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1.


    Su, Binbin.
    Unveiling Mn2+ dopant states in two-dimensional halide perovskite toward highly efficient photoluminescence / B. B. Su, M. S. Molokeev, Z. G. Xia // J. Phys. Chem. Lett. - 2020. - Vol. 11, Is. 7. - P. 2510-2517, DOI 10.1021/acs.jpclett.0c00593. - Cited References: 49. - This work is supported by the National Natural Science Foundation of China (51961145101, 51972118, and 51722202), Fundamental Research Funds for the Central Universities (D2190980), the Guangdong Provincial Science & Technology Project (2018A050506004), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137). This work is also funded by RFBR according to the research project no. 19-52-80003. . - ISSN 1948-7185
   Перевод заглавия: Открытие легирующих состояний Mn2 + в двумерном галоидном перовските для высокоэффективной фотолюминесценции
РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Atomic, Molecular & Chemical
Рубрики:
LEAD BROMIDE PEROVSKITES
   ENERGY-TRANSFER

   EXCITON DYNAMICS

   DOPING MN2+

Аннотация: Doping is able to create novel optoelectronic properties of halide perovskites, and the involved mechanism of efficient emission is still a challenge. Herein Mn2+ substitution into 2D layered perovskites (C8H20N2)PbBr4 was investigated, demonstrating broad-band orange-red emission originating from the 4T1 → 6A1 transition of Mn2+ dopant. The photoluminescence quantum yield (PLQY) of Mn2+ emission is up to 60.8% related to the energy transfer in coupled states. We verify that an actual Mn2+ dopant as low as 0.476% reaches a high PLQY, whereas the nominal adding amount is 0.8 as the Mn2+/Pb2+ ratio. The small activation energy (∼6.72 meV) between the Mn2+ d state and the trap state accounts for this highly efficient energy transfer and photoluminescence. The proposed luminescence mechanism in Mn2+-doped 2D halide perovskites would provide unique insights into the doping design toward high-performance luminescence materials.

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Держатели документа:
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangdong Prov Key Lab Fiber Laser Mat & Appl Tec, Sch Mat Sci & Technol, Guangzhou 510640, Guangdong, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Xia, Zhiguo
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2.


   
    Tuning of photoluminescence by cation nanosegregation in the (CaMg)x(NaSc)1-xSi2O6 solid solution / Z. Xia [et al.] // J. Am. Chem. Soc. - 2016. - Vol. 138, Is. 4. - P. 1158-1161, DOI 10.1021/jacs.5b12788. - Cited References: 23. - Work performed by Z.X. and Q.L. was supported by the National Natural Science Foundation of China (51272242 and 51572023), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), and the Beijing Nova Program (Z131103000413047). Work performed by G.L., J.W., Z.M., M.B., and D.J.M. at Argonne National Laboratory was supported by the Office of Basic Energy Sciences of the U.S. Department of Energy (DOE) through Grant DE-AC02-06CH11357 for research on heavy elements chemistry and materials sciences. TEM was accomplished in part at the Center for Nanoscale Materials, a DOE Office of Science User Facility under Contract DE-AC02-06CH11357. Sector 20 operations at APS are supported by DOE and the Canadian Light Source, with additional support from the University of Washington. G.L. acknowledges travel support from the CAS/SAFEA International Partnership Program for Creative Research Teams. K.R.P. gratefully acknowledges support from the National Science Foundation (DMR-1307698). . - ISSN 0002-7863
   Перевод заглавия: Управление люминесценцией за счет наносегрегации катионов в твердом растворе (CaMg)x(NaSc)1-xSi2O6
РУБ Chemistry, Multidisciplinary
Рубрики:
SPINODAL DECOMPOSITION
   ENERGY-TRANSFER

