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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rykshin A., Zatsepin P., Komarov S. A.
Заглавие : Electromagnetic Pulse Scattering by Dielectric Layer
Место публикации : 12th International Conference on Mathematical Methods in Electromagnetic Theory, 2008, Odessa, Ukraine, p. 20
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rasch J. C. E., Böhm M., Schefer J., Mutka H., Abramova M. G. , Vasilyeva I.
Заглавие : Spin-phonon coupling in CuCrS2 probed by inelastic neutron scattering
Коллективы : DPG - spring meeting of the Division Condensed Matter
Место публикации : DPG (Deutsche Physicalische Gesellschaft) Spring Meeting: Dresden, 22nd - 27th of March, 2009. - Ст.Th-D-2.4-06. - С. 367
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Smirnov L., Kolesnikov A., Flerov I. N., Laptash N. M.
Заглавие : The study of peculiarity of phase transitions in (NH4)2WO2F4 by inelastic neutrov scattering
Место публикации : 9th Russian/CIS/Baltic/Japan symposium on ferroelectricity, June 15-19, 2008, Vilnius, Lithuania, p.136
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Abramova G. A., Boehm M., Roessli B., Raseh J., Petrakovskiy G. A., Velikanov D. A., Vorotynov A. M., Bovina A. F., Sokolov V. V.
Заглавие : Neutron diffraction measurements of the FexMn1-xS solid solutions
Коллективы : European conference on neutron scattering
Место публикации : 4th European conference on neutron scattering: Lund, Sweden, 25-29 June 2007 : [сб. тезисов]. - p.128
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovkina E. V., Krylova S. N., Vtyurin A. N., Krylov A. S.
Заглавие : Analyzing the symmetry of the Raman spectra of crystals according to angular dependences
Колич.характеристики :6 с
Место публикации : Bull. Russ. Acad. Sci. Phys. - 2024. - Vol. 88, Is. 5. - P.773-778. - ISSN 10628738 (ISSN), DOI 10.1134/S1062873824706573. - ISSN 19349432 (eISSN)
Примечания : Cited References: 32. - This work was supported by the Russian Foundation for Basic Research, project no. 21-52-12018. The authors are grateful to Dr. Irena Senkovska for providing our DUT-8(Ni) samples
Аннотация: The authors propose a way of reconstructing the Raman tensor by studying the angular dependences of the intensities of the Raman lines of unoriented microcrystals. The technique is verified using familiar calomel Hg2Cl2 crystals. It is shown that the lines on DUT-8 (Ni) crystals indicating phases with open and closed pores have different types of symmetries. The technique can be used to reconstruct the Raman tensor for any unoriented crystalline sample.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dymova M. A., Malysheva D. O., Popova V. K., Dmitrienko E. V., Endutkin A. V., Drokov D. V., Mukhanov V. S., Byvakina A. A., Kochneva G. V., Artyushenko P. V., Shchugoreva I. A., Rogova A. V., Tomilin F. N., Kichkailo A. S., Richter V. A., Kuligina E. V.
