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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Kretinin V. V., Aplesnin S. S., Sitnikov M. N., Udod L. V., Yanushkevich K. I.
Заглавие : Electrical properties of the polycrystalline BiFe0.95Co0.05O3 films
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Belarusian Republican Foundation for Basic Research [20-52-00005]
Место публикации : Phys. Solid State. - 2021. - Vol. 63. Is. 6. - P.897-903. - ISSN 1063-7834, DOI 10.1134/S1063783421060184. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 34. - This study was supported by the Russian Foundation for Basic Research and the Belarusian Republican Foundation for Basic Research, project no. 20-52-00005
Предметные рубрики: BiFeO3 THIN-FILMS
PHASE-SEPARATION
CRYSTAL
MODEL
Аннотация: Semiconductor BiFe0.95Co0.05O3 thin-film compounds have been synthesized by a burst technique. The film surface morphology and the effect of electronic doping via substitution of cobalt ions for trivalent iron on the optical, magnetic, and kinetic properties have been investigated in the temperature range of 77-600 K in magnetic fields of up to 12 kOe. Two electron relaxation channels have been found in the impedance spectrum in the frequency range of 0.1-1000 kHz. The negative magnetoresistance in the anomalous magnetization region and the maximum magnetoimpedance in the vicinity of the surface phase transition have been established. Using the Hall measurements, carrier types dominating in the magnetoresistance and magnetoimpedance effects have been determined. The magnetization anomalies have been explained in the model of superparamagnetic clusters and the magnetoresistance, by the carrier scattering by spin fluctuations.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu, Youquan, Mei, Dajiang, Wang, Naizheng, Molokeev M. S., Jiang, Xingxing, Lin, Zheshuai
Заглавие : Intrinsic isotropic near-zero thermal expansion in Zn4B6O12X (X = O, S, Se)
Место публикации : ACS Appl. Mater. Interfaces. - 2020. - Vol. 12, Is. 34. - P.38435-38440. - ISSN 1944-8244, DOI 10.1021/acsami.0c12351. - ISSN 1944-8252(eISSN)
Примечания : Cited References: 43. - This work was supported by the National Scientific Foundations of China (Grants 51872297, 51702330, 11974360, 51972208, 51890864, and 51802321), Russian Foundation for Basic Research (Grant 17-52-53031), and Fujian Institute of Innovation (FJCXY18010201) in CAS. X.J. acknowledges the support from the Youth Innovation Promotion Association in CAS (Grant 2017035) and Youth Talent Promotion Project from China Association for Science and Technology
Предметные рубрики: CRYSTAL
Аннотация: Zero thermal expansion (ZTE) materials, keeping size constant as temperature varies, are valuable for resisting the deterioration of the performance from environmental temperature fluctuation, but they are rarely discovered due to the counterintuitive temperature-size effect. Herein, we demonstrate that a family of borates with sodalite cage structure, Zn4B6O12X (X = O, S, Se), exhibits intrinsic isotropic near-ZTE behaviors from 5 to 300 K. The very low thermal expansion is mainly owing to the coupling rotation of [BO4] rigid groups constrained by the bonds between Zn and cage-edged O atoms, while the central atoms in the cage have a negligible contribution. Our study has significant implications on the understanding of the ZTE mechanism and exploration of new ZTE materials.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu, Dongjie, Yun, Xiaohan, Li, Guogang, Dang, Peipei, Molokeev M. S., Lian, Hongzhou, Shang, Mengmeng, Lin, Jun
Заглавие : Enhanced cyan emission and optical tuning of Ca3Ga4O9:Bi3+ for high-quality full-spectrum white light-emitting diodes
Место публикации : Adv. Opt. Mater. - 2020. - Vol. 8, Is. 22. - Ст.2001037. - ISSN 2195-1071, DOI 10.1002/adom.202001037