   EXSOLUTION

   CLINOPYROXEN

   NANOCRYSTALS

   SEGREGATION

   MECHANISMS

   PYROXENESS

   JERVISITE

   PHOSPHORS

Аннотация: Controlled photoluminescence tuning is important for the optimization and modification of phosphor materials. Herein we report an isostructural solid solution of (CaMg)x(NaSc)1-xSi2O6 (0 < x < 1) in which cation nanosegregation leads to the presence of two dilute Eu2+ centers. The distinct nanodomains of isostructural (CaMg)Si2O6 and (NaSc)Si2O6 contain a proportional number of Eu2+ ions with unique, independent spectroscopic signatures. Density functional theory calculations provided a theoretical understanding of the nanosegregation and indicated that the homogeneous solid solution is energetically unstable. It is shown that nanosegregation allows predictive control of color rendering and therefore provides a new method of phosphor development. © 2016 American Chemical Society.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Chemical Sciences and Engineering Division, Argonne, IL, United States
Center for Nanoscale Materials, Nanoscience and Technology Division, Argonne, IL, United States
Nuclear Engineering Division, Argonne, IL, United States
X-ray Science Division, Argonne National Laboratory, Argonne, IL, United States
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, China
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, United States

Доп.точки доступа:
Xia, Z.; Liu, G.; Wen, J.; Mei, Z.; Balasubramanian, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Peng, L.; Gu, L.; Miller, D. J.; Liu, Q.; Poeppelmeier, K. R.
}
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3.


   
    Synthesis, crystal structure, and enhanced luminescence of garnet-type Ca3Ga2Ge3O12:Cr3+ by codoping Bi3+ / C. Y. Liu [et al.] // J. Am. Ceram. Soc. - 2015. - Vol. 98, Is. 6. - P. 1870-1876, DOI 10.1111/jace.13553. - Cited References:24. - This work was supported by the National Natural Science Foundations of China (grant nos. 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306) and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1). . - ISSN 0002. - ISSN 1551-2916
   Перевод заглавия: Синтез, кристаллическая структура и улучшенная люминесценция граната Ca3Ga2Ge3O12:Cr3+ содопированного Bi3+
РУБ Materials Science, Ceramics
Рубрики:
LIGHT-EMITTING-DIODES
   INFRARED PERSISTENT LUMINESCENCE

   ENERGY-TRANSFER

   PHOSPHOR

   RED

   NANOPARTICLES

   EFFICIENCY

Аннотация: Garnet-type compound Ca3Ga2Ge3O12 and Cr3+-doped or Cr3+/Bi3+ codped Ca3Ga2Ge3O12 phosphors were prepared by a solid-state reaction. The crystal structure of Ca3Ga2Ge3O12 host was studied by X-ray diffraction (XRD) analysis and further determined by the Rietveld refinement. Near-infrared (NIR) photoluminescence (PL) and long-lasting phosphorescence (LLP) emission can be observed from the Cr3+-doped Ca3Ga2Ge3O12 sample, and the enhanced NIR PL emission intensity and LLP decay time can be realized in Cr3+/Bi3+ codped samples. The optimum concentration of Cr3+ in Ca3Ga2Ge3O12 phosphor was about 6 mol%, and optimum Bi3+ concentration induced the energy-transfer (ET) process between Bi3+ and Cr3+ ions was about 30 mol%. Under different excitation wavelength from 280 to 453 nm, all the samples exhibit a broadband emission peaking at 739 nm and the intensity of NIR emission increases owing to the ET behavior from Bi3+ to Cr3+ ions. The critical ET distance has been calculated by the concentration-quenching method. The thermally stable luminescence properties were also studied and the introduction of Bi3+ can also improve the thermal stability of the NIR emission.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Liu, Chengyin; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Quanlin
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4.


   
    Synthesis and luminescence properties of Li2O–Y2O3–TeO2:Eu3+ tellurite glass / V. V. Atuchin [et al.] // Mater. Chem. Phys. - 2014. - Vol. 147, Is. 3. - P. 1191-1194, DOI 10.1016/j.matchemphys.2014.07.003. - Cited References: 26. - This study is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 0254-0584. - ISSN 1879-3312
РУБ Materials Science, Multidisciplinary
Рубрики:
LIGHT-EMITTING-DIODES
   SPECTROSCOPIC PROPERTIES

