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1.


   
    Состав, структура и реакционная способность при восстановлении водородом композиционных материалов системы α-Fe2O3–CaFe2O4 / В. В. Юмашев [и др.] // Журнал СФУ. Химия. - 2019. - Т. 12, Вып. 1. - С. 54-72 ; J. Sib. Fed. Univ. Chem., DOI 10.17516/1998-2836-0108. - Библиогр.: 37 . - ISSN 1998-2836. - ISSN 2313-6049
   Перевод заглавия: Composition, Structure and Reduction Reactivity of Composite Materials of the α-Fe2O3-CaFe2O4 System by Hydrogen
РУБ Chemistry, Multidisciplinary
Рубрики:
CHEMICAL LOOPING GASIFICATION
   OXYGEN CARRIER

   PARTIAL OXIDATION

Кл.слова (ненормированные):
твердофазный синтез -- феррит кальция -- РФА -- СЭМ-ЭДС -- термопрограммируемое восстановление водородом -- solid-phase synthesis -- calcium ferrite -- XRD -- SEM-EDS -- temperature-programmed reduction by hydrogen
Аннотация: В работе изучены композиционные материалы системы α-Fe2O3-CaFe2O4, полученные методом высокотемпературного твердофазного синтеза из оксидов Са и Fe(III) с вариацией мольного отношения СаО/Fe2O3 от 0.15 до 1.00. Материалы охарактеризованы методами рентгеновской дифракции (РФА), сканирующей электронной микроскопии с системой энергодисперсионного микроанализа (СЭМ-ЭДС) и синхронного термического анализа (СТА) в режиме термопрограммируемого восстановления водородом (H2-ТПВ). СЭМ-ЭДС - исследование образцов выявило формирование сложной микроструктуры материала по типу «ядро-оболочка» с фазой гематита в качестве «ядра». H2-ТПВ образцов позволило установить, что с увеличением содержания фазы CaFe2O4 (от 33.4 до 97.5 мас. %) наблюдается снижение вклада низкотемпературных форм решеточного кислорода в областях 350-510 °С (до 2.6 раза) и 510-650 °С (до 1.7 раза) и рост вклада высокотемпературной формы кислорода в интервале 650-900 °С (до 2 раз). На основе оценки подвижности решеточного кислорода высказано предположение о перспективности использования полученных композиционных материалов с содержанием фазы CaFe2O4 более 55.2 мас. % в качестве носителей кислорода в химических циклических процессах получения синтез-газа.
In this paper, α-Fe2O3–CaFe2O4 composite materials obtained by high-temperature solid-phase synthesis from Ca and Fe (III) oxides with varying molar ratio CaO/Fe2O3 in the range 0.15-1.00 were investigated. The materials are characterized by Х-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray microanalysis (SEM-EDS) and simultaneous thermal analysis (STA) in the hydrogen temperature-programmed reduction mode (H2-TPR). SEM-EDS studies of the specimens were revealed a formation of the “core-shell” type complex microstructure of material with the hematite phase as the “core”. H2-TPR of the specimens allowed to establish a decrease of the contribution of low-temperature forms of lattice oxygen in areas of 350-510 °С (up to 2.6 times) and 510-650 °С (up to 1.7 times), and the growth of the contribution of the high-temperature oxygen form in the range of 650-900 °С (up to 2 times) with an increase in the content of the phase CaFe2O4 from 33.4 to 97.5 wt. %. Relying on the assessment of lattice oxygen mobility, it was suggested, that the samples with content of CaFe2O4 phase more than 55.4 wt. % are promising for use as oxygen carriers in chemical looping processes of syngas production.

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Держатели документа:
FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia.
FRC Krasnoyarsk Sci Ctr SB RAS, Kirensky Inst Phys SB RAS, 50-38 Akademgorodok, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Юмашев, Владимир Витальевич; Yumashev, Vladimir V.; Кирик, Надежда Павловна; Kirik N. P.; Шишкина, Нина Николаевна; Shishkina, Nina N.; Князев, Юрий Владимирович; Knyazev, Yu. V.; Жижаев, Анатолий Михайлович; Zhyzhaev, A. M.; Соловьев, Леонид Александрович; Solov'ev, L. A.

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2.