Примечания : Cited References: 55. - This work was financially supported by the National Natural Science Foundation of China (NSFC No. 51932009, 51720105015, 51672265, 51672266, 51672257 and 51672259), the Key Research Program of Frontier Sciences, CAS (Grant No. YZDY-SSW-JSC018), Science and Technology Cooperation Project between Chinese and Australian Governments (2017YFE0132300), the Jiangmen Innovative Research Team Program (2017), and the Major Program of Basic Research and Applied Research of Guangdong Province (2017KZDXM083)
Предметные рубрики: ENERGY-TRANSFER
TUNABLE LUMINESCENCE
PHOSPHOR
CRYSTAL
MODULATION
Аннотация: Highly efficient cyan‐emitting phosphor materials are indispensable for closing the cyan gap in spectra of the traditional phosphor‐converted white light‐emitting diodes (WLEDs) to achieve high‐quality full‐spectrum white lighting. In this work, bright cyan‐emitting Ca3Ga4O9 (CGO):0.02Bi3+,0.07Zn2+ phosphor is developed to bridge the cyan gap. Such a Bi3+,Zn2+ codoping enhances the cyan emission of CGO:0.02Bi3+ by 4.1 times due to the influence of morphology and size of phosphor particles, charge compensation and lattice distortion. Interestingly, codoping La3+ ions into the current system can achieve a photoluminescence tuning of CGO:0.02Bi3+ from cyan to yellowish‐green by crystallographic site engineering. Besides, Bi3+–Eu3+ energy transfer is successfully realized in CGO:0.02Bi3+,0.07Zn2+,nEu3+ phosphors and the emission color tuning from cyan to orange is observed. The investigation of thermal quenching behaviors reveals that the incorporation of Zn2+ and La3+ improves the thermal stability of CGO:0.02Bi3+. Finally, CGO:0.02Bi3+,0.07Zn2+,0.10Eu3+ phosphor is employed to obtain a single‐phased warm WLED device. A full‐spectrum WLED device with remarkable color rendering index (Ra) of 97.4 and high luminous efficiency of 69.72 lm W−1 is generated by utilizing CGO:0.02Bi3+,0.07Zn2+ phosphor. This result suggests the important effect of CGO:0.02Bi3+,0.07Zn2+ phosphor on closing the cyan gap, providing new insights of cyan‐emitting phosphors applied in full‐spectrum white lighting.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Wei, Y.i., Yang, Hang, Gao, Zhiyu, Xing, Gongcheng, Molokeev M. S., Li, Guogang
Заглавие : Bismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting
Место публикации : Chem. Commun. - 2020. - Vol. 56, Is. 64. - P.9170-9173. - ISSN 1359-7345, DOI 10.1039/d0cc03975f. - ISSN 1364-548X(eISSN)
Примечания : Cited References: 27. - This work was supported by the National Natural Science Foundation of China (Grant No. 51672259) and the Fundamental Research Funds for the National Universities, China University of Geosciences (Wuhan) (No. 1910491T02)
Предметные рубрики: PHOTOLUMINESCENCE
PHOSPHORS
Bi3+
MODULATION
CRYSTAL
Аннотация: A novel La2Mg1.14Zr0.86O6:Bi3+ double perovskite phosphor with excitation-induced blue/green photoluminescence tuning is reported. By designing Bi3+ → Eu3+ energy transfer, single-composition white light with wide-scale adjustable corrected color temperatures (CCTs) is successfully achieved. This work initiates a new insight to explore phosphors with excitation-induced photoluminescence tuning and wide CCT control for future intelligent LED lighting.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Krylova S. N., Kopyl S., Kholkin A.
Заглавие : Non-hydrostatic pressure-induced phase transitions in self-assembled diphenylalanine microtubes
Коллективы : [TUBITAK/0006/2014]
Место публикации : Tech. Phys. - 2018. - Vol. 63, Is. 9. - P.1311-1315. - ISSN 1063-7842, DOI 10.1134/S1063784218090098. - ISSN 1090-6525(eISSN)
Примечания : Cited References: 17. - This study was supported by the Turkish-Portuguese project no. TUBITAK/0006/2014.