Заглавие : Characterizing aptamer interaction with the oncolytic virus VV-GMCSF-Lact
Колич.характеристики :14 с
Место публикации : Molecules. - 2024. - Vol. 29, Is. 4. - Ст.848. - ISSN 14203049 (eISSN), DOI 10.3390/molecules29040848
Примечания : Cited References: 46. - This study was supported by the Russian Science Foundation grant No. 22-64-00041, available online: https://rscf.ru/en/project/22-64-00041/ (accessed on 6 February 2024). This work was supported by the Russian state-funded project for ICBFM SB RAS (grant number 121030200173-6)
Аннотация: Aptamers are currently being investigated for their potential to improve virotherapy. They offer several advantages, including the ability to prevent the aggregation of viral particles, enhance target specificity, and protect against the neutralizing effects of antibodies. The purpose of this study was to comprehensively investigate an aptamer capable of enhancing virotherapy. This involved characterizing the previously selected aptamer for vaccinia virus (VACV), evaluating the aggregation and molecular interaction of the optimized aptamers with the recombinant oncolytic virus VV-GMCSF-Lact, and estimating their immunoshielding properties in the presence of human blood serum. We chose one optimized aptamer, NV14t_56, with the highest affinity to the virus from the pool of several truncated aptamers and built its 3D model. The NV14t_56 remained stable in human blood serum for 1 h and bound to VV-GMCSF-Lact in the micromolar range (Kd ≈ 0.35 μM). Based on dynamic light scattering data, it has been demonstrated that aptamers surround viral particles and inhibit aggregate formation. In the presence of serum, the hydrodynamic diameter (by intensity) of the aptamer–virus complex did not change. Microscale thermophoresis (MST) experiments showed that NV14t_56 binds with virus (EC50 = 1.487 × 109 PFU/mL). The analysis of the amplitudes of MST curves reveals that the components of the serum bind to the aptamer–virus complex without disrupting it. In vitro experiments demonstrated the efficacy of VV-GMCSF-Lact in conjunction with the aptamer when exposed to human blood serum in the absence of neutralizing antibodies (Nabs). Thus, NV14t_56 has the ability to inhibit virus aggregation, allowing VV-GMCSF-Lact to maintain its effectiveness throughout the storage period and subsequent use. When employing aptamers as protective agents for oncolytic viruses, the presence of neutralizing antibodies should be taken into account.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Yu. V., Aleksandrovsky A. S., Laptash N. M., Krylov A. S., Gerasimov M. A., Dubrovskiy A. A.
Заглавие : Raman scattering, absorption and luminescence spectroscopy of CoSiF6·6H2O crystal and CoSiF6·6H2O:Mn4+ red-emitting phosphor
Колич.характеристики :6 с
Место публикации : Opt. Mater. - 2023. - Vol. 144. - Ст.114343. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2023.114343. - ISSN 18731252 (eISSN)
Примечания : Cited References: 30. - The reported study was funded by Russian Science Foundation , Government of Krasnoyarsk Territory and Krasnoyarsk Regional Foundation of Science according to the research project ‘‘Synthesis, spectral and magnetic properties of ABF6·6H2O systems, new materials for photonics.” No. 23-22-10037 . https://rscf.ru/en/project/23-22-10037/ . Usage of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS is acknowledged. We thank A. Yu. Mamaev for recording the luminesce spectra of CoSiF6·6H2O:Mn 4+
Аннотация: CoSiF6·6H2O and CoSiF6·6H2O:Mn4+ crystals were investigated by means of Raman, optical absorption, and luminescence spectroscopy. Absorption spectra of CoSiF6·6H2O are analyzed by Tanabe-Sugano technique and are proved to be well-describable at crystal field strength Dq = 1000 cm−1, and Racah parameters B = 896 cm−1, C = 4408 cm−1, Dq/B = 1.116. Raman spectroscopy reveals a phase transition associated with the ordering of both the CoO6 and SiF6 octahedra, which occurs through the ordering of the H2O subsystem. Luminescence spectrum of Mn4+ ions in CoSiF6·6H2O lattice consists of six components corresponding to Stokes and anti-Stokes emission from 2E state of Mn4+ ion at vibrational frequencies of MnF6 octahedron ν6 = 230 cm−1, ν4 = 335 cm−1, and ν3 = 645 cm−1. Quantum efficiency of red emission maximizes at excitation wavelength 357 nm and equals to 5%. Decrease of quantum efficiency in comparison to other related materials is explained by absorption of Co2+ ions and non-radiative relaxation in the Co2+ subsystem.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slyusarenko N. V., Yushina I. D., Slyusareva E. A., Golovkina E. V., Krylova S. N., Vtyurin A. N., Krylov A. S.
Заглавие : Determination of the pore direction in a crystalline metal-organic framework by Raman spectroscopy and periodic calculations based on the electron density functional theory
Колич.характеристики :10 с
Место публикации : Optoelectron. Instrum. Data Process. - 2023. - Vol. 59, Is. 6. - P.693-702. - ISSN 87566990 (ISSN), DOI 10.3103/S8756699023060134. - ISSN 19347944 (eISSN)
Примечания : Cited References: 32. - This work was supported by the Russian Foundation for Basic Research (Russian Center of Scientific Information), project no. 21-52-12018We are grateful to Dr. Irena Senkovska for the presented DUT-8 (Ni, Co) samples
Аннотация: A method for the determination of pore orientation in metal-organic framework structures by polarized Raman spectra is proposed. The method involves sensitivity of the line intensity of Raman scattering to the geometry of propagation in a crystal. The operability of the method is shown by DUT-8 (Ni, Co) crystals. The obtained results are interpreted based on analysis of symmetry and direction of vibrations within periodic calculations of the electron density functional theory. The simultaneous approach allowed us to describe the vibrations and to find the principal crystal orientation collinear to the pore direction. The information on the pore orientation is necessary for problems of adsorption and design of complex multicomponent materials based on metal-organic framework.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Подопригора, Владимир Георгиевич, Раковская С. А.
