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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bartolome J., Arauzo A., Kazak N. V., Ivanova N. B., Ovchinnikov S. G., Knyazev Yu. V., Lyubutin I. S.
Заглавие : Uniaxial magnetic anisotropy in Co2.25Fe0.75O2BO3 compared to Co3O2BO3 and Fe3O2BO ludwigites
Разночтения заглавия :авие SCOPUS: Uniaxial magnetic anisotropy in Co2.25Fe0.75O 2BO3 compared to Co3O2BO3 and Fe3O2BO ludwigites
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2011. - Vol. 83, Is. 14. - Ст.144426. - ISSN 1098-0121, DOI 10.1103/PhysRevB.83.144426
Примечания : Cited References: 25. - The authors acknowledge V. V. Rudenko for the oxyborate samples they made and O. A. Bayukov for fruitful discussion. The financial support of Spanish MINCYT, Grant No. MAT08/1077, and the Aragonese E-34 project are acknowledged. Fruitful discussions with F. Bartolome and P. Bordet are acknowledged. The latter is thanked for providing the FeINF3/INFOINF2/INFBOINF3/INF single crystal. Also this study was supported by the Russian Foundation for Basic Research (Project No. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project No. MK-5632.2010.2), and the Physical Division of the Russian Academy of Science (Program "Strongly Correlated Electrons," Project No. 2.3.1).
Предметные рубрики: CRYSTAL-STRUCTURE
MOSSBAUER
CO3BO5
Аннотация: Magnetic and Mossbauer spectroscopy (MS) measurements have been performed on a single crystal of Co2.25Fe0.75O2BO3 with ludwigite structure. Two magnetic transitions (T-N = 115 K and T-C = 70 K) were traced from the ac susceptibility temperature dependence. The MS spectra as a function of temperature clearly show the onset of magnetic ordering below 115 K. Magnetization measurements on the parent Co3O2BO3 and Fe3O2BO3 compounds have been done for comparison. In Fe3O2BO3 the anisotropy of the different phases has been determined, showing that the anisotropy axis changes from the a to the b axis in the low-temperature antiferromagnetic phase. High magnetic uniaxial anisotropy has been detected for both Co3O2BO3 and Co2.25Fe0.75O2BO3. From the angle-dependent magnetization measurements it is found that in both compounds the easy axis of magnetization is the b [010] axis, where an antiferromagnetic component is superimposed on the main ferromagnetic component. In the c direction the behavior is purely antiferromagnetic. In Co2.25Fe0.75O2BO3 a strong reduction of the remanent magnetization and a very strong increase in coercive field along the b axis with respect to those found in Co3O2BO3 were observed from magnetic hysteresis cycles measured below T-C. The increase of coercive field is caused by the increase of defects upon Co substitution by Fe.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Dubrovskii A. A., Bayukov O. A., Stolyar S. V., Iskhakov R. S., Ladygina V. P., Yaroslavtsev R. N.
Заглавие : The effect of low-temperature heat treatment on the magnetic properties of biogenic ferrihydrite nanoparticles
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : Tech. Phys. Lett.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 41, Is. 7. - P.705-709. - ISSN 1063-7850, DOI 10.1134/S1063785015070172
Примечания : Cited References: 12. - This study was supported in part by the Ministry of Education and Science of the Russian Federation in the framework of a federal program for 2014-2016.
Предметные рубрики: BACTERIAL FERRIHYDRITE
MOSSBAUER
Аннотация: We have studied the influence of low-temperature heat treatment (annealing) on the magnetic properties of superparamagnetic nanoparticles of biogenic ferrihydrite. It is established that the proposed treatment leads to an increase in the blocking temperature and magnetic susceptibility of samples. After subsequent exposure in aqueous medium, the magnetic properties of annealed sol remain constant. The character of changes in the magnetic properties of samples studied shows that low-temperature heat treatment allows nanoparticle dimensions to be increased in a controlled way. © 2015, Pleiades Publishing, Ltd.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Semenov S. V., Dubrovskii A. A., Krasikov A. A., Popkov S. I., Yakushkin S. S., Kirillov V. L., Mart'yanov O. N.
Заглавие : Synthesis and magnetic properties of the core-shell Fe3O4/CoFe2O4 nanoparticles
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [17-12-01111]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P.285-290. - ISSN 1063-7834, DOI 10.1134/S1063783420020043. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 37. - This study was supported by the Russian Science Foundation, project no. 17-12-01111.
