binder’s structure formation in a dispersed-filled composite. The difference in the morphology and surface relief of filler particles was ensured by the implementation of plasma chemical modification. As a result of this modification, the filler consisted of core-shell particles characterized by a SiC core and a carbon shell (SiC@C), as well as a carbon shell decorated with silicon nanoparticles (SiC@C/SiNP) or nanos (SiC@C/SiNW). The study of the relaxation properties of polyurethane composites has shown that the strongest limiting effect on the molecular mobility of boundary layer’s chain segments is exerted by a highly developed surface with a complex relief of SiC@C/SiNP and SiC@C/SiNW particles. An empirical method was proposed to find the polymer fractions spent on the formation of the boundary, transition and bulk layers of the polymer matrix in the composite. It was shown that the morphology of the filler particles’ surface does not affect the dependence of the boundary layer thickness on the filler’s volume fraction. However, with an increase in the degree of surface development, the boundary layer thickness decreases.

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Держатели документа:
Smart Materials and Structures Lab., Department of Aircraft, Reshetnev Siberian State University of Science and Technology, 31 KrasnoyarskyRabochy Av., Krasnoyarsk 660037, Russia
L.V. Kirensky Institute of Physics SB RAS, Institute of Chemistry and Chemical Technology, Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk 660036, Russia
Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University, Vernadskogo Avenue 86, Moscow 119571, Russia

Доп.точки доступа:
Shalygina, T. A.; Rudenko, M. S.; Nemtsev, I. V.; Немцев, Иван Васильевич; Parfenov, V. A.; Парфенов В. А.; Voronina, S. Y.; Simonov-Emelyanov, I. D.; Borisova, P. E.
}
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15.

Laser processing of polymer films fabricated from phas differing in their monomer composition / T. G. Volova, A. I. Golubev, I. V. Nemtsev [et al.] // Polymers. - 2021. - Vol. 13, Is. 10. - Ст. 1553, DOI 10.3390/polym13101553. - Cited References: 87. - This work was supported by the Russian Foundation for Basic Research/Regional State Autonomous Institution “Krasnoyarsk Regional Fund for the Support of Scientific and Scientific-Technical Activities” foundations under Grant number 19-43-240012 (laser treatment and films properties) and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (polymer synthesis) . - ISSN 2073-4360
Кл.слова (ненормированные):
P(3HB) -- copolymers -- films -- CO2 laser -- SEM -- AFM -- water contact angles -- MTT assay -- NIH 3T3 fibroblasts
Аннотация: The study reports results of using a CO2-laser in continuous wave (3 W; 2 m/s) and quasi-pulsed (13.5 W; 1 m/s) modes to treat films prepared by solvent casting technique from four types of polyhydroxyalkanoates (PHAs), namely poly-3-hydroxybutyrate and three copolymers of 3-hydroxybutyrate: with 4-hydroxybutyrate, 3-hydroxyvalerate, and 3-hydroxyhexanoate (each second monomer constituting about 30 mol.%). The PHAs differed in their thermal and molecular weight properties and degree of crystallinity. Pristine films differed in porosity, hydrophilicity, and roughness parameters. The two modes of laser treatment altered these parameters and biocompatibility in diverse ways. Films of P(3HB) had water contact angle and surface energy of 92° and 30.8 mN/m, respectively, and average roughness of 144 nm. The water contact angle of copolymer films decreased to 80–56° and surface energy and roughness increased to 41–57 mN/m and 172–290 nm, respectively. Treatment in either mode resulted in different modifications of the films, depending on their composition and irradiation mode. Laser-treated P(3HB) films exhibited a decrease in water contact angle, which was more considerable after the treatment in the quasi-pulsed mode. Roughness parameters were changed by the treatment in both modes. Continuous wave line-by-line irradiation caused formation of sintered grooves on the film surface, which exhibited some change in water contact angle (76–80°) and reduced roughness parameters (to 40–45 mN/m) for most films. Treatment in the quasi-pulsed raster mode resulted in the formation of pits with no pronounced sintered regions on the film surface, a more considerably decreased water contact angle (to 67–76°), and increased roughness of most specimens. Colorimetric assay for assessing cell metabolic activity (MTT) in NIH 3T3 mouse fibroblast culture showed that the number of fibroblasts on the films treated in the continuous wave mode was somewhat lower; treatment in quasi-pulsed radiation mode caused an increase in the number of viable cells by a factor of 1.26 to 1.76, depending on PHA composition. This is an important result, offering an opportunity of targeted surface modification of PHA products aimed at preventing or facilitating cell attachment.

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Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av, Krasnoyarsk, 660041, Russian Federation
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Special Design and Technological Bureau ‘Nauka’ Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/45 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Volova, T. G.; Golubev, A. I.; Голубев Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.
}
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16.