Заглавие : Определение характеристик поверхности диэлектрических пластин с помощью рассеяния света
Место публикации : Международ. журн. прикл. и фундамент. исслед. - 2023. - № 6. - С. 59-62. - ISSN 19963955 (ISSN), DOI 10.17513/mjpfi.13554
Примечания : Библиогр.: 5
Аннотация: В работе предложен новый способ определения параметров шероховатостей и корреляционной функции (КФ) сверхгладких диэлектрических пластин. Способ основан на нахождении из экспериментальной индикатрисы рассеивания света коэффициентов разложения (КФ) в ряд по системе ортогональных функций с последующим вычислением среднеквадратичных отклонений высот неровностей поверхности σ и периода корреляции Т. Отличительными особенностями метода являются: 1) отсутствие неоднозначности, возникающей при подгонке к экспериментальной кривой рассеяния теоретических зависимостей с разными корреляционными функциями, которые сами зависят от параметров шероховатостей; 2) возможность избежать необходимости измерять индикатрису рассеяния во всей полусфере над образцом. Данный способ определения КФ и параметров шероховатости поверхности может применяться для любого типа границ раздела при соблюдении критерия Рэлея, определяющего степень неровности поверхности отражения по отношению к длине волны падающего излучения. Поэтому объектами исследования могут быть не только поверхности с нанометровыми шероховатостями, облучаемые лазерным светом, но и, например, земные покровы при их дистанционном зондировании радиосигналами навигационных спутников. Для полированных пластин кварца получены значения параметров поверхностей, близкие к аналогичным величинам, измеренным независимо на лазерном интерференционном профилометре другими авторами.The paper proposes a new method for determining the roughness parameters and the correlation function (CF) of supersmooth dielectric plates. The method is based on finding the expansion coefficients (CF) from the experimental light scattering indicatrix in a series according to a system of orthogonal functions, followed by the calculation of the standard deviations of the surface irregularity heights σ and the correlation period Т. Distinctive features of the method are: 1) the absence of ambiguity that arises when fitting theoretical dependences with different correlation functions, which themselves depend on the roughness parameters, to the experimental scattering curve; 2) the possibility of avoiding the need to measure the scattering indicatrix in the entire hemisphere above the sample. This method for determining the CF and surface roughness parameters can be used for any type of interface, subject to the Rayleigh criterion, which determines the degree of roughness of the reflection surface with respect to the wavelength of the incident radiation. Therefore, the objects of study can be not only surfaces with nanometer roughness irradiated by laser light, but also, for example, earth covers during their remote sensing by radio signals from navigation satellites. For polished quartz plates, the values of the surface parameters were obtained close to similar values measured independently on a laser interference profilometer by other authors.
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10.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Karavayskiy A. Yu., Lukin Y. I.
Заглавие : The effect of clay content on the spectra of permetivity of mineral soils at positive temperatures
Колич.характеристики :4 с
Коллективы : Radiation and Scattering of Electromagnetic Waves 2023
Место публикации : Conf. Proc. - Radiat. Scatt. Electromagn. Waves, RSEMW. - 2023. - P.456-459. - , DOI 10.1109/RSEMW58451.2023.10201998
Примечания : Cited References: 17. - The work was financially supported by the Russian Science Foundation and the Krasnoyarsk Regional Fund for Support of Scientific and Scientific and Technical Activities within the framework of the scientific project No. 22-27-20112
Аннотация: In this research, it was studied the crossover frequencies of the spectra of the real part of the permittivity of moist mineral soils with different clay content from 10 to 64% in the frequency range from 15 MHz to 15 GHz and in the temperature range from 25 to 0 °C. Based on the experimental dependences obtained, empirical models were proposed for the average crossover frequency of the soil of the real part of the permittivity spectra in the range of changes of these frequencies values with temperature changes, as well as for the half-widths of the ranges of changes.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shadrina G. V., Bulgakov E. N.
