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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Kutsak T. V., Sukhachev A. L., Aleksandrovsky A. S., Krylov A. S., Gudim, Irina A., Molokeev M. S.
Заглавие : Spectroscopic properties of ErAl3(BO3)4 single crystal
Место публикации : Chem. Phys.: Elsevier Science, 2014. - Vol. 428. - P.137–143. - ISSN 0301-0104, DOI 10.1016/j.chemphys.2013.11.008. - ISSN 1873-4421
Примечания : Cited References: 43. - The work was supported by the Russian Foundation for Basic Researches grant 12-02-00026, by the Russian President Grants SS-1044.2012.2 and 4828.2012.2, by project No 3.9.5 PSB RAS, and by the Ministry of Education and Science of Russian Federation grant 8365
Предметные рубрики: RARE-EARTH IONS
GREEN UP-CONVERSION
ER3+ IONS
MICROCHIP LASER
ABSORPTION INTENSITIES
YAL3(BO3)4 CRYSTAL
OPTICAL-ABSORPTION
FIELD ANALYSIS
GROWTH
LUMINESCENCE
Ключевые слова (''Своб.индексиров.''): rare earth compounds--er3+--spectroscopic properties--judd-ofelt analysis--luminescence
Аннотация: Single crystal of ErAl3(BO3)4 was grown and its structure was studied. Polarized absorption spectra of ErAl3(BO3)4 single crystal were measured in the spectral range 1670–330 nm (6000–30000 cm−1). The Judd–Ofelt spectroscopic parameters have been determined: Ω2 = 4.87 × 10−20 cm2, Ω4 = 2.49 × 10−20 cm2, Ω6 = 2.72 × 10−20 cm2. These parameters have been used to calculate the radiative transition probabilities, the multiplet luminescence branching ratios and the fluorescence life times of the manifolds. The luminescence spectra due to transitions 2H11/2 → 4I15/2 (526 nm), 4S3/2 → 4I15/2 (548 nm), 4F9/2 → 4I15/2 (662 nm), 2H11/2 → 4I13/2 + 4I9/2 → 4I15/2 (800 nm) and 4S3/2 → 4I13/2 (855 nm) were recorded in α, σ and π polarizations. The most intensive luminescence belonged to 4S3/2 → 4I15/2 transition (548 nm).Поляризованные спектры поглощения ErAl3 (BO3) 4 монокристалла были измерены в спектральном диапазоне 1670-330 нм (6000-30000 см-1). Спектроскопические параметры Джадда-Офельта были определены как: Ω2 = 4,87 • 10-20 см2, Ω4 = 2.49 • 10-20 см2, Ω6 = 2,72 • 10-20 см2. Параметры были использованы для расчета вероятностей излучающих переходов, мультиплетные отношения люминесценции раскола и времена жизни мультиплетов. Спектры люминесценции за счет переходов 2П11 / 2 → 4I15 / 2 (526 нм), 4S3 / 2 → 4I15 / 2 (548 нм), 4F9 / 2 → 4I15 / 2 (662 нм), 2П11 / 2 → 4I13 / 2 + 4I9 / 2 → 4I15 / 2 (800 нм) и 4S3 / 2 → 4I13 / 2 (855 нм) были записаны в α, σ и π поляризации. Наиболее интенсивное свечение принадлежало переходу 4S3 / 2 → 4I15 / 2 (548 нм).
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Sokolov V. V., Gudim, I. A.
Заглавие : Giant natural circular dichroism of vibronic transitions in HoAl3(BO3)4
Место публикации : JETP Letters. - 2015. - Vol. 102, Is. 8. - P.493-495. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364015200084
Примечания : Cited References: 15. - This work was supported by the Council of the President of the Russian Federation for the Support of Leading Scientific Schools (project no. NSh-2886.2014.2).
Предметные рубрики: SINGLE-CRYSTAL
OPTICAL-ABSORPTION
SPECTRA
Ho3+
IONS
PR3+
Аннотация: The giant natural optical activity of vibronic replicas of the f–f5/8 → 5F2 transition in HoAl3(BO3)4 is observed. It exceeds the optical activity related to purely electronic transitions by two orders of magnitude and corresponds to the almost complete circular polarization of the transitions. This effect is explained by the local distortions of the crystal in the excited electronic state, which lead to the mixing of electron and vibrational wavefunctions and, as a consequence, to the delocalization of the vibronic wavefunction and the enhancement of spatial dispersion, which is responsible for the optical activity.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pisarev R. V., Kalashnikova A. M., Schops O., Bezmaternykh L. N.
