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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Demidov A. A., Gudim, I. A., Eremin E. V.
Заглавие : Magnetic properties of Nd0.9Dy0.1Fe3(BO3)4
Место публикации : Physica B: Elsevier Science BV, 2012. - Vol. 407, Is. 3. - P.393-397. - ISSN 0921-4526, DOI 10.1016/j.physb.2011.11.004
Примечания : Cited References: 18. - This study was supported, in part, by Russian Federation's President Grant MK-497.2010.2 (A.A.D.).
Предметные рубрики: NDFE3(BO3)4
HOFE3(BO3)4
MULTIFERROICS
Ключевые слова (''Своб.индексиров.''): phase transitions--rare-earth ferroborates rfe3(bo3) 4--multiferroics
Аннотация: The magnetic properties of trigonal Nd0.9Dy0.1Fe3(BO3)4 substituted compound with the competitive Nd–Fe and Dy–Fe exchange interactions have been investigated. It has been shown that in Nd0.9Dy0.1Fe3(BO3)4 a spontaneous spin-reorientation transition from an ease-axis state to an easy-plane occurs near 8 K. Anomalies of the magnetization curves are observed in a spin-flop transition induced by the magnetic field B II c. The calculations were performed using a molecular-field approximation and a crystal-field model for the rare-earth subsystem. Extensive experimental data on the magnetic properties of Nd0.9Dy0.1Fe3(BO3)4 have been interpreted and good agreement between theory and experiment has been achieved using the obtained theoretical dependences.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zvyagina G. A., Zhekov K. R., Bilych I. V., Zvyagin A. A., Bludov A. N., Pashchenko V. A., Gudim, I. A.
Заглавие : Magnetic field-induced phase transitions in the antiferromagnet Nd 0.6Dy0.4Fe3(BO3)4
Место публикации : Low Temp. Phys.: AMER INST PHYSICS, 2014. - Vol. 40, Is. 2. - P.146-150. - ISSN 1063-777X, DOI 10.1063/1.4865561. - ISSN 1090-6517
Примечания : Cited References: 17
Предметные рубрики: EARTH FERROBORATE Nd0.75Dy0.25Fe3(BO3)4
NdFe3(BO3)4
Аннотация: Low-temperature studies of elastic and magnetic characteristics of the single crystal Nd0.6Dy0.4Fe3(BO3)4 have been performed. A transition to the antiferromagnetically ordered state of the magnetic subsystem has been manifested in the temperature behavior of the velocity and attenuation of acoustic modes and magnetization. Spin-reorientation phase transitions, which reveal themselves as anomalies in the behavior of elastic and magnetic characteristics of the crystal in the external magnetic field applied along the axis of the trigonal symmetry of the crystal have been discovered. The phase H–T diagram for H || C 3 has been constructed.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Sukhachev A. L., Temerov V. L.
Заглавие : Local magnetic properties of multiferroic Nd0.5Gd0.5Fe3(BO3)4 in the excited states of Nd3+ ion
Коллективы : Russian Foundation for Basic Researches [12-02-00026]; President of Russia grant [Nsh-2886.2014.2]
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2015. - Vol. 375. - P.153-163. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2014.09.077
Примечания : Cited References: 35. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by the President of Russia grant No Nsh-2886.2014.2.
Предметные рубрики: SINGLE-CRYSTAL
NdFe3(BO3)4
GdFe3(BO3)4
Ключевые слова (''Своб.индексиров.''): f-f transitions--nd3+ ion--excited states--local magnetic properties
Аннотация: Polarized absorption spectra of single-crystal Nd0.5Gd0.5Fe3(BO3)4 were studied in the region of the transition 4I9/2(4G5/2+2G7/2) in Nd3+ ion as a function of temperature (2-34 K) and magnetic field (0-65 kOe). The spectra of natural circular dichroism were measured in the range of 5-40 K. It was found out that the local magnetic properties in the vicinity of the excited ion substantially depended on its state. In particular, a weak ferromagnetic moment appears in some excited states. It was found out that the selection rules for electron transitions in the magnetically ordered state substantially deviated from those in the paramagnetic state of the crystal. They are different for different transitions and they are very sensitive to the orientation of the sublattice magnetic moment relative to the light polarization. In the spectrum of the natural circular dichroism, the transition is revealed which is not observed in the absorption spectrum.Поляризованные спектры поглощения монокристаллов Nd0.5Gd0.5Fe3 (BO3) 4 изучались в области переход 4 I9 / 2 (4G5 / 2þ27/2), в Nd3+ иона в зависимости от температуры (2-34 К) и магнитного поля (0-65 кЭ). Спектры природного кругового дихроизма были измерены в диапазоне 5-40 К. Было установлено, что локальные магнитные свойства в непосредственной близости от возбужденного иона существенно зависит от его состояния. В частности, в некоторых возбужденных состояниях появляется слабый ферромагнитный момент . Выяснилось, что правила отбора для электронных переходов в магнитоупорядоченных состоянии существенно отклонились от тех, которые в парамагнитного состояния кристалла. Они различны для разных переходов, и они очень чувствительны к ориентации подрешетки магнитного момента по отношению к поляризации света. В спектре естественного кругового дихроизма, проявляется переход , который не наблюдается в спектре поглощения.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zvyagina G. A., Zhekov K. R., Bilych I. V., Kolodyazhnaya M. P., Zvyagin A. A., Bludov A. N., Pashchenko V. A., Gudim, I. A.