Заглавие : Optical bistability and symmetry breaking at resonance scattering of light by a finite photonic crystal with a nonlinear resonant cavity
Место публикации : J. Exp. Theor. Phys. - 2022. - Vol. 135, Is. 5. - P.632-641. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776122110176. - ISSN 10906509 (eISSN)
Примечания : Cited References: 50. - This study was supported by the Russian Science Foundation, grant no. 22-12-00070
Аннотация: Optical bistability and symmetry breaking under the conditions of plane wave incidence on a system of coupled photonic crystal microcavities containing an inclusion with Kerr susceptibility have been studied. The T-matrix modal method has been generalized for the case of nonlinear microcavities supporting one monopole mode. It has been shown that both phenomena considerably depend not only on external field strength but also on angle of incidence and photonic crystal size.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mironov, Vladimir, Shchugoreva I. A., Artyushenko P. V., Morozov D. I., Borbone N., Oliviero G., Zamay T. N., Moryachkov R. V., Kolovskaya, ., Lukyanenko K. A., Song Y. L., Merkuleva I. A., Zabluda V. N., Peters G., Koroleva L. S., Veprintsev D. V., Glazyrin Y. E., Volosnikova E. A., Belenkaya S. V., Esina T. I., Isaeva A. A., Nesmeyanova, ., Shanshin D. V., Berlina A. N., Komova N. S., Svetlichnyi V. A., Silnikov V. N., Shcherbakov D. N., Zamay G. S., Zamay S. S., Smolyarova T. E., Tikhonova E. P., Chen U. S., Jeng G., Condorelli V., Franciscis G., Groenhof C. Y., Yang A. A., Moskovsky D. G., Fedorov F. N., Tomilin F. N., Tan Y., Alexeev M. V., Berezovski A. S., Kichkailo A.S.
Заглавие : Structure- and interaction-based design of anti-SARS-CoV-2 Aptamers
Коллективы : Aptamerlab LCC; U.S. Department of Energy, Office of ScienceUnited States Department of Energy (DOE) [DE-AC02-06CH11357]; European UnionEuropean Commission [H2020-INFRAEDI-02-2018-823830, H2020-EINFRA-2015-1-675728, 872391, PRISAR2 872860]; CSC-IT center in Espoo, Finland; PRACE; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-03-00043]; Ministry of Science and Higher Education of Russian Federation (state assignment of the Research Center of Biotechnology RAS); Italian Ministry of Education and ResearchMinistry of Education, Universities and Research (MIUR) [FISR2020 _00177]; Canadian Institutes of Health ResearchCanadian Institutes of Health Research (CIHR) [OV1-170353]; Russian Science FoundationRussian Science Foundation (RSF) [21-73-20240]
Место публикации : Chem. - Eur. J. - 2022. - Vol. 28, Is. 12. - Ст.e202104481. - ISSN 0947-6539, DOI 10.1002/chem.202104481. - ISSN 1521-3765(eISSN)
Примечания : Cited References: 85. - The authors are grateful to JCSS Joint Super Computer Center of the Russian Academy of Sciences – Branch of Federal State Institution “Scientific Research Institute for System Analysis of the Russian Academy of Sciences” for providing supercomputers for computer simulations. The authors thank the RSC Group (www.rscgroup.ru) and personally Mr. Oleg Gorbachev for the constant support and establishment of “The Good Hope Net Project” (www.thegoodhope.net) multifunctional non-profit anti-CoVID research project. The authors also thank the Helicon Company (www.helicon.ru) and personally Olesya Kucenko, Alexander Kolobov, Leonid Klimov for instrumental support and help with conducting fluorescence polarization assays, which were performed on a demo instrument Clariostar Plus microplate reader (BMG LABTECH, Germany). We thank Dr. Yong-Zhen Zhang for providing the genome sequence of 2019-nCoV and Dr. Xinquan Wang for providing the crystal structure of the binding domain of the SARS-2 Spike protein. The authors are grateful to Aptamerlab LCC financial support (www.aptamerlab.com). Y.A.’s work at Argonne National Laboratory was supported by the U.S. Department of Energy, Office of Science, under contract DE-AC02-06CH11357. The work of D.M. and G.G. has been done as part of the BioExcel CoE (www.bioexcel.eu), a project funded by the European Union contracts H2020-INFRAEDI-02-2018-823830 and H2020-EINFRA-2015-1-675728. D.M. and G.G. also thank the CSC-IT center in Espoo, Finland, as well as PRACE for awarding access to resource Curie-Rome based in France at GENCI. V.M. thanks