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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Epov M. I., Mironov V. L., Muzalevskiy K. V., Eltsov I. N., Salomatov U. P.
Заглавие : A geosteering tool for horizontal well logging
Место публикации : Rus. Geol. Geophys. - 2013. - Vol. 54, Is. 9. - P.1103-1107. - ISSN 1068-7971, DOI 10.1016/j.rgg.2013.07.022
Ключевые слова (''Своб.индексиров.''): downhole radar--geosteering--oil-water contact--saturated formation--ultrabroadband nanosecond electromagnetic pulse
Аннотация: A theoretical study has been performed to check the possibility of using ultrabroadband nanosecond electromagnetic pulses as a geosteering tool for horizontal drilling to estimate the distance to the oil-water contact (OWC) in a floating oil accumulation. The voltage of a microwave-bandwidth pulse at the dipole receiver of a downhole radar was modeled for the case of a horizontal borehole near OWC in a formation saturated with oil and water. Numerical solutions to the boundary problem formulated on the basis of the Maxwell equations were obtained with the Microwave Studio software (www.cst.com). The frequency-dependent dielectric constants of the layered saturated formation and the drilling fluid were assumed according to experimentally tested models. The modeling has demonstrated that nanosecond electromagnetic pulses arriving from a layered oil-water contact can in principle be acquired and the distance from the wellbore to the OWC median can be inferred from the respective time delays recorded by a downhole radar. Additionally, the possible dynamic range and accuracy of sensing have been estimated. В© 2013.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Epov M. I., Savin I. V., Mironov V. L.
Заглавие : A temperature-dependent dielectric model for water- and oil-containing rocks in the frequency range from 0.5 to 15 GHz
Место публикации : Russ. Geol. Geophys.: Elsevier Science BV, 2012. - Vol. 53, Is. 7. - P.698-703. - ISSN 1068-7971, DOI 10.1016/j.rgg.2012.05.008
Примечания : Cited References: 17
Предметные рубрики: MOIST SOILS
POLARIZATION PROCESSES
PERMITTIVITY METHOD
Ключевые слова (''Своб.индексиров.''): dielectric permittivity--effective conductivity--water-containing rocks--temperature-dependent dielectric model
Аннотация: Dielectric spectra of water-containing rocks forming a mineral framework of the oil-saturated bed (clay minerals amount to˂16%) were measured in the frequency range from 500 MHz to 15 GHz and in the temperature range from 20 to 80 °C. A physical model for computing spectra of the dielectric permittivity and effective conductivity of the studied rocks has been elaborated. Its input parameters are water (salt solution) content and temperature. The errors of the computed spectra relative to the measured ones are estimated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Lin, Chun-Rong, Edelman I. S., Svetlitsky E. S., Sokolov A. Е., Zharkov S. M., Sukhachev A. L., Vorobyev S. A., Petrov D. A., Lin, En-Szu
Заглавие : Adsorption properties and catalytic activity of Fe3O4-Ag nanostructures
Колич.характеристики :12 с
Место публикации : Appl. Surf. Sci. - 2024. - Vol. 665. - Ст.160236. - ISSN 01694332 (ISSN), DOI 10.1016/j.apsusc.2024.160236. - ISSN 18735584 (eISSN)
Примечания : Cited References: 48. - The work is supported by the Russian Science Foundation (project no. 23-22-10025, https://rscf.ru/project/ 23-22-10025/) and by the Krasnoyarsk Regional Fund of Science and Technology Support. The electron microscopy and EDS investigations were conducted in the SFU Joint Scientific Center. Magnetic investigations were carried out in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: The morphology and magnetic properties as well as adsorption capacity and catalytic activity of Fe3O4-Ag nanoparticles synthesized by the solvothermal method were studied in dependence on the duration of the thermolysis process (3, 6, and 8 h). X-ray diffraction, transmission electron microscopy, and energy-dispersive spectroscopy measurements showed that the morphology of nanoparticles changed strongly as the duration of thermolysis increased. At 6 and 8 h duration, Fe3O4 nanocrystals grow and assemble into porous spherical globules with an Ag core (samples 2 and 3). These samples demonstrate high magnetization value and very low coercivity. The adsorption capacity of nanoparticles was studied with respect to two organic dyes: cationic methylene blue (MB) and anionic Congo red (CR). The particles showed preferential adsorption of the cationic dye. High catalytic activity towards four dyes: MB, methyl orange (MO), CR, and Rhodamine C (RhC) at the presence of NaBH4 is the remarkable property of these samples. The rate constant of the catalytic reaction was 1.4 min−1. Simultaneous exposure of CR and MO dyes to nanoparticles and NaBH4 caused their irreversible 100 % degradation while in the case of MB and RhC, a transition to their leuco form occurred.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lin C. -R., Ivanova O. S., Petrov D. A., Sokolov A. Е., Chen Y. -Z., Gerasimova M. A., Zharkov S. M., Tseng Y. -T., Shestakov N. P., Edelman I. S.
