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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Jun, Li, Mingze, Ning, Lixin, Zhang, Ruiling, Molokeev M. S., Zhao, Jing, Yang, Songqiu, Han, Keli, Xia, Zhiguo
Заглавие : Broad-Band Emission in a Zero-Dimensional Hybrid Organic [PbBr6] Trimer with Intrinsic Vacancies
Место публикации : J. Phys. Chem. Lett. - 2019. - Vol. 10, Is. 6. - P.1337-1341. - ISSN 1948-7185, DOI 10.1021/acs.jpclett.9b00238
Примечания : Cited References: 28. - This work was supported by the National Natural Science Foundation of China (Grant Nos. 51722202, 91622125, 51572023, 11574003, 21833009, and 21533010) and the Natural Science Foundation of Beijing (2172036). We were grateful to Prof. Keli Han for his support to supply the femtosecond transient absorption spectroscopy device.
Предметные рубрики: WHITE-LIGHT EMISSION
HALIDE PEROVSKITES
LUMINESCENCE
Аннотация: The understanding of broad-band emission mechanisms on low-dimensional metal halides is an urgent need for the design principle of these materials and their photoluminescence tuning. Herein, a new zero-dimensional (0D) organic–inorganic hybrid material (C9NH20)6Pb3Br12 has been discovered, in which face-sharing PbBr6 trimer clusters crystallize with organic cations (C9NH20+), forming periodic structure with 0D blocks. Broad-band green emission peaking at about 522 nm was observed for this material, with a full width at half-maximum (fwhm) of 134 nm. The emission was attributed to excitons trapped at controlled intrinsic vacancies, and this is the new example in 0D metal halides, also confirmed by spectroscopy analysis and first-principles calculations. Discovery of the single-crystalline hybrid material and observation of defect-induced luminescence extend the scope of bulk 0D materials and understanding of photophysical properties for optoelectronic applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Deng, Chenkai, Hao, Shiqiang, Liu, Kunjie, Molokeev M. S., Wolverton, Christopher, Fan, Liubing, Zhou, Guojun, Chen, D.a., Zhao, Jing, Liu, Quanlin
Заглавие : Broadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures
Коллективы : Beijing Municipal Natural Science FoundationBeijing Natural Science Foundation [2182080]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51972021, 51702329]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [FRF-IDRY-19-005]; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]; Department of Energy, Office of Science Basic Energy SciencesUnited States Department of Energy (DOE) [DE-SC0014520]
Место публикации : J. Mater. Chem. C. - 2021. - Vol. 9, Is. 44. - P.15942-15948. - ISSN 2050-7526, DOI 10.1039/d1tc04198c. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 52. - This work was supported by Beijing Municipal Natural Science Foundation (2182080) and the National Natural Science Foundation of China (51972021 and 51702329). The work was partly supported by the Fundamental Research Funds for the Central Universities (FRF-IDRY-19-005) and by the RFBR according to the research project No. 19-52-80003. S. H. and C. W. (DFT calculations) acknowledge support from the Department of Energy, Office of Science Basic Energy Sciences under Grant DE-SC0014520. Access to QUEST, the supercomputing resources facilities at Northwestern University, is also acknowledged
Предметные рубрики: CRYSTAL-STRUCTURE
LONE-PAIR
EMISSION
PEROVSKITES
TIN
LUMINESCENCE
Аннотация: Low-dimensional organic–inorganic metal halides have recently attracted extensive attention because of their various structures and distinguished photoelectric properties. Herein, we report a series of new zero-dimensional organic–inorganic hybrid metal halides: (TMEDA)3Bi2Cl12·H2O, (TMEDA)3Bi2Br12·H2O, (TMEDA)3Sb2Br12·H2O, and (TMEDA)5Sb6Cl28·2H2O [TMEDA = N,N,N′·trimethylethylenediamine]. (TMEDA)3M2X12·H2O (M = Bi or Sb, X = Cl or Br) crystallizes in the monoclinic space group P21/n, and (TMEDA)5Sb6Cl28·2H2O crystallizes in the orthorhombic space group Pnma. (TMEDA)3M2X12 possesses a zero-dimensional structure