   OPTICAL-PROPERTIES

   ENERGY-TRANSFER

   CERAMICS

   Eu3+

   PHOTOLUMINESCENCE

   TEMPERATURE

   EMISSION

   PHOSPHOR

Кл.слова (ненормированные):
Glasses -- Heat treatment -- Photoluminescence spectroscopy -- Optical properties
Аннотация: The Eu3+-doped red-orange emitting phosphor of tellurite glass 0.25Li2O–0.20Y2O3–0.5TeO2–0.05Eu2O3 has been synthesized by the melt quenching method. The amorphous nature of the glass has been verified by XRD measurements. The photoluminescence excitation and emission spectra, the luminescence decay curves have been investigated for the composition. The phosphor can be efficiently excited by the near UV light to realize the intense narrow red emission line (611 nm) corresponding to forced electric dipole transition 5D0 → 7F2 of Eu3+ ions. The Li2O–Y2O3–TeO2:Eu3+glass phosphor is a potential red-orange emitting candidate for the application in WLEDs.

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
SB RAS, Inst Geol & Mineral, Lab High Pressure Minerals & Diamond Deposits, Novosibirsk 630090, Russia
Novosibirsk State Univ, Dept Appl Phys, Novosibirsk 630090, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Atuchin, V. V.; Yelisseyev, A. P.; Galashov, E. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ministry of Education and Science of the Russian Federation
}
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5.


   
    Synthesis and luminescence properties of blue-emitting phosphor Li3c2(PO4)3:Er2+ / S. X. Yu [et al.] // ECS J. Solid State Sci. Technol. - 2014. - Vol. 3, Is. 8. - P. R159-R163, DOI 10.1149/2.0071408jss. - Cited References: 33. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51002146, No. 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). Z. G. Xia is also grateful for the financial support from University of Science and Technology Beijing. V.V.A. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for the financial support. . - ISSN 2162-8769. - ISSN 2162-8777
   Перевод заглавия: Синтез и люминесцентные свойства синего люминофора Li3Sc2(PO4)3:Eu2+
РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
ENERGY-TRANSFER
   PHOTOLUMINESCENCE PROPERTIES

   INORGANIC-COMPOUNDS

   EMISSION COLOR

   FULL-COLOR

   DIODES

   Eu2+

   IONS

   LEDS

   Tb

Аннотация: A new blue-emitting phosphor Li3Sc2(PO4)3:Eu2+ was synthesized by a high temperature solid-state reaction method, and the crystal structure and photoluminescence properties were investigated in detail. The preferred crystallographic position of the Eu2+ ions in the Li3Sc2(PO4)3 host were determined from the structural analysis and spectroscopic properties. The as-prepared phosphor gave an intense blue emission band centered at 439 nm with the CIE coordinate of (0.1540, 0.0317) upon the excitation of the near ultraviolet light. The critical quenching concentration of Eu2+ in Li3Sc2(PO4)3:Eu2+ was about 15 mol%, and the corresponding concentration quenching mechanism was verified to be the dipole-quadrupole interaction. The fluorescence lifetime of Eu2+ emission and the thermal stable luminescence property have been investigated. Li3Sc2(PO4)3:Eu2+ was found to be a promising candidate as a blue-emitting n-UV convertible phosphor for the application in white light emitting diodes (w-LEDs).

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Yu, Shixin; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Miao, Hao; Atuchin, V. V.
}
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6.


   
    Role of Halogen Atoms on High-Efficiency Mn2+ Emission in Two-Dimensional Hybrid Perovskites / G. J. Zhou [et al.] // J. Phys. Chem. Lett. - 2019. - Vol. 10, Is. 16. - P. 4706-4712, DOI 10.1021/acs.jpclett.9b01996. - Cited References: 37. - This work is supported by the National Natural Science Foundation of China (No. 51722202 and 51572023), the Natural Science Foundations of Beijing (2172036), the Fundamental Research Funds for the Central Universities (FRF-TP-18-002C1), and the Guangdong Provincial Science & Technology Project (No. 2018A050506004). . - ISSN 1948-7185
   Перевод заглавия: Роль атомов галогенов в высокоэффективном излучении Mn2 + в двумерном гибридном перовските
РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Atomic, Molecular & Chemical
Рубрики:
ENERGY-TRANSFER
   LIGHT-EMISSION

