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1.


   
    A novel red-emitting La2CaHfO6:Mn4+ phosphor based on double perovskite structure for pc-WLEDs lighting / G. C. Xing [et al.] // CrystEngComm. - 2019. - Vol. 21, Is. 23. - P. 3605-3612, DOI 10.1039/c9ce00556k. - Cited References: 47. - This work is financially supported by the National Natural Science Foundation of China (NSFC No. 51672259). . - ISSN 1466-8033
   Перевод заглавия: Новый красный люминофор La2CaHfO6: Mn4+ на основе структуры двойного перовскита для светодиодных ламп pc-WLED
РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
LUMINESCENCE PROPERTIES
   ELECTRONIC-STRUCTURE

   OPTICAL-PROPERTIES

   SITE

Аннотация: Non-rare earth doped oxides with red emission are one of the current research hotspots for achieving the warm white light range in the phosphor converted white light emitting diodes (pc-WLEDs) field. In the current work, a novel Mn4+-activated La2CaHfO6 red phosphor is reported for the first time and its crystal structure is analyzed by Rietveld refinement. The photoluminescent properties of La2CaHfO6:Mn4+ are investigated in detail with the help of diffuse refletance spectroscopy, photoluminescence spectroscopy, and temperature-dependent PL spectroscopy. Based on the diffuse refletance spectra, the calculated optical band gap for La2CaHfO6 is 4.9 eV, indicating that La2CaHfO6 could be a suitable host for activators' doping. Under 380 nm near-ultraviolet (n-UV) light excitation, the as-prepared La2CaHfO6:Mn4+ displays intense red emission centered at 693 nm. Through an accurate calculation of Dq/B (2.47) and nephelauxetic effect β1 (0.949), the origination of strong crystal field (CF) and deep-red emission is demonstrated. By combining the representative La2CaHfO6:0.002Mn4+, blue BAM:Eu2+, and green (Ba,Sr)2SiO4:Eu2+ phosphors with a 380 nm UV chip to fabricate the pc-WLEDs device, a white light is obtained with low correlated color temperature (CCT = 5165 K) and high color rendering index (Ra = 87.8), demonstrating that the as-prepared La2CaHfO6:Mn4+ phosphors can be used as red-emitting candidate in pc-WLEDs lighting.

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Держатели документа:
China Univ Geosci, Fac Mat Sci & Chem, Minist Educ, Engn Res Ctr Nanogeomat, 388 Lumo Rd, Wuhan 430074, Hubei, Peoples R China.
FRC KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Xing, Gongcheng; Feng, Yuxin; Gao, Zhiyu; Tao, Mengxuan; Wang, Hongquan; Wei, Y.i.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Li, Guogang
}
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2.


   
    Agglomeration behavior of lipid-capped gold nanoparticles / R. Ranjan [et al.] // J. Nanopart. Res. - 2018. - Vol. 20, Is. 4. - Ст. 107, DOI 10.1007/s11051-018-4215-5. - Cited References:35. - The research was supported by the Russian Foundation for Basic Research [project no. 16-34-60100] and the state budget allocated to the fundamental research (project no. 0356-2017-0017). The authors thank Prof. Tatiana Volova, Prof. Evgenia Slyusareva, and Ms. Nina Slyusarenko of the Siberian Federal University for their assistance in the zeta potential and zeta-average analysis. . - ISSN 1388-0764. - ISSN 1572-896X
   Перевод заглавия: Характер агломирирования наночастиц золота, покрытых липидом
РУБ Chemistry, Multidisciplinary + Nanoscience & Nanotechnology + Materials
Рубрики:
COLORIMETRIC SENSOR ARRAY
   OPTICAL-PROPERTIES