   
    The relationship between the structural characteristics of α-Fe2O3 catalysts and their lattice oxygen reactivity regarding hydrogen / N. Kirik, A. Krylov, A. Boronin [et al.] // Materials. - 2023. - Vol. 16, Is. 12 : The 15th Anniversary of Materials — Recent Advances in Catalytic Materials. - Ст. 4466, DOI 10.3390/ma16124466. - Cited References: 63. - This work was conducted within the framework of the budget project for the Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences, Federal Research Center KSC SB RAS, No. FWES–2021–0013 . - ISSN 1996-1944
Кл.слова (ненормированные):
α-Fe2O3 -- catalysts -- calcinations -- XRD -- XPS -- Raman spectroscopy characterization -- temperature-programmed reduction
Аннотация: In this paper, the relationship between the structural features of hematite samples calcined in the interval of 800–1100 °C and their reactivity regarding hydrogen studied in the temperature-programmed reaction (TPR-H2) was studied. The oxygen reactivity of the samples decreases with the increasing calcination temperature. The study of calcined hematite samples used X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), and Raman spectroscopy, and their textural characteristics were studied also. According to XRD results, hematite samples calcined in the temperature range under study are monophase, represented by the α-Fe2O3 phase, in which crystal density increases with increasing calcination temperature. The Raman spectroscopy results also register only the α-Fe2O3 phase; the samples consist of large, well-crystallized particles with smaller particles on their surface, having a significantly lower degree of crystallinity, and their proportion decreases with increasing calcination temperature. XPS results show the α-Fe2O3 surface enriched with Fe2+ ions, whose proportion increases with increasing calcination temperature, which leads to an increase in the lattice oxygen binding energy and a decrease in the α-Fe2O3 reactivity regarding hydrogen.

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Держатели документа:
Federal Research Center “Krasnoyarsk Science Center of Siberian Branch of the Russian Academy of Sciences”, Institute of Chemistry and Chemical Technology, 50/24, Akademgorodok, 660036 Krasnoyarsk, Russia
Federal Research Center “Krasnoyarsk Science Center of Siberian Branch of the Russian Academy of Sciences”, Kirensky Institute of Physics, 50/38, Akademgorodok, 660036 Krasnoyarsk, Russia
Federal Research Center Boreskov Institute of Catalysis, 5, Ac. Lavrentieva Ave., 630090 Novosibirsk, Russia
Department of Chemistry, 79, Svobodny Ave., Siberian Federal University, 660041 Krasnoyarsk, Russia

Доп.точки доступа:
Kirik, N.; Krylov, A. S.; Крылов, Александр Сергеевич; Boronin, A.; Koshcheev, S.; Solovyov, L.; Rabchevskii, E.; Shishkina, N.; Anshits, A.
}
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3.


   
    The low-temperature germinating spores of the thermophilic Desulfofundulus contribute to an extremely high sulfate reduction in burning coal seams / O. V. Karnachuk, I. I. Rusanov, I. A. Panova [et al.] // Front. Microbiol. - 2023. - Vol. 14. - Ст. 1204102, DOI 10.3389/fmicb.2023.1204102. - Cited References: 80. - This study was supported by the Russian Science Foundation Projects 21-14-00114 (to OK, sampling, sulfate reduction rate measurements, pure culture isolation and physiological experiments with pure culture and spores) and 22-14-00178 (to NR, metagenome and genome sequencing and analysis) and the Ministry of Science and Higher Education of the Russian Federation . - ISSN 1664-302X
Кл.слова (ненормированные):
sulfate reduction -- thermophiles -- burning coal seams -- Desulfofundulus -- spores
Аннотация: Burning coal seams, characterized by massive carbon monoxide (CO) emissions, the presence of secondary sulfates, and high temperatures, represent suitable environments for thermophilic sulfate reduction. The diversity and activity of dissimilatory sulfate reducers in these environments remain unexplored. In this study, using metagenomic approaches, in situ activity measurements with a radioactive tracer, and cultivation we have shown that members of the genus Desulfofundulus are responsible for the extremely high sulfate reduction rate (SRR) in burning lignite seams in the Altai Mountains. The maximum SRR reached 564 ± 21.9 nmol S cm−3 day−1 at 60°C and was of the same order of magnitude for both thermophilic (60°C) and mesophilic (23°C) incubations. The 16S rRNA profiles and the search for dsr gene sequences in the metagenome revealed members of the genus Desulfofundulus as the main sulfate reducers. The thermophilic Desulfofundulus sp. strain Al36 isolated in pure culture, did not grow at temperatures below 50°C, but produced spores that germinated into metabolically active cells at 20 and 15°C. Vegetative cells germinating from spores produced up to 0.738 ± 0.026 mM H2S at 20°C and up to 0.629 ± 0.007 mM H2S at 15°C when CO was used as the sole electron donor. The Al36 strain maintains significant production of H2S from sulfate over a wide temperature range from 15°C to 65°C, which is important in variable temperature biotopes such as lignite burning seams. Burning coal seams producing CO are ubiquitous throughout the world, and biogenic H2S may represent an overlooked significant flux to the atmosphere. The thermophilic spore outgrowth and their metabolic activity at temperatures below the growth minimum may be important for other spore-forming bacteria of environmental, industrial and clinical importance.

