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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Geng K., Xia, Zhiguo, Molokeev M. S.
Заглавие : Crystal structure and luminescence property of a novel blue-emitting Cs2xCa2xGd2(1−x)(PO4)2:Eu2+ (x = 0.36) phosphor
Место публикации : Dalton Trans.: Royal Society of Chemistry, 2014. - Vol. 43, Is. 37. - P.14092-14098. - ISSN 1477-9226, DOI 10.1039/c4dt01578a. - ISSN 1477-9234
Примечания : Cited References: 29. - This present work was supported by the National Natural Science Foundation of China (grant no. 51002146, no. 51272242), Natural Science Foundation of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), the Fundamental Research Funds for the Central Universities (2011YYL131), Beijing Nova Program (Z131103000413047) and Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306).
Предметные рубрики: ENERGY-TRANSFER
DIODES
EARTH
EU-2+
PHASE
IONS
Аннотация: A novel blue-emitting double-phosphate phosphor Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ was synthesized by the sol-gel method, and the structure and luminescence properties were investigated in detail. The crystal structure and chemical composition of Cs0.72Ca0.72Gd1.28(PO4)(2) matrix was analyzed and determined based on Rietveld refinements and phase and chemical composition analysis. The composition-optimized Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ exhibited strong blue light, peaking at 462 nm upon excitation at 365 nm with the CIE coordinates of (0.139, 0.091). The quenching concentration of Eu2+ in the Cs0.72Ca0.72Gd1.28(PO4)(2) phase was about 0.01 and attributed to the dipole-quadrupole interaction. The thermally stable luminescence properties, fluorescence decay curves and diffuse reflectance spectra of Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ phosphors are also discussed, all of which indicate that the Cs0.72Ca0.72Gd1.28(PO4)(2):Eu2+ phosphor is a promising phosphor for application in white-light UV LEDs.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Guo Q. F., Ma B., Liao L. B., Molokeev M. S., Mei L. F., Liu H. K.
Заглавие : Crystal structure and luminescence properties of novel Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphor with apatite structure
Место публикации : Ceram. Int.: Elsevier Science, 2016. - Vol. 42, Is. 10. - P.11687-11691. - ISSN 0272-8842, DOI 10.1016/j.ceramint.2016.04.086. - ISSN 1873-3956(eISSN)
Примечания : Cited References:26. - This present work is supported by the National Natural Science Foundation of China (Grant no. 41172053).
Предметные рубрики: Light-Emitting-Diodes
Energy-transfer
Tunable phosphor
LEDs
Eu-2+
Ions
Ce3+
Ключевые слова (''Своб.индексиров.''): crystal structure--apatite--phosphor
Аннотация: In this paper, a series of novel luminescent Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors with apatite structure were synthesized by a high temperature solid-state reaction. The phase structure, photoluminescence (PL) properties, as well as the PL thermal stability were investigated. Sr9.92(SiO4)3(SO4)3O:0.08Eu2+ phosphor exhibits better thermal quenching resistance, retaining the luminance of 66.55% at 150 °C compared with that at 25 °C. The quenching concentration of Eu2+ in Sr10(SiO4)3(SO4)3O was about 0.08 (mol) with the dipole–quadrupole interaction. The Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors exhibited a broad-band green emission at 538 nm upon excitation at 396 nm. The results indicate that Sr10−x(SiO4)3(SO4)3O:xEu2+ phosphors have potential applications as near UV-convertible phosphors for white-light UV LEDs.
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