Russian Foundation for Basic Research (project number 19-03-00043). A.B.’s and N.K.’s work was supported by the Ministry of Science and Higher Education of Russian Federation (state assignment of the Research Center of Biotechnology RAS). V. deF. G.C., N.B and G.O. are grateful to FISR2020 _00177 Shield, Italian Ministry of Education and Research, for funding. GC is grateful to the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement: cONCReTE 872391; PRISAR2 872860. Use of the 13 A BioSAXS beamtime at the Taiwan Photon Source is acknowledged. The work of M.V.B was funded by the Canadian Institutes of Health Research grant OV1-170353. SAXS measurements and PIEDA analyses were funded by the Russian Science Foundation (project No 21-73-20240 for A.S.K.)
Предметные рубрики: BIOLOGICAL MACROMOLECULES
SOLUTION SCATTERING
BINDING
SPIKE
Аннотация: Aptamer selection against novel infections is a complicated and time-consuming approach. Synergy can be achieved by using computational methods together with experimental procedures. This study aims to develop a reliable methodology for a rational aptamer in silico et vitro design. The new approach combines multiple steps: (1) Molecular design, based on screening in a DNA aptamer library and directed mutagenesis to fit the protein tertiary structure; (2) 3D molecular modeling of the target; (3) Molecular docking of an aptamer with the protein; (4) Molecular dynamics (MD) simulations of the complexes; (5) Quantum-mechanical (QM) evaluation of the interactions between aptamer and target with further analysis; (6) Experimental verification at each cycle for structure and binding affinity by using small-angle X-ray scattering, cytometry, and fluorescence polarization. By using a new iterative design procedure, structure- and interaction-based drug design (SIBDD), a highly specific aptamer to the receptor-binding domain of the SARS-CoV-2 spike protein, was developed and validated. The SIBDD approach enhances speed of the high-affinity aptamers development from scratch, using a target protein structure. The method could be used to improve existing aptamers for stronger binding. This approach brings to an advanced level the development of novel affinity probes, functional nucleic acids. It offers a blueprint for the straightforward design of targeting molecules for new pathogen agents and emerging variants.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostyukov A. S., Gerasimov V. S., Ershov A. E., Bulgakov E. N.
Заглавие : Ring of bound states in the continuum in the reciprocal space of a monolayer of high-contrast dielectric spheres
Коллективы : RFBR Russian Foundation for Basic Research (RFBR); Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [20-42-240003]; Ministry of Science and Higher Education of the Russian Federation [FSRZ-20200008]
Место публикации : Phys. Rev. B. - 2022. - Vol. 105, Is. 7. - Ст.075404. - ISSN 2469-9950, DOI 10.1103/PhysRevB.105.075404. - ISSN 2469-9969(eISSN)
Примечания : Cited References: 43. - This research was supported by RFBR, Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science, Project No. 20-42-240003, by the Ministry of Science and Higher Education of the Russian Federation, Project No. FSRZ-20200008
Предметные рубрики: PHOTONIC BAND-STRUCTURE
FANO RESONANCES
SCATTERING
Аннотация: We consider light scattering by two-dimensional arrays of high-index dielectric spheres arranged into a triangular and square lattices. We demonstrate the appearance of the double degenerate accidental super-BIC modes with extremely suppressed radiative losses in the vicinity of the Γ point of the leaky band of the triangular lattice. Two rings of BICs (circular lines of BICs in reciprocal space) with different polarization appear at the point of the super-BIC destruction. The radius of the ring BIC (RBIC) changes as a function of the sphere's radius. We propose a generic analytical expression to describe the behavior of the guided mode decay rate as a function of the sphere radii and the wave vector in the vicinity of the RBIC. The results are explained using a multipolar approach.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Izotov A. V., Belyaev B. A., Boev N. M., Burmitskikh A. V., Skomorokhov G. V., Zharkov S. M., Solovev P. N.