Заглавие : Amino-functionalized Fe3O4@SiO2 core-shell magnetic nanoparticles for dye adsorption
Место публикации : Nanomaterials. - 2021. - Vol. 11, Is. 9. - Ст.2371. - ISSN 20794991 (ISSN), DOI 10.3390/nano11092371
Примечания : Cited References: 35. - The authors are thankful for the financial support the Russian Foundation for Basic Research, Grant № 19-52-52002, Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3 and № 109-2112-M-153-003-, the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project number 19-42-240005: “Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe”. We thank also the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out
Аннотация: Fe3O4@SiO2 core-shell nanoparticles (NPs) were synthesized with the co-precipitation method and functionalized with NH2 amino-groups. The nanoparticles were characterized by X-ray, FT-IR spectroscopy, transmission electron microscopy, selected area electron diffraction, and vibrating sample magnetometry. The magnetic core of all the nanoparticles was shown to be nanocrystalline with the crystal parameters corresponding only to the Fe3O4 phase covered with a homogeneous amorphous silica (SiO2) shell of about 6 nm in thickness. The FT-IR spectra confirmed the appearance of chemical bonds at amino functionalization. The magnetic measurements revealed unusually high saturation magnetization of the initial Fe3O4 nanoparticles, which was presumably associated with the deviations in the Fe ion distribution between the tetrahedral and octahedral positions in the nanocrystals as compared to the bulk stoichiometric magnetite. The fluorescent spectrum of eosin Y-doped NPs dispersed in water solution was obtained and a red shift and line broadening (in comparison with the dye molecules being free in water) were revealed and explained. Most attention was paid to the adsorption properties of the nanoparticles with respect to three dyes: methylene blue, Congo red, and eosin Y. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for all three dyes. The equilibrium data were more compatible with the Langmuir isotherm and the maximum adsorption capacity was reached for Congo red.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bolobanschikova G. N., Rogozin D. Y., Firsova A. D., Rodionova, E. V., Degermendzhy N. N., Shabanov A. V.
Заглавие : Analysis of diatom algae from the water column and bottom sediments of Shira Lake (Khakassia, Russia)
Место публикации : Contemp. Probl. Ecol.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 8, Is. 2. - P.173-185. - ISSN 1995, DOI 10.1134/S1995425515020031. - ISSN 19954263(eISSN)
Примечания : Cited References: 23. - This work was supported by Russian Foundation for Basic Research, project no. 13-05-00429-a and the Biodiversity Program for Basic Research, Russian Academy of Sciences, project no. 30.8.
Ключевые слова (''Своб.индексиров.''): paleolimnology--diatom algae--meromictic lake--sedimentation--cyclotella choctawhatcheeana--aulacoseira valida--aulacoseira ambigua
Аннотация: Lake Shira as a meromictic lake is object of interest for paleolimnological studies. In May 2011 core samples were collected from the bottom of Lake Shira and the species composition of diatom algae, which serve as bioindicators of the state of the lake, were studied. In addition, in 2012, seasonal water samples and material from sediment traps were collected and the species composition of diatoms in them was analyzed. The results of the analysis showed that the lake, like in previous years of research, was dominated by Cyclotella choctawhatcheeana Prasad. Diatoms were found twice in the studied core above the white carbonate layers and were absent in other layers. The species living in the lake at present were observed down to the first white carbonate layer, including the predominant Cyclotella choctawhatcheeana. This fact presumably proves the consistency of the species composition of diatoms and the overall stable condition of the lake since 1946 (Rogozin et al., 2005). Down to the second white carbonate layer, the dominant species were Aulcosira valida (Grunow) Krammer and Aulcosira italica (Grunow) Simonsen. Nitzchia sigmodea (Nitzsch) W. Smith and Fragilaria construens var. venter (Ehrenberg) Grunow were also observed at these depths, dating approximately to 1655-1690. These are freshwater species that belong to the diatoms of arctic, alpine, and temperate latitudes, which develop in shallow waters under moderate temperature conditions. This fact suggests that Lake Shira was less salty in the middle and end of the 17th century than today.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kovrov B. G., Terskov I. A., Gitelzon I. I., Lisovsky H. M., Pan'kova I. M., Trubachev I. N., Shilenko M. P., Alekseev S. S., Tirranen L. S., Sidko F. Ya., Okladnikov Yu. N.
