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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorelik V. S., Pyatyshev A. Y., Krylov A. S.
Заглавие : Raman scattering in sodium nitrite crystals near the phase transition
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 1. - P.170-176. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416010133
Примечания : Cited References: 39. - This study was supported by the Russian Foundation for Basic Research (project nos. 12-02-00491, 13-02-00449, 13-02-90420, and 14-02-00190).
Предметные рубрики: NaNO2
SPECTROSCOPY
DEPENDENCE
SPECTRUM
SEARCH
MODES
Аннотация: Optical Raman spectra of a ferroelectric sodium nitrite crystal have been detected in a wide spectrum range at various temperatures, including the region of the ferroelectric phase transition. A manifestation of a transverse soft polar mode of the A1(z) type responsible for the ferroelectric phase transition has been discovered in the spectrum at room temperature. This mode has been found to become overdamped even far from the ferroelectric phase transition temperature. This mode also appears as a central peak under heating. It has been found that the pseudoscalar mode of the A2 type has the highest intensity in the Raman spectrum of sodium nitrite. The frequency corresponding to the maximum intensity of this mode in the Raman spectrum varies from 130 cm–1 at 123 K to 106 cm–1 at T = 513 K. A fair agreement of the experimental data for the A1(z) mode with the Lyddane–Sachs–Teller relation has been established. The polariton curves for the A1(z) polar mode and the dispersion curves for axinons has been plotted. © 2016, Pleiades Publishing, Ltd.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorelik V. S., Pyatyshev, A. Yu., Krylov A. S.
Заглавие : Raman light scattering in sodium nitrite crystals
Коллективы : Russian Foundation for Basic Research [12-02-00491, 13-02-00449, 13-02-90420, 14-02-00190]
Место публикации : Bull. Lebedev Phys. Inst.: Allerton Press, 2016. - Vol. 43, Is. 5. - P.167-173. - ISSN 1068-3356, DOI 10.3103/S1068335616050043. - ISSN 1934-838X(eISSN)
Примечания : Cited References:37. - This study was supported by the Russian Foundation for Basic Research, projects nos. 12-02-00491, 13-02-00449,13-02-90420, 14-02-00190.
Предметные рубрики: NANO2
PHASE
SPECTROSCOPY
PARAPHOTONS
DEPENDENCE
SPECTRUM
SEARCH
Ключевые слова (''Своб.индексиров.''): sodium nitrite--raman scattering--spectrum--polar mode--polariton--ferroelectric--dispersion curves
Аннотация: Raman light scattering spectra of a ferroelectric sodium nitrite crystal is studied in the lattice mode region as the temperature is lowered from room temperature to 123 K. The existence of a Raman satellite corresponding to the soft lattice mode, i.e., transverse polar vibration responsible for the ferroelectric phase transition, is established for the first time. It is found that the intensity of the Raman scattering by the pseudo-scalar low-frequency A (2) mode exceeds the intensity of other lattice variations by an order of magnitude.
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