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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sofronova S. N., Bezmaternykh L. N., Eremin E. V., Nazarenko I. I., Volkov N. V., Kartashev A. V., Moshkina E. M.
Заглавие : The superexchange interactions and magnetic ordering in low-dimentional ludwigite Ni5GeB2O10
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2016. - Vol. 401. - P.217-222. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2015.10.024
Примечания : Cited References: 23. - This study was supported by Russian Foundation for Basic Research (RFFI Siberia No. 15-42-04186). We thank S. Popkov, G. Yurkin for help on the magnetic measurements and M.S. Molokeev for help on the x-ray diffraction
Предметные рубрики: DIELECTRICS
EXCHANGE
CATION
Ключевые слова (''Своб.индексиров.''): ludwigites--magnetic order--heat capacity--exchange interactions--ferrimagnetic
Аннотация: The ludwigite Ni5Ge(BO5)2 belongs to a family of oxyborates which have low-dimensional subunits in the form of three-leg ladders unit structure. This material was studied by magnetic and thermodynamic measurements. Ni5Ge(BO5)2 does not show full long-range magnetic order, but one goes into a partial ordering or spin-glass state at 87 K. The superexchange interactions were calculated in the framework of a simple indirect coupling model. Different models of magnetic structure of Ni5Ge(BO5)2 and its unique magnetic behaviour was discussed. © 2015 Elsevier B.V.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S.
Заглавие : Crystal structure of thallium(I) 2-thiobarbiturate
Коллективы : Siberian Federal University within Government task of the Ministry of Education and Science of the Russian Federation [3049]
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 61, Is. 4. - P.442-446. - ISSN 0036-0236, DOI 10.1134/S0036023616040100. - ISSN 1531-8613(eISSN)
Примечания : Cited References:25. - This work was performed in the Siberian Federal University within the Government task of the Ministry of Education and Science of the Russian Federation for 2014-2016 (project no. 3049).
Предметные рубрики: Thiobarbituric acid-derivatives
Cation
Аннотация: The crystal and molecular structures of thallium(I) thiobarbiturate C4H3N2O2STl (C4H4N2O2S is 2-thiobarbituric acid, Н2ТВА) have been determined. Crystallographic data for Tl(НТВА) are a = 11.2414(7) Å, b = 3.8444(3) Å, с = 14.8381(9) Å, β = 99.452(2)°, V = 649.00(7) Å3, space group P2/с, Z = 4. Each of the two independent thallium ions is bonded to four oxygen and two sulfur atoms to form a distorted tetrahedron. N‒H…O and C‒H…S hydrogen bonds form a branched three-dimensional network. The structure is also stabilized by π‒π interaction between heterocyclic НТВА- ions. The IR spectra of Tl(НТВА) agree with X-ray powder diffraction data. The compound is also stable below 280°C, and Tl2SO4 is one of the thermolysis products in an oxidative medium in the region of 500‒650°C.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nazarenko I. I., Sofronova S. N., Moshkina E. M.
Заглавие : Magnetic ordering dependence on iron ions distribution in Cu2FeBO5 ludwigite
Коллективы : Russian Foundation for Basic Research; Government of Krasnoyarsk Territory [16-42-243028]
Место публикации : J. Exp. Theor. Phys. - 2018. - Vol. 126, Is. 5. - P.674-682. - ISSN 1063-7761, DOI 10.1134/S1063776118050047. - ISSN 1090-6509(eISSN)
Примечания : Cited References: 18. - This study was supported by the Russian Foundation for Basic Research and the Government of Krasnoyarsk Territory (project no. 16-42-243028).
Предметные рубрики: DIELECTRICS
CATION
Аннотация: A comparative analysis of the copper and iron ions bonds exchange energies was conducted for various variants of orderings and distributions of iron ions among crystallographic positions in ludwigite Cu2FeBO5. Analysis showed that the exchange bonds of iron ions play a key role in the formation of magnetic order. The magnetic ordering strongly depends on the distribution of iron ions among the positions. In the case when the Fe3+ is in the same position as in Fe3BO5, the most favorable magnetic structure is similar to the magnetic structure of ludwigite Fe3BO5. In other cases, the type of magnetic ordering is different.
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