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Вид документа : Статья из журнала
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Автор(ы) : Bayukov O. A., Abd-Elmeguid M. M., Ivanova N. B., Kazak N. V., Ovchinnikov S. G., Rudenko V. V.
Заглавие : Mossbauer effect study in Fe1-xVxBO3 solid solutions
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2004. - Vol. 46, Is. 6. - P1088-1094. - ISSN 1063-7834, DOI 10.1134/1.1767250
Примечания : Cited References: 28. - One of the authors (M.M. A.-E.) would like to thank the Deutsche Forschungsgemeinschaft for financial support (SFB 608). This study was supported by the Russian Foundation for Basic Research (project no. 03-02-16286) and the federal program “Integration” (project no. Б0017)
Предметные рубрики: MAGNETO-OPTICAL PROPERTIES
FEBO3 SINGLE-CRYSTALS
FERRIC BORATE
CALCITE STRUCTURE
IRON BORATE
TEMPERATURE
FIELD
SPECTRA
FE3BO6
CRBO3
Аннотация: The Mossbauer effect in the Fe1 - xVxBO3 solid solutions has been measured at 130 and 300 K. The Fe0.05V0.95BO3 composition was studied in the interval 4.2-300 K. The experimental data obtained are described in terms of the model of a dilute magnetic insulator in which atoms of the first coordination sphere provide a major contribution to the hyperfine field at iron nucleus sites. It was found that, at low temperatures, the field H-hf is generated primarily by the iron ion itself and depends only weakly on substitution. The hyperfine interaction parameters in the discrete configuration series 6Fe, 5Fe1V, 4Fe2V, 3Fe3V, and 2Fe4V were determined. The magnitude of the isomer shift suggests that iron in the crystal resides in the trivalent state. (C) 2004 MAIK "Nauka/Interperiodica".
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