Заглавие : Artificial closed ecosystem "man-plants" with a full regeneration of atmosphere, water and ration vegetable part
Коллективы : International Astronautical Congress, Международный конгресс по астронавтике
Место публикации : 36th International Astronautical Congress: proceedings. - 1985. - Ст.IAF-85-308
Примечания : Bibliogr. at the end of the art.
Аннотация: In the present paper a description of the flow field in the base region of booster stages with clustered rocket engines is given. A flow model is derived from the bulk of available laboratory test an free flight measurements. Jet impingent theory is used for the determination of the convective heat transfer caused by the reverse flow. A comparison of the results of the present method with experimental data is followed by a discussion of its applicability and possible extension.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov S. V., Krylov A. S., Vtyurin A. N., Pan Y.
Заглавие : Behavior of CaBSiO4(OH) datolite at high temperatures and pressures of a water medium
Место публикации : Bull. Russ. Acad. Sci. Phys.: Allerton Press, 2015. - Vol. 79, Is. 6. - P.794-797. - ISSN 1062-8738, DOI 10.3103/S1062873815060118
Примечания : Cited References: 9. - This work was supported by the Russian Foundation for Basic Research, project nos. 13-05-00185 and 4-05-00616.
Предметные рубрики: Constant pressures
Constant temperature
High temperature
Polymorphic transitions
T parameter
Tectonic plates
Water mediums
Silicate minerals
Аннотация: The behavior of CaBSiO4(OH) datolite compressed in a water medium at simultaneous high temperatures and pressures corresponding to the cold zones of tectonic plate subduction (up to P ~5.3 GPa and T ~250°C) is studied in situ via Raman spectroscopy. Two polymorphic transitions are found: (i) upon an increase of up to 2 GPa in pressure at a constant temperature of 22°C and (ii) upon heating to ~90°C at a constant pressure of ~5–5.3 GPa. Major trends of the variations in the Raman spectra are identified for all phases of the indicated P–T parameters. No overhydration and amorphization of datolite is observed. © 2015, Allerton Press, Inc.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov S. V., Krylov A. S., Vtyurin A. N.
Заглавие : Behavior of natrolite zeolite and fluorapatite at high pressures in a water medium
Место публикации : Bull. Russ. Acad. Sci.: Phys. - 2013. - Vol. 77, Is. 3. - P.313-316. - DOI 10.3103/S106287381303012X
Аннотация: The hysteresises (~0.3–0.4 GPa) of two transitions in natrolite at 0.9 and 1.45 GPa, considerable changes in the Raman spectra, and the appearance of very intense low–frequency mode at 75 cm–1 in the overhydrated phase of high pressure of water medium up to 6.2 GPa are observed for the first time. The depen dences of the band frequencies of this phase are nonlinear, due clearly to changes in the positions of H2 O in the channels. According to Raman data, fluorapatite placed together with natrolite in a water medium in a diamond anvil cell exhibits no transitions up to 6.2 GPa and displays linear pressure dependences of the band frequencies.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gitelzon I. I., Filimonov V. S., Musonov V. M.
Заглавие : Bioluminescent glow of surface-water layer of the Central Arctic in spring
Место публикации : Doklady Akademii Nauk. - 1981. - Vol. 256, Is. 3. - P.723-726. - ISSN 0002-3264
Примечания : Cited References: 7
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N., Molokeev M. S.