Предметные рубрики: MOSSBAUER
ENSEMBLE
Аннотация: The Fe3O4/CoFe2O4 nanoparticles with a core-shell structure with an average size of 5 nm have been obtained by codeposition from the iron and cobalt chloride solutions. An analysis of the magnetic properties of the obtained system and their comparison with the data for single-phase Fe3O4 (4 nm) and CoFe2O4 (6 nm) nanoparticles has led to the conclusion about a noticeable interaction between the soft magnetic (Fe3O4) and hard magnetic (CoFe2O4) phases forming the core and shell of hybrid particles.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Raevski I. P., Titov V. V., Malitskaya M. A., Eremin E. V., Kubrin S. P., Blazhevich A. V., Chen H., Chou C.-C., Raevskaya S. I., Zakharchenko I. N., Sarychev D. A., Shevtsova S. I.
Заглавие : Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5Ta0.5O3-PbTiO3 solid solution ceramics
Коллективы : Russian Foundation for Basic Research (RFBR) [12-08-00887_a]; Research Committee of the University of Macau
Место публикации : J. Mater. Sci.: Springer, 2014. - Vol. 49, Is. 18. - P.6459-6466. - ISSN 0022-2461, DOI 10.1007/s10853-014-8376-z. - ISSN 1573-4803
Примечания : Cited References: 35. - This study is partially supported by the Russian Foundation for Basic Research (RFBR) Project 12-08-00887_a and Research Committee of the University of Macau under Research and Development Grant for Chair Professor.
Предметные рубрики: MOSSBAUER
CRYSTALS
BEHAVIOR
NIOBATE
Аннотация: Dielectric, X-ray, Mossbauer and magnetization studies of (1 − x)PbFe0.5Ta0.5O3–(x)PbTiO3 ceramics with 0 ≤ x ≤ 0.3 have been carried out to determine the compositional evolution of ferroelectric and magnetic phase transition temperatures. Addition of PbTiO3 to PbFe0.5Ta0.5O3 increases the temperature T m of the dielectric permittivity maximum, decreases both the diffusion of this maximum and its frequency dependence. However, the Curie–Weiss temperature exceeds T m for all the compositions studied, indicating that the phase transition still remains diffused. Dilution of the (Fe, Ta)-sublattice by Ti lowers the Neel temperature T N but above a certain compositional threshold (x ≈ 0.1) fast lowering of T N stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field-cooled (ZFC) and FC magnetization–temperature curves as well as between the temperatures of magnetic phase transition determined from Mossbauer and magnetization studies for compositions with x 0.1 implies that this state is a spin-glass phase.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bukhtiyarova G. A., Mart'yanov O. N., Yakushkin S. S., Shuvaeva M. A., Bayukov O. A.
Заглавие : State of iron in nanoparticles prepared by impregnation of silica gel and aluminum oxide with FeSO4 solutions
Коллективы :
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 4. - P826-837. - ISSN 1063-7834, DOI 10.1134/S1063783410040268
Примечания : Cited References: 27. - This study was supported by the Presidium of the Russian Academy of Sciences within the framework of the Program no. 27 "Principles of Basic Research of Nanotechnologies and Nanomaterials," Project no. 46 "Magnetically Ordered Nanoparticles in Catalytic Systems: Synthesis, Evolution, and Physicochemical Properties."
Предметные рубрики: THERMAL-DECOMPOSITION
BETA-FEOOH
MOSSBAUER
FERRIHYDRITE
EPSILON-FE2O3
FE-2(SO4)(3)
SULFATE
FE-57
Аннотация: The state of iron in nanoparticles prepared by impregnating silica gel and aluminum oxide with iron(II) sulfate solutions has been investigated using Mossbauer spectroscopy. It has been revealed that the state of iron depends on the nature of the support. Iron(III) hydroxysulfate and iron(III) oxysulfate nanoparticles are formed on the surface of silica gel, and iron oxide nanoparticles are formed on the surface of aluminum oxide. An increase in the concentration of iron ions or in the size of iron-containing particles leads to hydration of the nanoparticle surface. The calcination of the samples results in the formation of E -Fe2O3 oxide in a strongly disordered or amorphous state in iron-containing particles on the surface of silica gel.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anshits A. G., Bayukov O. A., Anshits N. N., Pletnev O. N., Rabchevskii E. V., Vereshchagin S. N., Kondratenko E. V.