Предметные рубрики: PEPTIDE NANOTUBES
CRYSTAL
Аннотация: The structural phase transitions in diphenylalanine microtubes caused by an increase in the non-hydrostatic pressure have been examined. Raman scattering investigations have been carried out and the results obtained have been interpreted and analyzed. Spectral variations in the ranges of phenyl ring vibrations and high-frequency oscillations of NH and CH groups have been analyzed. Under pressures of up to 9.8 GPa, four spectral anomalies indicative of the occurrence of phase transitions have been observed. The transitions under pressures of 1.7 and 4 GPa are shown to be reversible. The transition at 5.7 GPa is accompanied by partial sample amorphization.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Freydman A. L., Erofeev D. A., Temerov V. L., Gudim I. A.
Заглавие : The magnetoelectric MEE-effect in the SmFe3(BO3)4 multiferroic in dc and ac electric fields
Коллективы : Russian Foundation for Basic Research [17-32-50043_mol_nr, 18-02-00696_a]
Место публикации : J. Appl. Phys. - 2018. - Vol. 124, Is. 13. - Ст.134101. - ISSN 0021-8979, DOI 10.1063/1.5044598. - ISSN 1089-7550(eISSN)
Примечания : Cited References:22. - This work was supported by the Russian Foundation for Basic Research, projects no. 17-32-50043_mol_nr and no. 18-02-00696_a.
Предметные рубрики: CRYSTAL
Аннотация: The inverse magnetoelectric MEE-effect in the SmFe3(BO3)4 single-crystal sample in an applied electric field has been studied. The electric field E consists of two components: a constant one, e0, and a variable one, e × cos(ωt). The investigated compound evokes great interest due to the existence of both linear and quadratic contributions to the magnetoelectric effect. According to theoretical analysis, the effective susceptibility of the first harmonic of magnetic moment oscillations depends on the dc electric field component e0. Indeed, according to the measurement data, the dc field e0 significantly affects the MEE-effect first-harmonic amplitude: depending on the e0 sign, these oscillations can be either amplified or suppressed. This offers an opportunity for controlling the magnetic moment oscillation amplitude at the applied electric field frequency, including the signal modulation, which is promising for application. In the applied dc field e0, a slight change in the susceptibility of the MEE-effect term quadratic to the electric field was detected. The mathematical apparatus used correctly describes the qualitative dependence of the MEE-effect amplitude on the dc field e0, while the quantity appears to be approximately twofold overestimated.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Trabs, Peter, Noack, Frank, Aleksandrovsky A. S., Zaitsev A. I., Petrov, Valentin
Заглавие : Generation of coherent radiation in the vacuum ultraviolet using randomly quasi-phase-matched strontium tetraborate
Место публикации : Opt. Lett.: Optical Society of America, 2016. - Vol. 41, Is. 3. - P.618-621. - ISSN 0146-9592, DOI 10.1364/OL.41.000618. - ISSN 1539-4794(eISSN)
Примечания : Cited References:15
Предметные рубрики: Crystal
SrB4O7
nm
Аннотация: Tunable coherent radiation is generated in the vacuum ultraviolet down to 121 nm using random quasi-phase matching in strontium tetraborate, the shortest wavelength ever produced with a second-order nonlinear optical process in a solid-state material. Relevant properties of this radiation, the nonlinear process, and the nonlinear crystal are investigated.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A., Velikanov D. A., Zubavichus Y. V., Zaikovskii V .I., Stepanov S. A.