   DOPING MN2+

   LEAD-FREE

   NANOCRYSTALS

Аннотация: Doped halide pervoskites as highly efficient light emitters have recently fascinated the research community, while the influence of halogen atoms X (X = Cl, Br, I) on the hybrid energy levels and photoluminescence properties remains a challenge. Here, the role of X compositions in the two-dimensional hybrid perovskite BA2PbX4 (BA = C4H9NH3) on the doped Mn2+ emission is identified, wherein Mn2+ reveals a strong luminescence dependence on the nature of the halogen, and optimum Mn2+ emission with a record quantum yield of 60.1% has been achieved in BA2PbBr4. Density functional theory calculations show that BA2PbBr4 holds low Br vacancy concentration and unique coupled states of the Mn-3d level and Pb-6p level at the conduction band minimum, leading to efficient energy transfer from the host to Mn2+. Our work sheds new light on the methods to realize strong exciton–dopant exchange coupling for achieving high-efficiency dopant luminescence.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China.
Beihang Univ, Sch Phys, Minist Educ, Key Lab Micronano Measurement Manipulat & Phys, Beijing 100191, Peoples R China.
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Guangdong, Peoples R China.

Доп.точки доступа:
Zhou, Guojun; Jia, Xiaofang; Guo, Shaoqiang; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhang, Junying; Xia, Zhiguo
}
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7.


   
    Preparation, crystal structure and up-conversion luminescence of Er3+, Yb3+ co-doped Gd2(WO4)3 / M. Yin [et al.] // RSC Adv. - 2015. - Vol. 5, Is. 89. - P. 73077-73082, DOI 10.1039/c5ra12959a. - Cited References: 43. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51472223), the Fundamental Research Funds for the Central Universities (Grant No. 2652015008), and New Century Excellent Talents in University of Ministry of Education of China (Grant No. NCET-12-0951). . - ISSN 2046-2069
   Перевод заглавия: Синтез, кристаллическая структура и люминесценция с апконверсией Gd2(WO4)3 содопированного Er3+, Yb3+
РУБ Chemistry, Multidisciplinary
Рубрики:
HYDROTHERMAL SYNTHESIS
   ENERGY-TRANSFER

   RED PHOSPHORS

   NANOCRYSTALS

   EMISSION

   GREEN

   HO

   TEMPERATURE

   TUNGSTATES

   TM

Аннотация: Up-conversion (UC) phosphors Gd2(WO4)3:Er3+/Yb3+ were synthesized by a high temperature solid-state reaction method. The crystal structure of Gd2(WO4)3:3% Er3+/10% Yb3+ was refined by Rietveld method and it was showed that Er3+/Yb3+ were successfully doped into the host lattice replacing Gd3+. Under 980 nm laser excitation, intense green and weak red emissions centered at around 532 nm, 553 nm, and 669 nm were observed, which were assigned to the Er3+ ion transitions of 4H11/2 → 4I15/2, 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2, respectively. The optimum Er3+ doping concentration was determined as 3 mol% when the Yb3+ concentration was fixed at 10 mol%. The pump power study indicated that the energy transfer from Yb3+ to Er3+ in Er3+, Yb3+ co-doped Gd2(WO4)3 was a two-photon process, and the related UC mechanism of energy transfer was discussed in detail. This journal is © The Royal Society of Chemistry.

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Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, China University of GeosciencesBeijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yin, Mengyan; Liu, Yangai; Mei, Lefu; Molokeev, M. S.; Молокеев, Максим Сергеевич; Huang, Zhaohui; Fang, Minghao
}
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8.