Magnetic and thermophysical properties of GdxMn1-xS solid solutions / S. S. Aplesnin [et al.] // J. Phys.: Condens. Matter. - 2013. - Vol. 25, Is. 2. - Ст. 025802. - P. , DOI 10.1088/0953-8984/25/2/025802 . - ISSN 0953-8984
Кл.слова (ненормированные):
Antiferromagnetic orders -- Band state -- Face-centered cubic lattices -- Magnetic phase transitions -- Paramagnetic phase -- Temperature dependence -- Antiferromagnetism -- Electron transitions -- Gadolinium -- Manganese -- Paramagnetism -- Sodium chloride -- Specific heat -- Organic polymers
Аннотация: The structural, magnetic, and thermophysical properties of cation-substituted sulfides GdXMn1-XS (0.04 ? X ? 0.25) with the NaCl-type face-centered cubic lattice have been investigated. The range of existence of long-range antiferromagnetic order has been established. The anomalies observed in the temperature dependence of the specific heat correspond to the temperatures of the magnetic phase transition. The anomaly in the specific heat caused by electron transitions between the 4f levels and d band states has been observed. It has been found that the coefficient of thermal expansion decreases with increasing concentration of substituents in the magnetically ordered region and remains nearly invariable in the paramagnetic phase. В© 2013 IOP Publishing Ltd.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Daghestan Sci Ctr, Amirkhanov Inst Phys, Makhachkala 367003, Russia

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Romanova, O.; Романова, Оксана Борисовна; Gorev, M. V.; Горев, Михаил Васильевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Gamzatov, A. G.; Aliev, A. M.
}
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17.

MAGNETIC-PROPERTIES OF METAL-POLYMERS / G. A. PETRAKOVSKII [и др.] // Fiz. Tverd. Tela. - 1983. - Vol. 25, Is. 9. - P. 2644-2649. - Cited References: 20 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

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Доп.точки доступа:
PETRAKOVSKII, G. A.; PISKORSKII, V. P.; KOSOBUDSKII, I. D.; GUBIN, S. P.; BAYUKOV, O. A.
}
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18.

    Modification of polyhydroxyalkanoates polymer films surface of various compositions by laser processing / E. I. Shishatskaya, N. O. Zhila, A. E. Dudaev [et al.] // Polymers. - 2023. - Vol. 15, Is. 3. - Ст. 531, DOI 10.3390/polym15030531. - Cited References: 91. - The study was funded by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation (Project No. 0287-2021-0025) . - ISSN 2073-4360
   Перевод заглавия: Модификация поверхности полимерных пленок полигидроксиалканоатов различного состава методом лазерной обработки
Кл.слова (ненормированные):
PHAs -- polymer films -- CO2 laser -- laser processing -- SEM -- AFM -- water contact angles -- fibroblast NIH 3T3 -- MTT test
Аннотация: The results of surface modification of solvent casting films made from polyhydroxyalkanoates (PHAs) of various compositions are presented: homopolymer poly-3-hydroxybutyrate P(3HB) and copolymers comprising various combinations of 3-hydroxybutyrate (3HB), 3-hydroxyvalerate (3HV), 4-hydroxybutyrate(4HB), and 3-hydroxyhexanoate (3HHx) monomers treated with a CO2 laser in continuous and quasi-pulsed radiation modes. The effects of PHAs film surface modification, depending on the composition and ratio of monomers according to the results of the study of SEM and AFM, contact angles of wetting with water, adhesion and growth of fibroblasts have been revealed for the laser radiation regime used. Under continuous irradiation with vector lines, melted regions in the form of grooves are formed on the surface of the films, in which most of the samples have increased values of the contact angle and a decrease in roughness. The quasi-pulse mode by the raster method causes the formation of holes without pronounced melted zones, the total area of which is lower by 20% compared to the area of melted grooves. The number of viable fibroblasts NIH 3T3 on the films after the quasi-pulse mode is 1.5–2.0 times higher compared to the continuous mode, and depends to a greater extent on the laser treatment mode than on the PHAs’ composition. The use of various modes of laser modification on the surface of PHAs with different compositions makes it possible to influence the morphology and properties of polymer films in a targeted manner. The results that have been obtained contribute to solving the critical issue of functional biodegradable polymeric materials.

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Держатели документа:
Department of Medical Biology, School of Fundamental Biology and Biotechnology, Siberian Federal University, Svobodnyi Av., 79, 660041 Krasnoyarsk, Russia
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, 660036 Krasnoyarsk, Russia
Chemistry Engineering Centre, ITMO University, Kronverkskiy Prospekt, 49A, 197101 Saint Petersburg, Russia
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, Svobodnyi Av., 79, 660041 Krasnoyarsk, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 660036 Krasnoyarsk, Russia
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, 660041 Krasnoyarsk, Russia

Доп.точки доступа:
Shishatskaya, Ekaterina I.; Zhila, Natalia O.; Dudaev, Alexey E.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Volova, Tatiana G.
}
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19.