   AGGREGATION

   CANCER

Кл.слова (ненормированные):
Gold nanoparticles -- Ionic interference -- Agglomeration -- Stabilization -- Lipid capping -- Nanobiotechnology applications
Аннотация: The current investigation deciphers aggregation pattern of gold nanoparticles (AuNPs) and lipid-treated AuNPs when subjected to aqueous sodium chloride solution with increasing ionic strengths (100–400 nM). AuNPs were synthesized using 0.29 mM chloroauric acid and by varying the concentrations of trisodium citrate (AuNP1 1.55 mM, AuNP2 3.1 mM) and silver nitrate (AuNP3 5.3 μM, AuNP4 10.6 μM) with characteristic LSPR peaks in the range of 525–533 nm. TEM analysis revealed AuNPs to be predominantly faceted nanocrystals with the average size of AuNP1 to be 35 ± 5 nm, AuNP2 15 ± 5 nm, AuNP3 30 ± 5 nm, and AuNP4 30 ± 5 nm and the zeta-average for AuNPs were calculated to be 31.23, 63.80, 26.08, and 28 nm respectively. Induced aggregation was observed within 10 s in all synthesized AuNPs while lipid-treated AuNP2 (AuNP2-L) was found to withstand ionic interferences at all concentration levels. However, lipid-treated AuNPs synthesized using silver nitrate and 1.55 mM trisodium citrate (AuNP3, AuNP4) showed much lower stability. The zeta potential values of lipid-treated AuNPs (AuNP1-L-1x/200, − 17.93 ± 1.02 mV; AuNP2-L-1x/200, − 21.63 ± 0.70; AuNP3-L-1x/200, − 14.54 ± 0.90; AuNP3-L-1x/200 − 13.77 ± 0.83) justified these observations. To summarize, AuNP1 and AuNP2 treated with lipid mixture 1 equals or above 1x/200 or 1x/1000 respectively showed strong resistance against ionic interferences (up to 400 mM NaCl). Use of lipid mixture 1 for obtaining highly stable AuNPs also provided functional arms of various lengths which can be used for covalent coupling.

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Держатели документа:
Siberian Fed Univ, Inst Fundamental Biol & Biotechnol, Dept Biophys, Lab Bioluminescent Biotechnol, 79 Svobodny Prospect, Krasnoyarsk 660041, Russia.
RAS, Krasnoyarsk Sci Ctr SB, Fed Res Ctr, Inst Biophys, Akademgorodok 50-50, Krasnoyarsk 660036, Russia.
RAS, Krasnoyarsk Sci Ctr SB, Fed Res Ctr, Kirensky Inst Phys, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Electron Microscopy Lab, 79 Svobodny Prospect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Ranjan, Rajeev; Kirillova, Maria A.; Esimbekova, Elena N.; Zharkov, S. M.; Жарков, Сергей Михайлович; Kratasyuk, Valentina A.; Russian Foundation for Basic Research [16-34-60100]; [0356-2017-0017]
}
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3.


   
    Atypical quantum confinement effect in silicon nanowires / P. B. Sorokin [et al.] // J. Phys. Chem. A. - 2008. - Vol. 112, Is. 40. - P9955-9964, DOI 10.1021/jp805069b. - Cited Reference Count: 25. - Гранты: This work was in part partially supported by a CREST (Core Research for Evolutional Science and Technology) grant in the Area of High Performance Computing for Multiscale and Multiphysics Phenomena from the Japan Science and Technology Agency (JST) as well as by Russian Fund of Basic Researches (grant 08-02-01096) (L.A.C.). P.V.A. acknowledges the encouragement of Dr. Keiji Morokuma, Research Leader at Fukui Institute for Fundamental Chemistry. The geometry of all presented structures was visualized by ChemCraft software.SUP25/SUP L.A.C. acknowledges I. V. Stankevich for help and fruitful discussions. P.B.S. is grateful to the Joint Supercomputer Center of the Russian Academy of Sciences for access to a cluster computer for quantum-chemical calculations. - Финансирующая организация: Japan Science and Technology Agency (JST); Russian Fund of Basic Researches [08-02-01096] . - OCT 9. - ISSN 1089-5639
Рубрики:
ELECTRONIC-STRUCTURE
   OPTICAL-PROPERTIES

