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Chemistry of vinylidene complexes. XXIV. A new μ-vinylidene complex containing RePt core, and platinum-bound carbonyl ligand. Spectroscopic, structural and electrochemical study / V. V. Verpekin [et al.]> // J. Mol. Struct. - 2018. - Vol. 1163. - P. 308-315, DOI 10.1016/j.molstruc.2018.03.020. - Cited References: 45. - The reported study was funded by the State budget allocated to the fundamental research in the Russian Academy of Sciences in the framework of Project No. V.44.1.7 and was financially supported by Krasnoyarsk Region Science and Technology Support Fund (the junior scientists project no. 3/15).
. - ISSN 0022-2860. - ISSN 1872-8014РУБ Chemistry, Physical Рубрики: TRI-METAL COMPLEXES RAY CRYSTAL-STRUCTURE BRIDGING CARBENE CARBYNE Кл.слова (ненормированные): Rhenium -- Platinum -- Vinylidene complexes -- Heterometallic complexes -- Electrochemistry Аннотация: The novel heterobinuclear μ-vinylidene complex [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)(CO)] (1) was isolated from the reaction mixture of [Cp(CO)2Re(μ-C=CHPh)Fe(CO)4] and Pt(PPh3)4 for the first time. Alternative high-yield synthetic approaches to 1 were developed including the reactions of [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)2] (2) with Co2(CO)8 and Rh(acac)(CO)2. The complex was characterized by IR and ¹H, ¹³C and ³¹P NMR spectroscopy, a molecular structure of 1 was determined by X-ray diffraction analysis. The electrochemical behavior of the new complex was studied by cyclic voltammetry at platinum or glassed carbon electrodes and by dc polarography at a dropping mercury electrode.
Смотреть статью, Scopus, WOS, Читать в сети ИФ Держатели документа: RAS, SB, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr,Fed Res Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia. RAS, SB, Fed Res Ctr, Inst Phys,Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia. RAS, Fed Res Ctr, SB, Krasnoyarsk Sci Ctr, Akademgorodok 50, Krasnoyarsk 660036, Russia. Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia. Доп.точки доступа: Verpekin, V. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Kondrasenko, A. A.; Burmakina, G. V.; Chudin, O. S.; Pavlenko, N. I; Zimonin, Dmitry V.; Rubaylo, Anatoly I.; Russian Academy of Sciences [V.44.1.7]; Krasnoyarsk Region Science and Technology Support Fund [3/15] } Найти похожие
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