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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Sedykh A. E., Molokeev M. S., Oreshonkov A. S., Aleksandrovsky A. S., Krylov A. S., Khritokhin N. A., Sal'nikova E. I., Andreev O. V., Muller-Buschbaum K.
Заглавие : Crystal and electronic structure, thermochemical and photophysical properties of europium-silver sulfate monohydrate AgEu(SO4)2·H2O
Место публикации : J. Solid State Chem. - 2021. - Vol. 294. - Ст.121898. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2020.121898
Примечания : Cited References: 54. - This work was partially supported by the Russian Foundation for Basic Research (Grant 19-33-90258∖19 ). Use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center « Krasnoyarsk Science Center SB RAS» is acknowledged
Аннотация: In order to synthesize single crystals of europium-silver double sulfate monohydrate, a hydrothermal reaction route was used. It was found that the crystallization cannot be performed under standard conditions. The compound AgEu(SO4)2·H2O crystallizes in the trigonal crystal system, space group P3221 (a = 6.917(1), c = 12.996(2) Å, V = 538.53(17) Å3). The structure consists of triple-capped trigonal prisms [EuO9], in which one oxygen atom belongs to crystalline water, silver octahedra [AgO6], and sulfate tetrahedra [SO4]. The hydrogen bonds in the system additionally stabilize the structure. The electronic band structure wasstudied by density functional theory calculations which show that AgEu(SO4)2·H2O is an indirect band gap dielectric. Temperature dependent photoluminescence spectroscopy shows emission bands of transitions from the 5D0 state to the spin-orbit components of the 7FJmultiplet (J = 0–6).The ultranarrow transition 5D0 - 7F0 shows a red shift with respect to other europium-containing water-free sulfates that is ascribed to the presence of OH group in the crystal structure in the close vicinity of the Eu3+ ion. An effect of abnormal sensitivity of the Ω4 intensity factor to minor distortions of the local environment is detected for the observed low local symmetry of C2.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Grishina, Svetlana, Goryainov, Sergey, Oreshonkov A. S., Karmanov, Nikolay
Заглавие : Micro-Raman study of cesanite (Ca2Na3(OH)(SO4)3) in chloride segregations from Udachnaya-East kimberlites
Коллективы : International GeoRaman Conference
Место публикации : J. Raman Spectrosc. - 2022. - Vol. 53, Is. 3: Special Issue: GEORAMAN 2020. - P.497-507. - ISSN 0377-0486, DOI 10.1002/jrs.6168. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 33
Предметные рубрики: CARBONATE
IDENTIFICATION
INSIGHTS
APATITE
Аннотация: Cesanite (Ca2Na3(OH)(SO4)3), a rare mineral, has been found in a few places restricted to a geothermal field and caves. We report the new occurrence of cesanite in quite different geological site—within sulfate-rich melt inclusions in chloride segregations from kimberlites of Udachnaya-East pipe (Siberia). Two halite generations: сesanite free and сesanite-bearing, were distinguished in concentrically zonal segregations according to the results of the mineral and sulfate melt inclusion study by micro-Raman spectroscopy and SEM-EDS. We have applied the Raman spectroscopy and first principles calculations to understand structural and vibrational properties of cesanite daughter mineral in polyphase sulfate inclusions. Polarized spectra provided additional information on the overlapped components of the spectral profile. The Raman spectra of cesanite in the range of OH stretching vibrations are reported for the first time. The study aims to clarify the source of the NaSCl-enrichment in the Udachnaya-East pipe, which is highly discussed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Molokeev M. S., Oreshonkov A. S., Krylov A. S., Aleksandrovsky A. S., Azarapin N. O., Andreev O. V., Razumkova I. A., Atuchin V. V.