   SI

   DENSITY

   WIRES

   EXCHANGE

   ATOMS

   DOTS

Кл.слова (ненормированные):
Electric wire -- Energy gap -- Gallium alloys -- Mathematical models -- Nanostructured materials -- Nanostructures -- Nanowires -- Quantum confinement -- Quantum electronics -- Semiconductor quantum dots -- Silicon -- Ami methods -- Band gaps -- Blue shifts -- Dinger equations -- Linear junctions -- Monotonic decreases -- Quantum confinement effects -- Quantum dots -- Semiempirical -- Silicon nanowires -- System sizes -- Theoretical models -- Nanocrystalline silicon -- nanowire -- quantum dot -- silicon -- article -- chemistry -- electron -- quantum theory -- Electrons -- Nanowires -- Quantum Dots -- Quantum Theory -- Silicon
Аннотация: The quantum confinement effect (QCE) of linear junctions of silicon icosahedral quantum dots (IQD) and pentagonal nanowires (PNW) was studied using DFT and semiempirical AM1 methods. The formation of complex IQD/PNW structures leads to the localization of the HOMO and LUMO on different parts of the system and to a pronounced blue shift of the band gap; the typical QCE with a monotonic decrease of the band gap upon the system size breaks down. A simple one-electron one-dimensional Schrodinger equation model is proposed for the description and explanation of the unconventional quantum confinement behavior of silicon IQD/PNW systems. On the basis of the theoretical models, the experimentally discovered deviations from the typical QCE for nanocrystalline silicon are explained.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
LV Kirenskii Inst Phys, SB RAS, Krasnoyarsk 660036, Russia
RAS, N M Emanuel Inst Biochem Phys, Moscow 119334, Russia
Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan
Natl Inst Adv Ind Sci & Technol, Res Inst Computat Sci, Tsukuba, Ibaraki 3058568, Japan

Доп.точки доступа:
Sorokin, P. B.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Avramov, P. V.; Chernozatonskii, L.A.; Fedorov, D.G.
}
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4.


    Aver'yanov, E. M.
    Anisotropy of the Local Field in Anisotropic Films of Conjugated Polymers / E. M. Aver'yanov // Phys. Solid State. - 2011. - Vol. 53, Is. 9. - P. 1933-1942, DOI 10.1134/S1063783411090046. - Cited References: 51 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
MOLECULAR-WEIGHT DEPENDENCE
   OPTICAL-PROPERTIES

   THIN-FILMS

   MEH-PPV

   POLY(P-PHENYLENE VINYLENE)

   CHAIN ORIENTATION

   REFRACTIVE-INDEX

   CONSTANTS

   POLYACETYLENE

   LIGHT

Аннотация: Using the data on dispersion of refractive indices in the visible region, the experimental values of the components L-j of the Lorentz tensor have been obtained for uniaxial (crystalline, oriented on a substrate, and stretched) films of conjugated polymers from nanometer to micrometer thicknesses. The dependence of the components L-j on the axial and planar orientations of macromolecules with respect to the optical axis of the film, technology of fabricating the films, and chemical structure of macromolecules has been elucidated. The correlation between the components L-j and the measured parameter. has been determined and the analytical dependence L-j(eta) for films with both types of macromolecular orientation has been established. In the visible region (0

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50-38, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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5.


    Aver'yanov, E. M.
    Orientational order and evolution of the properties of biomolecules in anisotropic media / E.M. Aver'yanov // JETP Letters. - 2012. - Vol. 95, Is. 1. - P. 51-54, DOI 10.1134/S002136401201002X. - Cited References: 18 . - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Рубрики:
OPTICAL-PROPERTIES
   FILMS

Аннотация: Experimental values of the Lorentz tensor components and the local field of a light wave have been obtained for anisotropic films of polypeptide and DNA. These data indicate an increase in the mean value and anisotropy of the polarizability of biomolecules with respect to an isotropic solution. These changes in the polarizability as an indicator of the response of biomolecules to external actions, as well as their chemical and biological activity, specify the direction of the evolution of the properties of biomolecules in orientationally ordered media.

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Публикация на русском языке Аверьянов, Евгений Михайлович. Ориентационный порядок и эволюция свойств биомолекул в анизотропных средах [Текст] / Е.М. Аверьянов // Письма в Журн. эксперим. и теор. физ. : Наука, 2012. - Т. 95 Вып. 1-2. - С. 55-58


Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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6.


    Belyaev, B. A.
    Resonances of electromagnetic oscillations in a spherical metal nanoparticle / B. A. Belyaev, V. V. Tyurnev // Microw. Opt. Technol. Lett. - 2016. - Vol. 58, Is. 8. - P. 1883-1886, DOI 10.1002/mop.29930. - Cited References:18 . - ISSN 0895-2477. - ISSN 1098-2760
   Перевод заглавия: Резонансы электромагнитных колебаний в сферической металлической наночастице
РУБ Engineering, Electrical & Electronic + Optics
Рубрики:
OPTICAL-PROPERTIES
   LIGHT

Кл.слова (ненормированные):
plasmonics -- scattering -- particles -- resonators -- resonant modes
Аннотация: Electrodynamic analysis of plasma oscillations in a spherical metal nanoparticle is performed. It is shown that typical reduction in the frequency and quality factor of the resonances with increasing nanoparticle radius fades if the mode number grows. Depending on the particle radius, the resonant enhancement of the electric field might considerably either increase or decrease with increasing mode number. (C) 2016 Wiley Periodicals, Inc.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk, Russia.
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk, Russia.