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Держатели документа:
Laboratory of Biochemistry and Molecular Biology, Tomsk State University, Tomsk, Russia
Institute of Microbiology, Research Centre of Biotechnology of the Russian Academy of Sciences, Moscow, Russia
Institute of Bioengineering, Research Centre of Biotechnology of the Russian Academy of Sciences, Moscow, Russia
Kirensky Institute of Physics, Krasnoyarsk, Russia

Доп.точки доступа:
Karnachuk, O. V.; Rusanov, I. I.; Panova, I. A.; Kadnikov, V. V.; Avakyan, M. R.; Ikkert, O. P.; Lukina, A. P.; Beletsky, A. V.; Mardanov, A. V.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Pimenov, N. V.; Ravin, N. V.
}
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4.


   
    Synthesis and optical properties RE2O2S:Ln (RE = La, Y; Ln = Ce, Eu, Dy, Er) / E. I. Sal'nikova [et al.] // J. Solid State Chem. - 2019. - Vol. 279. - Ст. 120964, DOI 10.1016/j.jssc.2019.120964. - Cited References: 53 . - ISSN 0022-4596
Кл.слова (ненормированные):
Oxysulfides -- Sulfates -- Rare-earth -- Reduction -- Optical ceramic -- Luminescence
Аннотация: The phase formation sequence was studied in the preparation of solid solutions of RE2O2S: Ln’ (RE = La, Y; Ln’ = Ce, Eu, Dy, Er) by the reduction of the match co-precipitated sulfates, followed by sulfidization of the reduction products. For uniform distribution of cations in the matrix, a method of chemical homogenization was used, consisting in the preparation of an aqueous solution containing all the necessary cations and their subsequent precipitation in the form of sulfates. The use of sulfates as precursors facilitates the process of obtaining solid solutions of oxysulfides, since sulfates already contain SO4 2--ions. The phase and morphological certification of the obtained solid solutions was carried out. The study of steady state luminescent properties demonstrated characteristic bands which are assigned to 4f-4f and 5d-4f transition. The obtained results showed the possibility of applying the method to synthesize optical ceramics based on solid solutionsRE2O2S: Ln (RE = La, Y; Ln = Ce, Eu, Dy, Er).

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Держатели документа:
Department of Inorganic and Physical Chemistry, Tyumen State University, Tyumen, 625003, Russian Federation
Department of General Chemistry, Northern Trans-Ural Agricultural University, Tyumen, 625003, Russian Federation
Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen, 625000, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Center for Optical and Laser Materials Research, St. Petersburg State University, St. Petersburg, 199034, Russian Federation
Department of Physics, Lappeenranta University of Technology LUT, Lappeenranta, 53850, Finland

Доп.точки доступа:
Sal'nikova, E. I.; Denisenko, Y.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kolesnikov, I. E.; Lahderanta, E.; Andreev, P. O.; Azarapin, N. O.; Andreev, O. V.; Basova, S. A.; Matigorov, A. V.
}
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5.


   
    Synthesis and characterization of core-shell magnetic nanoparticles NiFe2O4@Au / D. Saykova, S. Saikova, Y. Mikhlin [et al.] // Metals. - 2020. - Vol. 10, Is. 8. - Ст. 1075, DOI 10.3390/met10081075. - Cited References: 45 . - ISSN 2075-4701
   Перевод заглавия: Синтез и характеристика магнитных наночастиц ядро-оболочка NiFe2O4@Au
РУБ Materials Science, Multidisciplinary + Metallurgy & Metallurgical
Рубрики:
NICKEL FERRITE NANOPARTICLES
   GOLD NANOPARTICLES