Заглавие : Crystal structure, vibrational, spectroscopic and thermochemical properties of double sulfate crystalline hydrate [CsEu(H2O)3(SO4)2]·H2O and its thermal dehydration product CsEu(SO4)2
Место публикации : Crystals. - 2021. - Vol. 11, Is. 9. - Ст.1027. - ISSN 20734352 (ISSN), DOI 10.3390/cryst11091027
Примечания : Cited References: 103. - This work was partially supported by the Russian Foundation for Basic Research (grant 19-33-90258\19)
Аннотация: Crystalline hydrate of double cesium europium sulfate [CsEu(H2O)3(SO4)2]·H2O was synthesized by the crystallization from an aqueous solution containing equimolar amounts of 1Cs+:1Eu3+:2SO42− ions. Anhydrous salt CsEu(SO4)2 was formed as a result of the thermal dehydration of the crystallohydrate. The unusual effects observed during the thermal dehydration were attributed to the specific coordination of water molecules in the [CsEu(H2O)3(SO4)2]·H2O structure. The crystal structure of [CsEu(H2O)3(SO4)2]·H2O was determined by a single crystal X-ray diffraction analysis, and the crystal structure of CsEu(SO4)2 was obtained by the Rietveld method. [CsEu(H2O)3(SO4)2]·H2O crystallizes in the monoclinic system, space group P21/c (a = 6.5574(1) Å, b = 19.0733(3) Å, c = 8.8364(2) Å, β = 93.931(1)°, V = 1102.58(3) Å3). The anhydrous sulfate CsEu(SO4)2 formed as a result of the thermal destruction crystallizes in the monoclinic system, space group C2/c (a = 14.327(1) Å, b = 5.3838(4) Å, c = 9.5104(6) Å, β = 101.979(3) °, V = 717.58(9) Å3). The vibration properties of the compounds are fully consistent with the structural models and are mainly determined by the deformation of non-rigid structural elements, such as H2O and SO42−. As shown by the diffused reflection spectra measurements and DFT calculations, the structural transformation from [CsEu(H2O)3(SO4)2]·H2O to CsEu(SO4)2 induced a significant band gap reduction. A noticeable difference of the luminescence spectra between cesium europium sulfate and cesium europium sulfate hydrate is detected and explained by the variation of the extent of local symmetry violation at the crystallographic sites occupied by Eu3+ ions, namely, by the increase in inversion asymmetry in [CsEu(H2O)3(SO4)2]·H2O and the increase in mirror asymmetry in CsEu(SO4)2. The chemical shift of the 5D0 energy level in cesium europium sulfate hydrate, with respect to cesium europium sulfate, is associated with the presence of H2O molecules in the vicinity of Eu3+ ion.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Atuchin V. V., Molokeev M. S., Wang N., Jiang X., Aleksandrovsky A. S., Krylov A. S., Oreshonkov A. S., Sedykh A. E., Volkova S. S., Lin Z., Andreev O. V., Muller-Buschbaum K.
Заглавие : Negative thermal expansion in one-dimension of a new double sulfate AgHo(SO4)2 with isolated SO4 tetrahedra
Место публикации : J. Mater. Sci. Technol. - 2021. - Vol. 76. - P.111-121. - ISSN 10050302 (ISSN), DOI 10.1016/j.jmst.2020.10.026
Примечания : Cited References: 55. - This work was financially supported by the Russian Foundation for Basic Research (Nos. 18-02-00754 and 18-32-20011 ), the National Scientific Foundations of China (No. 11974360 ) and the Russian Science Foundation (No. 19-42-02003 , in the part of conceptualization). M.S. Molokeev, A.S. Aleksandrovsky, A.S. Krylov, and A.S. Oreshonkov are grateful to Basic Project of the Ministry of Science of the Russian Federation in part of XRD, luminescent and Raman studies. IR-spectrometry was performed using resources of the Research Resource Center "Natural Resource Management and Physico-Chemical Research". Use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» is acknowledged
Аннотация: A double holmium-silver sulfate was obtained for the first time. The temperature intervals for the formation and stability of the compound were determined by differential scanning calorimetry. The crystal structure of AgHo(SO4)2 was determined by Rietveld method. The X-ray diffraction (XRD) analysis showed that the compound crystallizes in the monoclinic syngony, space group P21/m, with the unit cell parameters a = 4.71751 (4) Å, b = 6.84940 (6) Å and c = 9.89528 (9) Å, β = 95.1466 (4)°, V = 318.448 (5) Å3, Z = 2, RB = 1.55 %, T = 303 K. Two types of sulfate tetrahedra were found in the structure, which significantly affected the spectral properties in the infrared range. In the temperature range of 143−703 K, a negative thermal expansion along the b direction accompanied by a positive thermal expansion along the a and c directions was observed. It was established that negative thermal expansion is the result of the deformation of sulfate tetrahedra, which is affected by the movement of holmium and silver atoms. The excitation in the blue spectral range (457.9 nm) produces a luminescence in light blue (489 nm), green (545 nm) and red (654 nm) spectral ranges, and the latter two were of comparable intensity that is favorable for WLED sources. The observed luminescent band distribution is ascribed to the specific crystal field at Ho3+ ion sites rather than a variation of radiationless probability.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Kartashev A. V., Gorev M. V., Molokeev M. S., Korotkov L. N., Rysiakiewicz-Pasek E.
Заглавие : Specific heat and thermal expansion of triglycine sulfate-porous glass nanocomposites
Коллективы : Russian Foundation for Basic Research [16-32-00092 mol-a]
Место публикации : Phys. Solid State. - 2018. - Vol. 60, Is. 7. - P.1338-1343. - ISSN 1063-7834, DOI 10.1134/S1063783418070181. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 27. - This study was supported by the Russian Foundation for Basic Research, project no. 16-32-00092 mol-a.