Заглавие : Bridging behaviour of the 2-thiobarbiturate anion in its complexes with LiI and NaI
Место публикации : Acta Crystallographica Section C Crystal Structure Communications. - 2013. - Vol. 69, Pt. 7. - P.704-708. - ISSN 0108-2701, DOI 10.1107/S0108270113014078
Ключевые слова (''Своб.индексиров.''): 2-thiobarbituric acid--coordinated water--dihydrates--edge sharing--hydrogen bonding interactions--three-dimensional networks--atoms--complex networks--hydrogen bonds--ligands--negative ions--positive ions--three dimensional--lithium
Аннотация: The structures of the LiI and NaI salts of 2-thiobarbituric acid (2-sulfanylidene-1-3-diazinane-4,6-dione, H 2TBA) have been studied. μ-Aqua-octaaquabis(μ-2- thiobarbiturato-κ2 O:O′)bis(2-thiobarbiturato-κO) tetralithium(I) dihydrate, [Li4(C4H3N 2O2S)4(H2O)9]·2H 2O, (I), crystallizes with four symmetry-independent four-coordinated LiI cations and four independent HTBA- anions. The structure contains two structurally non-equivalent LiI cations and two non-equivalent HTBA- anions (bridging and terminal). Eight of the coordinated water ligands are terminal and the ninth acts as a bridge between LiI cations. Discrete [Li4(HTBA)4(H2O)9] ·2H2O complexes form two-dimensional layers. Neighbouring layers are connected via hydrogen-bonding interactions, resulting in a three-dimensional network. Poly[μ2-aqua-tetraaqua(μ4-2- thiobarbiturato-κ4 O:O:S:S)(μ2-thiobarbiturato- κ2 O:S)disodium(I)], [Na2(C4H 3N2O2S)2(H2O) 5] n , (II), crystallizes with six-coordinated NaI cations. The octahedra are pairwise connected through edge-sharing by a water O atom and an O atom from the μ4-HTBA- ligand, and these pairs are further top-shared by the S atoms to form continuous chains along the a direction. Two independent HTBA- ligands integrate the chains to give a three-dimensional network. © 2013 International Union of Crystallography.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pyatnov M. V., Bikbaev R. G., Timofeev I. V., Ryzhkov I. I., Vetrov S. Ya., Shabanov V. F.
Заглавие : Broadband Tamm plasmons in chirped photonic crystals for light-induced water splitting
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 6. - Ст.928. - ISSN 20794991 (ISSN), DOI 10.3390/nano12060928
Примечания : Cited References: 41
Аннотация: An electrode of a light-induced cell for water splitting based on a broadband Tamm plasmon polariton localized at the interface between a thin TiN layer and a chirped photonic crystal has been developed. To facilitate the injection of hot electrons from the metal layer by decreasing the Schottky barrier, a thin n-Si film is embedded between the metal layer and multilayer mirror. The chipping of a multilayer mirror provides a large band gap and, as a result, leads to an increase in the integral absorption from 52 to 60 percent in the wavelength range from 700 to 1400 nm. It was shown that the photoresponsivity of the device is 32.1 mA/W, and solar to hydrogen efficiency is 3.95%.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Svetlichnyi V. A., Shabalina A. V., Lapin I. N., Goncharova D. A., Velikanov D. A., Sokolov A. Е.
Заглавие : Characterization and magnetic properties study for magnetite nanoparticles obtained by pulsed laser ablation in water
Место публикации : Appl. Phys. A. - 2017. - Vol. 123, Is. 12. - Ст.763. - ISSN 09478396 (ISSN), DOI 10.1007/s00339-017-1390-7
Примечания : Cited References: 40. - This work was conducted as a government task of the Ministry of Education and Science of the Russian Federation, Project Number 3.9604.2017/8.9.
Ключевые слова (''Своб.индексиров.''): magnetite--pulsed laser ablation--nanoparticles--dispersion
Аннотация: Magnetite (Fe3O4) nanoparticles of 1–10 nm (with the maximum at 2 nm) were obtained via pulsed laser ablation of iron target in water in form of a stable dispersion without addition of surfactants and stabilizers. The structure of the material obtained was investigated using transmission electron microscopy, scanning electron microscopy, and Brunauer–Emmett–Teller methods. To investigate the composition of the particles in the sample, such methods as Fourier transform infrared spectroscopy, Raman spectroscopy, differential scanning calorimetry, and X-ray diffraction, were applied. Magnetite phase was found to be sufficiently pure, it was not contaminated by other iron oxide phases and contained not more than 0.5% of metallic iron in form of large particles. The study of the magnetic properties of the magnetite nanoparticles obtained has shown that they exhibit ferrimagnetic behavior at room temperature with the paramagnetic contribution explained by the presence of fine superparamagnetic particles.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anghel L., Balasoiu M., Ishchenko L. A., Stolyar S. V., Kurkin T. S., Rogachev A. V., Kuklin A. I., Kovalev Yu.S., Raikher Yu.L., Iskhakov R. S., Duca G.