Заглавие : Ferromagnetic resonance line broadening and shift effect in nanocrystalline thin magnetic films: Relation with crystalline and magnetic structure
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund; JSC "NPP "Radiosviaz" [20-42-242901]; Ministry of Science and Higher Education of the Russian Federation [075-11-2019-054, FSRZ-2020-0011]
Место публикации : J. Alloy. Compd. - 2022. - Vol. 900. - Ст.163416. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2021.163416. - ISSN 1873-4669(eISSN)
Примечания : Cited References: 52. - The reported study was funded by RFBR, the Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund and JSC "NPP "Radiosviaz", project number 20-42-242901 and was supported by the Ministry of Science and Higher Education of the Russian Federation, agreement number 075-11-2019-054 dated 22.11.2019.; The electron microscopy investigations were conducted in the SFU Joint Scientific Center whose infrastructure was supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Предметные рубрики: SUSCEPTIBILITY
RIPPLE
ANISOTROPIES
ALLOYS
Аннотация: With the rapid development of telecommunication technologies and highly integrated electronic devices, researchers show great interest in nanocrystalline soft magnetic thin films with unique characteristics for microwave applications. An important direction of the current research in this field is the study of high-frequency magnetization dynamics that directly depends on the damping processes in a magnetic medium. This paper reports on the effect of sharp broadening and shift of the ferromagnetic resonance (FMR) line revealed experimentally in a 40-nm-thick nanocrystalline permalloy (Fe20Ni80) thin film at a frequency of about 5 GHz. The effect arises only in films with crystallite size exceeding some critical value Dcr. The micromagnetic simulation demonstrates that exchange and dipolar interactions between randomly oriented crystallites form in the film a quasiperiodic magnetic structure with a characteristic wavelength in the range from 36 nm to 3.3 µm. An analysis of the two-magnon scattering model and simulation results shows that the formed magnetic structure provides the energy transfer from uniform magnetization oscillations (uniform FMR) to spin waves, which results in an additional energy dissipation channel and, consequently, sharp FMR line broadening. A theoretical estimate of the critical crystallite size Dcr based on this model yields a value of ~14.3 nm for 40-nm-thick Fe20Ni80 films.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shvets P., Shabanov A. V., Maksimova K., Goikhman A.
Заглавие : Micro-Raman mapping of VO2 (T) microcrystals orientation
Место публикации : Vib. Spectrosc. - 2022. - Vol. 118. - Ст.103328. - ISSN 09242031 (ISSN), DOI 10.1016/j.vibspec.2021.103328
Примечания : Cited References: 38. - This work was prepared with support from Ministry of Science and Higher Education of the Russian Federation (project FZWM-2020-0008)
Аннотация: Microcrystals orientation distribution in triclinic vanadium dioxide VO2 (T) films was investigated by polarized Raman scattering with a resolution of few ?m and confirmed by electron backscatter diffraction. Euler angles used to describe the orientation of the crystal were determined by two different techniques and good agreement between the values was achieved. Finally, it was demonstrated that Raman scattering could be used to identify the direction of the lattice vector c for (002) crystals in consequence of the triclinic nature of VO2 (T)
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prosnikov M. A., Bal M. E., Kolkov M. I., Pankrats A. I., Pisarev, R., V, Christianen, P. C. M.