   
    Preparation and luminescence properties of the blue-emitting phosphor BaBPO5:Eu2+ / L. Zhang [et al.] // Sci. Adv. Mater. - 2016. - Vol. 8, Is. 5. - P. 1086-1092, DOI 10.1166/sam.2016.2704. - Cited References: 22. - This work was financially supported by the National Natural Science Foundation of China (NSFC Grant no. 51172216) and the Fundamental Research Funds for the Central Universities (Grant no. 2652015022). . - ISSN 1947-2935
   Перевод заглавия: Синтез и люминесцентные свойства синего люминофора BaBPO5:Eu2+
РУБ Nanoscience & Nanotechnology + Physics, Applied + Physics, Applied
Рубрики:
Energy-transfer
   Diodes

   Ions

   Eu3+

   Photoluminescence

   Reduction

   Tb3+

Кл.слова (ненормированные):
BaBPO5 -- Eu2+ -- Phosphor -- White light emitting diodes
Аннотация: Blue-emitting BaBPO5:xEu2+ phosphors were prepared by a high-temperature solid-state reaction route. The crystal phase, luminescence properties, lifetime, and thermal stability were investigated, respectively. The phase analysis indicated that BaBPO5 crystallize with the structure of stillwellite-type compounds. Under the excitation at 310 nm, the phosphor exhibited an asymmetric broad-band blue emission with peak at 410 nm, which was ascribed to the 4f-5d transition of Eu2+. It was further calculated that the dipole-dipole interactions were responsible for a concentration quenching effect in BaBPO5:xEu2+ phosphors at x = 0.08. The lifetime decreased with the increasing concentration of Eu2+ ions. The temperature-dependent emission spectra indicated an excellent thermal stability of the BaBPO5:0.08Eu2+ samples. Surface morphology and CIE coordinate were also investigated. All the properties assessed indicated that the developed blue-emitting BaBPO5:Eu2+ phosphor is a good candidate for application in white-light emitting diodes. © 2016 by American Scientific Publishers.

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Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences (Beijing), Beijing, China
National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, Grirem Advanced Materials Co., Ltd., Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Zhang, L.; Fang, M.; Huang, Z.; Liu, Y.; Min, X.; Tang, H.; Chen, K.; Guan, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич
}
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9.


   
    Photoluminescence of monoclinic Li3AlF6 crystals under vacuum ultraviolet and soft X-ray excitations / V. A. Pustovarov [et al.] // Opt. Mater. - 2015. - Vol. 49. - P. 201-207, DOI 10.1016/j.optmat.2015.09.011. - Cited References: 49. - This work was partly supported by the Ministry of Education and Science of the Russian Federation (the basic part of the government mandate); Center of Excellence "Radiation and Nuclear Technologies" (Competitiveness Enhancement Program of Ural Federal University, Russia), HASYLAB DESY (Projects Nos. 20110843, 20080119EC), European Social Fund ("Mobilitas" program, MJD219), Estonian Research Council (Institutional Research Funding IUT02-26) and Baltic Science Link project coordinated by the Swedish Research Council, VR . - ISSN 0925-3467
   Перевод заглавия: Люминесценция моноклинных кристаллов Li3AlF6 под вакуумным ультрафиолетом и мягким рентгеновским излучением
РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
LiBaAlF6 single-crystals
   F-type centers

   LiBaF3 crystals

   Color-centers

   Recombination luminescence

   Rietveld refinement

   VUV spectroscopy

   Trapped excitons

   Energy-transfer

   Pure

Кл.слова (ненормированные):
Li3AlF6 -- Time-resolved luminescence -- VUV spectroscopy -- Defects
Аннотация: Using Bridgman technique we have grown monoclinic β-LiAF crystals suitable for optical studies, performed XRD-identification and Rietveld refinement of the crystal structure and carried out a photoluminescence study upon vacuum ultraviolet (VUV) and extreme ultraviolet (XUV)-excitations, using the low-temperature (T = 7.2 K) time-resolved VUV-spectroscopy technique. The intrinsic PL emission band at 340–350 nm has been identified as due to radiative recombination of self-trapped excitons. The electronic structure parameters were determined: bandgap E g ≈ 12.5 eV, energy threshold for creation of unrelaxed excitons 11.8 eV < E n < 12.5 eV . The PL emission bands at 320–325 and 450 nm were attributed to luminescence caused by lattice defects. We have discovered an efficient excitation of PL emission bands in the energy range of interband transitions ( E ex > 13.5 eV), as well as in the energy range of core transitions at 130 eV. We have revealed UV–VUV PL emission bands at 170 and 208 nm due to defects. A reasonable assumptions about the origin of the UV–VUV bands were discussed.