Заглавие : Characterization of bio-synthesized nanoparticles produced by Klebsiella oxytoca
Коллективы : International Workshop on SANS-YuMO User Meeting at the Start-up of Scientific Experiments on the IBR-2M Reactor: Devoted to the 75th Anniversary of Yu M Ostanevich's Birth
Место публикации : Journal of Physics: Conference Series. - 2012. - Vol. 351, Is. 1. - Ст.012005. - P. - ISSN 1742-6588, DOI 10.1088/1742-6596/351/1/012005
Ключевые слова (''Своб.индексиров.''): absorption peaks--biominerals--chemical compositions--exopolysaccharides--ferrihydrites--fitting procedure--ftir spectroscopy--klebsiella oxytoca--model calculations--morphological analysis--radius of gyration--scattering objects--small angle x-ray scattering--structural and morphological properties--structural investigation--uv-vis spectroscopy--water dispersion--water-dispersed--experiments--nanoparticles--polysaccharides--raman spectroscopy--scattering--ultraviolet visible spectroscopy--synthesis (chemical)
Аннотация: Structural and morphological properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. The stability of water dispersions of biomineral particles produced by Klebsiella oxytoca was monitored by UV-Vis spectroscopy. Their chemical composition was determined by FT-IR spectroscopy. The vibrational spectra of biogenic ferrihydrite nanoparticles revealed typical absorption peaks of exopolysaccharides. Morphological analysis based on Raman spectroscopy indicated the presence of exopolysaccharides on the surface as well as inside the pores of the ferrihydrite nanoparticles. Structural investigations of ultrasonic assisted samples of different concentration of water dispersed particles were performed using small angle X-ray scattering analysis. Model calculations and fitting procedures revealed scattering objects of an elongated shape with 6.73В±0.16 nm radius of gyration. В© Published under licence by IOP Publishing Ltd.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zos’ko, Nikolay A., Aleksandrovsky A. S., Kenova, Tatyana, Gerasimova, Marina A., Maksimov, Nikolay G., Taran, Oxana P.
Заглавие : Cyclic voltammetry as an activation method of TiO2 nanotube arrays for improvement of photoelectrochemical water splitting performance
Колич.характеристики :11 с
Место публикации : ChemPhotoChem. - 2023. - Vol. 7, Is. 9. - Ст.e202300100. - ISSN 23670932 (eISSN), DOI 10.1002/cptc.202300100
Примечания : Cited References: 36. - The authors express their gratitude to A. M. Zhizhaev for the microscopy and XRD analysis and V. F. Shabanov for the fruitful discussionThis work was conducted within the framework of the budget project FWES-2021-0023 for Institute of Chemistry and Chemical Technology SB RAS using the equipment of Krasnoyarsk Regional Research Equipment Centre of SB RAS
Аннотация: A facile and eco-friendly method for activating anodic TiO2 nanotubes (TNTs) by cyclic voltammetry (CV) is proposed, and photoelectrochemical properties of CV-activated TNTs are compared with those of non-activated TNTs and of TNTs activated by hydrogen-thermal reduction. EPR and luminescence studies show that the pristine samples demonstrate rather large content of paramagnetic and luminescing defects, while hydrogenation and CV-activation lead to the different type of rearrangement of defects. TNTs activated by CV-Na2SO4 demonstrate significantly improved photocurrent density (2.25 mA cm-2) in comparison with that of the hydrogen treated and pristine ones (0.93 mA cm-2 and 0.31 mA cm-2) under NUV-irradiation at 0.2 V (RHE). Enhanced photoactivity of Na2SO4-activated TNTs correlates with higher luminescence quantum yield, lowest paramagnetic defects content and larger decay time of the luminescence. Thus, a decrease in the content of defects is an important factor that reduces the non-radiative recombination of charge carriers. The activation-induced redistribution of surface and bulk defects in nanotubes explains the increased photoelectrochemical activity of TiO2-based anodes. Cyclic voltammetry has been proved to be a reliable method to increase the efficiency of TNTs in PEC water splitting.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mironov V. L., Bobrov P. P., Fomin S. V.