Morozov, E. V.
MRI monitoring and non-destructive quality measurement of polymeric patterns manufactured via stereolithography / E. V. Morozov, M. M. Novikov, V. M. Bouznik // Addit. Manuf. - 2016. - Vol. 12. - P. 16-24, DOI 10.1016/j.addma.2016.05.015 . - ISSN 2214-8604
Кл.слова (ненормированные):
Aging -- Build parameters -- MRI -- Polymers -- Stereolithography
Аннотация: The use of Magnetic Resonance Imaging (MRI) for monitoring, studying and performing output quality measurements of the acrylate-based polymeric patterns manufactured using stereolithography (SL) was introduced in this work. The effects of build parameters and humid environment on sample homogeneity, distribution of crosslink density, stability and defect formation were examined. The spatial resolution of the method was found to be sufficient to identify patterns according to the build parameters used and to detect specific hatch-predicted crosslink density variations. Qualitative information obtained using MRI visualisation was supplemented by quantitative measurements of Nuclear Magnetic Resonance (NMR) relaxation times and 1H NMR spectra. NMR spectroscopy confirmed the identity of the chemical composition among the patterns and showed that the crosslink density variation observed via spatially resolved T2-profiles stems from the difference of the build parameters. Different types of defects in the samples were observed and classified; some defects originated from local matrix continuity failures (partially cured resin trapping within the polymer or bubbles formation), while other defects were found in the form of bulk layering. MRI visualisation coupled with relaxometry and 1H spectroscopy of patterns during their interaction with humidity allowed tracking water distribution inside the sample and observing effects of swelling, fracturing and chemical decomposition. It was found that the initial inhomogeneous structure of the specimen has a crucial role in subsequent fracturing due to non-uniform expansion of the swollen parts. As a result, the approach presented in this work improves the output quality control and current testing techniques, provides insight how physical properties of the 3D parts are affected by different technical parameters, and eventually can help the use of SL technologies for a variety of applications. © 2016 Elsevier B.V.

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Держатели документа:
Kirensky Institute of Physics SB RAS, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk, Russian Federation
Institute on Laser and Information Technologies RAS, Shatura, Russian Federation
All-Russian Scientific Research Institute of Aviation Materials, Moscow, Russian Federation

Доп.точки доступа:
Novikov, M. M.; Bouznik, V. M.; Морозов, Евгений Владимирович
}
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20.

    Nematic structures under conical anchoring at various director tilt angles specified by polymethacrylate compositions / D. A. Kostikov, M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Polymers. - 2021. - Vol. 13, Is. 17. - Ст. 2993, DOI 10.3390/polym13172993. - Cited References: 49. - Mikhail N. Krakhalev and Oxana O. Prishchepa acknowledge financial support from Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (No 20-42-240007) . - ISSN 2073-4360
   Перевод заглавия: Нематические структуры с коническим сцеплением при различных углах наклона директора, задаваемых составами полиметакрилатов

РУБ Polymer Science
Рубрики:
LIQUID-CRYSTAL
   PRETILT ANGLE
   ALIGNMENT LAYERS
   SURFACE
   INTERFACE
Кл.слова (ненормированные):
conical anchoring -- polymethacrylate -- nematic liquid crystal -- orientational structure -- director tilt angle -- domain wall -- electrically-induced reorientation
Аннотация: Dependence of the director tilt angle of nematic liquid crystal (LC) under conical anchoring from the two-component polymer mixture composition has been studied. We varied the ratio of poly(isobutyl methacrylate) (PiBMA), which specifies a conical anchoring for the nematic liquid crystal LN-396, and poly(methylmethacrylate) (PMMA) assigning a tangential alignment for the same nematic. An oblique incidence light technique to determine a tilt angle has been used. It has been shown that the tilt angle increases from 0∘ to 47.7∘ when PiBMA:PMMA ratio changes in the range 30:70 to 100:0. The specific optical textures viewed under the polarizing microscope and proper orientational structures have been considered for various compositions of the polymer films. An electric field action on the formed orientational structures has been investigated. The obtained results are promising for the application in various electro-optical LC devices with a conical anchoring in which the director tilt angle is a crucial parameter: a controlled diffraction gratings, an electrically operated achromatic rotators of linear light polarization, etc.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Kostikov, D. A.; Костиков, Денис Андреевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [20-42-240007]
}
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