Доп.точки доступа:
Tyurnev, V. V.; Тюрнев, Владимир Вениаминович; Беляев, Борис Афанасьевич
}
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7.


   
    Density-functional theory study of the electronic structure of thin Si/SiO2 quantum nanodots and nanowires / P. V. Avramov [et al.] // Phys. Rev. B. - 2007. - Vol. 75, Is. 20. - Ст. 205427, DOI 10.1103/PhysRevB.75.205427. - Cited References: 63 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
ERBIUM ION LUMINESCENCE
   TOTAL-ENERGY CALCULATIONS

   WAVE BASIS-SET

   POROUS SILICON

   OPTICAL-PROPERTIES

   OXIDIZED SI

   SEMICONDUCTOR NANOWIRES

   PHASE-TRANSFORMATIONS

   NANOCRYSTALS

   CONFINEMENT

Аннотация: The atomic and electronic structures of a set of proposed pentagonal thin (1.6 nm in diameter) silicon/silica quantum nanodots (QDs) and nanowires (NWs) with narrow interface, as well as parent metastable silicon structures (1.2 nm in diameter), were studied using cluster B3LYP/6-31G(*) and periodic boundary condition (PBC) plane-wave (PW) pseudopotential (PP) local-density approximation methods. The total density of states (TDOS) of the smallest quasispherical QD (Si-85) corresponds well to the PBC PW PP LDA TDOS of the crystalline silicon. The elongated SiQDs and SiNWs demonstrate the metallic nature of the electronic structure. The surface oxidized layer opens the band gap in the TDOS of the Si/SiO2 species. The top of the valence band and the bottom of conduction band of the particles are formed by the silicon core derived states. The theoretical band gap width is determined by the length of the Si/SiO2 clusters and describes the size confinement effect in the experimental photoluminescence spectra of the silica embedded nanocrystalline silicon with high accuracy.

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Держатели документа:
Japan Atom Energy Agcy, Adv Sci Res Ctr, Takasaki Branch, Takasaki, Gumma 3701292, Japan
Russian Acad Sci, LV Kirensky Phys Inst, SB, Krasnoyarsk 660036, Russia
Russian Acad Sci, NM Emanuel Inst Biochem Phys, Moscow 119334, Russia
Kyoto Univ, Dept Energy Sci & Technol, Kyoto 6068501, Japan
ИФ СО РАН

Доп.точки доступа:
Avramov, P. V.; Аврамов, Павел Вениаминович; Kuzubov, A. A.; Кузубов, Александр Александрович; Fedorov, A. S.; Федоров, Александр Семенович; Sorokin, P. B.; Tomilin, F. N.; Томилин, Феликс Николаевич; Maeda, Y.
}
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8.


   
    Effect of local environment in resonant domains of polydisperse plasmonic nanoparticle aggregates on optodynamic processes in pulsed laser fields / A. E. Ershov [et al.] // Chin. Phys. B. - 2015. - Vol. 24, Is. 4. - Ст. 047804, DOI 10.1088/1674-1056/24/4/047804. - Cited References:25. - Project supported by the Russian Academy of Sciences (Grant Nos. 24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), and 3-9-5). . - ISSN 1674. - ISSN 1741-4199. -
РУБ Physics, Multidisciplinary
Рубрики:
METAL NANOPARTICLES
   GOLD NANOPARTICLES

   OPTICAL-PROPERTIES

Кл.слова (ненормированные):
nanoparticle -- surface plasmon -- colloid aggregate -- optodynamics
Аннотация: Interactions of pulsed laser radiation with resonance domains of multiparticle colloidal aggregates having an increasingly complex local environment are studied via an optodynamic model. The model is applied to the simplest configurations, such as single particles, dimers, and trimers consisting of mono- and polydisperse Ag nanoparticles. We analyze how the local environment and the associated local field enhancement by surrounding particles affect the optodynamic processes in domains, including their photomodification and optical properties.

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Держатели документа:
Russian Acad Sci, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Computat Modeling, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Siberian Fed Univ, Krasnoyarsk 660028, Russia

Доп.точки доступа:
Ershov, A. E.; Ершов, Александр Евгеньевич; Gavrilyuk, A. P.; Karpov, S. V.; Карпов, Сергей Васильевич; Semina, P. N.; Семина, Полина Николаевна; Russian Academy of Sciences [24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), 3-9-5]
}
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9.