   OXIDATION

   REDUCTION

Кл.слова (ненормированные):
nickel ferrite nanoparticles -- NiFe2O4@Au core-shell nanoparticles -- synthesis -- X-ray photoelectron spectroscopy -- magnetic circular dichroism
Аннотация: In this study, NiFe2O4@Au core–shell nanoparticles were prepared by the direct reduction of gold on the magnetic surface using amino acid methionine as a reducer and a stabilizing agent simultaneously. The obtained nanoparticles after three steps of gold deposition had an average size of about 120 nm. The analysis of particles was performed by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis spectroscopy techniques. The results indicate successful synthesis of core–shell particles with the magnetic core, which consists of a few agglomerated nickel ferrite crystals with an average size 25.2 ± 2.0 nm, and the thick gold shell consists of fused Au0 nanoparticles (NPs). Magnetic properties of the obtained nanoparticles were examined with magnetic circular dichroism. It was shown that the magnetic behavior of NiFe2O4@Au NPs is typical for superparamagnetic NPs and corresponds to that for NiFe2O4 NPs without a gold shell. The results indicate the successful synthesis of core–shell particles with the magnetic nickel ferrite core and thick gold shell, and open the potential for the application of the investigated hybrid nanoparticles in hyperthermia, targeted drug delivery, magnetic resonance imaging, or cell separation. The developed synthesis strategy can be extended to other metal ferrites and iron oxides.

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Держатели документа:
Siberian Fed Univ, Sch Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Fed Res Ctr,Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Saykova, Diana; Saikova, Svetlana; Mikhlin, Yuri; Panteleeva, Marina; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Belova, E.
}
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6.


   
    Structural changes of Co caused a change of the solution pH during chemical deposition / S. A. Podorozhnyak, A. V. Chzhant, V. K. Maltsevt [et al.] // J. Sib. Fed. Univ. Math. Phys. - 2020. - Vol. 13, Is. 4. - P. 451-458 ; Журн. СФУ. Матем. и физика, DOI 10.17516/1997-1397-2020-13-4-451-458. - Cited References: 10 . - ISSN 1997-1397. - ISSN 2313-6022
   Перевод заглавия: Структурные изменения кобальта, вызванные изменением pH при химическом осаждении
РУБ Mathematics
Рубрики:
COBALT
   MICROSTRUCTURE

Кл.слова (ненормированные):
Co-P films -- chemical reduction of metals -- induced magnetic anisotropy -- nanocrystalline material -- пленки Co-P -- химическое восстановление металлов -- наведенная магнитная анизотропия -- нанокристаллический материал
Аннотация: The phase transformations of the Co lattice are discussed, which determine the anomalous changes in the magnetic properties of chemically deposited Co-P films obtained at various pH values. The coercivity of the H-c films obtained at low pH values exceeds 1 kOe and decreases to several units Oe in the films obtained at high pH values. It is shown that the observed changes in the magnetic properties of Co-P films are caused by the transition of the cobalt crystal lattice to the nanocrystalline state.
Обсуждаются фазовые превращения решетки Co, которые определяют аномальные изменения магнитных свойств химически осажденных пленок Co-P, полученных при различных значениях pH. Коэрцитивная сила пленок, полученных при низких значениях pH, превышает 1 кЭ и снижается до нескольких единиц Э в пленках, полученных при высоких значениях pH. Показано, что наблюдаемые изменения магнитных свойств пленок Co-P вызваны переходом кристаллической решетки кобальта в нанокристаллическое состояние.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Krasnoyarsk State Agr Univ, Krasnoyarsk, Russia.
RAS, Kirensky Inst Phys FIC KNC SB, Krasnoyarsk, Russia.

Доп.точки доступа:
Podorozhnyak, Sergey A.; Chzhant, Anatoly, V; Maltsevt, Vadim K.; Krayuhin, Ivan N.; Patrin, G. S.; Патрин, Геннадий Семёнович; Sakash, Irina Yu

}
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7.


   
    Stability and electronic properties of PtPd nanoparticles via MD and DFT calculations / I. V. Chepkasov [et al.] // J. Phys. Chem. C. - 2018. - Vol. 122, Is. 31. - P. 18070-18076, DOI 10.1021/acs.jpcc.8b04177. - Cited References: 62. - The authors are grateful to Vladislav A. Kalyuzhny for the assistance with the computational resources. The research is carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University and resources of the Center for the Information and Computing of Novosibirsk State University. The work was supported by the Russian Foundation for Basic Research (RFBR no. 17-42-190308-r) and Foundation for Assistance to Small Innovative Enterprises (FASIE) (Project no. 0033625). E.A.K. would also like to thank the Ministry of Education and Science of the Russian Federation (the government contract to Siberian Federal University, grant no. 16.1455.2017/PCh) and the Foundation for Assistance to Small Innovative Enterprises (FASIE) (Project no. 0033639). . - ISSN 1932-7447
РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
OXYGEN REDUCTION REACTION
   CORE-SHELL NANOPARTICLES

