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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Sutormin V. S., Prishchepa O. O., Kuz'menok N. M., Mikhalyonok S. G., Bezborodov V. S., Zyryanov V. Ya.
Заглавие : Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals
Коллективы : International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018 , Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]
Место публикации : J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P.57-62. - ISSN 0167-7322, DOI 10.1016/j.molliq.2019.02.132. - ISSN 1873-3166(eISSN)
Примечания : Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
TRANSITION
DROPLETS
CONFIGURATION
LAYER
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gunyakov V. A., Sutormin V. S., Timofeev I. V., Shabanov V. F., Zyryanov V. Ya.
Заглавие : Anomalous spectral shift of o-modes in multilayer photonic structure induced by homeotropic–homeoplanar transition in chiral–nematic defect layer
Колич.характеристики :11 с
Место публикации : Photonics. - 2023. - Vol. 10, Is. 9. - Ст.959. - ISSN 23046732 (eISSN), DOI 10.3390/photonics10090959
Примечания : Cited References: 39
Аннотация: A chiral nematic is embedded between multilayer mirrors to obtain voltage-inducible polarized resonance spectra. Initially, the nematic director is uniformly oriented perpendicular to the mirrors’ surfaces because the chiral nematic helix is completely untwisted due to the homeotropic boundary conditions specified by the adsorbed cations. Then, a voltage is applied to remove the layer of surface-active cations from the input mirror. The obtained twisted homeoplanar configuration has a helix pitch exceeding the layer’s thickness. The twisting leads to the anomalous blue shift of the o-modes in the transmittance spectrum of the photonic structure. This blue shift can be effectively compensated by repulsion of spectral peaks as a result of mode coupling in the vicinity of the virtual avoided crossing point. The experimental results obtained are confirmed numerically using the 4 ˣ 4 transfer matrix method and explained with the contribution of a geometric phase.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sutormin V. S., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Electrically induced anchoring transition in cholesteric liquid crystal cells with different confinement ratios
Место публикации : Liq. Cryst. - 2018. - Vol. 45, Is. 8. - P.1129-1136. - ISSN 02678292 (ISSN), DOI 10.1080/02678292.2017.1416504
Примечания : Cited References: 29. - This work was supported by Russian Foundation for Basic Research (RFBR) [grant number 16-53-00073]. Vitaly S. Sutormin acknowledges financial support from RFBR [grant number 16-32-60036].
Ключевые слова (''Своб.индексиров.''): cholesteric--ionic surfactant--anchoring transition--modulated hybrid-aligned cholesteric layer--diffraction grating
Аннотация: Reorientation of cholesteric liquid crystal induced by the electrically controlled ionic modification of surface anchoring within the cell with confinement ratio exceeding 1 has been studied. The change of homeotropic surface anchoring to the planar one on the electrode-anode substrate under the action of DC voltage causes the formation of the modulated hybrid-aligned cholesteric layer in the cell. Optical texture of the liquid crystal layer with such an orientation structure is the linear periodic stripes. Homogeneity of emerging optical texture depending on the confinement ratio as well as on the prehistory of voltage application has been considered. It has been found that the ionic modification of surface anchoring results in total transformation of the diffraction pattern observed after the laser beam passing through the sample.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sutormin V. S., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Electrically induced anchoring transition in nematics with small or zero dielectric anisotropy
Коллективы : Russian Foundation for Basic Research [15-02-06924, 16-53-00073, 16-32-60036, 16-32-00164]; Siberian Branch of Russian Academy of Sciences [II.2P 0358-2015-0010]
Место публикации : Liq. Cryst.: Taylor & Francis, 2017. - Vol. 44, Is. 3. - P.577-581. - ISSN 0267-8292, DOI 10.1080/02678292.2016.1225840. - ISSN 1366-5855(eISSN)
Примечания : Cited References:23. - This work was supported by Russian Foundation for Basic Research under Grants [15-02-06924 and 16-53-00073] and by the Siberian Branch of Russian Academy of Sciences under Complex Program [II.2P 0358-2015-0010]. V.S.S. acknowledges financial support from Russian Foundation for Basic Research under Grants [16-32-60036 and 16-32-00164].