   
    Effect of nickel on the magnetic state of dysprosium in Dy1-xNix-Ni bilayer films / I. S. Edelman [et al.] // Phys. Solid State. - 2003. - Vol. 45, Is. 8. - P. 1493-1499, DOI 10.1134/1.1602886. - Cited References: 21. - This work was supported by the Russian Foundation for Basic Research, project nos. 00-02-16098 and 02-02-06734 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
OPTICAL-PROPERTIES
   DY

   MULTILAYERS

Аннотация: This paper reports on the results of investigations into the temperature and spectral dependences of the magnetic circular dichroism in Dy1-xNix-Ni bilayer films prepared through thermal sputter deposition of components under ultrahigh vacuum. The distribution of the components over the layer thickness is examined by Auger spectroscopy. The nickel content x in Dy1-xNix layers varies from 0.005 to 0.06. It is shown that, in the temperature range 80-300 K, the contribution made to the magnetic circular dichroism by a Dy1-xNix layer in a bilayer film with a nickel content higher than the threshold value is approximately equal to the magnetic circular dichroism observed in an isolated Dy1-xNix film at temperatures below the temperature of the phase transition to a ferromagnetic state (similar to100 K). This phenomenon is explained by magnetic ordering in theDy(1-x)Ni(x) layer of the bilayer film due to the combined effect of two factors, namely, the incorporation of nickel into a dysprosium layer and the presence of a continuous nickel sublayer in the film. (C) 2003 MAIK "Nauka/Interperiodica".

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Публикация на русском языке Влияние Ni на магнитное состояние Dy в двухслойных пленках Dy[1-x]Ni[x]-Ni [Текст] / И. С. Эдельман [и др.] // Физ. тверд. тела. - 2003. - Т. 45 Вып. 8. - С. 1423-1428

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Semicond Phys, Siberian Div, Novosibirsk 630090, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 13, Novosibirsk 630090, Russian Federation

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Markov, V. V.; Марков, Владимир Витальевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Khudyakov, A. E.; Zabluda, V. N.; Заблуда, Владимир Николаевич; Kesler, V. G.; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич
}
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10.


   
    Effects of size polydispersity on the extinction spectra of colloidal nanoparticle aggregates / A. E. Ershov [et al.] // Phys. Rev. B. - 2012. - Vol. 85, Is. 4. - Ст. 045421. - P. , DOI 10.1103/PhysRevB.85.045421. - Cited References: 41. - This work was supported by grants from the following foundations of the Russian Federation: Presidium of RAS, OFN RAS, and SB RAS. . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
METAL FRACTAL CLUSTERS
   OPTICAL-PROPERTIES

   ABSORPTION

   NONLINEARITIES

   COMPOSITES

   SCATTERING

   PARTICLES

   SPHERES

   GRAINS

Аннотация: We investigate the effect of particle polydispersity on the optical extinction spectra of colloidal aggregates of spherical metallic (silver) nanoparticles, taking into account the realistic interparticle gaps caused by layers of stabilizing polymer adsorbed on the metal surface (adlayers). The spectra of computer-generated aggregates are computed using two different methods. The coupled-multipole method is used in the quasistatic approximation and the coupled-dipole method beyond the quasistatics. The latter approach is applicable if the interparticle gaps are sufficiently wide relative to the particle radii. Simulations are performed for two different particle size distribution functions (bimodal and Gaussian), varying the number of particles per aggregate, and different distribution functions of the interparticle gap width. The strong influence of the latter factor on the spectra is demonstrated and investigated in detail.

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Держатели документа:
[Ershov, Alexander E.
Isaev, Ivan L.
Semina, Polina N.
Karpov, Sergei V.] Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ershov, Alexander E.
Karpov, Sergei V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Markel, Vadim A.] Univ Penn, Dept Bioengn, Dept Radiol, Philadelphia, PA 19104 USA
[Markel, Vadim A.] Univ Penn, Grad Grp Appl Math & Computat Sci, Philadelphia, PA 19104 USA

Доп.точки доступа:
Ershov, A. E.; Ершов, Александр Евгеньевич; Isaev, I. L.; Исаев, Иван Леонидович; Semina, P. N.; Семина, Полина Николаевна; Markel, V. A.; Karpov, S. V.; Карпов, Сергей Васильевич
}
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