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Держатели документа:
Ural Federal University, 19, Mira Street, Yekaterinburg, Russian Federation
Institute of Physics, University of Tartu, 14c, Ravila Street, Tartu, Estonia
Kirensky Institute of Physics, SB RAS, Akademgorodok 50, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, 47, Serysheva Street, Khabarovsk, Russian Federation
Institute of Geology and Mineralogy, SB RAS, 43, Russkaya Street, Novosibirsk, Russian Federation
Novosibirsk National Research University, 2, Pirogova Street, Novosibirsk, Russian Federation

Доп.точки доступа:
Pustovarov, V. A.; Пустоваров В. А.; Ogorodnikov, I. N.; Огородников И. Н.; Omelkov, S. I.; Омелков С. И.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kozlov, A. V.; Козлов А. В.; Isaenko, L. I.; Исаенко Л. И.
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    Optically Modulated Ultra-Broad-Band Warm White Emission in Mn2+-Doped (C6H18N2O2)PbBr4 Hybrid Metal Halide Phosphor / G. J. Zhou [et al.] // Chem. Mater. - 2019. - Vol. 31, Is. 15. - P. 5788-5795, DOI 10.1021/acs.chemmater.9b01864. - Cited References: 47. - This work is supported by the National Natural Science Foundation of China (nos. 51722202 and 51572023), Natural Science Foundations of Beijing (2172036), the Fundamental Research Funds for the Central Universities (FRF-TP-18-002C1), and the Guangdong Provincial Science & Technology Project (no. 2018A050506004). . - ISSN 0897-4756. - ISSN 1520-5002
   Перевод заглавия: Оптически модулированное ультраширокополосное излучение теплого белого света в гибридном металл-галоидном люминофоре допированным Mn2 + (C6H18N2O2)PbBr4
РУБ Chemistry, Physical + Materials Science, Multidisciplinary
Рубрики:
LIGHT EMISSION
   PEROVSKITE NANOCRYSTALS

   ENERGY-TRANSFER

   STATE

   Br

Аннотация: Finding new low-dimensional metal halides with broad-band emission is attracting interest in single-component phosphor for white light-emitting diodes (WLEDs). The full-spectrum white light still remains a challenge as found in the two-dimensional hybrid material (C6H18N2O2)PbBr4 exhibiting the intrinsic free exciton (FE) and broad-band self-trap exciton (STE) emission upon 365 nm ultraviolet excitation, and a combined strategy has been proposed through doping the Mn2+ ions enabling a superposition of multiple emission centers toward the ultra-broad-band warm white light. The occupation of Mn2+ in (C6H18N2O2)PbBr4 has been discussed, and optical investigations verify that the warm white-light emission of Mn2+-doped (C6H18N2O2)PbBr4 originates from the coupling effects of the FE, STEs, and the 4T1–6A1 transition of the doped Mn2+. When the concentration of Mn2+ is 5%, the emission spectrum of the phosphor covers all visible-light areas with a full width at half maximum (FWHM) of about 230 nm. The high Ra (84.9) and warm light CCT (3577 K) values of the as-fabricated WLED lamp demonstrate that (C6H18N2O2)Pb1–xMnxBr4 can be promising as single-component white-light phosphor in solid-state lighting. Our work could provide a new understanding and perspective about hybrid metal halides for designing superior phosphor toward single-component white emission.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China.
Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China.
Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Sun Yat Sen Univ, Sch Mat Sci & Engn, Sch Chem,Minist Educ, Key Lab Bioinorgan & Synthet Chem,State Key Lab O, Guangzhou 510275, Guangdong, Peoples R China.
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Guangdong, Peoples R China.

Доп.точки доступа:
Zhou, Guojun; Jiang, Xingxing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lin, Zheshuai; Zhao, Jing; Wang, Jing; Xia, Zhiguo
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