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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gabrienko A. A., Morozov E. V., Subramani V., Martyanov O. N., Kazarian S. G.
Заглавие : Chemical visualization of asphaltenes aggregation processes studied in situ with ATR-FTIR spectroscopic imaging and NMR imaging
Коллективы :
Skolkovo Foundation; BP
Место публикации : J. Phys. Chem. C: American Chemical Society, 2015. - Vol. 119, Is. 5. - P.2646-2660. - ISSN 1932-7447, DOI 10.1021/jp511891f
Примечания : Cited References:78. - This research was performed under the UNIHEAT project. The authors wish to acknowledge the Skolkovo Foundation and BP for financial support. The authors thank BP for providing samples of crude oil
Предметные рубрики: MEXICAN CRUDE OILS
X-RAY-DIFFRACTION
INFRARED-SPECTROSCOPY
PETROLEUM ASPHALTENES
MOLECULAR-DYNAMICS
VARIABLE SELECTION
ORGANIC-SOLVENTS
LIGHT-SCATTERING
N-HEPTANE
NEAR-IR
Аннотация: Crude oil phase behavior and asphaltene precipitation have been studied by two complementary chemical imaging methods for the first time. ATR-FTIR spectroscopic imaging approach has revealed the chemical composition of agglomerated and precipitated asphaltenes upon dilution with a flocculant. Asphaltenes, containing oxygen and nitrogen heteroatomic functional groups, have been detected to be least stable. Aromatic abundant asphaltenes have been observed to have relatively high solubility in crude oil/heptane blends. NMR imaging approach, capable of imaging in the bulk of crude oil samples, has demonstrated that n-heptane causes aggregation which can lead to the stable suspension or to the sedimentation followed by the formation of deposits, depending on flocculant concentration. These processes have been monitored for small and large amounts of heptane added to crude oil. The data obtained by ATR-FTIR spectroscopic imaging and NMR imaging have been correlated to propose a possible link between the chemical structure of asphaltenes and a mechanism of the formation of deposits.
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