Заглавие : Subterahertz and terahertz spin and lattice dynamics of the insulating ferromagnet PbMnBO4
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [20-42-240006]; BASIS Foundation [21-1-4-33-1]; HFML-RU/NWO-I, a member of the European Magnetic Field Laboratory (EMFL)
Место публикации : Phys. Rev. Res. - 2022. - Vol. 4, Is. 1. - Ст.013004. - ISSN 2643-1564(eISSN), DOI 10.1103/PhysRevResearch.4.013004
Примечания : Cited References: 62. - M.A.P. greatly acknowledges D. A. Andronikova for aid, B. T. Crow for fruitful discussions, and P. Albers for technicalassistance. Crystal growth was supported by RFBR and the Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, through Research Project No. 20-42-240006. The theoretical part of the spin dynamics calculations was supported by BASIS Foundation Grant No. 21-1-4-33-1. The support of HFML-RU/NWO-I, a member of the European Magnetic Field Laboratory (EMFL) , is acknowledged
Предметные рубрики: LIGHT-SCATTERING
ANTI-STOKES
BRILLOUIN-SCATTERING
Аннотация: Orthorhombic PbMnBO4 is a rare example of an insulating ferromagnet in which the magnetic properties, in particular the strong magnetic anisotropy, are determined by the Mn3+ Jahn-Teller ion. Here, we report on the detailed investigation of magnetic excitations in the subterahertz and terahertz frequency ranges, as well as lattice excitations in the terahertz range. Using polarized azimuthally resolved Raman spectroscopy, four branches of magnetic excitations were observed and assigned to one acoustic and three optical one-magnon modes. The coupling between ferromagnetic ordering at TC=31K and the Jahn-Teller distortions of [MnO6] octahedra due to the spin-phonon interaction was directly observed for some specific phonon modes involved in these distortions. A spin-wave Hamiltonian was developed that allowed us to determine a unique set of exchange and effective anisotropy parameters. The intensity ratio of the anti-Stokes to Stokes acoustic magnon peaks is found to be anomalous and directly indicates the involvement of the magneto-optical parameters in the magnetic Raman scattering process.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Skorobogatov S. A., Shaykhutdinov K. A., Balaev D. A., Pavlovskii M. S., Krasikov A. A., Terentjev K. Yu.
Заглавие : Spin dynamics and exchange interaction in orthoferrite TbFeO3 with non-Kramers rare-earth ion
Место публикации : Phys. Rev. B. - 2022. - Vol. 106, Is. 18. - Ст.184404. - ISSN 24699950 (ISSN), DOI 10.1103/PhysRevB.106.184404
Примечания : Cited References: 41. - We acknowledge A. Podlesnyak for help with INS experiments and S. E. Nikitin for stimulating discussion. The reported study was funded by RFBR, Project No. 20-32-90142. This research used resources at Spallation Neutron Source, a DOE Office of Science User Facility operated by the Oak Ridge National Laboratory
Аннотация: The low-temperature spin dynamics of the orthorhombic TbFeO3 perovskite has been studied. It has been found that the inelastic neutron scattering (INS) spectrum of the investigated compound contains two modes corresponding to different sublattices. It is shown that the iron subsystem orders antiferromagnetically at TN=632 K and exhibits the high-energy magnon dispersion. The magnetic dynamics of this subsystem has been described within the linear spin wave theory and the in-plane and out-of-plane exchange anisotropy has been demonstrated. The approach proposed previously to describe the magnon dispersion in the TmFeO3 compound has been used. Three levels of the nondispersive crystal electric field corresponding to Tb3+ ions have been found in the energy region below 40 meV at about 17, 26, and 35 meV. The behavior of the magnetic correlation length of the terbium subsystem has been determined by studying the diffuse scattering at different temperatures. The evolution of this subsystem has been numerically described within the point charge model. It is shown that the numerical data agree satisfactorily with the experiment and with the general concept of the single-ion approximation applied to the rare-earth subsystem of orthorhombic perovskites.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Igumenov A. Yu., Andryushchenko T. A.
Заглавие : Different approaches for SiO2 inelastic electron scattering cross section spectra dissolving
Коллективы : Reshetnev Readings 2019
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2022. - Vol. 1230: Reshetnev Readings 2019 11th-15th November 2019, Krasnoyarsk, Russian Federation. - Ст.012007. - ISSN 17578981 (ISSN), DOI 10.1088/1757-899X/1230/1/012007. - ISSN 1757899X (eISSN)
Примечания : Cited References: 14. - The authors express gratitude to Parshin A.S. for assignation the SiO2 Kλ-spectra
Аннотация: Inelastic electron scattering cross section spectra (Kλ-spectra) of SiO2 were dissolved into bulk-loss and surface-loss components using factor analysis and Tougaard functions approximation. Primary electron energy dependences of various components intensities were received. It was shown that joint using of factor analysis and Tougaard functions approximation allows receiving more reliable results in inelastic electron scattering cross section spectra studies.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Bayukov O. A., Balaev D. A., Ladygina V. P., Yaroslavtsev R. N., Knyazev Yu. V., Balasoiu M., Kolenchukova O. A., Iskhakov R. S.