Заглавие : Nature of the active sites of ferrospheres in the oxidative condensation of methane
Коллективы : Russian Science Foundation [4-13-00289], Russian Congress on Catalysis (2; 2014 ; Oct. ; 2–5; Samara)
Место публикации : Kinet. Catal.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 56, Is. 4. - P.523-531. - ISSN 0023, DOI 10.1134/S0023158415040023. - ISSN 16083210(eISSN)
Примечания : Cited References:37. - This work was supported by the Russian Science Foundation (grant no. 14-13-00289).
Предметные рубрики: GLASS CRYSTAL CATALYSTS
HIGH-TEMPERATURE
MOSSBAUER
MAGNETITES
MICROSPHERES
SELECTIVITY
CONVERSION
FERRITES
ASHES
IRON
Ключевые слова (''Своб.индексиров.''): oxidative condensation of methane--ferrospheres--iron spinel--mossbauer spectroscopy--structural defects
Аннотация: The catalytic properties of ferrospheres containing 76–97 wt % Fe2O3 in the oxidative condensation of methane were compared with their phase composition and the distribution of iron cations over the crystallographic positions of iron-containing phases in a steady state. It was established that the reaction route of methane oxidation changed at a Fe2O3 content of 89 wt %. Deep oxidation was the main reaction route on ferrospheres with a Fe2O3 content of 88.8 wt %. At a Fe2O3 content of ≥89 wt %, the yield of C2 hydrocarbons sharply increased and the contribution of deep oxidation decreased. The yield of C2 hydrocarbons correlated with the amount of defects in the structure of iron spinel, which are iron ions with the tetrahedral cation of Ca2+ and the octahedral cation vacancy among the nearest neighbors.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Petrakovskiy G. A., Zuberek R., Nabialek A., Boem M., Sokolov V. V., Bovina A. F.
Заглавие : Magnetostriction of FexMn1-xS (x=0.27) Crystals
Коллективы : Siberian Branch, Russian Academy of Sciences; INTAS [06-1000013-9002]
Разночтения заглавия :авие SCOPUS: Magnetostriction of FexMn1 - xS (x = 0.27) crystals
Место публикации : JETP Letters. - 2009. - Vol. 90, Is. 3. - P.207-210. - ISSN 0021-3640, DOI 10.1134/S0021364009150107
Примечания : Cited References: 19. - This work was supported by the Siberian Branch, Russian Academy of Sciences, and INTAS, joint project no. 06-1000013-9002.
Предметные рубрики: ALPHA-MNS
SINGLE-CRYSTALS
TRANSITION
MOSSBAUER
Аннотация: The magnetostriction of FexMn1-xS (x = 0.27) single crystals in strong magnetic fields up to 120 kOe has been investigated. It has been found that the magnetostriction reaches colossal values (+/-3 x 10(-4)) atypical of compounds of 3d elements. It has been found that the magnetostriction changes sign when varying temperature and magnetic field; this behavior indicates an important role of the spin-phonon interactions in the formation of the magnetic order in solid solutions of iron-manganese sulfides.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Dubrovskiy A. A., Popkov S. I., Stolyar S. V., Bayukov O. A., Iskhakov R. S., Ladygina V. P., Yaroslavtsev R. N.
Заглавие : Magnetic properties of heat treated bacterial ferrihydrite nanoparticles
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2016. - Vol. 410. - P.171-180. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2016.02.059
Примечания : Cited References: 66. - TEM studies were performed on facility of Resource Sharing Center of Krasnoyarsk Scientific Center of Siberian Branch of Russian Academy of Sciences. Authors acknowledge to M.N. Volochaev for the TEM measurements.