Предметные рубрики: LIQUID-CRYSTAL
IONIC MODIFICATION
ORIENTATION
ALIGNMENT
DROPLETS
Ключевые слова (''Своб.индексиров.''): nematic--ionic surfactant--anchoring transition--hybrid homeoplanar--structure--dielectric anisotropy--electrooptics
Аннотация: The orientational transitions induced by electrically controlled ionic modification of surface anchoring in liquid crystal cells based on the nematics with small or zero dielectric anisotropy Δε are considered. The type of director reorientation is shown to be independent of the sign of dielectric anisotropy and can be the same for the nematics with both negative and positive Δε. Besides, the orientational transition and corresponding switchable optical states do not depend on the Δε value and can be effectively realised even for the nematics with zero dielectric anisotropy.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zyryanov V.Ya., Sutormin V. S., Krakhalev M. N., Prishchepa O. O.
Заглавие : Electrically-controlled anchoring transitions in nematics doped with ionic surfactant
Коллективы : European Conference on Liquid Crystals
Место публикации : 12th Eur. Conf. Liq. Cryst. (ECLC-2013). - 2013. - Ст.O.29
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Loiko V. A., Zyryanov V. Y.
Заглавие : Electro-Optical Characteristics of Polymer-Dispersed Liquid Crystal Film Controlled by Ionic-Surfactant Method
Разночтения заглавия :авие SCOPUS: Electro-optical characteristics of polymer-dispersed liquid crystal film controlled by ionic-surfactant method
Место публикации : Tech. Phys. Lett.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 37, Is. 1. - P34-36. - ISSN 1063-7850, DOI 10.1134/S1063785011010056
Примечания : Cited References: 5. - This study was supported in part by Russian Federal Agencies (project nos. P901 and 02.740.11.0220), the Russian Foundation for Basic Research (project no. 08-03-01007), and the Siberian Branch of the Russian Academy of Sciences (project nos. 27.1, 110, and 144).
Аннотация: The electro-optical characteristics of a composite film based on a polymer containing dispersed nematic liquid crystal (NLC) doped with an ionic surfactant have been studied. The threshold character of the reorientation of NLC droplets as well as the dependence of the modulation amplitude of light transmission on the electric field strength has been revealed for the effect of ionic modification of surface anchoring. The dynamical parameters of the optical response have been determined.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Misckevich A. A., Krakhalev M. N., Prishchepa O. O., Shabanov A. V., Zyryanov V. Ya.
Заглавие : Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant
Место публикации : Liquid crystal polymer nanocomposites/ ed.: P. M. Visakh [et al.]: Elsevier, 2022. - Chap. 7. - P.163-211. - (Woodhead publishing in materials). - ISBN 978-0-12-822128-0, DOI https://doi.org/10.1016/B978-0-12-822128-0.00006-6
Примечания : References: 86
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.
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Вид документа : Однотомное издание
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Krakhalev M. N., Prishchepa O. O., Shabanov A. V., Zyryanov V. Ya.
Заглавие : Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant
Место публикации : Liquid Crystal Polymer Nanocomposites: Woodhead Publishing, 2022. - Chapter 7. - P.163-211. - , DOI 10.1016/B978-0-12-822128-0.00006-6
Примечания : Cited References: 86
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Inverse mode of ion-surfactant method of director reorientation inside nematic droplets
Место публикации : Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P.1998-2003. - ISSN 1542-1406, DOI 10.1080/15421400903050814
Примечания : Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation.Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation
Ключевые слова (''Своб.индексиров.''): electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--applied voltages--crossed polarizers--director fields--director reorientation--droplet structure--electrically commanded surfaces--high concentration--homeotropic--initial state--ionic modification--liquid-crystal droplets--nematic droplets--nematic polymer--surface-active cations--surface-anchoring--trimethyl--ammonium compounds--cationic surfactants--crystals--drop formation--dyes--ionization of liquids--ions--liquid crystal displays--liquid crystals--liquids--nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Shabanov A. V., Zyryanov V. Ya.
Заглавие : Inverse mode of ionic-surfactant method of director reorientation inside nematic droplets
Коллективы : IInternational LC Conference
Место публикации : 22nd International LC Conference: Abstracts. - 2008. - Vol. 1. - P.380
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