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    Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals / M. N. Krakhalev [et al.] // J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P. 57-62, DOI 10.1016/j.molliq.2019.02.132. - Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006). . - ISSN 0167-7322. - ISSN 1873-3166
   Перевод заглавия: Смесь анионного и катионного сурфактантов, обеспечивающая электроуправляемое гомеотропное поверхностное сцепление в жидких кристаллах

РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
IONIC MODIFICATION
   TRANSITION
   DROPLETS
   CONFIGURATION
   LAYER
Кл.слова (ненормированные):
Polymer dispersed liquid crystal -- Nematic droplet -- Ionic surfactant -- Anchoring transition -- Director configuration -- Optical texture
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Belarusian State Technol Univ, Minsk 220006, BELARUS.

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Kuz'menok, N. M.; Mikhalyonok, S. G.; Bezborodov, V. S.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]; International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018(XIII ; August 6-12, 2018 ; Suzdal - Moscow, Russia)
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    Anomalous spectral shift of o-modes in multilayer photonic structure induced by homeotropic–homeoplanar transition in chiral–nematic defect layer / V. A. Gunyakov, V. S. Sutormin, I. V. Timofeev [et al.] // Photonics. - 2023. - Vol. 10, Is. 9. - Ст. 959, DOI 10.3390/photonics10090959. - Cited References: 39 . - ISSN 2304-6732
   Перевод заглавия: Аномальный спектральный сдвиг о-мод в мультислойной фотонной структуре индуцированный переходом от гомеотропной к гомеопланарной конфигурации в хиральном нематическом дефектном слое
Кл.слова (ненормированные):
liquid crystal -- hybrid aligned cholesteric -- ionic surfactant -- multilayer photonic structure -- geometric phase
Аннотация: A chiral nematic is embedded between multilayer mirrors to obtain voltage-inducible polarized resonance spectra. Initially, the nematic director is uniformly oriented perpendicular to the mirrors’ surfaces because the chiral nematic helix is completely untwisted due to the homeotropic boundary conditions specified by the adsorbed cations. Then, a voltage is applied to remove the layer of surface-active cations from the input mirror. The obtained twisted homeoplanar configuration has a helix pitch exceeding the layer’s thickness. The twisting leads to the anomalous blue shift of the o-modes in the transmittance spectrum of the photonic structure. This blue shift can be effectively compensated by repulsion of spectral peaks as a result of mode coupling in the vicinity of the virtual avoided crossing point. The experimental results obtained are confirmed numerically using the 4 ˣ 4 transfer matrix method and explained with the contribution of a geometric phase.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Shabanov, V. F.; Шабанов, Василий Филиппович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
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Electrically induced anchoring transition in cholesteric liquid crystal cells with different confinement ratios / V. S. Sutormin [et al.] // Liq. Cryst. - 2018. - Vol. 45, Is. 8. - P. 1129-1136, DOI 10.1080/02678292.2017.1416504. - Cited References: 29. - This work was supported by Russian Foundation for Basic Research (RFBR) [grant number 16-53-00073]. Vitaly S. Sutormin acknowledges financial support from RFBR [grant number 16-32-60036]. . - ISSN 0267-8292
Кл.слова (ненормированные):
Cholesteric -- ionic surfactant -- anchoring transition -- modulated hybrid-aligned cholesteric layer -- diffraction grating
Аннотация: Reorientation of cholesteric liquid crystal induced by the electrically controlled ionic modification of surface anchoring within the cell with confinement ratio exceeding 1 has been studied. The change of homeotropic surface anchoring to the planar one on the electrode-anode substrate under the action of DC voltage causes the formation of the modulated hybrid-aligned cholesteric layer in the cell. Optical texture of the liquid crystal layer with such an orientation structure is the linear periodic stripes. Homogeneity of emerging optical texture depending on the confinement ratio as well as on the prehistory of voltage application has been considered. It has been found that the ionic modification of surface anchoring results in total transformation of the diffraction pattern observed after the laser beam passing through the sample.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center – Krasnoyarsk Scientific Center, Siberian Branch of Russian Academy of Sciences, Krasnoyarsk, Russia
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russia

Доп.точки доступа:
Sutormin, V. S.; Сутормин, Виталий Сергеевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
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Electrically induced anchoring transition in nematics with small or zero dielectric anisotropy / V. S. Sutormin [et al.] // Liq. Cryst. - 2017. - Vol. 44, Is. 3. - P. 577-581, DOI 10.1080/02678292.2016.1225840. - Cited References:23. - This work was supported by Russian Foundation for Basic Research under Grants [15-02-06924 and 16-53-00073] and by the Siberian Branch of Russian Academy of Sciences under Complex Program [II.2P 0358-2015-0010]. V.S.S. acknowledges financial support from Russian Foundation for Basic Research under Grants [16-32-60036 and 16-32-00164]. . - ISSN 0267-8292. - ISSN 1366-5855

РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science,
Рубрики:
LIQUID-CRYSTAL
   IONIC MODIFICATION
   ORIENTATION
   ALIGNMENT
   DROPLETS
Кл.слова (ненормированные):
Nematic -- ionic surfactant -- anchoring transition -- hybrid homeoplanar -- structure -- dielectric anisotropy -- electrooptics
Аннотация: The orientational transitions induced by electrically controlled ionic modification of surface anchoring in liquid crystal cells based on the nematics with small or zero dielectric anisotropy Δε are considered. The type of director reorientation is shown to be independent of the sign of dielectric anisotropy and can be the same for the nematics with both negative and positive Δε. Besides, the orientational transition and corresponding switchable optical states do not depend on the Δε value and can be effectively realised even for the nematics with zero dielectric anisotropy.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk, Russia.