Заглавие : Dielectric model of moist soils with varying clay content in the 0.04 to 26.5 GHz frequency range
Коллективы : International Siberian Conference on Control and Communications
Место публикации : Int. Sib. Conf. on Control and Communicat.: Proc. - 2013. - Ст.6693613. - ISSN 978-1-4799-1060-1, DOI 10.1109/SIBCON.2013.6693613. - ISSN 978-14799-1062-5
Примечания : This work was supported by the Program of the Siberian Branch of the Russian Academy of Sciences, 2013-2016. Project II.12.1.1. - Загл. с этикетки диска
Ключевые слова (''Своб.индексиров.''): moist soil--dielectric model--dielectric spectra--dielectric relaxations--bound soil water--free soil water
Аннотация: In this paper, a soil texture dependent multirelaxation generalized refractive mixing dielectric model (MR GRMDM) for moist soils was developed. The model provides for complex permittivity of moist soils in both the gigahertz and megahertz frequency ranges, namely, from 40 MHz to 26.5 GHz.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bobrov P. P., Mironov V. L., Repin A. V.
Заглавие : Dielectric permittivity spectra of oil-water-saturated sandy-clayey rocks of different mineralogical compositions and relaxation properties of water in these rocks
Коллективы : RFBR [12-05-00502a, 14-05-00151a]
Место публикации : Russ. Geol. Geophys.: Elsevier Science, 2015. - Vol. 56, Is. 7. - P.1065-1073. - ISSN 1068-7971, DOI 10.1016/j.rgg.2015.06.007
Примечания : Cited References: 21. - This work was supported by RFBR (grant nos. 12-05-00502a and 14-05-00151a).
Предметные рубрики: MOIST SOILS
FREQUENCY
MODEL
TEMPERATURE
SALINITY
RANGE
GHZ
Ключевые слова (''Своб.индексиров.''): conductivity--dielectric permittivity--multifrequency dielectric relaxation--oil-bearing deposits--sandy-clayey rocks
Аннотация: Experimental measurements of the dielectric permittivity and equivalent conductivity of sandy-clayey samples (a mixture of river sand with bentonite or kaolin) saturated with salt-solution-diesel-fuel emulsions were performed in the frequency range from 10 kHz to 1 GHz at temperatures of 25-65 °C. It is shown that when the content of the salt solution in the saturating fluid does not exceed 10%, the dielectric permittivity in the frequency range from 1 MHz to 1 GHz depends little on the mineral composition of the sample and on the concentration of the saturating solution. When the portion of water is 33.3% or higher, increasing the concentration of the salt solution leads to an increase in the equivalent conductivity and the real part of the complex dielectric permittivity. Using the refractive model of the complex dielectric permittivity, we have estimated the dielectric properties of bound water, which depend on temperature and the type of clay (bentonite or kaolin) in the sand-clay mixture but are independent of the water saturation and the amount of clay in the sample.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Yu. V., Krylov A. S., Vtyurin A. N., Laptash N. M., Pogoreltsev E. I., Dubrovskiy A. A., Gerasimov M. A.
Заглавие : Dynamic processes of the water sublattice in FeTiF6·xH2O·yD2O crystal
Место публикации : J. Raman Spectrosc. - 2022. - Vol. 53, Is. 10: Special Issue: Vibrational Spectroscopy of Water. - P.1704-1709. - ISSN 03770486 (ISSN), DOI 10.1002/jrs.6430
Примечания : Cited References: 31. - The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory and Krasnoyarsk Regional Foundation of Science according to the research project “Spectral and magnetic properties of single crystals of transition metal fluoride hexahydrates” No. 20-42-240014
Аннотация: Phase transition in FeTiF6·xH2O·yD2O crystals has been studied by Raman spectroscopy. The 611 cm-1 line corresponding to mode A1g of [TiF6]2- system does not exhibit anomalous behavior associated with the phase transition. The temperature studies showed that below the phase transition temperature, the equivalence of D2O molecules in FeTiF6·xH2O·yD2O octahedron is broken. The phase transition mechanism in the compound under study is associated with Fe(xH2O·yD2O) complex.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov, Sergey, V, Krylova S. N., Borodina, Ulyana O., Krylov A. S.