Заглавие : Electronic transitions and genuine crystal-field parameters in copper metaborate CuB2O4
Разночтения заглавия :авие SCOPUS: Electronic transitions and genuine crystal-field parameters in copper metaborate CuB 2O 4
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2011. - Vol. 84, Is. 7. - Ст.75160. - ISSN 1098-0121, DOI 10.1103/PhysRevB.84.075160
Примечания : Cited References: 65. - Useful discussions with W. Weber on crystal-field splitting of 3d states in cuprates are appreciated. We thank H.-J. Weber for the help in using Cary 2300 spectrophotometer. This work is supported by the Russian Foundation for Basic Research (project No. 09-02-00070) and Federal Agency for Science and Innovations (Grant No. 02.740.11.0384). A. M. K. acknowledges the financial support from the Committee for Science and Higher Education of the Government of Saint Petersburg.
Предметные рубрики: OPTICAL-ABSORPTION
PHASE-DIAGRAM
CUGEO3
SPECTRUM
SUPERCONDUCTORS
EXCITATIONS
SR2CUO2CL2
SCATTERING
LA2CUO4
CUPRATE
Аннотация: We present and analyze high-resolution alpha-, sigma-, and pi-polarized absorption spectra related to d-d electronic transitions in tetragonal metaborate CuB2O4 where copper Cu2+ ions occupy two crystallographically distinct 4b and 8d positions. The spectra are characterized by exceptionally rich fine structure in the spectral range of 1.4-2.4 eV. Six zero-phonon (ZP) lines originating from the electronic transitions within the Cu2+ ions in both positions are distinguished and identified. Symmetry analysis explains polarization properties of the ZP lines in the 8d positions but only partially explains them in the 4b positions. Reliable assignment of all six ZP lines to specific transitions allowed us to calculate genuine cubic Dq and tetragonal Ds and Dt crystal-field parameters for both positions. We show that the (3r(2) - z(2)) state, the energy of which is the measure of the Jahn-Teller splitting, is the highest 3d state for both types of Cu2+ ion positions. Using the obtained crystal-field parameters as the reference values, we estimated Dq, Ds, and Dt for several other cuprates with different Cu-O bond lengths. In particular, the 3d level splitting in La2CuO4, Nd2CuO4, CuGeO3, Sr2CuO2Cl2, and Cu3B7O13Cl was analyzed. Our estimates suggest that the Jahn-Teller splitting in some of these cuprates is larger than it was assumed previously.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov A. E., Temerov V. L., Bezmaternykh L. N., Sukhachev A. L., Seredkin V. A., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G.
Заглавие : Polarized absorption spectra and spectroscopic parameters of Tm3+ in the TmAl3(BO3)(4) single crystal
Разночтения заглавия :авие SCOPUS: Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 7. - P1287-1293. - ISSN 1063-7834, DOI 10.1134/S1063783408070159
Примечания : Cited References: 36
Предметные рубрики: RARE-EARTH IONS
ELECTRONIC ENERGY LEVELS
DIODE-PUMPED LASER
OPTICAL-ABSORPTION
ALUMINUM GARNET
MU-M
INTENSITIES
FLUORESCENCE
GLASSES
OXIDE
Аннотация: High-optical-quality single crystals of the TmAl3(BO3)(4) compound were synthesized from a solution in the melt. The absorption spectra in the sigma and pi polarizations for the H-3(6) - F-3(4), H-3(6) - H-3(5), H-3(6) - H-3(4), H-3(6) - F-3(3), H-3(6) - F-3(2), H-3(6) - (1)G(4), and H-3(6) - D-1(2) transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Omega(2) = 6.14 x 10(-20) cm(2), Omega(4) = 3.09 x 10(-20) cm(2), and Omega(6) = 2.04 x 10(-20) cm(2). The lifetimes and the branching ratios were determined for all possible transitions.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popov E. A., Beznosikov B. V.
Заглавие : Absorption of light by exchange-coupled ions in a 2D antiferromagnet
Место публикации : Phys. Solid State. - 2003. - Vol. 45, Is. 8. - P.1475-1478. - ISSN 1063-7834, DOI 10.1134/1.1602882
Примечания : Cited References: 9
Предметные рубрики: OPTICAL-ABSORPTION
RB2MNCL4
Аннотация: The optical absorption spectra of Rb2MnxCd1-xCl4 crystals are experimentally studied in the vicinity of a magnon sideband of the exciton band at a manganese content x ranging from 1.0 to 0.4. Additional absorption bands are observed with an increase in the magnetic structural disorder upon replacement of manganese ions by cadmium ions. An analysis of the evolution of the additional absorption bands in a magnetic field during the spin-flop phase transition and the change in the intensity with variations in the manganese content x demonstrates that these bands are associated with the excitation of the exchange-coupled pairs of manganese ions located in different environments in a plane square lattice. The phase boundary between the antiferromagnetic and spin-flop phases is constructed using the results of optical measurements. The manganese content corresponding to the magnetic percolation point is evaluated. (C) 2003 MAIK "Nauka/Interperiodica".
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