   GAS-PHASE

Аннотация: The structural as well as electronic properties of PtPd nanoparticles (NPs) were investigated by using molecular dynamics simulations and density functional theory calculations. A wide range of NPs of different sizes (from 1.5 to 4 nm), structures (core–shell, alloy, Janus), and compositions were taken into consideration. It was shown that PtPd NPs of less than ∼2.0 nm are prone to structural transformations to icosahedral (Ih) shape, regardless of their initial structure and composition. On the other hand, for NPs of size ∼2.5 nm, the increase of temperature up to 700–900 K leads to structural changes only for compositions close to 40% Pt, which corresponds to energetic minimum for Pt@Pd NPs. The Ih form of Pd@Pt NPs with monolayer thickness of Pt on the surface appears to have the most negatively charged surface which makes this kind of NPs the best candidate for catalysis application.

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Держатели документа:
Katanov Khakas State Univ, 90 Lenin Pr, Abakan 655017, Russia.
Kirensky Inst Phys, 50-38 Akademgorodok, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Natl Univ Sci & Technol MISiS, 4 Leninskiy Pr, Moscow 119049, Russia.

Доп.точки доступа:
Chepkasov, I. V.; Visotin, M. A.; Высотин, Максим Александрович; Kovaleva, E. A.; Manakhov, A. M.; Baidyshev, V. S.; Popov, Z. I.; Russian Foundation for Basic Research (RFBR) [17-42-190308-r]; Foundation for Assistance to Small Innovative Enterprises (FASIE) [0033625, 0033639]; Ministry of Education and Science of the Russian Federation (the government contract to Siberian Federal University) [16.1455.2017/PCh]
}
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8.


   
    Short-term culture of monocytes as an in vitro evaluation system for bionanomaterials designated for medical use / E. I. Shishatskaya [et al.] // Food Chem. Toxicol. - 2016. - Vol. 96. - P. 302-308, DOI 10.1016/j.fct.2016.08.025. - Cited References: 46 . - ISSN 0278-6915
РУБ Food Science & Technology + Toxicology
Рубрики:
MAGNETIC NANOPARTICLES
   CELLULAR REDUCTION

   PROTEIN CORONA

   CELLS

   MECHANOTRANSDUCTION

   NANOMATERIALS

   LOCALIZATION

   BIOMATERIALS

   CYTOSKELETON

   ACTIVATION

Кл.слова (ненормированные):
Biocompatible biopolymers -- Polyhydroxyalkanoates -- Nanomaterials -- Nanodiamonds -- Fullerenes -- Bio-nanomaterials -- Monocytes
Аннотация: We studied the feasibility of using a short-term culture of monocytes, isolated from peripheral donor blood, to assess the biological activity of different types of bionanomaterials (BNM): biodegradable polimeric particles, fiber and film substrates of micro- and nano-dimensions, fullerenes (F) and nanodiamonds (ND), which are either currently in use and/or potentially applicable in medicine. Additionally, the effect of creating a protein corona on ND and F particles was investigated. The cellular reduction of (4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) is a well-established tool for assessing the viability/metabolic activity of cells. The scanning electron microscopy assay can detect fine changes in cell morphology. In the present study BNM have been shown to affect; in a size, chemical composition and morphological characteristics-dependent manner, the ability of monocytes to reduce MTT as well as their morphology. Moreover, the specific effects of ND and F on MTT reduction and cell morphology were exhibited in a dose-dependent manner and sensitive to the formation of surface protein corona. Our results suggest that short-term culture of monocytes is a sensitive model system for assessing the biological effects of BMPs in vitro. © 2016 Elsevier Ltd

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Держатели документа:
Siberian Federal University, Svobodnuy Av. 79, Krasnoyarsk, Russian Federation
Laboratory of Anatomy, Histology, Embryology, School of Medicine, University of Crete, Heraklion, Greece
Institute of Physics, Russian Academy of Science, Siberian Division, Akademgorodok, 50, Build. 38, Krasnoyarsk, Russian Federation
Laboratory of Toxicology, Medical School, University of Crete, Heraklion, Greece

Доп.точки доступа:
Shishatskaya, E. I.; Шишацкая, Екатерина Игоревна; Nikitovic, D.; Shabanov, A. V.; Шабанов, Александр Васильевич; Tzanakakis, G. N.; Tsatsakis, A. M.; Menzianova, N. G.
}
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9.