with the metal halide ions of [MBr6]3− isolated by the organic TMEDA2+ cations. Interestingly, the (TMEDA)5Sb6Cl28·2H2O structure consists of a combination of corner-connected octahedra [Sb4Cl18]6− and edge-shared [Sb2Cl10]4−, which is quite rare. The light emission of all these compounds was measured, and (TMEDA)3Sb2Br12·H2O exhibits the most intense luminescence. Upon 400 nm ultraviolet light excitation, (TMEDA)3Sb2Br12·H2O exhibited strong broadband yellow emission centered at 625 nm with a full-width at half-maximum of ∼150 nm originating from self-trapped excitons. This work suggests the possibility of new types of hybrid halides by introducing different metal centers and probing the structural evolution and photoluminescent properties, serving as a reference for the relationship between structure and luminescent performance and demonstrating their potential use as phosphors in light-emitting diodes.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yang, Zhiyu, Liu, Gaochao, Zhao, Yifei, Zhou, Yayun, Qiao, Jianwei, Molokeev M. S., Swart, Hendrik C., Xia, Zhiguo
Заглавие : Competitive site occupation toward improved quantum efficiency of SrLaScO4:Eu red phosphors for warm white LEDs
Коллективы : International Cooperation Project of National Key Research and Development Program of China [2021YFE0105700]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51972118, 51961145101]; Guangzhou Science & Technology Project [202007020005]; State Key Laboratory of Luminescent Materials and Devices [Skllmd-2021-09]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2021M691053]; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01X137]; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]; NRF International: SA/China Joint Research Programme 2021 [CHIN2002265 06921 UID 132785]
Место публикации : Adv. Opt. Mater. - 2022. - Vol. 10. Is. 6. - Ст.2102373. - ISSN 2195-1071, DOI 10.1002/adom.202102373
Примечания : Cited References: 42. - This research was supported by the International Cooperation Project of National Key Research and Development Program of China (Program No. 2021YFE0105700), National Natural Science Foundation of China (Grant Nos. 51972118 and 51961145101), Guangzhou Science & Technology Project (Project No. 202007020005), the State Key Laboratory of Luminescent Materials and Devices (Grant No. Skllmd-2021-09), China Postdoctoral Science Foundation (Grant No. 2021M691053), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (Program No. 2017BT01X137). This work was also funded by RFBR according to the research Project No. 19-52-80003 and the NRF International: SA/China Joint Research Programme 2021 - CHIN2002265 06921 UID 132785
Предметные рубрики: LUMINESCENCE
EUROPIUM
BLUE
EU2+
STABILIZATION
EPR
Аннотация: The discovery of Eu2+-doped high-efficiency red phosphors remains a vital challenge for white light-emitting diode (WLED) applications. It is therefore urgent to find effective strategies managing the oxidation state to help reduce Eu3+ to Eu2+ and accordingly increase the photoluminescence quantum yield (PLQY). Herein, a new red-emitting SrLaScO4:Eu phosphor is designed, and the PLQY is enhanced from 13% to 67% under 450 nm excitation by employing (NH4)2SO4-assisted sintering. Combined structural analysis, optical spectroscopy, and theoretical calculation reveal that predominant Eu2+ prefers to occupy the Sr2+ sites in the SrLaScO4 enabling red emission, and a competitive site occupation of Eu3+ in La3+ can be restrained, and the reduction mechanism of Eu3+ to Eu2+ originating from the (NH4)2SO4 addition is analyzed. The fabricated WLED device using red-emitting SrLaScO4:Eu and yellow-emitting Y3(Al,Ga)5O12:Ce3+ exhibits a high color-rendering index of 86.7 at a low correlated color temperature of 4005 K. This work provides a feasible reduction strategy for guiding the development of high-efficiency Eu2+-doped red phosphor for WLED applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ma L., Xia Z., Atuchin V. V., Molokeev M. S., Auluck S., Reshak A. H., Liu Q.