Предметные рубрики: Hematite nanoparticles
NiO nanoparticles
Porous-glass
Ferritin
Particles
Temperature
Hysteresis
Transition
Anomalies
Mossbauer
Ключевые слова (''Своб.индексиров.''): ferrihydrite--nanoparticles--superparamagnetism
Аннотация: The magnetic properties of ferrihydrite nanoparticles, which are products of vital functions of Klebsiella oxitoca bacteria, have been studied. The initial powder containing the nanoparticles in an organic shell was subjected to low-temperature (T=160 °C) heat treatment for up to 240 h. The bacterial ferrihydrite particles exhibit a superparamagnetic behavior. Their characteristic blocking temperature increases from 26 to 80 K with the heat treatment. Analysis of the magnetization curves with regard to the magnetic moment distribution function and antiferromagnetic contribution shows that the low-temperature heat treatment enhances the average magnetic moment of a particle; i.e., the nanoparticles coarsen, probably due to their partial agglomeration during heat treatment. It was established that the blocking temperature nonlinearly depends on the particle volume. Therefore, a model was proposed that takes into account both the bulk and surface magnetic anisotropy. Using this model, the bulk and surface magnetic anisotropy constants KV≈1.7×105 erg/cm3 and KS≈0.055 erg/cm2 have been determined. The effect of the surface magnetic anisotropy of ferrihydrite nanoparticles on the observed magnetic hysteresis loops is discussed.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Dubrovskii A. A., Semenov S. V., Bayukov O. A., Stolyar S. V., Iskhakov R. S., Ladygina V. P., Ishchenko L. A.
Заглавие : Magnetic properties and the mechanism of formation of the uncompensated magnetic moment of antiferromagnetic ferrihydrite nanoparticles of a bacterial origin
Коллективы : Ministry of Education and Science of the Russian Federation; Siberian Branch of the Russian Academy of Sciences
Место публикации : J. Exp. Theor. Phys.: Pleiades Publishing, 2014. - Vol. 119, Is. 3. - P.479-487. - ISSN 1063-7761, DOI 10.1134/S1063776114080044. - ISSN 1090-6509
Примечания : Cited References: 42. - This work was supported by the Ministry of Education and Science of the Russian Federation (state contract in 2014-2016) and a program of the Siberian Branch of the Russian Academy of Sciences.
Предметные рубрики: NIO NANOPARTICLES
EXCHANGE BIAS
HYSTERESIS ANOMALIES
FERRITIN
SURFACE
MOSSBAUER
ORDER
SIZE
Аннотация: The magnetic properties of the superparamagnetic ferrihydrite nanoparticles that form as a result of the vital activity of Klebsiella oxytoca bacteria are studied. Both an initial powder with an average number of iron atoms N Fe ∼ 2000–2500 in a particle and this powder after annealing at 140°C for 3 h in air are investigated. The following substantial modifications of the magnetic properties of the ferrihydrite nanoparticles are detected after annealing: the superparamagnetic blocking temperature increases from 23 to 49.5 K, and the average magnetic moment of a particle increases (as follows from the results of processing of magnetization curves). The particles have antiferromagnetic ordering, and the magnetic moment resulting in the superparamagnetism of the system appears due to random spin decompensation inside the particle. For this mechanism, the number of uncompensated spins is proportional to the number of magnetically active atoms raised to the one-half power, and this relation holds true for the samples under study at a good accuracy. The possible causes of the detected shift of magnetic hysteresis loops at low temperatures upon field cooling are discussed.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorev M. V., Flerov I. N., Tressaud A., Bogdanov E. V., Kartashev A. V., Bayukov O. A., Eremin E. V., Krylov A. S.
Заглавие : Heat capacity and magnetic properties of fluoride CsFe2+Fe3+F6 with defect pyrochlore structure
Место публикации : J. Solid State Chem. - 2016. - Vol. 237. - P.330-335. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2016.02.045
Примечания : Cited References: 19. - This study was partially supported by the Grant NSh-924.2014.2 of the President of the Russian Federation for the Support of Leading Scientific Schools.
Предметные рубрики: Crystal-structure
Mossbauer
CsFe2F6
Spectra
Ключевые слова (''Своб.индексиров.''): pyrochlore structure--phase transition--magnetic properties--thermal properties
Аннотация: Heat capacity, Mossbauer and Raman spectra as well as magnetic properties of fluoride CsFe2F6 with defect pyrochlore structure were studied. In addition to recently found above room temperature three successive structural transformations Pnma-Imma-I41amd-Fd-3m, phase transition of antiferromagnetic nature with the 13.7 K Neel temperature and a broad heat capacity anomaly with a maximum at about 30 K were observed. The room temperature symmetry Pnma is unchanged at least down to 7 K. Simple model of indirect bond used to estimate the exchange interactions and to propose a magnetic structure model. © 2016 Elsevier Inc. All rights reserved.
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 1-10    11-19 
 

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