Заглавие : Dynamical immiscibility of aqueous carbonate fluid in the shortite-water system at high-pressure-temperature conditions
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); DFGGerman Research Foundation (DFG)European Commission [21-52-12018]; Ministry of Science and Higher EducationMinistry of Science and Higher Education, PolandEuropean Commission
Место публикации : J. Phys. Chem. C. - 2021. - Vol. 125, Is. 33. - P.18501-18509. - ISSN 1932-7447, DOI 10.1021/acs.jpcc.1c05077. - ISSN 1932-7455(eISSN)
Примечания : Cited References: 47. - The reported study was funded by the RFBR and DFG, project number 21-52-12018. Work is done on the state assignment of the Sobolev Institute of Geology and Mineralogy, Kirensky Institute of Physics SB RAS, Equipment of Federal Research Center of Krasnoyarsk Science Center SB RAS, and supported by the Ministry of Science and Higher Education. Authors thank A.N. Vtyurin, A.G. Sokol, A.Yu. Likhacheva, and A.F. Shatskiy for fruitful discussion
Предметные рубрики: SIMULTANEOUSLY HIGH-PRESSURE
SODIUM FORMATE
RAMAN-SPECTRA
Аннотация: Anhydrous carbonate shortite, Na2Ca2(CO3)3, compressed in water at high pressure–temperature (up to 5 GPa, 350 °C) was studied by Raman spectroscopy. At 3.2 GPa and 250 °C, shortite begins to dissolve, followed by crystallization of aragonite and aragonite’. The unusual behavior of aqueous carbonate fluid was observed at 4.8 GPa and 300–350 °C. This process is characterized by the active formation of microbubbles within 2–60 s that are inserted one into another. Microbubbles are considered to be a result of the two immiscible fluid stratification. This dynamical immiscibility of the fluid accompanies the appearance of several crystalline carbonates and organic molecular crystals. Na-formate and some polymorphs of Ca-formate were observed.
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19.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Stebeleva O. P., Kashkina L. V., Rubleva T. V., Dobrosmyslov S. S., Vshivkova O. A.
Заглавие : Effect of cavitational conditioning of water on stability of coal-water slurry
Коллективы : International Scientific Conference on Applied Physics, Information Technologies and Engineering
Место публикации : J. Phys. Conf. Ser. - 2020. - Vol. 1679, Is. 5. - Ст.052045. - DOI 10.1088/1742-6596/1679/5/052045
Примечания : Cited References: 13
Аннотация: Coal-water slurry (CWS) is the basis of modern alternative fuel - coal-water fuel (CWF). To produce stable coal-water slurry, i.e. coagulation and separation is an important technological problem. The paper studies CWS the disperse part of which is fine brown Kansk-Achinsk coal, the dispersive part is distilled water. Effect of cavitational conditioning on CWS stability has been studied. The efficiency was for the first time studied by magnetic resonance tomography (MRT). In the experiment spin-lattice relaxation time profiles T1 were recorded along the central vertical axis of the samples. T1 dynamics correlates well with the local density of CWS solid phase. MRT data was sequentially interpreted with rheological characteristics of CWS. Feasibility of applying MRT method to find out time and space evolution of CWS has been estimated. The MRT methods has been shown to be efficient in resolution of technological problems to improve consumer properties of the coal-water fuel.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korshunov M. A., Shabanov A. V., Bukhanov E. R., Shabanov V. F.
Заглавие : Effect of long-period ordering of the structure of a plant on the initial stages of photosynthesis
Место публикации : Dokl. Phys. - 2018. - Vol. 63, Is. 1. - P.1-4. - ISSN 10283358 (ISSN), DOI 10.1134/S1028335818010068
Примечания : Cited References: 15
Ключевые слова (''Своб.индексиров.''): electromagnetic fields--plants (botany)--density of photonic state--long wavelength--photosystems--plant leaves--soft modes--stopband--two bands--water dissociation--transfer matrix method
Аннотация: Using data on the structure of plant leaves, specific features of light propagation in biophotoniccrystal structures have been established by the transfer matrix method. Splitting of the stopband in two bands has been found. The density of photonic states and the electromagnetic field value have been calculated. The occurrence of two photosystems (splitting of the stopband in two bands), the peculiarity of the long-wavelength quantum yield and its enhancement (Emerson effect), and water dissociation in the soft mode due to an increase in the electromagnetic field on the layers are explained.
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