Заглавие : Engineering oxygen vacancies towards self-activated BaLuAlxZn4-xO7-(1-x)/2 photoluminescent materials: An experimental and theoretical analysis
Место публикации : Phys. Chem. Chem. Phys.: Royal Society of Chemistry, 2015. - Vol. 17, Is. 46. - P.31188-31194. - ISSN 14639076 (ISSN), DOI 10.1039/c5cp05130d
Примечания : Cited References: 28. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51572023, 51272242 and 51511130035), and Fundamental Research Funds for the Central Universities (FRF-TP-15-005A1). The author A. H. Reshak would like to acknowledge the CENTEM project, reg. no. CZ.1.05/2.1.00/03.0088, cofunded by the ERDF as part of the Ministry of Education, Youth and Sports OP RDI programme and, in the follow-up sustainability stage, supported through CENTEM PLUS (LO1402) by financial means from the Ministry of Education, Youth and Sports under the National Sustainability Programme I. Computational resources were provided by MetaCentrum (LM2010005) and CERIT-SC (CZ.1.05/3.2.00/08.0144) infrastructures. SA would like to thank CSIR-NPL and Physics Department IIT Delhi for financial support. This work was partly supported by the Russian Foundation for Basic Research (Grant No. 15-52-53080 GFEN_a). VVA was partly supported by the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: PHOSPHOR
LUMINESCENCE
EVOLUTION
OXIDES
IONS
Аннотация: Novel self-activated yellow-emitting BaLuAlxZn4-xO7-(1-x)/2 photoluminescent materials were investigated by a combined experimental and theoretical analysis. The effects of Al/Zn composition modulation, calcination atmosphere and temperature on the crystal structure and photoluminescence properties have been studied via engineering oxygen vacancies. Accordingly, BaLuAl0.91Zn3.09O7 prepared in an air atmosphere was found to be the stable crystalline phase with optimal oxygen content and gave a broad yellow emission band with a maximum at 528 nm. The self-activated luminescence mechanism is ascribed to the O-vacancies based on the density functional theory (DFT) calculation. A theoretical model originating from the designed oxygen vacancies has been proposed in order to determine the influence of O-vacancies on the band structure and self-activated luminescence. Therefore, the appearance of a new local energy level in the band gap will cause the wide-band optical transitions in the studied BaLuAlxZn4-xO7-(1-x)/2 materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Jun, Rong, Ximing, Molokeev M. S., Zhang, Xiuwen, Xia, Zhiguo
Заглавие : Exploring the transposition effects on the electronic and optical properties of Cs2AgSbCl6 via a combined computational-experimental approach
Место публикации : J. Mater. Chem. A. - 2018. - Vol. 6, Is. 5. - P.2346-2352. - ISSN 2050-7488, DOI 10.1039/c7ta10062k. - ISSN 2050-7496(eISSN)
Примечания : Cited References:34. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125, 51572023, 11774239 and 51722202), Natural Science Foundations of Beijing (2172036), and National Key R&D Program of China (Grant 2016YFB0700700). M. Molokeev acknowledges the support of the Russian Foundation for Basic Research (17-52-53031).
Предметные рубрики: PEROVSKITE SOLAR-CELLS
SPECTROSCOPIC PROPERTIES
LUMINESCENCE
Аннотация: The electronic and optical properties of perovskites are related to the local structures of the compounds and define their functional applications. Herein we have prepared a double perovskite Cs2AgSbCl6, which crystallized in the cubic structure with the space group Fm-3m and the material is found to have a varied band gap associated with different body colors. The anti-site defect model was established to investigate transposition influence on the optical and electronic properties of the double-perovskite Cs2AgSbCl6, and the proposed model clearly explained the as-observed variable body color. Cs2AgSbCl6 perovskite has a high decomposition temperature and is stable upon prolonged exposure to air and moisture, which emphasize its potential in the field of photovoltaic absorbers and optoelectronic applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yang, Xiang, Zhang, Y.u., Zhang, Xuejie, Chen, Jian, Huang, Haisen, Wang, Dongsheng, Chai, Xirong, Xie, Gening, Molokeev M. S., Zhang, Haoran, Liu, Yingliang, Lei, Bingfu