Доп.точки доступа:
Sutormin, V. S.; Сутормин, Виталий Сергеевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Russian Foundation for Basic Research [15-02-06924, 16-53-00073, 16-32-60036, 16-32-00164]; Siberian Branch of Russian Academy of Sciences [II.2P 0358-2015-0010]
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Electrically-controlled anchoring transitions in nematics doped with ionic surfactant / V. Ya. Zyryanov [et al.] // 12th Eur. Conf. Liq. Cryst. (ECLC-2013). - 2013. - Ст. O.29

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Доп.точки доступа:
Zyryanov, V.Ya.; Зырянов, Виктор Яковлевич; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; European Conference on Liquid Crystals(12 ; 2013 ; Sept. ; 22-27)
}
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Krakhalev, M. N.
Electro-Optical Characteristics of Polymer-Dispersed Liquid Crystal Film Controlled by Ionic-Surfactant Method / M. N. Krakhalev, V. A. Loiko, V. Y. Zyryanov // Tech. Phys. Lett. - 2011. - Vol. 37, Is. 1. - P. 34-36, DOI 10.1134/S1063785011010056. - Cited References: 5. - This study was supported in part by Russian Federal Agencies (project nos. P901 and 02.740.11.0220), the Russian Foundation for Basic Research (project no. 08-03-01007), and the Siberian Branch of the Russian Academy of Sciences (project nos. 27.1, 110, and 144). . - ISSN 1063-7850

РУБ Physics, Applied

Аннотация: The electro-optical characteristics of a composite film based on a polymer containing dispersed nematic liquid crystal (NLC) doped with an ionic surfactant have been studied. The threshold character of the reorientation of NLC droplets as well as the dependence of the modulation amplitude of light transmission on the electric field strength has been revealed for the effect of ionic modification of surface anchoring. The dynamical parameters of the optical response have been determined.

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Держатели документа:
[Krakhalev, M. N.] Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Natl Acad Sci Belarus, BI Stepanov Phys Inst, Minsk 220072, Byelarus
ИФ СО РАН
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State Aerospace University, Krasnoyarsk, 660014, Russian Federation
Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk, 220072, Belarus

Доп.точки доступа:
Loiko, V. A.; Zyryanov, V. Y.; Зырянов, Виктор Яковлевич; Крахалев, Михаил Николаевич
}
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    Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant / V. A. Loiko, A. V. Konkolovich, A. A. Misckevich [et al.] // Liquid crystal polymer nanocomposites / ed.: P. M. Visakh [et al.] : Elsevier, 2022. - Chap. 7. - P. 163-211. - (Woodhead publishing in materials), DOI https://doi.org/10.1016/B978-0-12-822128-0.00006-6. - References: 86 . - ISBN 978-0-12-822128-0
   Перевод заглавия: Электро-оптический отклик монослоя нематического жидкого кристалла, допированного сурфактантом, диспергированного в полимере
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.

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Доп.точки доступа:
Visakh, P. M. \ed.\; Semkin, Artem \ed.\; Özdemir, Zeynep Güven \ed.\; Loiko, V. A.; Konkolovich, A. V.; Misckevich, A. A.; Мискевич А. А.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
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Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant / V. A. Loiko, A. V. Konkolovich, A. A. Miskevich [et al.] // Liquid Crystal Polymer Nanocomposites : Woodhead Publishing, 2022. - Chapter 7. - P. 163-211, DOI 10.1016/B978-0-12-822128-0.00006-6. - Cited References: 86
Кл.слова (ненормированные):
Polymer dispersed liquid crystal film -- Liquid crystal droplet -- Transmission -- Angular distribution of scattered light -- Quenching effect -- Symmetry breaking effect -- Photonic band gap
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.

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Держатели документа:
Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk, Belarus
Kirensky Institute of Physics, Federal Research Center-Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russian Federation
Military Academy of the Republic of Belarus, Belarus

Доп.точки доступа:
Loiko, V. A.; Konkolovich, A. V.; Miskevich, A. A.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
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Inverse mode of ion-surfactant method of director reorientation inside nematic droplets / M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P. 1998-2003, DOI 10.1080/15421400903050814. - Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation. - Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation . - ISSN 1542-1406
Кл.слова (ненормированные):
electrically commanded surfaces -- ion surfactant -- nematic -- polymer dispersed liquid crystals -- surface anchoring -- Electrically commanded surfaces -- Ion surfactant -- Nematic -- Polymer dispersed liquid crystals -- Surface anchoring -- Applied voltages -- Crossed polarizers -- Director fields -- Director reorientation -- Droplet structure -- Electrically commanded surfaces -- High concentration -- Homeotropic -- Initial state -- Ionic modification -- Liquid-crystal droplets -- Nematic droplets -- Nematic polymer -- Surface-active cations -- Surface-anchoring -- Trimethyl -- Ammonium compounds -- Cationic surfactants -- Crystals -- Drop formation -- Dyes -- Ionization of liquids -- Ions -- Liquid crystal displays -- Liquid crystals -- Liquids -- Nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk, Russia

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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10.

Inverse mode of ionic-surfactant method of director reorientation inside nematic droplets / Krakhalev M.N., Prishchepa O.O., Shabanov A.V., Zyryanov V.Ya. // 22nd International LC Conference : Abstracts. - 2008. - Vol. 1. - P. 380

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; IInternational LC Conference(22 ; 2008 ; Jeju, Korea)
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