Заглавие : Identification of ε-Fe2O3 nano-phase in borate glasses doped with Fe and Gd
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2016. - Vol. 401. - P.880-889. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2015.10.126
Примечания : Cited References: 40. - This work was supported partly by the Russian Foundation for Basic Research, Grants No 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. Authors are grateful to G.A. Bukhtiyarova and U.N. Martyanov for the assistance in the ε-Fe2O3 nanoparticles prepared by a wet chemical pore filling impregnation method and for the discussion of the obtained results
Предметные рубрики: MAGNETIC-PROPERTIES
IRON-OXIDE
NANOPARTICLES
CERAMICS
CRYSTAL
PARTICLES
SURFACE
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--ε-fe2o3--magnetic circular dichroism--electron magnetic resonance
Аннотация: A new type of magnetic nanoparticles was revealed in borate glasses co-doped with low contents of iron and gadolinium. Structure and magnetic properties of the particles differ essentially from that of the α-Fe2O3, γ-Fe2O3, or Fe3O4 nanoparticles which were detected earlier in similar glass matrices. Transmission electron microscopy including STEM-HAADF and EDX, synchrotron radiation-based XRD, static magnetic measurements, magnetic circular dichroism, and electron magnetic resonance studies allow referring the nanoparticles to the iron oxide phase-ε-Fe2O3. Analysis of the data set has shown that it is Gd atoms that govern the process of nanoparticles' nucleation and its incorporation into the particles in different proportions can be used to adjust their magnetic and magneto-optical characteristics. © 2015 Elsevier B.V.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O. B., Galyas A. I., Sokolov V. V.
Заглавие : Study of electrical and thermoelecrical properties of sulfides TmxMn1-xS
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 1. - P.19-24. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416010029
Примечания : Cited References: 25. - This study was supported by the Russian Foundation for Basic Research (project no. 15-42-04099 r_si-bir_a) and State Contract no. 114090470016.
Предметные рубрики: SmxMn1-xS solid-solutions
MnS
Gd
Transition
Transport
Crystal
Аннотация: Variable-valence TmxMn1–xS (0 ⩽ x ⩽ 0.15) compounds have been synthesized and their structural, electrical, and thermoelectrical properties have been studied in the temperature range of 80–1100 K. The regions of existence of solid solutions of sulfides TmxMn1–xS with the NaCl-type fcc lattice have been determined. It has been found that, as thulium ions are substituted for manganese cations, the electrical resistivity increases, and the lattice parameter increases more sharply than that corresponding to the Vegard’s law. The study of the temperature dependences of the thermopower coefficient has revealed that the current carrier sign is retained to 500 K for all the substitution concentrations, and the charge carrier type changes from the hole type to the electron type with variations in the temperature. The experimental data have been explained in terms of the exciton model.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lim C. S., Atuchin V. V., Aleksandrovsky A. S., Molokeev M. S.
Заглавие : Preparation of NaSrLa(WO4)3:Ho3+/Yb3+ ternary tungstates and their upconversion photoluminescence properties
Место публикации : Mater. Lett.: Elsevier, 2016. - Vol. 181. - P.38-41. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2016.05.121
Примечания : Cited References: 24. - This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2015-058813), SB RAS Program No.II.2P (No. 0358-2015-0012) and Russian Foundation for Basic Research (15-52-53080).
Предметные рубрики: VIBRATIONAL PROPERTIES
LUMINESCENCE PROPERTIES
MODULATED STRUCTURE
PHOSPHORS
CRYSTAL
RED
Ключевые слова (''Своб.индексиров.''): tungstate--phosphor--sol-gel preparation--luminescence--raman spectroscopy--xrd
Аннотация: NaSrLa1-x(WO4)3:Ho3+/Yb3+ ternary tungstates were synthesized via microwave sol-gel route. Well-crystallized particles with particle sizes of 2-5 ?m were obtained after heat-treatment at 900 °C for 16 h. Under the excitation at 980 nm, the particles showed yellow emissions based on the strong 545 and 655 nm emission bands. The preferable Yb3+:Ho3+ ratio was obtained to be 9:1. Raman spectra of the doped particles indicated the presence of strong Ho3+ luminescence lines. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated. © 2016 Published by Elsevier B.V.
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