Заглавие : Facile synthesis of the desired red phosphor Li2Ca2Mg2Si2N6:Eu2+ for high CRI white LEDs and plant growth LED device
Место публикации : J. Am. Ceram. Soc. - 2020. - Vol. 103, Is. 3. - P.1773-1781. - ISSN 0002-7820, DOI 10.1111/jace.16858. - ISSN 1551-2916(eISSN)
Примечания : Cited References: 34. - National Natural Science Foundations of China, Grant/Award Number: 21671070 and 51802101; Project GDUPS; Natural Science Foundation of Guangdong Province, Grant/Award Number: 2018A030310217; Guangzhou Science & Technology Project, Grant/Award Number: 201704030086; Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams; National Undergraduate Innovation and Entrepreneurship Training Program granted for Gening Xie, Grant/Award Number: 201910564035
Предметные рубрики: IN-GLASS
LUMINESCENCE
PERFORMANCE
EFFICIENT
EMISSION
ROUTE
Аннотация: The red emission with suitable peak wavelength and narrow band is acutely required for high color rendering index (CRI) white LEDs without at the cost of the luminous efficacy. Herein, the Li2Ca2Mg2Si2N6:Eu2+ red phosphor was prepared with facile solid‐state method using Ca3N2, Mg3N2, Si3N4, Li3N, and Eu2O3 as the safety raw materials under atmospheric pressure for the first time, which shows red emission peaking at 638 nm with full width at half maximum (FWHM) of 62 nm under blue light irradiation and becomes the desired red phosphor to realize the balance between luminous efficacy and high CRI in white LEDs. The morphology, structure, luminescence properties, thermal quenching behavior, and chromaticity stability of the Li2Ca2Mg2Si2N6:Eu2+ phosphor are investigated in detail. Concentration quenching occurs when the Eu2+ content exceeds 1.0 mol%, whereas high‐temperature photoluminescent measurements show a 32% drop from the room‐temperature efficiency at 423 K. In view of the excellent luminescence performances of Li2Ca2Mg2Si2N6:Eu2+ phosphor, a white LEDs with CRI of 91 as a proof‐of‐concept experiment was fabricated by coating the title phosphor with Y3Al5O12:Ce3+ on a blue LED chip. In addition, the potential application of the title phosphor in plant growth LED device was also demonstrated. All the results indicate that Li2Ca2Mg2Si2N6:Eu2+ is a promising red‐emitting phosphor for blue LED‐based high CRI white LEDs and plant growth lighting sources.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moiseev N. V., Popov P. A., Solomennik V. D., Zaitsev A. I., Cherepakhin A. V.
Заглавие : Heat capacity and thermodynamic properties of crystalline SrB4O7
Место публикации : Inorg. Mater.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 48, Is. 5. - P.504-507. - ISSN 0020-1685, DOI 10.1134/S0020168512050123
Примечания : Cited References: 24. - This work was supported in part by the RF President's Grants Council (grant no. NSh-4645.2010.2), the RF Ministry of Education and Science (analytical departmental targeted program Development of the Scientific Potential of Higher Education Institutions, grant no. RNP 2.1.1/10747), Bryansk State University (project no. 1.1.11), and the Physical Sciences Division of the Russian Academy of Sciences (Physics of Advanced Materials and Structures Program, project no. 2.5.2).
Предметные рубрики: STRONTIUM TETRABORATE
SINGLE-CRYSTALS
LUMINESCENCE
Аннотация: The heat capacity of a strontium tetraborate (SrB4O7) single crystal has been determined in the temperature range 55-300 K by adiabatic calorimetry, and its Debye characteristic temperature, entropy change, enthalpy increment, and phonon mean free path have been calculated as functions of temperature.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liao, Hongxu, Zhao, Ming, Molokeev M. S., Liu, Quanlin, Xia, Zhiguo
Заглавие : Learning from a mineral structure toward an ultra-narrow-band blue-emitting silicate phosphor RbNa3(Li3SiO4)4:Eu2+
Место публикации : Angew. Chem. - Int. Edit. - 2018. - Vol. 57, Is. 36. - P.11728-11731. - ISSN 1433-7851, DOI 10.1002/anie.201807087. - ISSN 1521-3773(eISSN)
Примечания : Cited References: 22. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51722202, 91622125 and 51572023), and Natural Science Foundations of Beijing (2172036), and M.S.M. acknowledges support of the Russian Foundation for Basic Research (17-52-53031).