   
    Preparation and luminescence properties of the blue-emitting phosphor BaBPO5:Eu2+ / L. Zhang [et al.] // Sci. Adv. Mater. - 2016. - Vol. 8, Is. 5. - P. 1086-1092, DOI 10.1166/sam.2016.2704. - Cited References: 22. - This work was financially supported by the National Natural Science Foundation of China (NSFC Grant no. 51172216) and the Fundamental Research Funds for the Central Universities (Grant no. 2652015022). . - ISSN 1947-2935
   Перевод заглавия: Синтез и люминесцентные свойства синего люминофора BaBPO5:Eu2+
РУБ Nanoscience & Nanotechnology + Physics, Applied + Physics, Applied
Рубрики:
Energy-transfer
   Diodes

   Ions

   Eu3+

   Photoluminescence

   Reduction

   Tb3+

Кл.слова (ненормированные):
BaBPO5 -- Eu2+ -- Phosphor -- White light emitting diodes
Аннотация: Blue-emitting BaBPO5:xEu2+ phosphors were prepared by a high-temperature solid-state reaction route. The crystal phase, luminescence properties, lifetime, and thermal stability were investigated, respectively. The phase analysis indicated that BaBPO5 crystallize with the structure of stillwellite-type compounds. Under the excitation at 310 nm, the phosphor exhibited an asymmetric broad-band blue emission with peak at 410 nm, which was ascribed to the 4f-5d transition of Eu2+. It was further calculated that the dipole-dipole interactions were responsible for a concentration quenching effect in BaBPO5:xEu2+ phosphors at x = 0.08. The lifetime decreased with the increasing concentration of Eu2+ ions. The temperature-dependent emission spectra indicated an excellent thermal stability of the BaBPO5:0.08Eu2+ samples. Surface morphology and CIE coordinate were also investigated. All the properties assessed indicated that the developed blue-emitting BaBPO5:Eu2+ phosphor is a good candidate for application in white-light emitting diodes. © 2016 by American Scientific Publishers.

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Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences (Beijing), Beijing, China
National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, Grirem Advanced Materials Co., Ltd., Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Zhang, L.; Fang, M.; Huang, Z.; Liu, Y.; Min, X.; Tang, H.; Chen, K.; Guan, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич
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10.


   
    Novel Derivatives of Adamantyl-substituted Quinolin-6-amines and Synthesis of Imidazo[4,5-f]quinolines Therefrom / A. A. Abramov [et al.] // Russ. J. Organ. Chem. - 2019. - Vol. 55, Is. 8. - P. 1234-1237, DOI 10.1134/S1070428019080256. - Cited References: 7 . - ISSN 1070-4280. - ISSN 1608-3393
РУБ Chemistry, Organic

Кл.слова (ненормированные):
amination -- adamantanylalkylamines -- reduction -- cyclization -- 5-nitroso-6-quinolinamines -- quinoline-5,6-diamines -- 3H-imidazo[4,5-f]quinolines
Аннотация: N-(Adamantan-1-yl)alkyl-substituted 5-nitrosoquinolin-6-amines were synthesized for the first time by the amination of 5-nitrosoquinolin-6-ol with primary N-[(adamantan-1-yl)alkyl]amines. The resulting nitrosoquinolinamines were reduced with hydrazine hydrate over Pd/C to N6-[(adamantan-1-yl)alkyl]quinoline-5,6-diamines. The latter were heated in formic acid to obtain previously unknown 3-[(adamantan-1-yl)alkyl]-3H-imidazo[4,5-f]quinolines.

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Публикация на русском языке

Держатели документа:
Reshetnev Siberian State Univ Sci & Technol, Pr Im Gazety Krasnoyarskii Rabochii 31, Krasnoyarsk 660037, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk Res Ctr, Akad Gorodok 50,Stroenie 24, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Res Ctr, Siberian Branch, Kirenskii Inst Phys, Akad Gorodok 50,Stroenie 38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Abramov, A. A.; Kulagina, M. V.; Gavrilova, N. A.; Semichenko, E. S.; Kondrasenko, A. A.; Suboch, G. A.
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