Предметные рубрики: PHASE-TRANSITIONS
DIELECTRIC-PROPERTIES
FERROELECTRIC COMPOSITES
Аннотация: The effect of restricted geometry on specific heat capacity and thermal expansion of the triglycine sulfate (TGS)–borosilicate glass composites have been studied first. A decrease in the entropy and temperature of the P21 ↔ P21/m phase transition in the TGS component with decreasing the glass matrix pore diameter at the invariable specific heat and thermal expansion coefficient has been observed. The estimates are indicative of the minor effect of internal pressure on the TGS pressure coefficient dTC/dp in the composites.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Aleksandrovsky A. S., Atuchin V. V., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Shestakov N. P., Andreev O. V.
Заглавие : Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups
Место публикации : J. Ind. Eng. Chem. - 2018. - Vol. 68. - P.109-116. - ISSN 1226086X (ISSN), DOI 10.1016/j.jiec.2018.07.034
Примечания : Cited References: 83. - This work was supported by the Russian Foundation for Basic Research ( 16-52-48010 , 17-52-53031 ). The equipments of the Collective Use Center — Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch Russian Academy of Sciences [ http://ccu.kirensky.ru/ ] was used.
Ключевые слова (''Своб.индексиров.''): europium sulfate--synthesis--structure--thermal analysis--photoluminescence
Аннотация: Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Atuchin V. V., Molokeev M. S., Aleksandrovsky A. S., Krylov A. S., Oreshonkov A. S., Volkova S. S., Andreev O. V.
Заглавие : Structure, thermal stability, and spectroscopic properties of triclinic Double sulfate AgEu(SO4)2 with isolated SO4 groups
Место публикации : Inorg. Chem. - 2018. - Vol. 57, Is. 21. - P.13279-13288. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.8b01837
Примечания : Cited References: 81. - This work was supported by the Russian Foundation for Basic Research (Grants 16-52-48010 and 17-52-53031). The equipment of the Collective Use Center, Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch Russian Academy of Sciences (http://ccu.kirensky.ru/) were used.
Аннотация: Silver–europium double sulfate AgEu(SO4)2 was obtained by solid-phase reaction between Ag2SO4 and Eu2(SO4)3. The crystal structure of AgEu(SO4)2 was determined by Monte Carlo method with simulated annealing, and after that, it was refined by the Rietveld method from X-ray powder diffraction data. The compound crystallizes in the triclinic symmetry, space group P1̅ (a = 0.632929(4), b = 0.690705(4), c = 0.705467(4) nm, α = 98.9614(4), β = 84.5501(4), γ = 88.8201(4)°, V = 0.303069(3) nm3). Two types of sulfate tetrahedra were found in the structure, which significantly affects the spectroscopic properties in the IR-range. In the temperature range of 143–703 K, the average linear thermal expansion coefficients of cell parameters a, b, and c are very similar, (1.11–1.67) × 10–5 K–1 in magnitude, and therefore, AgEu(SO4)2 expands almost isotropically. Upon heating in argon flow, AgEu(SO4)2 is stable up to 1053 K. The luminescence spectra in the region of ultranarrow 5D0–7F0 transition contain a single narrow and symmetric line at 579.5 nm that is evidence of good crystalline quality of AgEu(SO4)2 and uniform local environment of Eu3+ ions in the structure. Distribution of luminescence bands is determined by the environment of Eu3+ ions in the structure. Influence of Ag+ ions on the electron density distribution at Eu sites is detected.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karnachuk O. V., Rusanov I. I., Panova I. A., Kadnikov V. V., Avakyan M. R., Ikkert O. P., Lukina A. P., Beletsky A. V., Mardanov A. V., Knyazev Yu. V., Volochaev M. N., Pimenov N. V., Ravin N. V.