Предметные рубрики: RED PHOSPHORS
COLOR-GAMUT
LUMINESCENCE
Ключевые слова (''Своб.индексиров.''): luminescence--minerals--phosphors--rigid structure--silicates
Аннотация: Learning from natural mineral structures is an efficient way to develop potential host lattices for applications in phosphor converted (pc)LEDs. A narrow‐band blue‐emitting silicate phosphor, RbNa3(Li3SiO4)4:Eu2+ (RNLSO:Eu2+), was derived from the UCr4C4‐type mineral model. The broad excitation spectrum (320–440 nm) indicates this phosphor can be well matched with the near ultraviolet (n‐UV) LED chip. Owing to the UCr4C4‐type highly condensed and rigid framework, RNLSO:Eu2+ exhibits an extremely small Stokes shift and an unprecedented ultra‐narrow (full‐width at half‐maximum, FWHM=22.4 nm) blue emission band (λem=471 nm) as well as excellent thermal stability (96 %@150 °C of the initial integrated intensity at 25 °C). The color gamut of the as‐fabricated (pc)LEDs is 75 % NTSC for the application in liquid crystal displays from the prototype design of an n‐UV LED chip and the narrow‐band RNLSO:Eu2+ (blue), β‐SiAlON:Eu2+ (green), and K2SiF6:Mn4+ (red) components as RGB emitters.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Vtyurin A. N., Voronov V. N., Krylova S. N.
Заглавие : Manifestations of Structural Phase Transitions in a Rb2KLuF6 Crystal in Its Raman Spectra
Коллективы : Russian Foundation for Basic Research [16-02-00102, 18-02-00754]
Место публикации : Opt. Spectrosc. - 2019. - Vol. 126, Is. 4. - P.341-345. - ISSN 0030-400X, DOI 10.1134/S0030400X1904012X. - ISSN 1562-6911(eISSN)
Примечания : Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project nos. 16-02-00102, 18-02-00754.
Предметные рубрики: SCATTERING
ELPASOLITES
LUMINESCENCE
TRANSFORMATIONS
FLUORIDES
Аннотация: The Raman spectra of an Rb2KLuF6 crystal are studied in the temperature range from 8 to 375 K, which includes two phase transitions: one of which proceeds from a cubic to a tetragonal phase, while the other transition takes place from a tetragonal to a monoclinic phase. An analysis of the temperature dependences of parameters of spectral lines shows that the former transition is of the second kind, while the latter transition is of the first kind, close to the tricritical point. It is shown that the structural phase transitions in the Rb2KLuF6 double perovskite are not associated with disordering. The former transition is associated with rotations of LuF6 octahedra around the fourth-order axis, while the latter transition is related with rotations of octahedra and displacements of rubidium ions.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Oreshonkov A. S., Shestakov N. P., Molokeev M. S., Aleksandrovsky A. S., Gudim I. A., Temerov V. L., Adichtchev S. V., Pugachev A. M., Nemtsev I. V., Pogoreltsev E. I., Denisenko Y. G.
Заглавие : Monoclinic SmAl3(BO3)4: synthesis, structural and spectroscopic properties
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00750, 18-05-00682, 18-32-20011]
Место публикации : Acta Crystallogr. B. - 2020. - Vol. 76. - P.654-660. - ISSN 2052-5206(eISSN), DOI 10.1107/S2052520620008781
Примечания : Cited References: 38. - Funding for this research was provided by: Russian Foundation for Basic Research (grant Nos. 18-03-00750, 18-05-00682 and 18-32-20011 to AO)
Предметные рубрики: Optical-properties
Luminescence
Spectra
Crystals
Sm
Аннотация: Single crystals of SmAl3(BO3)4 were synthesized by the group growth on seeds method. The crystal structure was solved using a single-crystal experiment and the purity of the bulk material was proved by the Rietveld method. This borate crystallizes in the monoclinic C2/c space group with unit-cell parameters a = 7.2386 (3), b = 9.3412 (5), c = 11.1013 (4) Å and β = 103.2240 (10)°. IR and Raman spectroscopic analyses confirmed the monoclinic structure of SmAl3(BO3)4. Under 532.1 nm excitation, luminescence spectra exhibit bands assignable to the transitions from 4G5/2 to 6H5/2, 6H7/2, 6H9/2 and 6H11/2. The similarity of the luminescence spectra of the trigonal and monoclinic polymorphs is explained by the minor role of Sm—O bond distortion and the primary role of rotational distortion of SmO6 octahedra. The smaller covalency of the Sm—O bond in alumoborates is deduced in comparison with galloborates. Calorimetric measurements did not reveal high-temperature structural phase transitions up to a temperature of 720 K.
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