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Автор(ы) : Popkov S. I., Krasikov A. A., Dubrovskiy A. A., Volochaev M. N., Kirillov V. L., Martyanov O. N., Balaev A. D.
Заглавие : Size effects in the formation of an uncompensated ferromagnetic moment in NiO nanoparticles
Коллективы : Ministry of Science and Higher Education of the Russian Federation; Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory [18-42-240012]; Krasnoyarsk Territorial Foundation [18-42-240012]
Место публикации : J. Appl. Phys. - 2019. - Vol. 126, Is. 10. - Ст.103904. - ISSN 0021-8979, DOI 10.1063/1.5109054. - ISSN 1089-7550(eISSN)
Примечания : Cited References: 54. - This study was supported by the Ministry of Science and Higher Education of the Russian Federation and by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project: "Magnetic Reversal of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields-A New Approach to the Study of Dynamic Effects Associated with the Magnetization of Magnetic Nanoparticles," Project No. 18-42-240012.
Предметные рубрики: MAGNETIC-PROPERTIES
TEMPERATURE
SUSCEPTIBILITY
NANOFERRIHYDRITE
Аннотация: The magnetic properties of samples of NiO nanoparticles with average sizes of 23, 8.5, and 4.5 nm were investigated. Using the magnetization curves measured in strong (up to 250 kOe) pulsed magnetic fields, the contributions of the free spin and ferromagnetic subsystems were extracted. It has been found that the ferromagnetic contribution increases with a decrease in the nanoparticle size and is proportional to the fraction of uncompensated exchange-coupled spins. It is demonstrated that the uncompensated spins form in the antiferromagnetic NiO oxide due to an increase in the fraction of surface atoms in the nanoparticles with decreasing particle size and defects in the bulk of particles.
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