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Вид документа : Статья из журнала Шифр издания :
Автор(ы) : Aleksandrov K. S., Bartolome J., Gorev M. V., Flerov I. N.
Заглавие : Hydrostatic pressure effect on phase transitions in perovskites with ammonium cations
Место публикации : Phys. Status Solidi B. - 2000. - Vol. 217, Is. 2. - P.785-791. - ISSN 0370-1972, DOI 10.1002/(SICI)1521-3951(200002)217:2785::AID-PSSB7853.0.CO;2-Y Примечания : Cited References: 36
Предметные рубрики: XMF3 CUBIC PEROVSKITES THERMAL-PROPERTIES HEAT-CAPACITY TEMPERATURE DEPENDENCE DIELECTRIC PROPERTIES X-RAY NH4ZNF3 NH4MNCL3 NH4COF3 NH4CDF3 Аннотация: The pressure dependence of the structural phase transition temperature has been measured for the powder samples of NH4MgF3, NH4ZnF3, NH4MnF3, NH4CoF3, NH4CdF3, and NH4MnCl3 perovskites in the pressure range 0 to 600 MPa. It was found that the values of dT(0)/dP are negative for the Mg, Zn. Co. Mn trifluorides and positive for NH4CdF3 and NH4MnCl3. Comparison with the known data for other halide and oxide perovskites allowed to conclude that the sign of dT(0)/dP is correlated with the value of the Goldschmidt tolerance factor of the perovskite, and its value is closely related to the temperature and mechanism of the transition.
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