Заглавие : The low-temperature germinating spores of the thermophilic Desulfofundulus contribute to an extremely high sulfate reduction in burning coal seams
Колич.характеристики :13 с
Место публикации : Front. Microbiol. - 2023. - Vol. 14. - Ст.1204102. - ISSN 1664302X (eISSN), DOI 10.3389/fmicb.2023.1204102
Примечания : Cited References: 80. - This study was supported by the Russian Science Foundation Projects 21-14-00114 (to OK, sampling, sulfate reduction rate measurements, pure culture isolation and physiological experiments with pure culture and spores) and 22-14-00178 (to NR, metagenome and genome sequencing and analysis) and the Ministry of Science and Higher Education of the Russian Federation
Аннотация: Burning coal seams, characterized by massive carbon monoxide (CO) emissions, the presence of secondary sulfates, and high temperatures, represent suitable environments for thermophilic sulfate reduction. The diversity and activity of dissimilatory sulfate reducers in these environments remain unexplored. In this study, using metagenomic approaches, in situ activity measurements with a radioactive tracer, and cultivation we have shown that members of the genus Desulfofundulus are responsible for the extremely high sulfate reduction rate (SRR) in burning lignite seams in the Altai Mountains. The maximum SRR reached 564 ± 21.9 nmol S cm−3 day−1 at 60°C and was of the same order of magnitude for both thermophilic (60°C) and mesophilic (23°C) incubations. The 16S rRNA profiles and the search for dsr gene sequences in the metagenome revealed members of the genus Desulfofundulus as the main sulfate reducers. The thermophilic Desulfofundulus sp. strain Al36 isolated in pure culture, did not grow at temperatures below 50°C, but produced spores that germinated into metabolically active cells at 20 and 15°C. Vegetative cells germinating from spores produced up to 0.738 ± 0.026 mM H2S at 20°C and up to 0.629 ± 0.007 mM H2S at 15°C when CO was used as the sole electron donor. The Al36 strain maintains significant production of H2S from sulfate over a wide temperature range from 15°C to 65°C, which is important in variable temperature biotopes such as lignite burning seams. Burning coal seams producing CO are ubiquitous throughout the world, and biogenic H2S may represent an overlooked significant flux to the atmosphere. The thermophilic spore outgrowth and their metabolic activity at temperatures below the growth minimum may be important for other spore-forming bacteria of environmental, industrial and clinical importance.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Semenov S. V., Knyazev Yu. V., Balaev D. A., Karnachuk O. V., Ikkert O. P.
Заглавие : Biosyntesis of magnetic nanocomposites using sulfate-reducing bacteria
Коллективы : Байкальская международная конференция "Магнитные материалы. Новые технологии", "Магнитные материалы. Новые технологии", Байкальская международная конференция, "Magnetic materials. New tecnologies", Baikal International Conference, Иркутский государственный университет
Место публикации : Магнитные материалы. Новые технологии: тез. докл. IX Байкал. междунар. конф. BICMM-2023/ чл. прогр. ком.: S. S. Aplesnin [et al.] ; чл. орг. ком. R. S. Iskhakov [et al.]. - Иркутск, 2023. - P.170. - ISBN 978-5-00133-051-6, DOI 10.26516/978-5-9624-2178-0.2023.1-207
Примечания : Библиогр.: 2
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Basova S. A., Molokeev M. S., Oreshonkov A. S., Zhernakov M. A., Khritokhin N. A., Aleksandrovsky A. S., Krylov A. S., Sal’nikova E. I., Azarapin N. O., Shelpakova N. A., Muller-Buschbaum K., Denisenko Yu. G.
Заглавие : Thermochemistry, structure, and optical properties of a new β-La2(SO4)3 polymorphic modification
Колич.характеристики :14 с
Место публикации : Inorganics. - 2023. - Vol. 11, Is. 11. - Ст.434. - ISSN 23046740 (eISSN), DOI 10.3390/inorganics11110434
Примечания : Cited References: 58. - The work was partly carried out within the framework of the Strategic Academic Leadership Program “Priority-2030” for the Kazan Federal University and the state assignment of the Kirensky Institute of PhysicsWe acknowledge Lisa-Marie Wagner (JLU Giessen) for help with X-ray powder diffractometry, and Svetlana Volkova and Irina Palamarchuk (UTMN) for help with IR- and UV-spectrometry. The use of equipment provided by the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged
Аннотация: A new polymorphic modification of lanthanum sulfate was obtained by thermal dehydration of the respective nonahydrate. According to powder X-ray diffraction, it was established that β-La2(SO4)3 crystallized in the C2/c space group of the monoclinic system with the KTh2(PO4)3 structure type (a = 17.6923(9), b = 6.9102(4), c = 8.3990(5) Å, β = 100.321(3)°, and V = 1010.22(9) Å3). Temperature dependency studies of the unit cell parameters indicated almost zero expansion along the a direction in the temperature range of 300–450 K. Presumably, this occurred due to stretching of the [LaO9]n chains along the c direction, which occurred without a significant alteration in the layer thickness over the a direction. A systematic study of the formation and destruction processes of the lanthanum sulfates under heating was carried out. In particular, the decisive impact of the chemical composition and formation energy of compounds on the thermodynamic and kinetic parameters of the processes was established. DFT calculations showed β-La2(SO4)3 to be a dielectric material with a bandgap of more than 6.4 eV. The processing of β-La2(SO4)3 with the Kubelka–Munk function exhibited low values below 6.4 eV, which indicated a fundamental absorption edge above this energy that was consistent with LDA calculations. The Raman and infrared measurements of β-La2(SO4)3 were in accordance with the calculated spectra, indicating that the obtained crystal parameters represented a reliable structure.
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