Заглавие : Ferrihydrite nanoparticles produced by Klebsiella oxytoca: Structure and properties dependence on the cultivation time
Место публикации : Adv. Powder Technol. - 2022. - Vol. 33, Is. 8. - Ст.103692. - ISSN 09218831 (ISSN), DOI 10.1016/j.apt.2022.103692
Примечания : Cited References: 59. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects No. 20-416-242907
Аннотация: Ferrihydrite nanoparticles were synthesized using Klebsiella oxytoca microorganisms under various cultivation conditions. The cultivation of bacteria was carried out under various lighting conditions, and the duration of cultivation varied from 3 to 56 days. Biogenic ferrihydrite nanoparticles were studied by Mössbauer spectroscopy, magnetometry, and small-angle X-ray scattering. The process of formation of ferrihydrite nanoparticles and the states arising during the cultivation of microorganisms have been investigated. The results of Mössbauer spectroscopy showed that, depending on the time of cultivation, three different states of ferrihydrite can be realized. States differ both in the ratio of defective and non-defective positions, and the size of the particle. Experimental results indicate that ferrihydrite nanoparticles are a system of variable composition and pass through several structural (or morphological) states during the cultivation of microorganisms. A model of the structure of ferrihydrite nanoparticles is proposed, which consists in the presence of an antiferromagnetic dense core with a high Néel temperature and a friable shell with a significantly lower temperature of magnetic ordering.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y. L., Borisov R. V., Vorobyev S. A., Tomashevich Y. V., Romanchenko A. S., Likhatski M. N., Karacharov A. A., Bayukov O. A., Knyazev Yu. V., Velikanov D. A., Zharkov S. M., Krylov A. S., Krylova S. N., Nemtsev I. V.
Заглавие : Synthesis and characterization of nanoscale composite particles formed by 2D layers of Cu-Fe sulfide and Mg-based hydroxide
Место публикации : J. Mater. Chem. A. - 2022. - Vol. 10, Is. 17. - P.9621-9634. - ISSN 20507488 (ISSN), DOI 10.1039/d2ta00877g
Примечания : Cited References: 84. - This research was supported by the Russian Foundation for Basic Research, Krasnoyarsk Territory Administration and Krasnoyarsk Territory Science Foundation, project 20-43-242903. Facilities of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” were employed in the work
Аннотация: We introduce here a multifunctional material composed of alternating atomic sulfide sheets close to the composition of CuFeS2 and Mg-based hydroxide ones (valleriite), which are assembled due to their electric charges of opposite sign. Valleriite particles 50-200 nm in lateral size and 10-20 nm in thickness were synthesized via a simple hydrothermal pathway using various concentrations of precursors and dopants, and examined with XRD, TEM, EDS, X-ray photoelectron spectroscopy, reflection electron energy loss spectroscopy (REELS), Mossbauer, Raman and UV-vis-NIR spectroscopies, and magnetization, dynamic light scattering, and zeta potential measurements. The electronic, magnetic and optical characteristics are found to be critically dependent on the charge (electron density) at the narrow-gap sulfide layers containing Cu+ and Fe3+ cations, and can be tuned via the composition of the hydroxide part. Particularly, substitution of Mg2+ with Al3+ increases the negative charge of the hydroxide layers and reduces the content of Fe3+-OH centers (10-45% of total iron); the effects of Cr and Co dopants entering both layers are more complicated. Mossbauer doublets of paramagnetic Fe3+ detected at room temperature transform into several Zeeman sextets at 4.2 K; the hyperfine fields up to 500 kOe and complex magnetic behavior, but not pure paramagnetism or antiferromagnetism, were observed for valleriites with the higher positive charge of the sulfide sheets, probably due to the depopulation of the minority-spin 3d states of S-bonded Fe3+ ions. Aqueous colloids of valleriite show optical absorption at 500-750 nm, which, along with the peaks at the same energies in REELS, may arise due to quasi-static dielectric resonance involving the vacant Fe 3d band and being dependent on the composition of both layers too. These and other findings call attention to valleriites as a new rich family of 2D materials for a variety of potential applications.
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