Заглавие : Low-temperature magnetic phase transitions in the multiferroic Nd0.9Dy0.1Fe3(BO3)4. Part 1. Transitions induced by magnetic fields directed along the trigonal symmetry axis. Spontaneous transitions with temperature changes
Место публикации : Low Temp. Phys.: American Institute of Physics, 2016. - Vol. 42, Is. 4. - P.273-279. - ISSN 1063-777X, DOI 10.1063/1.4947480. - ISSN 1090-6517(eISSN)
Примечания : Cited References:19
Предметные рубрики: Earth ferroborate Nd0.75Dy0.25Fe3(BO3)4
Magnetoelastic properties
NdFe3(BO3)4
Аннотация: The elastic and magnetic characteristics of single-crystal Nd0.9Dy0.1Fe3(BO3)4 are studied at low temperatures in zero magnetic field and in external fields H||C3. The temperature dependences of the acoustic mode velocities and the magnetic susceptibility manifest a transition of the magnetic subsystem into a magnetically ordered state and two successive, spontaneous spin-reorientation phase transitions. The possibility of a spontaneous transition into an incommensurate (spiral) magnetic phase in the crystal is discussed. It is shown that an external magnetic field directed along the trigonal axis of the crystal induces a sequence of spin-reorientation phase transitions. An H-Tphase diagram (H||C3) is constructed for this compound.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Leont'ev A. A., Temerov V. L.
Заглавие : Magnetic and natural optical activity of f–f transitions in multiferroic Nd0.5Gd0.5Fe3(BO3)4
Коллективы : Council on Grants from the President of the Russian Federation for the State Support of Leading Scientific Schools [NSh-2886.2014.2]; Russian Foundation for Basic Research [16-02-00273]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 5. - P.952-958. - ISSN 1063-7834, DOI 10.1134/S1063783416050152. - ISSN 1090-6460(eISSN)
Примечания : Cited References:29. - This study was supported by the Council on Grants from the President of the Russian Federation for the State Support of Leading Scientific Schools (grant no. NSh-2886.2014.2) and the Russian Foundation for Basic Research (project no. 16-02-00273).
Предметные рубрики: Circular-dichroism spectra
Magnetooptical properties
Single-crystal
Absorption
Ions
NdFe3(BO3)4
Nd3+
Pr3+
Ho3+
Аннотация: Spectra of absorption, magnetic circular dichroism, and natural circular dichroism of the f–f transitions 4I9/2 → 4F3/2, 2H9/2 + 4F5/2, 4S3/2 + 4F7/2, 2G7/2 + 4G5/2, 2K13/2 + 4G7/2, and 4G9/2 in the Nd3+ ions in the Nd0.5Gd0.5Fe3(BO3)4 crystal have been measured as a function of the temperature in the interval of 90–300 K. Temperature dependences of the magneto-optical activity (MOA) and natural optical activity (NOA) of the transitions have been obtained. It has been found that, in contrast to allowed transitions, the temperature dependence of the MOA of the f–f transitions does not obey the Curie–Weiss law and the NOA depends on temperature. The NOA of some transitions changes the sign with variation in temperature. These phenomena have been explained by the presence of three contributions to the allowance of the f–f transitions, which lead to three contributions of different signs to the MOA and NOA. The range of the MOA of the f–f transitions in the Nd3+ ion has been predicted theoretically and confirmed experimentally.
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